PL10320B1 - Sposób wydzielania tlenku wegla z mieszanin gazu. - Google Patents
Sposób wydzielania tlenku wegla z mieszanin gazu. Download PDFInfo
- Publication number
- PL10320B1 PL10320B1 PL10320A PL1032027A PL10320B1 PL 10320 B1 PL10320 B1 PL 10320B1 PL 10320 A PL10320 A PL 10320A PL 1032027 A PL1032027 A PL 1032027A PL 10320 B1 PL10320 B1 PL 10320B1
- Authority
- PL
- Poland
- Prior art keywords
- carbon monoxide
- gas mixtures
- separation
- ammonium
- cuprous chloride
- Prior art date
Links
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims description 5
- 239000000203 mixture Substances 0.000 title claims description 3
- 238000000034 method Methods 0.000 title claims 2
- 238000000926 separation method Methods 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims description 4
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims description 4
- 229940045803 cuprous chloride Drugs 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- VUCAVCCCXQVHAN-UHFFFAOYSA-L azane dichlorocopper Chemical compound N.Cl[Cu]Cl VUCAVCCCXQVHAN-UHFFFAOYSA-L 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- -1 cuprous chloride Chemical compound 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004868 gas analysis Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
Description
Znanem jest, ze amonjakalne lugi 7,5% miedzi, 2,5% chloru, 7% amon jaku chlorku miedziawego, stosowane przy ana¬ lizie gazów, nagryzaja silnie metaliczne ze¬ lazo, wobec czego nie nadaja sie do usu¬ wania tlenku wegla z gazów technicznych i z mieszanin gazów w aparaturach zelaz¬ nych, szczególnie przy wyzszych cisnie¬ niach. Nagryzanie zelaza mozna wpraw¬ dzie znacznie oslabic przez stosowanie a- monjakalnych roztworów chlorku miedzia¬ wego ze znacznym nadmiarem amon jaku; lugi te posiadaja jednak z powodu cisnie¬ nia amon jaku te wade, ze podczas wype¬ dzania pochlonietego tlenku wegla wielkie ilosci amon jaku ulatniaja sie wraz z tlen¬ kiem wegla.Znaleziono, ze zdolnosc nagryzania ze¬ laza przez amonjakalne lugi chlorku mie¬ dziawego mozna znacznie oslabic domiesz¬ ka siarczanów, np. miedzi lub amonjaku.Wytwarza sie np. lug, zawierajacy i ilosc SO±, równowazna stosowanej mie¬ dzi. Obojetnym jest przytem sposób przy¬ rzadzania rozczynu; mozna np. zmieszac siarczan miedzi i chlorek amonowy z od¬ powiednia iloscia amonjaku lub tez chlorek miedziawy i siarczan anionowy z odpowied¬ nia iloscia amonjaku. PL
Claims (1)
1. Zastrzezenie patentowe. Sposób wydzielania tlenku wegla z mieszanin gazów przy uzyciu aparatury zelaznej, szczególnie pracujacej pod ci¬ snieniem, znamienny tern, ze stosuje sie a- monjakalny roztwór chlorku miedziawego z okreslona zawartoscia siarczanu. Anton Kauzner. Zastepca: Inz. H. Sokal, rzecznik patentowy. Druk L. Boguslawskiego, Warszawa. PL
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL10320B1 true PL10320B1 (pl) | 1929-05-31 |
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