PL14747B1 - A method of securing wool, fur, bristles and moth-like materials. - Google Patents
A method of securing wool, fur, bristles and moth-like materials. Download PDFInfo
- Publication number
- PL14747B1 PL14747B1 PL14747A PL1474729A PL14747B1 PL 14747 B1 PL14747 B1 PL 14747B1 PL 14747 A PL14747 A PL 14747A PL 1474729 A PL1474729 A PL 1474729A PL 14747 B1 PL14747 B1 PL 14747B1
- Authority
- PL
- Poland
- Prior art keywords
- materials
- fur
- moth
- wool
- bristles
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims description 6
- 210000002268 wool Anatomy 0.000 title claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 150000003585 thioureas Chemical class 0.000 claims description 2
- 210000004209 hair Anatomy 0.000 claims 1
- -1 cyidohexia Chemical group 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- QAOJBHRZQQDFHA-UHFFFAOYSA-N 2,3-dichlorobenzoic acid Chemical compound OC(=O)C1=CC=CC(Cl)=C1Cl QAOJBHRZQQDFHA-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
Description
Stwierdzono, ze tiomoczniki o wzorze: -< NH.R S = C NH . /?! kwasu octowego, walerjanowego, steary¬ nowego, olej owego, benzoesowego lub ich produktów podstawienia, jak reszte kwasu dwuchlorobenzoesowego, fenylooctowego, parachlorofenoksyoctowego w którym R oznacza reszte alkylowa, cy- kloalkylowa, aralkylowa lub arylowa i Rt — reszte kwasowa, sa doskonalemi srodkami, zabezpieczaj acemi trwale welne, futra, skórki i materjaly podobne przeciw¬ ko pozeraniu ich przez mole i inne szkod¬ niki zwierzece.Jako podstawniki R mozna tu stosowac reszty alkylowe wzglednie arylowe, np. allyl, cyidoheksyj, benzyl, fenyl, tolyl, me- toksyfenyl, chDbrotolyl, trójchlorofenyl i t. d, jako reiszty kwasowe Rx — reszte Cl -/ \-0-CH2-COOH9 heksahydrobenzoesowego i wielu innych.Otrzymane wedlug wynalazku (srodki ochronne stosuje sie w ten sposób, iz podle¬ gajace zabezpieczeniu materjaly pokrywa sie niemi w postaci roztworu w ilosci do¬ statecznej.Przyklad I. Materjal traktuje sie roz¬ tworem fenylowalerylo-tiomocznika o wzo¬ rzeyNH — fenyl s—c/ ^Mf-waleryl w ten sposób, iz na materjale pozostaje po wysuszeniu 1 — 2% substancji, poczem towar jest trwale zabezpieczony od moli.Zamiast zwiazku walerylowego do za¬ bezpieczania materjalów od moli mozna stosowac z takim samym skutkiem pochod¬ ne oleyiowe, benzoylowe, dwuchlorobenzo- ylowe i im podobne. PLIt was found that the thioureas of the formula: - <NH.R S = C NH. / ?! acetic acid, valeric acid, stearic acid, oil, benzoic acid or their substitution products, such as dichlorobenzoic acid, phenylacetic acid, parachlorophenoxyacetic acid residues in which R is an alkyl, cycloalkyl, aralkyl or aryl residue, and Rt - an acid residue, are perfect They protect permanently wool, fur, skins and similar materials against moth eating and other animal pests. As R substituents, it is possible to use alkyl or aryl residues, e.g. allyl, cyidohexia, benzyl, phenyl, tolyl, methyl toxyphenyl, chDbrotolyl, trichlorophenyl etc. as acidic residues Rx - Hexahydrobenzoic Cl - / -O-CH2-COOH9 residues and many others. Obtained according to the invention (protective measures are used in such a way that the materials to be secured are covered They are mixed in the form of a solution in a sufficient amount. If 1 - 2% of the substance remains on the material after drying, then the goods are permanently protected from moles. Instead of a valeryl compound to protect materials from moles, oleyl, benzoyl, dichlorobenzoyl and other derivatives can be used with the same effect. similar. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL14747B1 true PL14747B1 (en) | 1931-11-30 |
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