AR106872A1 - PIRIDINE COMPOUNDS AS FUNGICIDES - Google Patents
PIRIDINE COMPOUNDS AS FUNGICIDESInfo
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- AR106872A1 AR106872A1 ARP160103661A ARP160103661A AR106872A1 AR 106872 A1 AR106872 A1 AR 106872A1 AR P160103661 A ARP160103661 A AR P160103661A AR P160103661 A ARP160103661 A AR P160103661A AR 106872 A1 AR106872 A1 AR 106872A1
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- alkyl
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- heteroaryl
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- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/70—Sulfur atoms
- C07D213/71—Sulfur atoms to which a second hetero atom is attached
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/26—Radicals substituted by halogen atoms or nitro radicals
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- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/61—Halogen atoms or nitro radicals
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/70—Sulfur atoms
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- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/81—Amides; Imides
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- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
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- Chemical & Material Sciences (AREA)
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Abstract
La presente solicitud se refiere a compuestos de piridina como antifúngicos, a procesos e intermediarios y composiciones de los mismos. Reivindicación 1: Compuestos de la fórmula (1), en donde R¹ se selecciona de halógeno, CN, NO₂, SH, NH₂, NH(C₁₋₄-alquilo), N(C₁₋₄-alquilo)₂, NH-SO₂-R¹¹, C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₁₋₆-alcoxi, C(=O)-(R¹²), C₃₋₆-cicloalquilo, heteroarilo y arilo de 5 ó 6 miembros; en donde el heteroarilo contiene 1, 2 ó 3 heteroátomos seleccionados de N, O y S; en donde R¹¹ se selecciona de C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, arilo o heteroarilo que es no sustituido o sustituido con 1, 2, 3, 4 ó 5 sustituyentes R¹¹¹ seleccionados independientemente de C₁₋₄-alquilo; y R¹² se selecciona independientemente de H, C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₃₋₈-cicloalquilo, O-R¹²¹, N(R¹²²)(R¹²³); R¹²¹ se selecciona independientemente de H, C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₃₋₈-cicloalquilo; R¹²², R¹²³ se seleccionan independientemente de H, C₁₋₆-alquilo, C₁₋₆-alquenilo, C₁₋₆-alquinilo y C₃₋₈-cicloalquilo; en donde las porciones alifáticas de R¹ son no sustituidas o sustituidas con grupos R¹ᵃ idénticos o diferentes que se seleccionan, independientemente entre sí, de: R¹ᵃ halógeno, OH, CN, C₁₋₆-alcoxi, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi, C₁₋₆-alquiltio, fenilo y fenoxi, en donde los grupos fenilo y fenoxi son no sustituidos o tienen 1, 2, 3, 4 ó 5 sustituyentes R¹¹ᵃ seleccionados del grupo que consiste en halógeno, OH, C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, C₁₋₄-alcoxi y C₁₋₄-halógenoalcoxi; y en donde las porciones cicloalquilo, heteroarilo y arilo de R¹ son no sustituidas o sustituidas con 1, 2, 3, 4, 5 o hasta la máxima cantidad de grupos R¹ᵇ idénticos o diferentes que se seleccionan, independientemente entre sí, de: R¹ᵇ halógeno, OH, CN, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₁₋₄-halógenoalquilo, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi y C₁₋₆-alquiltio; R² se selecciona de halógeno, CN, NO₂, SH, NH₂, NH(C₁₋₄-alquilo), N(C₁₋₄-alquilo)₂, NH-SO₂-R²¹, C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₁₋₆-alcoxi, C(=O)-(R²²), C₃₋₆-cicloalquilo, heteroarilo y arilo de 5 ó 6 miembros; en donde el heteroarilo contiene 1, 2 ó 3 heteroátomos seleccionados de N, O y S; en donde R²¹ se selecciona de C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, arilo o heteroarilo que es no sustituido o sustituido con 1, 2, 3, 4 ó 5 sustituyentes R²¹¹ seleccionados independientemente de C₁₋₄-alquilo; y R²² se selecciona independientemente de H, C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₃₋₈-cicloalquilo, O-R²²¹, N(R²²²)(R²²³); R²²¹ se selecciona independientemente de H, C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₃₋₈-cicloalquilo; R²²², R²²³ se seleccionan independientemente de H, C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₃₋₈-cicloalquilo; en donde las porciones alifáticas de R² son no sustituidas o sustituidas con grupos R²ᵃ idénticos o diferentes que se seleccionan, independientemente entre sí, de: R²ᵃ halógeno, OH, CN, C₁₋₆-alcoxi, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi, C₁₋₆-alquiltio, fenilo y fenoxi, en donde los grupos fenilo y fenoxi son no sustituidos o tienen 1, 2, 3, 4 ó 5 sustituyentes R²¹ᵃ seleccionados del grupo que consiste en halógeno, OH, C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, C₁₋₄-alcoxi y C₁₋₄-halógenoalcoxi; y en donde las porciones cicloalquilo, heteroarilo y arilo de R² son no sustituidas o sustituidas con 1, 2, 3, 4, 5 o hasta la máxima cantidad de grupos R²ᵇ idénticos o diferentes que se seleccionan, independientemente entre sí, de: R²ᵇ halógeno, OH, CN, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₁₋₄-halógenoalquilo, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi y C₁₋₆-alquiltio; R³ se selecciona de H, halógeno, OH, CN, NO₂, SH, NH₂, NH(C₁₋₄-alquilo), N(C₁₋₄-alquilo)₂, NH-SO₂-R³¹, C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₁₋₆-alcoxi, C₃₋₆-cicloalquilo, heteroarilo y arilo de 5 ó 6 miembros; en donde el heteroarilo contiene 1, 2 ó 3 heteroátomos seleccionados de N, O y S; en donde R³¹ se selecciona de C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, arilo o heteroarilo que es no sustituido o sustituido con 1, 2, 3, 4 ó 5 sustituyentes R³¹¹ seleccionados independientemente de C₁₋₄-alquilo; y en donde las porciones alifáticas de R³ son no sustituidas o sustituidas con grupos R³ᵃ idénticos o diferentes que se seleccionan, independientemente entre sí, de: R³ᵃ halógeno, OH, CN, C₁₋₆-alcoxi, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi, C₁₋₆-alquiltio, fenilo y fenoxi, en donde los grupos fenilo y fenoxi son no sustituidos o tienen 1, 2, 3, 4 ó 5 sustituyentes R³¹ᵃ seleccionados del grupo que consiste en halógeno, OH, C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, C₁₋₄-alcoxi y C₁₋₄-halógenoalcoxi; y en donde las porciones cicloalquilo, heteroarilo y arilo de R³ son no sustituidas o sustituidas con 1, 2, 3, 4, 5 o hasta la máxima cantidad de grupos R³ᵇ idénticos o diferentes que se seleccionan, independientemente entre sí, de: R³ᵇ halógeno, OH, CN, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₁₋₄-halógenoalquilo, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi y C₁₋₆-alquiltio; R⁴ se selecciona de H, halógeno, OH, CN, NO₂, SH, NH₂, NH(C₁₋₄-alquilo), N(C₁₋₄-alquilo)₂, NH-SO₂-R⁴¹, C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₁₋₆-alcoxi, C₃₋₆-cicloalquilo, heteroarilo y arilo de 5 ó 6 miembros; en donde el heteroarilo contiene 1, 2 ó 3 heteroátomos seleccionados de N, O y S; en donde R⁴¹ se selecciona de C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, arilo o heteroarilo que es no sustituido o sustituido con 1, 2, 3, 4 ó 5 sustituyentes R⁴¹¹ seleccionados independientemente de C₁₋₄-alquilo; y en donde las porciones alifáticas de R⁴ son no sustituidas o sustituidas con grupos R⁴ᵃ idénticos o diferentes que se seleccionan, independientemente entre sí, de: R⁴ᵃ halógeno, OH, CN, C₁₋₆-alcoxi, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi, C₁₋₆-alquiltio, fenilo y fenoxi, en donde los grupos fenilo y fenoxi son no sustituidos o tienen 1, 2, 3, 4 ó 5 sustituyentes R⁴¹ᵃ seleccionados del grupo que consiste en halógeno, OH, C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, C₁₋₄-alcoxi y C₁₋₄-halógenoalcoxi; y en donde las porciones cicloalquilo, heteroarilo y arilo de R⁴ son no sustituidas o sustituidas con 1, 2, 3, 4, 5 o hasta la máxima cantidad de grupos R⁴ᵇ idénticos o diferentes que se seleccionan, independientemente entre sí, de: R⁴ᵇ halógeno, OH, CN, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₁₋₄-halógenoalquilo, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi y C₁₋₆-alquiltio; Y es O ó S(O)ₙ en donde n es 0, 1 ó 2; Q¹ se selecciona de C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₃₋₆-cicloalquilo, heteroarilo y arilo de 5 ó 6 miembros; en donde el heteroarilo contiene 1, 2 ó 3 heteroátomos seleccionados de N, O y S; en donde las porciones alifáticas de Q¹ son no sustituidas o sustituidas con grupos Q¹ᵃ idénticos o diferentes que se seleccionan, independientemente entre sí, de: Q¹ᵃ halógeno, OH, CN, C₁₋₆-alcoxi, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi, C₁₋₆-alquiltio, fenilo y fenoxi, en donde los grupos fenilo y fenoxi son no sustituidos o tienen 1, 2, 3, 4 ó 5 sustituyentes Q¹¹ᵃ seleccionados del grupo que consiste en halógeno, OH, C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, C₁₋₄-alcoxi y C₁₋₄-halógenoalcoxi; en donde las porciones cicloalquilo, heteroarilo y arilo de Q¹ son no sustituidas o sustituidas con 1, 2, 3, 4, 5 o hasta la máxima cantidad de grupos Q¹ᵇ idénticos o diferentes que se seleccionan, independientemente entre sí, de: Q¹ᵇ halógeno, OH, CN, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₁₋₄-halógenoalquilo, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi y C₁₋₆-alquiltio; Q² se selecciona de H, C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₃₋₆-cicloalquilo, heteroarilo y arilo de 5 ó 6 miembros; en donde el heteroarilo contiene 1, 2 ó 3 heteroátomos seleccionados de N, O y S; en donde las porciones alifáticas de Q² son no sustituidas o sustituidas con grupos Q²ᵃ idénticos o diferentes que se seleccionan, independientemente entre sí, de: Q²ᵃ halógeno, OH, CN, C₁₋₆-alcoxi, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi, C₁₋₆-alquiltio, fenilo y fenoxi, en donde los grupos fenilo y fenoxi son no sustituidos o sustituidos con 1, 2, 3, 4 ó 5 sustituyentes Q¹² seleccionados del grupo que consiste en halógeno, OH, C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, C₁₋₄-alcoxi y C₁₋₄-halógenoalcoxi; en donde las porciones cicloalquilo, heteroarilo y arilo de Q² son no sustituidas o sustituidas con 1, 2, 3, 4, 5 o hasta la máxima cantidad de grupos Q²ᵇ idénticos o diferentes que se seleccionan, independientemente entre sí, de: Q²ᵇ halógeno, OH, CN, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₁₋₄-halógenoalquilo, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi y C₁₋₆-alquiltio; Q¹ y Q², junto con el átomo de carbono al que están unidos, forman un carbo- o heterociclo saturado o parcialmente insaturado de 3 a 7 miembros en donde el anillo también puede contener 1, 2, 3 ó 4 heteroátomos seleccionados de N-RN, O y S, en donde RN se selecciona de H, C₁₋₄-alquilo y SO₂RQ; en donde RQ se selecciona de C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, arilo no sustituido o heteroarilo sustituido con 1, 2, 3, 4 ó 5 sustituyentes RQ¹ seleccionados independientemente de C₁₋₄-alquilo; y en donde S puede ser en forma de su óxido SO o SO₂; y en donde, en cada caso, 1 ó 2 grupos CH₂ del carbo- o heterociclo se pueden reemplazar por un grupo seleccionado independientemente de C(=O) y C(=S); y en donde el anillo es no sustituido o sustituido con 1, 2, 3, 4, 5 o hasta la máxima cantidad de grupos RQR idénticos o diferentes, que se seleccionan independientemente entre sí de: QQR halógeno, OH, CN, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₁₋₄-halógenoalquilo, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi y C₁₋₆-alquiltio; Q³ se selecciona de H, C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₃₋₆-cicloalquilo, heteroarilo y arilo de 5 ó 6 miembros; en donde el heteroarilo contiene 1, 2 ó 3 heteroátomos seleccionados de N, O y S; en donde las porciones alifáticas de Q³ son no sustituidas o sustituidas con grupos Q³ᵃ idénticos o diferentes que se seleccionan, independientemente entre sí, de: Q³ᵃ halógeno, OH, CN, C₁₋₆-alcoxi, C₃₋₆-cicloalquilo, C₃₋₆-cicloalquiloxi, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi, C₁₋₆-alquiltio, fenilo, fenoxi y heterociclo, heteroarilo, heterocicloxi, heteriloxi de 5 a 10 miembros; en donde el heterociclo o heteroarilo contiene 1, 2 ó 3 heteroátomos seleccionados de N, O y S; en donde los grupos cicloalquilo, cicloalquiloxi, fenilo, fenoxi, heterociclo y heteroarilo son no sustituidos o sustituidos con 1, 2, 3, 4 ó 5 sustituyentes Q¹³ᵃ seleccionados del grupo que consiste en halógeno, OH, C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, C₁₋₄-alcoxi, C₁₋₄-halógenoalcoxi, CR=NOR; C₃₋₆-cicloalquilo, C₃₋₆-cicloalquiloxi, fenilo, fenoxi y heterociclo, heterocicloxi, heteroarilo y heteroariloxi de 5 a 10 miembros; en donde el heterociclo, heterocicloxi, heteroarilo o heteroariloxi contiene 1, 2 ó 3 heteroátomos seleccionados de N, O y S; y en donde los grupos fenilo, fenoxi, heterociclo, cicloalquilo y heteroarilo son no sustituidos o sustituidos con 1, 2, 3, 4 ó 5 sustituyentes Q¹¹³ᵃ seleccionados del grupo que consiste en halógeno, OH, C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, C₁₋₄-alcoxi, CN, CR=NOR y C₁₋₄-halógenoalcoxi; en donde las porciones cicloalquilo, heteroarilo y arilo de Q³ son no sustituidas o sustituidas con 1, 2, 3, 4, 5 o hasta la máxima cantidad de grupos Q³ᵇ idénticos o diferentes que se seleccionan, independientemente entre sí, de: Q³ᵇ halógeno, OH, CN, C₁₋₆-alcoxi, C₃₋₆-cicloalquilo, C₃₋₆-cicloalquiloxi, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi, C₁₋₆-alquiltio, fenilo, fenoxi y heterociclo, heteroarilo, heterocicloxi, heteriloxi de 5 a 10 miembros; en donde el heterociclo o heteroarilo contiene 1, 2 ó 3 heteroátomos seleccionados de N, O y S; en donde los grupos fenilo, fenoxi, heterociclo, cicloalquilo y heteroarilo son no sustituidos o sustituidos con 1, 2, 3, 4 ó 5 sustituyentes Q¹³ᵇ seleccionados del grupo que consiste en halógeno, OH, C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, C₁₋₄-alcoxi, C₁₋₄-halógenoalcoxi, CR=NOR; C₃₋₆-cicloalquilo, C₃₋₆-cicloalquiloxi, fenilo, fenoxi y heterociclo, heterocicloxi, heteroarilo y heteroariloxi de 5 a 10 miembros; en donde el heterociclo, heterocicloxi o heteroarilo, heteroariloxi contienen 1, 2 ó 3 heteroátomos seleccionados de N, O y S; y en donde los grupos fenilo, fenoxi, heterociclo, cicloalquilo y heteroarilo son no sustituidos o sustituidos con 1, 2, 3, 4 ó 5 sustituyentes Q¹¹³ᵇ seleccionados del grupo que consiste en halógeno, OH, C₁₋₄-alquilo, C₁₋₄-halógenoalquilo, C₁₋₄-alcoxi, CN, CR=NOR y C₁₋₄-halógenoalcoxi; y en donde R y R son independientemente no sustituidos o sustituidos con R que se selecciona independientemente de halógeno, OH, CN, NO₂, SH, NH₂, NH(C₁₋₄-alquilo), N(C₁₋₄-alquilo)₂, C₁₋₆-alquilo, C₁₋₆-halógenoalquilo, C₂₋₆-alquenilo, C₂₋₆-halógenoalquenilo, C₂₋₆-alquinilo, C₂₋₆-halógenoalquinilo, C₁₋₆-alcoxi, C₁₋₆-halógenoalcoxi, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo y fenilo; W es O ó S; X se selecciona de H, halógeno, OH, CN, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₁₋₄-halógenoalquilo, C₃₋₆-cicloalquilo, C₃₋₆-halógenocicloalquilo, C₁₋₄-halógenoalcoxi y C₁₋₆-alquiltio; en donde n es 0, 1, 2, 3 ó 4; siempre que si R¹ es CH₃, R² no sea CH₃; y si R² es CH₃, R¹ no sea CH₃; y los N-óxidos y las sales de estos aceptables en la agricultura.The present application relates to pyridine compounds as antifungals, processes and intermediates and compositions thereof. Claim 1: Compounds of formula (1), wherein R¹ is selected from halogen, CN, NO₂, SH, NH₂, NH(C₁₋₄-alkyl), N(C₁₋₄-alkyl)₂, NH-SO₂- R¹¹, C₁₋₆-alkyl, C₂₋₆-alkenyl, C₂₋₆-alkynyl, C₁₋₆-alkoxy, C(=O)-(R¹²), C₃₋₆-cycloalkyl, heteroaryl and 5- or 6-membered aryl ; wherein heteroaryl contains 1, 2 or 3 heteroatoms selected from N, O and S; wherein R¹¹ is selected from C₁₋₄-alkyl, C₁₋₄-halogenoalkyl, aryl or heteroaryl which is unsubstituted or substituted with 1, 2, 3, 4 or 5 R¹¹¹ substituents independently selected from C₁₋₄-alkyl; and R¹² is independently selected from H, C₁₋₆-alkyl, C₂₋₆-alkenyl, C₂₋₆-alkynyl, C₃₋₈-cycloalkyl, O-R¹²¹, N(R¹²²)(R¹²³); R¹²¹ is independently selected from H, C₁₋₆-alkyl, C₂₋₆-alkenyl, C₂₋₆-alkynyl, C₃₋₈-cycloalkyl; R¹²², R¹²³ are independently selected from H, C₁₋₆-alkyl, C₁₋₆-alkenyl, C₁₋₆-alkynyl, and C₃₋₈-cycloalkyl; wherein the aliphatic portions of R¹ are unsubstituted or substituted with identical or different R¹ᵃ groups which are independently selected from: R¹ᵃ halogen, OH, CN, C₁₋₆-alkoxy, C₃₋₆-cycloalkyl, C₃₋₆ -halogenocycloalkyl, C₁₋₄-halogenoalkoxy, C₁₋₆-alkylthio, phenyl and phenoxy, wherein the phenyl and phenoxy groups are unsubstituted or have 1, 2, 3, 4 or 5 substituents R¹¹ᵃ selected from the group consisting of halogen, OH, C₁₋₄-alkyl, C₁₋₄-haloalkyl, C₁₋₄-alkoxy and C₁₋₄-haloalkoxy; and wherein the cycloalkyl, heteroaryl and aryl portions of R¹ are unsubstituted or substituted with 1, 2, 3, 4, 5 or up to the maximum number of identical or different R¹ᵇ groups that are independently selected from: R¹ᵇ halogen , OH, CN, C₁₋₄-alkyl, C₁₋₄-alkoxy, C₁₋₄-haloalkyl, C₃₋₆-cycloalkyl, C₃₋₆-halocycloalkyl, C₁₋₄-haloalkoxy, and C₁₋₆-alkylthio; R² is selected from halogen, CN, NO₂, SH, NH₂, NH(C₁₋₄-alkyl), N(C₁₋₄-alkyl)₂, NH-SO₂-R²¹, C₁₋₆-alkyl, C₂₋₆-alkenyl , C₂₋₆-alkynyl, C₁₋₆-alkoxy, C(=O)-(R²²), C₃₋₆-cycloalkyl, heteroaryl and 5- or 6-membered aryl; wherein heteroaryl contains 1, 2 or 3 heteroatoms selected from N, O and S; wherein R²¹ is selected from C₁₋₄-alkyl, C₁₋₄-haloalkyl, aryl or heteroaryl which is unsubstituted or substituted with 1, 2, 3, 4 or 5 R²¹¹ substituents independently selected from C₁₋₄-alkyl; and R²² is independently selected from H, C₁₋₆-alkyl, C₂₋₆-alkenyl, C₂₋₆-alkynyl, C₃₋₈-cycloalkyl, O-R²²¹, N(R²²²)(R²²³); R²²¹ is independently selected from H, C₁₋₆-alkyl, C₂₋₆-alkenyl, C₂₋₆-alkynyl, C₃₋₈-cycloalkyl; R²²², R²²³ are independently selected from H, C₁₋₆-alkyl, C₂₋₆-alkenyl, C₂₋₆-alkynyl, C₃₋₈-cycloalkyl; wherein the aliphatic portions of R² are unsubstituted or substituted with identical or different R²ᵃ groups which are independently selected from: R²ᵃ halogen, OH, CN, C₁₋₆-alkoxy, C₃₋₆-cycloalkyl, C₃₋₆ -halogenocycloalkyl, C₁₋₄-halogenoalkoxy, C₁₋₆-alkylthio, phenyl and phenoxy, wherein the phenyl and phenoxy groups are unsubstituted or have 1, 2, 3, 4 or 5 R²¹ᵃ substituents selected from the group consisting of halogen, OH, C₁₋₄-alkyl, C₁₋₄-haloalkyl, C₁₋₄-alkoxy and C₁₋₄-haloalkoxy; and wherein the cycloalkyl, heteroaryl and aryl portions of R² are unsubstituted or substituted with 1, 2, 3, 4, 5 or up to the maximum number of identical or different R²ᵇ groups that are independently selected from: R²ᵇ halogen , OH, CN, C₁₋₄-alkyl, C₁₋₄-alkoxy, C₁₋₄-haloalkyl, C₃₋₆-cycloalkyl, C₃₋₆-halocycloalkyl, C₁₋₄-haloalkoxy, and C₁₋₆-alkylthio; R³ is selected from H, halogen, OH, CN, NO₂, SH, NH₂, NH(C₁₋₄-alkyl), N(C₁₋₄-alkyl)₂, NH-SO₂-R³¹, C₁₋₆-alkyl, C₂ ₋₆-alkenyl, C₂₋₆-alkynyl, C₁₋₆-alkoxy, C₃₋₆-cycloalkyl, heteroaryl and 5- or 6-membered aryl; wherein heteroaryl contains 1, 2 or 3 heteroatoms selected from N, O and S; wherein R³¹ is selected from C₁₋₄-alkyl, C₁₋₄-haloalkyl, aryl or heteroaryl which is unsubstituted or substituted with 1, 2, 3, 4 or 5 R³¹¹ substituents independently selected from C₁₋₄-alkyl; and wherein the aliphatic portions of R³ are unsubstituted or substituted with identical or different R³ᵃ groups which are independently selected from: R³ᵃ halogen, OH, CN, C₁₋₆-alkoxy, C₃₋₆-cycloalkyl, C₃₋ ₆-halogenocycloalkyl, C₁₋₄-halogenoalkoxy, C₁₋₆-alkylthio, phenyl and phenoxy, wherein the phenyl and phenoxy groups are unsubstituted or have 1, 2, 3, 4 or 5 R³¹ᵃ substituents selected from the group consisting of halogen , OH, C₁₋₄-alkyl, C₁₋₄-haloalkyl, C₁₋₄-alkoxy and C₁₋₄-haloalkoxy; and wherein the cycloalkyl, heteroaryl and aryl portions of R³ are unsubstituted or substituted with 1, 2, 3, 4, 5 or up to the maximum number of identical or different R³ᵇ groups that are independently selected from: R³ᵇ halogen , OH, CN, C₁₋₄-alkyl, C₁₋₄-alkoxy, C₁₋₄-haloalkyl, C₃₋₆-cycloalkyl, C₃₋₆-halocycloalkyl, C₁₋₄-haloalkoxy, and C₁₋₆-alkylthio; R⁴ is selected from H, halogen, OH, CN, NO₂, SH, NH₂, NH(C₁₋₄-alkyl), N(C₁₋₄-alkyl)₂, NH-SO₂-R⁴¹, C₁₋₆-alkyl, C₂ ₋₆-alkenyl, C₂₋₆-alkynyl, C₁₋₆-alkoxy, C₃₋₆-cycloalkyl, heteroaryl and 5- or 6-membered aryl; wherein heteroaryl contains 1, 2 or 3 heteroatoms selected from N, O and S; wherein R⁴¹ is selected from C₁₋₄-alkyl, C₁₋₄-halogenoalkyl, aryl or heteroaryl which is unsubstituted or substituted with 1, 2, 3, 4 or 5 R⁴¹¹ substituents independently selected from C₁₋₄-alkyl; and wherein the aliphatic portions of R⁴ are unsubstituted or substituted with identical or different R⁴ᵃ groups which are independently selected from: R⁴ᵃ halogen, OH, CN, C₁₋₆-alkoxy, C₃₋₆-cycloalkyl, C₃₋ ₆-halogenocycloalkyl, C₁₋₄-halogenoalkoxy, C₁₋₆-alkylthio, phenyl and phenoxy, wherein the phenyl and phenoxy groups are unsubstituted or have 1, 2, 3, 4 or 5 substituents R⁴¹ᵃ selected from the group consisting of halogen , OH, C₁₋₄-alkyl, C₁₋₄-haloalkyl, C₁₋₄-alkoxy and C₁₋₄-haloalkoxy; and wherein the cycloalkyl, heteroaryl and aryl portions of R⁴ are unsubstituted or substituted with 1, 2, 3, 4, 5 or up to the maximum number of identical or different R⁴ᵇ groups that are independently selected from: R⁴ᵇ halogen , OH, CN, C₁₋₄-alkyl, C₁₋₄-alkoxy, C₁₋₄-haloalkyl, C₃₋₆-cycloalkyl, C₃₋₆-halocycloalkyl, C₁₋₄-haloalkoxy, and C₁₋₆-alkylthio; Y is O or S(O)ₙ where n is 0, 1 or 2; Q¹ is selected from C₁₋₆-alkyl, C₂₋₆-alkenyl, C₂₋₆-alkynyl, C₃₋₆-cycloalkyl, heteroaryl, and 5- or 6-membered aryl; wherein heteroaryl contains 1, 2 or 3 heteroatoms selected from N, O and S; wherein the aliphatic portions of Q¹ are unsubstituted or substituted with identical or different Q¹ᵃ groups which are independently selected from: Q¹ᵃ halogen, OH, CN, C₁₋₆-alkoxy, C₃₋₆-cycloalkyl, C₃₋₆ -halogenocycloalkyl, C₁₋₄-halogenoalkoxy, C₁₋₆-alkylthio, phenyl and phenoxy, wherein the phenyl and phenoxy groups are unsubstituted or have 1, 2, 3, 4 or 5 substituents Q¹¹ᵃ selected from the group consisting of halogen, OH, C₁₋₄-alkyl, C₁₋₄-haloalkyl, C₁₋₄-alkoxy and C₁₋₄-haloalkoxy; wherein the cycloalkyl, heteroaryl and aryl portions of Q¹ are unsubstituted or substituted with 1, 2, 3, 4, 5 or up to the maximum number of identical or different Q¹ᵇ groups that are independently selected from: Q¹ᵇ halogen, OH, CN, C₁₋₄-alkyl, C₁₋₄-alkoxy, C₁₋₄-haloalkyl, C₃₋₆-cycloalkyl, C₃₋₆-halocycloalkyl, C₁₋₄-haloalkoxy, and C₁₋₆-alkylthio; Q² is selected from H, C₁₋₆-alkyl, C₂₋₆-alkenyl, C₂₋₆-alkynyl, C₃₋₆-cycloalkyl, heteroaryl, and 5- or 6-membered aryl; wherein heteroaryl contains 1, 2 or 3 heteroatoms selected from N, O and S; wherein the aliphatic portions of Q² are unsubstituted or substituted with identical or different Q²ᵃ groups which are independently selected from: Q²ᵃ halogen, OH, CN, C₁₋₆-alkoxy, C₃₋₆-cycloalkyl, C₃₋₆ -halogenocycloalkyl, C₁₋₄-halogenoalkoxy, C₁₋₆-alkylthio, phenyl and phenoxy, wherein the phenyl and phenoxy groups are unsubstituted or substituted with 1, 2, 3, 4 or 5 substituents Q¹² selected from the group consisting of halogen , OH, C₁₋₄-alkyl, C₁₋₄-haloalkyl, C₁₋₄-alkoxy and C₁₋₄-haloalkoxy; wherein the cycloalkyl, heteroaryl and aryl portions of Q² are unsubstituted or substituted with 1, 2, 3, 4, 5 or up to the maximum number of identical or different Q²ᵇ groups that are independently selected from: Q²ᵇ halogen, OH, CN, C₁₋₄-alkyl, C₁₋₄-alkoxy, C₁₋₄-haloalkyl, C₃₋₆-cycloalkyl, C₃₋₆-halocycloalkyl, C₁₋₄-haloalkoxy, and C₁₋₆-alkylthio; Q¹ and Q², together with the carbon atom to which they are attached, form a 3 to 7 membered saturated or partially unsaturated carbo- or heterocycle where the ring may also contain 1, 2, 3 or 4 heteroatoms selected from N-RN , O and S, where RN is selected from H, C₁₋₄-alkyl and SO₂RQ; wherein RQ is selected from C₁₋₄-alkyl, C₁₋₄-haloalkyl, unsubstituted aryl or heteroaryl substituted with 1, 2, 3, 4 or 5 RQ¹ substituents independently selected from C₁₋₄-alkyl; and where S can be in the form of its oxide SO or SO₂; and wherein, in each occurrence, 1 or 2 CH₂ groups of the carbo- or heterocycle may be replaced by a group independently selected from C(=O) and C(=S); and wherein the ring is unsubstituted or substituted with 1, 2, 3, 4, 5 or up to the maximum number of identical or different RQR groups, which are independently selected from: QQR halogen, OH, CN, C₁₋₄ -alkyl, C₁₋₄-alkoxy, C₁₋₄-haloalkyl, C₃₋₆-cycloalkyl, C₃₋₆-halogenocycloalkyl, C₁₋₄-haloalkoxy, and C₁₋₆-alkylthio; Q³ is selected from H, C₁₋₆-alkyl, C₂₋₆-alkenyl, C₂₋₆-alkynyl, C₃₋₆-cycloalkyl, heteroaryl, and 5- or 6-membered aryl; wherein heteroaryl contains 1, 2 or 3 heteroatoms selected from N, O and S; wherein the aliphatic portions of Q³ are unsubstituted or substituted with identical or different Q³ᵃ groups which are independently selected from: Q³ᵃ halogen, OH, CN, C₁₋₆-alkoxy, C₃₋₆-cycloalkyl, C₃₋₆ -cycloalkyloxy, C₃₋₆-halogenocycloalkyl, C₁₋₄-halogenoalkoxy, C₁₋₆-alkylthio, phenyl, phenoxy and 5- to 10-membered heterocycle, heteroaryl, heterocycloxy, heteroryloxy; wherein the heterocycle or heteroaryl contains 1, 2 or 3 heteroatoms selected from N, O and S; wherein the cycloalkyl, cycloalkyloxy, phenyl, phenoxy, heterocycle and heteroaryl groups are unsubstituted or substituted with 1, 2, 3, 4 or 5 Q¹³ᵃ substituents selected from the group consisting of halogen, OH, C₁₋₄-alkyl, C₁₋ ₄-halogenoalkyl, C₁₋₄-alkoxy, C₁₋₄-halogenoalkoxy, CR’=NOR’’; C₃₋₆-cycloalkyl, C₃₋₆-cycloalkyloxy, phenyl, phenoxy, and 5- to 10-membered heterocycle, heterocycleoxy, heteroaryl, and heteroaryloxy; wherein the heterocycle, heterocycleoxy, heteroaryl or heteroaryloxy contains 1, 2 or 3 heteroatoms selected from N, O and S; and wherein the phenyl, phenoxy, heterocycle, cycloalkyl and heteroaryl groups are unsubstituted or substituted with 1, 2, 3, 4 or 5 substituents Q¹¹³ᵃ selected from the group consisting of halogen, OH, C₁₋₄-alkyl, C₁₋₄ -halogenoalkyl, C₁₋₄-alkoxy, CN, CR'=NOR'' and C₁₋₄-halogenoalkoxy; wherein the cycloalkyl, heteroaryl and aryl portions of Q³ are unsubstituted or substituted with 1, 2, 3, 4, 5 or up to the maximum number of identical or different Q³ᵇ groups that are independently selected from: Q³ᵇ halogen, OH, CN, C₁₋₆-alkoxy, C₃₋₆-cycloalkyl, C₃₋₆-cycloalkyloxy, C₃₋₆-halogenocycloalkyl, C₁₋₄-halogenoalkoxy, C₁₋₆-alkylthio, phenyl, phenoxy and heterocycle, heteroaryl, heterocyclooxy, 5- to 10-membered heteroryloxy; wherein the heterocycle or heteroaryl contains 1, 2 or 3 heteroatoms selected from N, O and S; wherein the phenyl, phenoxy, heterocycle, cycloalkyl and heteroaryl groups are unsubstituted or substituted with 1, 2, 3, 4 or 5 Q¹³ᵇ substituents selected from the group consisting of halogen, OH, C₁₋₄-alkyl, C₁₋₄- halogenoalkyl, C₁₋₄-alkoxy, C₁₋₄-halogenoalkoxy, CR'=NOR"; C₃₋₆-cycloalkyl, C₃₋₆-cycloalkyloxy, phenyl, phenoxy, and 5- to 10-membered heterocycle, heterocycleoxy, heteroaryl, and heteroaryloxy; wherein the heterocycle, heterocycleoxy or heteroaryl, heteroaryloxy contains 1, 2 or 3 heteroatoms selected from N, O and S; and wherein the phenyl, phenoxy, heterocycle, cycloalkyl and heteroaryl groups are unsubstituted or substituted with 1, 2, 3, 4 or 5 substituents Q¹¹³ᵇ selected from the group consisting of halogen, OH, C₁₋₄-alkyl, C₁₋₄ -halogenoalkyl, C₁₋₄-alkoxy, CN, CR'=NOR'' and C₁₋₄-halogenoalkoxy; and wherein R' and R'' are independently unsubstituted or substituted with R''' which is independently selected from halogen, OH, CN, NO₂, SH, NH₂, NH(C₁₋₄-alkyl), N(C₁₋ ₄-alkyl)₂, C₁₋₆-alkyl, C₁₋₆-halogenoalkyl, C₂₋₆-alkenyl, C₂₋₆-halogenoalkenyl, C₂₋₆-alkynyl, C₂₋₆-halogenoalkynyl, C₁₋₆-alkoxy, C₁₋ ₆-halogenoalkoxy, C₃₋₆-cycloalkyl, C₃₋₆-halogenocycloalkyl and phenyl; W is O or S; X is selected from H, halogen, OH, CN, C₁₋₄-alkyl, C₁₋₄-alkoxy, C₁₋₄-halogenoalkyl, C₃₋₆-cycloalkyl, C₃₋₆-halogenocycloalkyl, C₁₋₄-halogenoalkoxy, and C₁₋ ₆-alkylthio; where n is 0, 1, 2, 3 or 4; provided that if R¹ is CH₃, then R² is not CH₃; and if R² is CH₃, R¹ is not CH₃; and the N-oxides and the agriculturally acceptable salts thereof.
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- 2016-11-28 BR BR112018010316A patent/BR112018010316A2/en active Search and Examination
- 2016-11-28 EP EP16801781.2A patent/EP3383849B1/en active Active
- 2016-11-28 WO PCT/EP2016/078958 patent/WO2017093167A1/en unknown
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