OA19262A

OA19262A - Reducing the need for tailings storage dams in mineral flotation.

Info

Publication number: OA19262A
Application number: IBPCT/IB2016/056324W
Authority: OA
Inventors: Anthony Owen FILMER; Daniel John ALEXANDER
Original assignee: Anglo American Services (Uk) Ltd
Priority date: 2016-05-11
Filing date: 2016-10-21
Publication date: 2020-06-05

Abstract

This invention relates to a process for recovering value metals from ore (50) configured such as to substantively reduce or eliminate the need for a tailings storage facility. This object is achieved through an integrated processing system designed to enhance the ratio of sand residue from coarse flotation (62) to the amount of tailings arising from fine flotation (72), and then blending a proportion of coarse and fine flotation gangue materials into a free draining stack (82).

Description

According to the présent invention there is provided a process to eliminate or greatly reduce the proportion of the run of mine ore which must be impounded in a purpose built tailings storage facility (TSF).

These objects are achieved through an integrated Processing System designed to enhance the ratio of sand residue from coarse flotation to the amount of tailings arising from fine flotation, and then managing the placement of ail or a proportion of the combined coarse and fine flotation gangue materials into a single free draining stack. Through this a novel System, the need for any purpose built TSF can be eliminated or at worst, reduced very substantially.

The essence of the invention is an integrated System of comminution, classification, coarse flotation, fine flotation, residue drainage, blending, and dry stacking. By effective control of fines, and in particular silt, génération at ail stages of comminution, a high proportion of the run of mine (ROM) ore is separated into a desired particle size window for coarse flotation. This enables both high flotation recoveries of the valuable component, and rejection of a large proportion of the gangue as a coarse sand residue. This free draining residue can then be blended with the thickened fine tailings slurry, to produce a composite material with a silt content which still allows draining, and hence is suitable to be independently stacked.

With reference to Figure 3, in a process of a first embodiment of the invention, run of mine (ROM) ore 50 from blasting and crushing 52 is ground 54 to expose the valuable components for coarse flotation. Two stages of classification, a first classification stage 56 and a second classification stage 58, are used sequentially to recycle the ore that is still too coarse for coarse flotation for further comminution, and to separate the fines to bypass the coarse flotation and go direct to fine flotation. Oversize material 60 from the first classification stage 56 is recycled. The ore which is in the desired operational size window, is subjected to coarse flotation 62 to produce an intermediate concentrate 64 and coarse sand residue 66 containing most of the gangue. The intermediate concentrate 64 from coarse flotation 62 is reground 68, and together with the fines 70 from the original classification, are subjected to fine flotation 72 to obtain a concentrate 74. The sand residue 66 from coarse flotation 62 is drained 76 to recover the contained water 78 which is recycled, and the tailings 80 from the fine flotation are thickened to reduce the contained water. The coarse sand and thickened fine tailings are then blended, and stacked 82.

The key to producing a stackable tailings 82 is the quantity of fines contained in the blend, and in particular the amount of silt (defined as tailings of less than 75 micron diameter). This fine silt greatly inhibits the drainage characteristics of the final stack. Whilst each ore will be slightly different, it is known that stacked heaps of coarse sand can be stable up to around 25% contained silt. Above around 25% of silt, the hydraulic conductivity of the stack déclinés substantially, making uncontained storage of such material increasingly problematic in wet climates, or areas subject to seismic activity, or on mountain slopes, or where the stack is required to exhibit structural integrity.

The first component of the complété integrated system, that is the subject of this invention, is a comminution and classification process (both in the primary grind and regrind). The primary grinding process should be configured to generate a silt content in the comminuted ore that is below 20%, and preferably below 15%, whilst ensuing the feed to coarse flotation is ground to the size required for exposure of at least 85% and preferably greater than 90% of the values in the ore being processed. Through operating known comminution devices with a high Schumann modulus, such as tertiary crushers and rod mills, or somewhat lower modulus, (HPGR, SAG and bail mill) in a closed circuit with known classification devices with a sharp partition curve (such as Derrick or DSM screens or various hydraulic classifiers) or not so efficient classifiers such as hydrocylones, the comminuted ore inside the selected operating window can be ‘scalped’ for coarse flotation. To achieve this, the equipment sélection, configuration and recirculating flows are specifically designed to avoid formation of fines in comminution, and to avoid displacement of material which is already ground to within the selected size window; into the recirculating load to comminution. The size for the classification from the recirculating comminution load is set to maximize the scalp from the recirculation comminution load, consistent with achieving satisfactory recoveries in coarse flotation. For copper ores, this upper size is typically in the range 350-600 micron. The system design principle is to avoid génération of fines in comminution and then maximize removal of material below the upper size range from the comminution circuit, to avoid the possibility that is will be over-ground to produce silt. This affects the idéal sélection of comminution and classification devices. For instance, a rod mill is well known to provide a sharper size distribution curve than a bail mill. And the use of a conventional cyclone for classification, provides an inferior partition curve to screens or classifiers.

The second component of the System is classification of material that is finer than that suited to coarse flotation. The séparation efficiency of fines in coarse flotation is limited, relative to conventional fine flotation. If the selected coarse flotation equipment does not require fines removal, this component becomes optional, with the fine material being floated along with the exposed minéralisation.

The third component of the complété System, is the coarse flotation itself, and the subséquent dewatering of the coarse flotation residue. The mass pull of the intermediate concentrate from coarse flotation can be adjusted to yield a satisfactory recovery and grade. (Typically this will be a mass pull to concentrate of 5-30% of the feed, and preferably around 10-20%). The resulting coarse sand residue (around 50-60% of the run of mine ore), has most of the sulphides removed and has a high hydraulic conductivity and can be readily screened, or allowed to drain naturally, to recover the contained water. The recovered water is essentially free of sûmes and is readily recyclable. The dewatered coarse sand residue then typically contains around 10% by weight water.

In the fourth component of the complété System, this intermediate concentrate is reground to more fully liberate the values. It is mixed with the stream of undersize material produced by earlier classification, and floated to produce a saleable concentrate. Or in the case of gold, leached to recover the exposed gold. The final tailings from this further flotation represents around 40-50% of the total mass of the ROM ore, with a contained fraction of sub 75 micron silt typically around half of the total material in this fine flotation reject stream. This typically equates to a total of sub 75 micron material of around 20-25% by mass of the original ROM.

In the fifth component of the complété System, the tailings from fine flotation is dewatered to the extent possible. This is typically undertaken in a thickener to produce a thickened tailings or paste, but the fine tailings could also be filtered to recover additional water.

In the sixth component of the complété System, this thickened slurry or paste is blended back in part or totally, with the drained coarse sand residue. The desired blending ratio will be limited according to the geotechnical requirements for the residue heap. Meeting these spécifications will be affected by the quantity of silt, resulting from the design and operation of other parts of the System. For a free standing sand heap akin to waste rock, it is désirable that the silt content is less than around 25%, whilst for more load bearing applications such as dam construction, preferably less than 15% silt. Above 25% silt, there will be an increased need for compaction and buttressing. The water content of this combined residue is typically around 20% by weight.

In the event that the System of comminution and classification, for a particular orebody, does not achieve a blended product with acceptable geotechnical characteristics for disposai, a proportion of the fines will require storage in a TSF. Or, in the case where there is a lower cost disposai option for a fraction of the fines into a conventional TSF, the blending ratio can be adjusted accordingly.

The blended residue can be transported by truck or conveyor, and stacked in a manner conducive to long term sustainable disposai.

In summary, the overall System of comminution, classification, coarse and fine flotation, draining, thickening and blending, results in a significantly lower unit cost to process low grade ore. This is a conséquence of significantly lower comminution costs (coarser grind); lower water consumption, and capacity requirements for any purpose built TSF. This lower unit cost structure can reduce the viable cut-off grade, thus increasing the économie resource recovery and substantively improving the mine life. It is applicable to both resources where storage of tailings in a slurry form is particularly problematic, and where a more sustainable disposai method is désirable from a long term closure perspective.

A second embodiment of the invention outlined in Figure 4, in which the process is configured in a low grade storage configuration. With reference to Figure 4, run of mine (ROM) ore 50 from blasting and crushing 52 is ground 54 to expose the valuable components for coarse flotation. Two stages of classification, a first classification stage 56 and a second classification stage 58, are used sequentially to recycle the ore that is still too coarse for coarse flotation for further comminution, and to separate the fines to bypass the coarse flotation and go direct to fine flotation. Oversize material 60 from the first classification stage 56 is recycled. Ore which is in the desired operational size window is subjected to coarse flotation 62 to produce an intermediate concentrate 64 and coarse sand residue 66 containing most of the gangue. The intermediate concentrate 64 from coarse flotation 62 is reground 68, and together with the fines 70 from the original classification, are subjected to fine flotation 72 to obtain a concentrate 74.

In this second embodiment of the invention, the upper size limit for the operational window processed through coarse flotation 62 is set at a higher particle size. This upper size limit can be between 500 and 1500 micron, depending on exposure characteristics of the spécifie ore and the flotation characteristics of the coarse flotation equipment. The increased size range of the operational window, increases the scalp of material taken from each pass of the circulating load between comminution and classification. As such, it reduces the cycle of material 60 just above the idéal size range for coarse flotation, and hence the proportion of silt being formed in this initial comminution circuit.

In this configuration, it is accepted that a significant fraction of the values contained in the coarsest of the ore particles sent to coarse flotation will be occluded in gangue, and thus not hâve an appropriate surface for bubble attachment during coarse flotation. Recoveries through coarse flotation will therefore be restricted to the exposed grains, and hence recovery of the coarsest ore fraction will be lower than achievable with a finer classification size. However, most of the occluded valuable ore remaining in the coarse flotation residue 66 will be in the coarsest particles, and can be separated from the coarse flotation residue by normal classification devices. This coarsest fraction, whilst lower grade than the ROM feed due to natural partitioning during comminution and being partially denuded of its values by coarse flotation, is still worthy of further grinding for minerai recovery. The coarsest fraction can be separated from the coarse flotation residue using well known size classification equipment 84, drained and stored as a middlings 86, for retreatment at an appropriate time by regrinding or heap leaching. The finer fraction from this post flotation classification (typically between 150 and around 600 microns depending on the ore libération characteristics) then forms the final coarse flotation residue 88 which is drained 76 to recover the contained water 78 which is recycled, and the tailings 80 from the fine flotation are thickened to reduce the contained water. The coarse sand and fine tailings are then blended, and stacked 82.

The advantage of this configuration is that additional higher grade ROM ore can replace the lower grade middlings in the available comminution capacity, thus improving the production profile of the mine. Ultimately, the middlings can be reclaimed from storage and reprocessed later in the life of mine, and hence is not sterilised. Alternatively, the middlings can be subjected to a heap leach. In this sense, this variant is akin to the grade engineering method that is practiced with coarsely crushed ore.

A third embodiment of the invention is illustrated in Figure 5. This embodiment is typically used where the slurry transport of the residue and tailings to a disposai site is a spécifie considération. With reference to Figure 5, run of mine (ROM) ore 50 from blasting and crushing 52 is ground 54 to expose the valuable components for coarse flotation. Two stages of classification, a first classification stage 56 and a second classification stage 58, are used sequentially to recycle the ore that is still too coarse for coarse flotation for further comminution, and to separate the fines to bypass the coarse flotation and go direct to fine flotation. Oversize material 60 from the first classification stage 56 is recycled. Ore which is in the desired operational size window is subjected to coarse flotation 62 to produce an intermediate concentrate 64 and coarse sand residue 66 containing most of the gangue. The intermediate concentrate 64 from coarse flotation 62 is reground 68, and together with the fines 70 from the original classification, are subjected to fine flotation 72 to obtain a concentrate 74. The system is similar to the first embodiment of the invention, except that the waste materials from both the fine and coarse flotation, i.e. the course residue 66 and fine tailings 90, are recombined to transport them as a combined slurry to their disposai location. Here they can be filtered, or the predominantly coarse fraction (> 150 micron) can be separated using a cyclone or similar classification device 92, and drained 94 to mostly replicate the original formulation of free draining coarse sand residue. Water 96 drained at 94 can be recycled. The fine material in the cyclone overflow replicates the fines flotation tailings, which again is treated as described previously. The thickened fines 98 are blended with the drained coarse material 100 and dry stacked 102.

In summary, through sélection of appropriate comminution and classification designs and operating conditions, and using coarse flotation techniques, and draining of the coarse residue, and blending this with the thickened fine tailings, in an integrated production system, this invention can:

• achieve high minerai recoveries • at reduced energy consumptions;

• and recover a substantive proportion of the water from the residue;

• and eliminate or greatly reduce the requirement for a TSF.

Further benefits may also accrue for some orebodies. Through the resulting unit cost savings, the integrated system also enables a réduction in the économie cut-off-grade of the ore, and hence enhances the overall resource recovery. The integrated system also potentially improves the capital intensity of the overall comminution and classification circuit.

Example

Partially ground ROM ore from a Chilean mine from the cyclone underflow in the existing comminution circuit. It was used for testing coarse flotation and dry stacking. Recoveries of copper were consistent with the degree of exposure of the copper mineralization on the surface of the particles. Copper recoveries were greater than 90% at a particle size of 350 micron, falling to less than 70% recovery at a particle size of 500 micron. The overall mass pull was 20%. Thus a high recovery in coarse flotation can be achieved when the ROM material classified to a maximum particle size of around 450 micron. The sulphur content of the residue was 0.3%, with no observable surface expression of sulphides.

The coarse residue drained freely to a contained water content of 10%. The thickened fine residue had a water content of 40%. When mixed in a ratio of 0.6 coarse to 0.4 fine material, the combined solids exhibited sufficient structural integrity for independent stacking.

Modelling of the comminution circuit (SAG and bail mill) indicates that with use of a classification device with a Sharp partition curve (either a screen or hydraulic classifier), the % of silt reporting to combined residue would be significantly less than 30% of the ROM ore. Use of a comminution device with less propensity for fines formation (e.g. cône crusher or rod mill or minerai sizer or vertical shaft impactor), this silt content would reduce further.

Claims

1. An integrated process for recovering value metals from ore, including the steps of:

a) comminution of the ore in a comminution device,

b) classification of the comminuted ore in a classification device to obtain a classified fraction suitable for further comminution, a classified fraction suitable for coarse flotation with a particle size of greater than 150 micron up to 1000 micron, and classified fraction suitable for fine flotation with a particle size of less than 150 micron;

c) subjecting the fraction suitable for coarse flotation to coarse flotation to obtain an intermediate concentrate and a coarse sand residue with a particle size of greater than 150 micron up to 1000 micron;

d) dewatering the coarse sand residue to obtain a dewatered coarse residue;

e) grinding the oversize intermediate concentrate to a size suitable for fine flotation;

f) subjecting the fractions suitable for fine flotation to fine flotation and obtaining a fine tailings;

g) thickening the fine tailings to obtain thickened fine tailings; and

h) blending the dewatered coarse residue with the thickened fine tailings to obtain a blend wherein the blend contains a ratio of 0.5 to 0.7 coarse residue to 0.5 to 0.3 fine tailings, by mass, and dry stacking the blend thereby to obtain a stacked heap.

2. The process claimed in claim 1, wherein the blend contains from 10% up to 30% by mass thickened fine tailings, and from 70% to 90% by mass dewatered coarse residue.

3. The process claimed in claim 1, wherein the blend contains a ratio of 0.6 coarse residue to 0.4 fine tailings, by mass.

4. The process claimed in claim 1 wherein comminution of the ore at step a) is carried out in closed circuit with coarse classification.

5. The process claimed in claim 1, wherein the comminution device has a Schumann modulus that minimises the génération of fines.

6. The process claimed in claim 1, wherein, in step b), the classification device has a sharp partition curve with an alpha value greater than 3.

7. The process claimed in claim 1, wherein, in step b), the classification device has a sharp partition curve with an alpha value greater than 5.

8. The process claimed in claim 6, wherein the classification device is a screen or hydraulic classifier.

9. The process claimed in claim 1, wherein the comminution device is operated so that the silt content formed in comminution of step a) is less than 25% by mass of the ore.

10. The process claimed in claim 9, wherein the silt content formed in comminution of step

a) is less than 20% by mass of the ore.

11. The process claimed in claim 10, wherein the silt content formed in comminution of step

a) is less than 15% by mass of the ore.

12. The process claimed in claim 1, wherein at step a) the ore is ground to a size required for exposure of at least 85% of the values in the ore being processed.

13. The process claimed in claim 12, wherein at step a) the ore is ground to a size required for exposure of greater than 90% of the values in the ore being processed.

14. The process claimed in claim 1, wherein at steps a) and b) the ore is ground and classified to a particle size range of greater than 200 micron up to 800 micron.

15. The process claimed in claim 14, wherein at steps a) and b) the ore is ground and classified to a particle size range of greater than 200 micron up to 500 micron.

16. The process claimed in claim 1, the classified fraction suitable for recycling, in step b), has particles over a maximum size selected within the range of 350 to 1000 micron.

17. The process claimed in claim 16, wherein the classified fraction suitable for recycling is recycled for further comminution.

18. The process claimed in claim 1, wherein undersize particles less than 150 micron in size from the classification device are subjected to further classification in a second classification device, and a separated fines fraction is subjected to either fine grinding at step e), or to fine flotation at step f).

19. The process claimed in claim 1, wherein, at step c) the fraction suitable for coarse flotation has a particle size of greater than 150 micron up to 700 micron.

20. The process claimed in claim 1, wherein, in step c), the mass of the intermediate concentrate is less than 25% of the feed.

21. The process claimed in claim 20, wherein, in step c), the mass of the intermediate concentrate is less than 20% of the feed

22. The process claimed in claim 21, wherein, in step c), the mass of the intermediate concentrate is less than 15% of the feed.

23. The process claimed in claim 1, wherein the intermediate concentrate from step c) is directed to a regrind and classification process in step e), which is operated to produce the optimum size distribution for fine flotation of 20 to 125 micron, where the mass of silt is constrained to less than 50% of the mass of the feed to regrind.

24. The process claimed in claim 23, wherein the mass of silt is constrained to less than 40% of the mass of the feed to regrind.

25. The process claimed in claim 24, wherein the mass of silt is constrained to less than 30% of the mass of the feed to regrind.

26. The process claimed in claim 1, wherein the comminution device has a high Schumann modulus to minimise the génération of silt during comminution.

27. The process claimed in claim 26, wherein the material flows through the comminution and classification equipment is configured to maximize the rejection of liberated gangue as a coarse sand residue.

28. The process claimed in claim 1, wherein the coarse sand residue in step c) has a hydraulic conductivity higher than 1 cm/sec.

29. The process claimed in claim 1, wherein the coarse sand residue in step c) has a hydraulic conductivity higher than 0.1 cm/sec.

30. The process claimed in claim 1, wherein the coarse sand residue in step c) has a hydraulic conductivity higher than 0.01 cm/sec.

31. The process claimed in claim 1, wherein the coarse sand residue in step c) contains more than 60% by weight of the gangue présent in the ROM ore.

32. The process claimed in claim 1, wherein the coarse sand residue is dewatered to about 8 to 12% water by weight.

33. The process claimed in claim 32, wherein the coarse sand residue is dewatered to about 10% water by weight.

34. The process claimed in claim 1, wherein water in the thickened fine tailings in step g) is reduced to 35 to 45% water by weight.

35. The process claimed in claim 34, wherein water in the thickened fine tailings in step g) is reduced to about 40% water by weight.

36. The process claimed in claim 1, wherein an upper classification size in step b) is increased beycnd that for optimum recovery in coarse flotation in step c).

37. The process claimed in claim 36, wherein an upper classification size in step b) is up to a maximum size of 0.7 to 1.5 micron.

38. The process claimed in claim 37, wherein coarse flotation residue from step c) is further classified to separate a coarser middlings fraction, with a size range from 150 - 600 micron, and a middlings fraction is stored for reprocessing later in the mine life.

39. The process claimed in claim 1, wherein the residues from coarse flotation and fine flotation are recombined, and then subsequently reclassified to provide a course sand which is dewatered and fine tailings that are thickened, and the dewatered course sand and thickened tailings are combined to provide said blend.