PL114262B1 - Means for optical recording - Google Patents

Means for optical recording Download PDF

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Publication number
PL114262B1
PL114262B1 PL1978209912A PL20991278A PL114262B1 PL 114262 B1 PL114262 B1 PL 114262B1 PL 1978209912 A PL1978209912 A PL 1978209912A PL 20991278 A PL20991278 A PL 20991278A PL 114262 B1 PL114262 B1 PL 114262B1
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PL
Poland
Prior art keywords
layer
light
agent according
reflecting
laser
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PL1978209912A
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Polish (pl)
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PL209912A1 (en
Inventor
Leonard J Levin
Fred W Spong
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Rca Corp
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Publication of PL209912A1 publication Critical patent/PL209912A1/en
Publication of PL114262B1 publication Critical patent/PL114262B1/en

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    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/258Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers
    • G11B7/2585Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers based on aluminium
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/246Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/253Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
    • G11B7/2533Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins

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  • Optical Record Carriers And Manufacture Thereof (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)

Description

Przedmiotem wynalazku jest srodek rejestracji optycznej do zastosowania w optycznym urzadze¬ niu rejestrujacym i optycznym urzadzeniu odtwa¬ rzajacym.Znane jest urzadzenie opisane w opublikowa- 5 nym we Francji zgloszeniu Sponga, numer po¬ rzadkowy 2 3449i2i0, ogloszonym w Dzienniku Urze¬ dowym nr 41 z 14 pazdziernika 1977. Jest to abla- cyjny srodek rejestrujacy, w postaci plaskiego krazka szklanego posiadajacy warstwe materialu i0 dobrze odbijajacego, jak aluminium, pokryta cien¬ ka warstwa materialu silnie absorbujacego swiatlo przy czestotliwosci swiatla rejestrowanego. Pod¬ czas rejestracji zmodulowane swiatlo lasera, za¬ równo padajace jak i odbite, przechodzi przez 15 cienka warstwe absorbujaca, zwiekszajac jej tem¬ perature tak, ze sublimuje ona lub topi sie two¬ rzac wzór w postaci dziur w warstwie absorbu¬ jacej, reprezentatywny dla informacji rejestrowa¬ nej. 20 Grubosc warstwy absorbujacej swiatlo dobrana jest tak, zeby spelnic warunek braku odblasku dla pokrytej plyty informacyjnej przy czestotli¬ wosci swiatla rejestrowanego. Realizowane jest bardzo skuteczne ogrzewainie do temperatur top- 25 nienia lub sublimacji, a wzdluz sciezki tworzony jest szereg dziur o regularnych ksztaltach o wy¬ miarach mikronowyeh lub submikronowych. Dlu¬ gosc i rozmieszczenie tych dziur niesie informacje, na przyklad przy modulacji czestotliwosciowej sy- ^ gnalów wizyjnych zapewniajac doskonale nagrania o stosunku sygnalu do szumu do- 50 decybeli (w dalszym ciagu dB) przy bardzo- duzeij gestosci upakowania zarejestrowanej informacji. Na przy¬ klad jedna ramka telewizyjna zajmuje powierzch¬ nie tylko okolo 1 milimetra kwadratowego. Wyzej opisany srodek rejestrujacy moze wiec sluzyc do wysokiej jakosci odtwarzania zarejestrowanych sygnalów telewizyjnych o jakosci wystepujacej w transmisjach telewizyjnych.Jednakze wyzej opisany srodek rejestrujacy po¬ siada wade — jest on kosztowny. Podklad, na- któ¬ rym polozone sa warstwy odbijajaca i absorbujaca musi posiadac wysoki stopien doskonalosci po¬ wierzchni, poniewaz defekty o wymiarach mikro¬ nowyeh lub nawet mniejszych powoduja zaniki sygnalu lub zaklócenia w odtwarzanym sygnale wizyjnym.Znanych jest kilka ukladów kompensatora za¬ ników, dzialajacych w przypadku, gdy zaburzenie sygnalu wychodzi poza normalny zakres poziomów sygnalu wizyjnego odpowiadajacy informacji obra¬ zowej. Nierównosci powierzchni podkladu plyty moga takze byc kompensowane za pomoca serwo¬ mechanizmów ogniskujacych, aby utrzymywac so¬ czewke obiektywu w ognisku przy ustalonej od¬ leglosci od powierzchni rejestrujacej.Jednakze mikroskopijne niedoskonalosci podkla¬ du srodka rejestrujacego dotychczas byly usuwane przez dokladne polerowanie mechainiczne szklanej 114 262114 262 powierzchni krazka. Metoda ta, chociaz skuteczna, ^est kosztowna. Poza tym szklo jest materialem bardzo kruchym, narazonym na pekniecie, szcze¬ gólnie podczas wirowania z duzymi predkosciami, zwykle 1800 obrotów na minute, podczas rejestra¬ cji i odczytu. Nie tylko niszczone jest nagranie, ale oczywiste jest pewne niebezpieczenstwo dla obslu¬ gujacego urzadzenie.Mniej kruche materialy, jak fotograficznej ja¬ kosci folia poliestrowa, folia akrylowa i prasowa¬ ny winyl, nie maja wymaganego stopnia gladkosci powierzchniowej i sa calkowicie nieodpowiednie do niniejszego zastosowania. Wobec tego poszuki¬ wano niedrogiego, bezpiecznego, plaskiego krazka o powierzchni wolnej od makroskopowych i mi¬ kroskopowych nierównosci i odpowiedniego do nagran telewizyjnych o jakosci wystepujacej w transmisjach telewizyjnych.Istota wynalazku polega na tym, ze srodek re¬ jestrujacy do uzycia z laserem zapisujacym, do¬ starczajacym swiatlo o danej czestotliwosci, zgod¬ nie z wynalazkiem zawiera: warstwe podkladu z tworzywa sztucznego; cienka, gladka, lsniaca, twarda, chemicznie obojetna warstwe pokrywa¬ jaca, wolna od makroskopowych i mikroskopo¬ wych nierównosci powierzchniowych, lezaca na warstwie podkladu; warstwe odbijajaca swiatlo, która odbija swiatlo o danej czestotliwosci wy¬ twarzane przez laser, lezaca na warstwie podkla¬ du; warstwe absorbujaca swiatlo, która pochlania swiatlo o danej czestotliwosci wytwarzane przez laser, lezaca na warstwie odbijajacej.Warstwa pokrywajaca pochodzi z grupy obej¬ mujacej lateks akrylowy, farby epoksydowe, zy- latyne dwuchromianowa, lakier poliuretanowy, lakier aikidowy i polimery fotoutwardzalne, a warstwe odbijajaca stanowi aluminium. Warstwa odbijajaca pokryta jest warstwa krzemionki o grubosci wystarczajacej do spelnienia warunku braku odblasku dla podkladu z pokryciem', a war¬ stwe absorbujaca swiatlo stanowi tytan o grubosci okolo 7,5 nm. Mternatywnie warstwe absorbujaca swiatlo moze stanowic 4-tfenylazo-l-naftyloamina o grubosci 40 nm. Na warstwe absorbujaca swia¬ tlo nalozona jest wierzchnia warstwa zabezpiecza¬ jaca. Odcinki warstwy absorbujacej swiatlo sa naswietlane przez laser zapisujacy, aby utworzyc wzór odbijajaco-nieodbijajacy swiatlo, odpowiada¬ jacy informacji wizyjnej.Wynalazek zostanie blizej objasniony w przy¬ kladach wykonania na rysunku, na którym fig. 1 przedstawia przekrój pewnego wykonania srodka rejestrujacego, fig. 2 — przekrój innego wykona¬ nia srodka rejestrujacego, fig. 3—przekrój jeszcze innego wykonania srodka, fig. 4 — schemat blo¬ kowy ukiadu rejestracji i odtwarzania.Do wytwarzania srodka rejestracji 10 (fig. 1,2,3) moga byc uzyte rózne pokrycia i powloki dostep¬ ne na rynku, takie jak: lakiery epoksydowe, po¬ liuretanowe powloki do podlóg i, mebli, oraz po¬ dlogowe powloki z lateksu akrylowego, jak rów¬ niez utwardzalne zelatyny i fotoutwardzalne poli¬ mery. Moga byc one nakladane na materialy pod¬ kladowe z tworzywa sztucznego o powierzchniach wyisoce nierównych, a nastepnie suszone lub utwardzane w celu otrzymania podkladu posia¬ dajacego mikroskopowo gladka powierzchnie, od¬ powiednia do rejestracji i odtwarzania informacji wizyjnej o jakosci wystepujacej w transmisjach telewizyjnych. Podklad 12 moze byc niedrogim tworzywem sztucznym, jak polichlorek winylu (PCV), polimery akrylowe i z polietereftalami etylenu i podobne i moze byc w postaci tasimy lub krazka, ale w dalszym ciagu bedzie opisywany w postaci krazka.Przydatnymi materialami podkladowymi, moga byc: folia poliestrowa, folia z polimetakrylanu metylu lub akrylowai, oraz plyty PCV podobne do powszechnie uzywanych w przemysle fonogra¬ ficznym. Nawet starannie przygotowane wysokiej jakosci materialy powyzszych typów nie maja po¬ wierzchni o odpowiedniej równosci do wykonania optycznych krazków. ; * v Materialy, które okazaly sie odpowiednie do po¬ krywania podkladu z tworzywa sztucznego, obej¬ muja podlogowe powloki z lateksu akrylowego, lakiery epoksydowe bez pigmentu, rozcienczone znanym rozcienczalnikami; zelatyne dwuchromia¬ nowa, na przyklad w roztworze 2^-5% wagowo z dodatkiem okolo 2% wagowo dwuchromianu so¬ dowego; lakiery poliuretanowe; lakiery alkidowe, jak roztwór 36% wagowo zywicy estrowej zmo¬ dyfikowanej sojowolniana zywica alkidowa w 6(5% weglowodoru alifatycznego i monomery, które tworza wiazania poprzeczne lub tezeja po na¬ swietleniu promieniami ultrafioletowymi oraz po¬ dobne.Warstwa pokrywajaca 14 moze byc nalozona, na krazek podkladowy 12 (fig. 1, 2, i 3) w jakikol¬ wiek wygodny sposób, jak przez wirowanie i po¬ dobne. Waine jest, zeby pokrycie bylo nakladane tak, aby zapobiec tworzeniu sie zmarszczek i in¬ nych razacych defektów powierzchni. Korzystne jest dodanie do lakieru kilka kropel odczynnika wyrównujacego powierzchnie. Material pokrywa¬ jacy moze byc rozcienczony w celu uzyskania po¬ krycia o zadanej grubosci. Warstwa pokrywajaca musi byc dostatecznie gruba, aby wypelnic wszy¬ stkie nierównosci powierzchni krazka.Nastepnie pokrycie schnie lub tezeje az do stwardnienia. Na przyklad lakiery moga byc na¬ kladane za pomoca wirowania i suszenia w po¬ wietrzu, ewentualnie przy nieco podwyzszonej temperaturze, na przyklad okolo 45°C. Materialy oparte na wodzie moga byc suszone w piecu z przeplywem goracego powietrza aby usunac resztki wody. Nalezy zwrócic uwage na utrzymy¬ wanie otaczajacego powietrza bez kurzu podczas nakladania i suszenia warstwy pokrywajacej.Metailiczna warstwa odbijajaca swiatlo 16 jest nakladana przewaznie przez naparowywanie1 próz¬ niowe na wysuszona i/lub utwardzona warstwe pokrywajaca. Na •przyklad moze byc zastosowana warstwa aluminium o grubosci, okolo 50 nm, war¬ stwa rodu o grubosci okolo 100 nm lub warstwa zlota o grubosci okolo 80 nm.Nastepnie na warstwe odbijajaca nakladana jest warstwa absorbujaca swiatlo 18. Odpowiednia absorbujaca, bezodblaskowa warstwa moze byc pojedyncza warstwa barwnika organicznego, jak 10 15 20 25 30 35 40 45 50 55 60114262 5 6 ujawniono w opublikowanym we Francji zglosze¬ niu Sjponga dotyczacym powyzszego i pokazano na fig. 1 i 2 lub dwuwarstwowy uklad skladajacy sie z warstwy absorbujacej 24 oraz nieafosorfouja- cej warstwy przekladkowej 26, jak pokazano na fig. 3.Odpowiednie warstwy barwnikowe obejmuja fluoresceine lufo 4-feinylazo- bosci okolo 40i—ftO nm. Odpowiednie uklady dwu¬ warstwowe obejmuja warstwe bizmutu lufo tytanu o grubosci, okolo 7,5 nm, lub warstwe rodu o gru¬ bosci okolo 3*0.0 nm na warstwie- przekladkowej z tlenku krzemu.W kazdym przypadku nagranie jest dokonywa¬ ne poprzez wytopienie lub odsiuiblimowainie dziur, albo zmienienie warstwy aibsorfoujacej w inny sposób. Cieplo zwiazane z tym procesem ma sklonnosc do. przenikania' przez warstwe odbija¬ jaca swiatlo do podkladu. Poniewaz omówione materialy na podklad z pokryciem moga byc wra¬ zliwe na cieplo, pozadane jest zastosowanie war¬ stwy izolujacej cieplnie (nie pokazanej) miedzy warstwa pokrywajaca z niniejszego wynalazku i warstwa odbijajaca. Odpowiednia jest warstwa krzemioinki o grubosci okoto 3<00 nm, aczkolwiek grubosc takiej warstwy n,ie jest krytyczna.Alternatywnie mozna, wykorzystac optyczna warstwe przekladkowa z wyzej opisanego dwu¬ warstwowego ukladu absorbujacego swiatla, które moze sluzyc zarówno jako optyczna warstwa przekladkowa jak i warstwa izolujaca cieplnie.Jednakze w tym przypadku grubosc warstwy przekladkowej jest wazna i zalezy od stalych optycznych warstwy odbijajacej swiatlo, warstwy przekladkowej i warstwy aibsorfoujacej swiatlo, poniewaz wymagane jest spelnienie warunku bra¬ ku odblasku. przez odsuiblimowanie szeregu jam, jak jama 22 na fig. 2 ,i jama 32 na fig. 3, w warstwie afosor^ bujacej. Srodek reejstrujacy 10 jest skanowany spiralna sciezka przy pomocy talerza obrotowego 5 124 wirujacego z predkoscia okolo 1800 obrotów na minute. Serwomechanizm ogniskujacy 126 utrzymuje stala odleglosc miedzy soczewka obiek¬ tywu 118 i. powierzchnia srodka rejestrujacego 10.W celu odczytu niezmodulowana i o mniejszej mocy wiazka laserowa, taka która nie spowoduje zmian w srodku rejestrujacym., przechodzi te sa¬ ma droge co wiazka rejestrujaca do srodka reje¬ strujacego 10. Zapisany wzór- odfoijajaco-nieodfoi- ^ajacy moduluje swiatlo odbite do soczewki obiektywu 118 i plytki cwiercfalowej 122. Swiatlo, teraz o polaryzacji obróconej o 9-0° przez dwa przejscia przez plytke cwierófalowa 122, przecho¬ dzi przez polaryzacyjny rozdzielacz wiazki 120 " kierowane jest przez urzadzenia optyczne od¬ czytu 128 do" fotodetektora 130. Fotodetektor 130 przetwarza odbita wiazke swiatla na elektryczny sygnal wyjsciowy na zacisku 132, sygnal ten od¬ powiada sygnalowi wejsciowemu. Serwomecha¬ nizm prowadzacy 134 kontroluje swiatlo przez urzadzenia optyczne odczytu 128, afoy zapewnic sciezke po srodku rejestrujacym 10 .podczas od¬ czytu taka sama jak .podczas rejestracji.Wyzej opisany srodek rejestrujacy dostarcza plyte niezapisana, na której moze byc zarejestro¬ wana informacja wizyjna w sposób opisany wy¬ zej. Natezenie swiatla rejestrujacego sterowane jest zgodnie z informacja przeznaczona do zare¬ jestrowania, jak za pomoca fali nosnej zmodulo¬ wanej czestotliwosciowo przez sygnaly wizyjne reprezentujace obraz, z natezeniem wiazki swietl¬ nej wahajacym sie pomiedzy poziomem dostatecz¬ nie wysokim do spowodowania zmian w warstwie absorbujacej i nizszym poziomem, niewystarcza¬ jacym do spowodowania takich zmian, przy czym czestotliwosc zmian poziomu, waha sde w takt zmian amplitudy sygnalu wizyjnego.Sciezka informacyjna zawierajaca szereg dziur lufo jam, takich jak jama 22 (fig. 2) i jama 32 (fig. 3), jest tworzona w warstwie aibsorfoujacej krazka przez zmiany termiczne materialu absor¬ bujacego w odpowiedzi' na naswietlenie zmodulo¬ wana wiazka swiatla. Niniejszy srodek rejestru¬ jacy zapewnia nagrania wizyjne o stosunku sy¬ gnalu do szumu takim jak w transmisjach tele¬ wizyjnych.Przyklad I. 12i-calowy krazek (3i0,5 cm) z polichlorku winylu, wytworzony na prasie, zostal pokryty przez wirowanie warstwa akrylowej po¬ wloki podlogowej w roztworze wodnym i pozo- staiwiony do wyschniecia w temperaturze poko¬ jowej. Nla warstwe akrylowa naparowano warstwe dwutlenku krzemu o grubosci okolo 300 nm afoy utworzyc izolacje cieplna.Nastepnie na tak przygotowany krazek w znany sposób nalozono warstwe aluminium o grufoosci okolo 5<0 nm pokryta warstwa dwutlenku krzemu o grubosci okolo 80 nm i warstwa tytanu o gru¬ bosci okolo 7,i5 nm. Wreszcie nalozono wierzchnia warstwe zywicy silikonowej wulkainizowalnej w W celu zabezpieczenia srodka rejestrujacego przed wplywem kurzu powierzchniowego' i innych zanieczyszczen,, na warstwie aibsorfoujacej swiatlo 40 moze byc polozona wierzchnia warstwa pokrywa¬ jaca 20, jak pokazano na fig. 2 i 3. Mozna tu za¬ stosowac warstwe przezroczystej wulkanizowalnej w temperaturze pokojowej', zywicy silikonowej.Zastosowanie niniejszego srodka rejestrujacego 45 moze byc wytlumaczone bardziej szczególowo za pomoca fig. 4. W celu zarejestrowania, swiatlo emitowane prze*z laser argonowy 110 jest dopro¬ wadzane do modulatora 112, który moduluje ja- snosoiowo swiatlo zgodnie z elektrycznym sygna- w lem wejsciowym ze zródla 114. Zmodulowane swiatlo jest rozszerzane przez urzadzenia optyczne rejestracji 116, afoy zwiekszyc srednice zmodulo¬ wanej jasnosciowo wiazki laserowej tak, zeby wy-^ pelnila ona zadana aparature soczewki obiek- . 65 tywu 118.Rozszerzona zmodulowana wiazka laserowa jest calkowicie odbijana przez polaryzacyjny rozdzie¬ lacz wiazki 120 i przechodzi przez obracajaca ; wiazke plytke cwierófalowa 122 do soczewki i60 obiektywu. Zmodulowana wiazka rejestrujaca pada nastepnie na srodek rejestrujacy 10, jak po- - kazany na fig. 1, 2 i 3 i zmienia warstwe absor¬ bujaca' srodka rejestrujacego, jak na przyklad' 15 20 25 30114 262 temperaturze pokojowej o grubosci okolo 75 ^m.Nagrania dokonano przy uzyciu urzadzenia jak opisano na fig. 4, zmieniajacego moc lasera za¬ pisujacego. Charakterystyki zapisu zebrano w po¬ nizszej tablicy, gdzie badanie 1 przeprowadzono bez warstw izolacyjnej i wierzchniej, a badanie 2 przeprowadzono bez warstwy wierzchniej.Tablica Moc lasera 1 mW 400 .350 300 250 Stosunek sygnalu bo szumu, dB 1 Przyklad 1 46 48 50 40 Badanie 1 42 43 42 <3(5 Badanie 2 45 44 40 <35 | Przyklad II. Przy uzyciu krazka podkladu z pokryciem z przykladu I, wykonano plyte, nie- zapisana nakladajac kolejno warstwe odbijajaca ze zlota o grubosci okolo 80 nm, warstwe absor¬ bujaca swiatlo z 4-tfenylazo-l-naiftyloamiiny o gru¬ bosci okolo 40 nm, warstwe izolacyjna z dwu¬ tlenku krzemu o' grubosci okolo 167 nm i wUlka- nizowalna w temperaturze pokojowej silikonowa warstwe zabezpieczajaca o grubosci okolo 75 ^m.Nagranie dokonane jak w przykladzie I przy mocy lasera okolo 300 mV mialo stosunek sygnalu do szumu 47 dB.Przyklad III. Przefiltrowany roztwór 2% zelatyny dwuchromianowej w wodzie nalozono wirowo na plyte bez rowków z polichlorku wi¬ nylu i pozostawiono do wyschniecia w czystym powietrzu w 45°C na 24 godziny. Srodek rejestru¬ jacy sporzadzono jak w przykladzie I. Zanotowano tylko 1—5 zaników na jedna ramke telewizyjna.Zapisano podobny srodek rejestrujacy, rózniacy sie od poprzedniego jedynie brakiem pokrycia podkladu z polichlorku winylu. Obraz mial setki zaników na jedna ramke. 10 15 20 25 35 40 Zastrzezenia patentowe 1. Srodek rejestrujacy do uzycia z laserem zai- pisuijacym dostarczajacym swiatlo o danej czesto¬ tliwosci, znamienny tym, ze zawiera warstwe pod¬ kladu z tworzywa sztucznegoi, cienka, gladka, lsniaca, twarda, chemicznie obojetna warstwe po¬ krywajaca, wolna od makroskopowych i mikro¬ skopowych nierównosci powierzchniowych, lezaca na warstwie podkladu, warstwe odbijajaca swia¬ tlo, która odbija swiatlo o danej czestotliwosci, wytwarzane przez laser i lezaca na warstwie pod¬ kladu, warstwe absorbujaca swiatlo., która absor¬ buje swiatlo o danej czestotliwosci, wytwarzane przez laser i lezaca na warstwie odbijajacej. 2.. Srodek wedlug zastrz. 1, znamienny tym, ze zawarta w nim warstwa pokrywajaca pochodzi- z grupy obejmujacej lateks akrylowy, farby epoksy¬ dowe, zelatyne dwuchromianowa, lakier poliure¬ tanowy, lakier alkidowy i polimery fotoutwar- dzalne. 3. Srodek wedlug zastrz. 1, znamienny tym, ze zawarta w nim warstwa odbijajaca jest z alumi¬ nium. 4. Srodek wedlug zastrz. 1, znamienny tym, ze zawarta w nim warstwa odbijajaca pokryta jest warstwa krzemionki o grubosci wystarczajacej do spelnienia warunku braku odblasku dla podkladu z pokryciem i ze zawarta, w nim warstwa absor¬ bujaca swiatlo jest z tytanu o grubosci okolo 7,5 nm. i5. Srodek wedlug zastrz. 1, znamienny tym, ze zawarta w nim warstwa- absorbujaca swiatlo- jest z 4^fenylazo-ll-naftyloaminy o grubosci okolo 40 nm, 6. Srodek wedlug zastrz. 1, znamienny tym, ze zawarta w nim wierzchnia warstwa zabezpieczac jaca jest nalozona na warstwe absorbujaca swiatlo. 7. Srodek wedlug zastrz. 1, znamienny tym, ze odcinki zawartej w nim warstwy absorbujacej swiatlo sa naswietlane przez laser zapisujacy, aby utworzyc wzór odbijajaco^nieodbijajacy swiatlo, odpowiadajacy informacji wizyjnej. 18 16 14 12 B Figi. 20 |3 I6,IVI2 Fig. 2\114 262 114 110 112 I -U X-L H 126 128—r ¦/ i/4 --C \| 1 —1 130 ) t f 1 "TT^ i e 1 LJ Ar 134 \ 132 J .—120 -122 Ir"8 cjO. -124 ' Fig 4. ^ PL PL PL The subject of the invention is an optical recording means for use in an optical recording device and an optical reproduction device. A known device is described in the Sponga application published in France, rare number 2 3449i2i0, published in the Official Journal No. 41 of October 14, 1977. It is an ablative recording medium in the form of a flat glass disc with a layer of a highly reflective material, such as aluminum, covered with a thin layer of material that strongly absorbs light at the frequency of the light being recorded. During recording, modulated laser light, both incident and reflected, passes through the thin absorbing layer, increasing its temperature so that it sublimates or melts, creating a pattern of holes in the absorbing layer, representative of for recorded information. 20 The thickness of the light-absorbing layer is selected so as to meet the condition of no reflection for the covered information board at the frequency of the recorded light. Very effective heating to melting or sublimation temperatures is performed and a series of regularly shaped holes of micron or submicron dimensions are created along the path. The length and arrangement of these holes carries information, for example in the frequency modulation of video signals, providing excellent recordings with a signal-to-noise ratio of up to 50 decibels (still dB) at a very high density of recorded information. For example, one television frame covers an area of only about 1 square millimeter. The above-described recording means can therefore be used for high-quality reproduction of recorded television signals of the quality occurring in television broadcasts. However, the above-described recording means has a drawback - it is expensive. The substrate on which the reflecting and absorbing layers are placed must have a high degree of surface perfection, because defects with dimensions of microns or even smaller cause signal loss or interference in the reproduced video signal. Several decay compensator systems are known. , operating when the signal distortion goes beyond the normal range of video signal levels corresponding to the image information. Irregularities in the plate backing surface can also be compensated for by using servo focusing mechanisms to keep the objective lens in focus at a fixed distance from the recording surface. However, microscopic imperfections in the recording medium backing have previously been removed by careful mechanical polishing of glass. 262 disc surface. This method, although effective, is expensive. Moreover, glass is a very brittle material, susceptible to cracking, especially when centrifuged at high speeds, usually 1800 rpm, during recording and reading. Not only is the recording destroyed, but there is obviously some danger to the operator. Less brittle materials, such as photo-quality polyester film, acrylic film and pressed vinyl, do not have the required degree of surface smoothness and are completely unsuitable for this application. . Therefore, they were looking for an inexpensive, safe, flat disk with a surface free from macroscopic and microscopic irregularities and suitable for television recordings of the quality found in television broadcasts. The essence of the invention is that a recording means for use with a recording laser, providing light of a given frequency, according to the invention, includes: a layer of plastic primer; a thin, smooth, shiny, hard, chemically neutral covering layer, free from macroscopic and microscopic surface irregularities, lying on the base layer; a light reflecting layer, which reflects light of a given frequency produced by the laser, lying on the base layer; a light-absorbing layer, which absorbs light of a given frequency produced by the laser, lying on the reflecting layer. The covering layer comes from the group consisting of acrylic latex, epoxy paints, zylatin dichromate, polyurethane varnish, aikid varnish and photocurable polymers, and the reflecting layer is aluminum. The reflecting layer is covered with a layer of silica of sufficient thickness to meet the non-reflective condition of the coated substrate, and the light-absorbing layer is titanium with a thickness of approximately 7.5 nm. Alternatively, the light-absorbing layer may be 4-phenylazo-l-naphthylamine with a thickness of 40 nm. A top protective layer is placed on the light-absorbing layer. Sections of the light-absorbing layer are illuminated by the recording laser to create a light-reflecting/non-reflecting pattern corresponding to the video information. The invention will be explained in more detail in embodiments in the drawing, in which Fig. 1 shows a sectional view of an embodiment of the recording means, Fig. 2 - cross-section of another embodiment of the recording means, Fig. 3 - cross-section of yet another embodiment of the recording means, Fig. 4 - block diagram of the recording and playback system. For the production of the recording means 10 (FIGS. 1, 2, 3) can be used various coverings and coatings available on the market, such as epoxy varnishes, polyurethane floor and furniture coatings, and acrylic latex floor coatings, as well as curable gelatins and photocurable polymers. They can be applied to plastic backing materials with highly uneven surfaces and then dried or cured to obtain a backing having a microscopically smooth surface suitable for recording and reproducing broadcast quality video information. Backing 12 may be an inexpensive plastic such as polyvinyl chloride (PVC), acrylic and polyethylene ether polymers and the like, and may be in tape or disc form, but will still be described in disc form. Useful backing materials may be: polyester film , polymethylmethacrylate or acrylic foil, and PVC boards similar to those commonly used in the recording industry. Even carefully prepared high-quality materials of the above types do not have a surface with sufficient evenness to produce optical discs. ; * v Materials that have been found to be suitable for covering plastic underlays include acrylic latex floor coatings, unpigmented epoxy varnishes thinned with known thinners; dichromate gelatin, for example in a solution of 2-5% by weight with the addition of about 2% by weight of sodium dichromate; polyurethane varnishes; alkyd varnishes, such as a solution of 36% by weight ester resin modified soybean alkyd resin in 6(5% aliphatic hydrocarbon) and monomers that form cross-links or the like after exposure to ultraviolet rays and the like. Covering layer 14 may be applied, onto the backing disc 12 (FIGS. 1, 2, and 3) by any convenient means, such as by spinning or the like. It is desirable that the coating be applied so as to prevent the formation of wrinkles and other gross surface defects. .It is advantageous to add a few drops of surface leveling agent to the varnish. The covering material can be diluted to obtain a covering of the desired thickness. The covering layer must be thick enough to fill any irregularities in the disc surface. The covering then dries or hardens. until hardened. For example, varnishes can be applied by spinning and air drying, possibly at a slightly elevated temperature, for example about 45°C. Water-based materials can be oven-dried with hot air to remove any remaining water. Care must be taken to keep the surrounding air dust-free during the application and drying of the cover layer. The metallic light reflecting layer 16 is applied preferably by vacuum vapor deposition onto the dried and/or cured cover layer. For example, an aluminum layer about 50 nm thick, a rhodium layer about 100 nm thick, or a gold layer about 80 nm thick may be used. A light-absorbing layer 18 is then applied to the reflective layer. A suitable absorbing, non-reflective layer may be a single layer of an organic dye, such as 10 15 20 25 30 35 40 45 50 55 60114262 5 6 disclosed in Sjpong's French application relating thereto and shown in FIGS. 1 and 2, or a two-layer system consisting of an absorbent layer 24 and a non-phosphorus second interlayer 26, as shown in Fig. 3. Suitable dye layers include fluorescein or 4-phenyllase with a density of about 40 µm. Suitable two-layer systems include a layer of bismuth or titanium about 7.5 nm thick, or a layer of rhodium about 3*0.0 nm thick on a silicon oxide sandwich layer. In each case, the recording is made by smelting or reducing holes or changing the absorbing layer in another way. The heat associated with this process tends to. penetration through the light-reflecting layer into the substrate. Since the covered backing materials discussed may be heat sensitive, it is desirable to provide a heat insulating layer (not shown) between the covering layer of the present invention and the reflective layer. A layer of silica with a thickness of about 300 nm is suitable, although the thickness of such a layer is not critical. Alternatively, an optical sandwich layer of the above-described two-layer light absorbing system can be used, which can serve both as an optical sandwich layer and as an optical layer. thermally insulating. However, in this case the thickness of the spacer layer is important and depends on the optical constants of the light-reflecting layer, the spacer layer and the light-absorbing layer, because the condition of non-reflection is required. by emphasizing a series of cavities, such as cavities 22 in Fig. 2 and cavities 32 in Fig. 3, in the aphosphor layer. The recording means 10 is scanned in a spiral path by means of a turntable 5 124 rotating at a speed of approximately 1800 revolutions per minute. The focusing servo 126 maintains a constant distance between the objective lens 118 and the surface of the recording means 10. For reading purposes, an unmodulated and lower power laser beam, one that will not cause changes in the recording means, follows the same path as the recording beam to the center. recording device 10. The recorded dephoto-non-dephoto pattern modulates the light reflected to the objective lens 118 and the quarter-wave plate 122. The light, now with its polarization rotated 9-0° by two passes through the quarter-wave plate 122, passes through the polarizing The beam splitter 120 is directed by the optical reading devices 128 to the photodetector 130. The photodetector 130 converts the reflected light beam into an electrical output signal at terminal 132, which corresponds to the input signal. The guide servo mechanism 134 controls the light through the optical reading devices 128 and ensures that the path along the recording means 10 during reading is the same as during recording. The above-described recording means provides a blank disc on which the video information can be recorded in method described above. The intensity of the recording light is controlled in accordance with the information to be recorded, as by a carrier wave frequency modulated by the video signals representing the image, with the intensity of the light beam varying between a level high enough to cause changes in the absorbing layer and a lower level, insufficient to cause such changes, and the frequency of the level changes varies with changes in the amplitude of the video signal. An information path including a series of holes or cavities, such as cavity 22 (FIG. 2) and cavity 32 (FIG. 3) ), is created in the absorbing layer of the disk by thermal changes of the absorbing material in response to exposure to a modulated light beam. This recording medium provides video recordings with a signal-to-noise ratio similar to that of television broadcasts. Example I. A 12-inch (3-0.5 cm) disc of polyvinyl chloride, produced on a press, was spin-coated with an acrylic layer floor coating in an aqueous solution and left to dry at room temperature. On top of the acrylic layer, a layer of silicon dioxide with a thickness of about 300 nm was vapor-deposited to create thermal insulation. Then, a layer of aluminum with a thickness of about 5-0 nm was applied to the disk prepared in a known manner, covered with a layer of silicon dioxide with a thickness of about 80 nm and a layer of titanium with a thickness of bosci about 7. and 5 nm. Finally, a top layer of vulcainizable silicone resin was applied. In order to protect the recording medium from the influence of surface dust and other contaminants, a top covering layer 20 may be placed over the light-absorbing layer 40, as shown in Figures 2 and 3. Here, ¬ use a layer of transparent, room temperature vulcanizable silicone resin. The use of the present recording means 45 can be explained in more detail with the help of FIG. 4. For recording, the light emitted by the argon laser 110 is fed to a modulator 112 which brightness modulates the light in accordance with the electrical input signal from the source 114. The modulated light is expanded by optical registration devices 116 to increase the diameter of the brightness modulated laser beam so that it serves as the desired objective lens apparatus. 65 of the beam 118. The expanded modulated laser beam is completely reflected by the polarizing beam splitter 120 and passes through the rotating beam; beam of the 122 quarter-wave plate to the i60 lens of the objective. The modulated recording beam then falls on the recording means 10, as shown in Figures 1, 2 and 3, and changes the absorbing layer of the recording means, for example at room temperature, to a thickness of about 75 µm. The recording was made using a device as described in Fig. 4, which varies the power of the recording laser. The recording characteristics are summarized in the table below, where test 1 was performed without the insulating and covering layers, and test 2 was performed without the top layer. Table Laser power 1 mW 400 .350 300 250 Signal to noise ratio, dB 1 Example 1 46 48 50 40 Test 1 42 43 42 <3(5 Test 2 45 44 40 <35 | Example II. Using a backing disk with the coating from Example I, an unrecorded plate was made by successively applying a reflecting layer of gold with a thickness of about 80 nm and an absorbing layer ¬ a light-emitting layer of 4-phenylazo-l-naphthylamine with a thickness of approximately 40 nm, an insulating layer of silicon dioxide with a thickness of approximately 167 nm and a silicone protective layer, vulcanizable at room temperature, with a thickness of approximately 75 μm. Recording made as in Example 1 at a laser power of approximately 300 mV had a signal-to-noise ratio of 47 dB. Example 3. A filtered solution of 2% dichromate gelatin in water was spin-applied onto a grooveless polyvinyl chloride board and allowed to dry in clean air at 45 °C for 24 hours. The recording medium was prepared as in Example I. Only 1-5 dropouts were recorded per TV frame. A similar recording medium was prepared, differing from the previous one only in the lack of covering the polyvinyl chloride backing. The image had hundreds of fades per frame. 10 15 20 25 35 40 Patent claims 1. A recording medium for use with a recording laser supplying light of a given frequency, characterized in that it comprises a plastic backing layer, a thin, smooth, shiny, hard, chemically inert covering layer, free from macroscopic and microscopic ¬ optical surface irregularities, lying on the base layer, a light-reflecting layer that reflects light of a given frequency, produced by the laser, and lying on the base layer, a light-absorbing layer, which absorbs light of a given frequency, produced by laser and lying on the reflecting layer. 2.. Agent according to claim. 1, characterized in that the covering layer contained therein comes from the group consisting of acrylic latex, epoxy paints, dichromate gelatin, polyurethane varnish, alkyd varnish and photocurable polymers. 3. The agent according to claim 1, characterized in that the reflective layer contained therein is made of aluminum. 4. The agent according to claim The method of claim 1, characterized in that the reflective layer included therein is covered with a layer of silica having a thickness sufficient to meet the non-reflective condition of the coated substrate and that the light-absorbing layer included therein is made of titanium having a thickness of about 7.5 nm. i5. Agent according to claim 1, characterized in that the light-absorbing layer contained therein is made of 4-phenylase-ll-naphthylamine with a thickness of about 40 nm, 6. Agent according to claim 1. 1, characterized in that the top protective layer contained therein is superimposed on a light-absorbing layer. 7. The agent according to claim The method of claim 1, characterized in that sections of the light-absorbing layer contained therein are exposed to a recording laser to form a light-reflecting and non-reflecting pattern corresponding to the video information. 18 16 14 12 B Figs. 20 |3 I6,IVI2 Fig. 2\114 262 114 110 112 I -U X-L H 126 128—r ¦/ i/4 --C \| 1 —1 130 ) t f 1 "TT^ i e 1 LJ Ar 134 \ 132 J .—120 -122 Ir"8 cjO. -124 ' Fig 4.^ PL PL PL

Claims (7)

1. Zastrzezenia patentowe 1. Srodek rejestrujacy do uzycia z laserem zai- pisuijacym dostarczajacym swiatlo o danej czesto¬ tliwosci, znamienny tym, ze zawiera warstwe pod¬ kladu z tworzywa sztucznegoi, cienka, gladka, lsniaca, twarda, chemicznie obojetna warstwe po¬ krywajaca, wolna od makroskopowych i mikro¬ skopowych nierównosci powierzchniowych, lezaca na warstwie podkladu, warstwe odbijajaca swia¬ tlo, która odbija swiatlo o danej czestotliwosci, wytwarzane przez laser i lezaca na warstwie pod¬ kladu, warstwe absorbujaca swiatlo., która absor¬ buje swiatlo o danej czestotliwosci, wytwarzane przez laser i lezaca na warstwie odbijajacej.1. Claims 1. A recording means for use with a writing laser providing light of a given frequency, characterized in that it comprises a plastic backing layer and a thin, smooth, shiny, hard, chemically inert covering layer , free from macroscopic and microscopic surface irregularities, lying on the base layer, a light-reflecting layer that reflects light of a given frequency produced by the laser and lying on the base layer, a light-absorbing layer, which absorbs light of a given frequency, produced by the laser and lying on the reflecting layer. 2.. Srodek wedlug zastrz. 1, znamienny tym, ze zawarta w nim warstwa pokrywajaca pochodzi- z grupy obejmujacej lateks akrylowy, farby epoksy¬ dowe, zelatyne dwuchromianowa, lakier poliure¬ tanowy, lakier alkidowy i polimery fotoutwar- dzalne.2.. Agent according to claim. 1, characterized in that the covering layer contained therein comes from the group consisting of acrylic latex, epoxy paints, dichromate gelatin, polyurethane varnish, alkyd varnish and photocurable polymers. 3. Srodek wedlug zastrz. 1, znamienny tym, ze zawarta w nim warstwa odbijajaca jest z alumi¬ nium. 3. The agent according to claim 1, characterized in that the reflective layer contained therein is made of aluminum. 4. Srodek wedlug zastrz. 1, znamienny tym, ze zawarta w nim warstwa odbijajaca pokryta jest warstwa krzemionki o grubosci wystarczajacej do spelnienia warunku braku odblasku dla podkladu z pokryciem i ze zawarta, w nim warstwa absor¬ bujaca swiatlo jest z tytanu o grubosci okolo 7,5 nm. i 4. The agent according to claim The method of claim 1, characterized in that the reflective layer included therein is covered with a layer of silica having a thickness sufficient to meet the non-reflective condition of the coated substrate and that the light-absorbing layer included therein is made of titanium having a thickness of about 7.5 nm. and 5. Srodek wedlug zastrz. 1, znamienny tym, ze zawarta w nim warstwa- absorbujaca swiatlo- jest z 4^fenylazo-ll-naftyloaminy o grubosci okolo 40 nm, 5. Agent according to claim. 1, characterized in that the light-absorbing layer contained therein is made of 4-phenyl-III-naphthylamine with a thickness of approximately 40 nm, 6. Srodek wedlug zastrz. 1, znamienny tym, ze zawarta w nim wierzchnia warstwa zabezpieczac jaca jest nalozona na warstwe absorbujaca swiatlo. 6. Agent according to claim. 1, characterized in that the top protective layer contained therein is superimposed on a light-absorbing layer. 7. Srodek wedlug zastrz. 1, znamienny tym, ze odcinki zawartej w nim warstwy absorbujacej swiatlo sa naswietlane przez laser zapisujacy, aby utworzyc wzór odbijajaco^nieodbijajacy swiatlo, odpowiadajacy informacji wizyjnej. 18 16 14 12 B Figi. 20 |3 I6,IVI2 Fig. 2\114 262 114 110 112 I -U X-L H 126 128—r ¦/ i/4 --C \| 1 —1 130 ) t f 1 "TT^ i e 1 LJ Ar 134 \ 132 J .—120 -122 Ir"8 cjO. -124 ' Fig4. ^ PL PL PL7. The agent according to claim The method of claim 1, characterized in that sections of the light-absorbing layer contained therein are exposed to a recording laser to form a light-reflecting and non-reflecting pattern corresponding to the video information. 18 16 14 12 B Figs. 20 |3 I6,IVI2 Fig. 2\114 262 114 110 112 I -U X-L H 126 128—r ¦/ i/4 --C \| 1 —1 130 ) t f 1 "TT^ i e 1 LJ Ar 134 \ 132 J .—120 -122 Ir"8 cjO. -124 ' Fig4. ^PL PL PL
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JPS5454634A (en) 1979-05-01
IT1099139B (en) 1985-09-18
CA1135413A (en) 1982-11-09
FR2404887A1 (en) 1979-04-27

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