NZ736163B2 - Pyrolysis apparatus and method - Google Patents

Abstract

The present invention relates to a pyrolysis apparatus comprising a pyrolysis chamber have a first end and a second end, a feed inlet connected adjacent the first end of the pyrolysis chamber, a biochar outlet connected adjacent the second end of the pyrolysis chamber, a gas outlet in fluid communication with the pyrolysis chamber and located adjacent the first end, and one or more gas injection ports located adjacent the second end. The pyrolysis chamber and feed inlet further comprise centreless screw conveyors. The present invention alleviates the problems associated with dust, oils and tars being present in the generated syngas. The present invention can also be used in a method of continuously processing biomass. ation with the pyrolysis chamber and located adjacent the first end, and one or more gas injection ports located adjacent the second end. The pyrolysis chamber and feed inlet further comprise centreless screw conveyors. The present invention alleviates the problems associated with dust, oils and tars being present in the generated syngas. The present invention can also be used in a method of continuously processing biomass.

Description

W0 2016!168894 PYROLYSIS APPARATUS AND METHOD FIELD OF THE INVENTION The present invention relates to the field of pyrolysis. More particularly, the invention relates to an apparatus and a method for the pyrolysis and processing of biomass.

BACKGROUND TO THE INVENTION Biomass is ical material which may be derived from recently living organisms including plant and animal material. Examples of als from which biomass can be derived are wood from forests, material left over from agricultural and forestry processes, and organic wastes derived from humans, industrial ses and animals. Biomass may be used as a renewable source of fuel to produce heat or electricity. The composition of s is largely carbon, hydrogen and oxygen. Biomass may also be employed as a feedstock for other fuels, including the production of syngas, via its pyrolysis.

Pyrolysis is the thermochemical decomposition of organic material at ed temperatures. Pyrolysis should occur in an atmosphere absent of oxygen (or reactive gas) to ensure that the organic material does not undergo combustion. At these elevated atures and in the absence of oxygen the organic material undergoes a chemical decomposition to form syngas and the by-product, biochar. Biochar can be used to generate energy or can, alternatively, be used as a soil amendment agent. r useful characteristic of the pyrolysis of organic material is that potential greenhouse emissions remain in the solid state (biochar) and are ore not released into the here, making it a more environmentally friendly process.

A problem currently encountered in pyrolysis is that dust, oils and tars are often present in the ted syngas. As a result, the syngas will need to be ed before it can be used. Another problem ated with large scale pyrolysis is that it is difficult to continuously pyrolyze biomass. Many pyrolysis systems are sequential systems, whereby biomass is loaded into a chamber, pyrolysis is initiated, syngas is generated and the chamber opened to remove W0 2016!168894 the biochar before a new biomass load can then be added. Disadvantages to this system include syngas being lost when the chamber is opened, the time required for reloading the chamber and the poor energy efficiency due to frequent cooling and ramping up of heat. rmore, biomass with high moisture content can be difficult to pyrolyze because additional heat energy is ed to remove the moisture before pyrolysis can occur. As such, high moisture t biomass is required to be separately dried or treated prior to introduction to the pyrolysis chamber.

Due to this requirement, many high moisture t biomasses are overlooked for use in pyrolysis when low moisture content biomass is accessible. Due to this, many types of s are overlooked as possible fuel sources and their energy value is not ed.

It would be advantageous to provide for a pyrolysis apparatus and method of use thereof that addresses one or more of these drawbacks or provides a useful commercial alternative.

SUMMARY OF THE ION In a first aspect, although it need not be the only or indeed the broadest form, the invention resides in a pyrolysis tus comprising: a. a pyrolysis chamber having a first end and a second end and comprising a centreless pyrolysis screw conveyor extending from the first end at least partially towards the second end of the pyrolysis chamber; b. a feed inlet adjacent the first end of the pyrolysis chamber; c. a r outlet adjacent the second end of the pyrolysis chamber; and d. a gas outlet in fluid communication with the pyrolysis chamber and located adjacent the first end, wherein the feed inlet comprises a centreless feed screw conveyor and the second end of the sis chamber is free of gas outlets.

W0 2016!168894 In an embodiment, the sis apparatus further comprises at least one gas ion port adjacent the second end.

In one embodiment, all gas outlets in fluid communication with the pyrolysis chamber are located substantially adjacent the first end.

In one embodiment, the centreless pyrolysis screw conveyor extends from the first end to at least about one third of the way along the pyrolysis chamber towards the second end.

In a further embodiment, the centreless pyrolysis screw conveyor extends from the first end to at least about half of the way along the sis r towards the second end.

Preferably, the centreless pyrolysis screw conveyor extends substantially between the first end and the second end.

In one ment, the centreless pyrolysis screw conveyor has an aperture or bore forming the centre of the centreless pyrolysis screw conveyor and this aperture or bore is substantially free from any structure or device. That is, the re or bore of the centreless pyrolysis screw conveyor is clear and/or can be described as a void which is defined by the flights of the centreless sis screw conveyor.

In certain embodiments, there is a spacing between an end of the centreless feed screw conveyor and the pyrolysis chamber.

In one embodiment, the biochar outlet comprises a centreless biochar screw conveyor.

In certain embodiments, there is a spacing between an end of the centreless biochar screw conveyor and an exit of the biochar outlet.

In another embodiment, the pyrolysis apparatus further comprises a biochar valve.

Preferably, the r valve is located at the end of the biochar outlet that is furthest away from the pyrolysis chamber. wo 2016;168:394 In a further embodiment, the pyrolysis apparatus further ses a biomass feed hopper in ication with the feed inlet.

In one embodiment, the pyrolysis apparatus further comprises a transfer chute extending between the feed inlet and the sis chamber.

In one embodiment, the pyrolysis r comprises an expansion chamber which the transfer chute and gas outlet open into.

In a second , the invention resides in a method of processing biomass including the steps of: a. providing a pyrolysis apparatus comprising i. a pyrolysis chamber having a first end and a second end and comprising a centreless pyrolysis screw conveyor extending from the first end at least partially towards the second end of the pyrolysis chamber; ii. a feed inlet adjacent the first end of the pyrolysis chamber; iii. a biochar outlet adjacent the second end of the pyrolysis chamber; and iv. a gas outlet in fluid communication with the pyrolysis chamber and located adjacent the first end, wherein the feed inlet comprises a centreless feed screw conveyor and the second end of the pyrolysis r is substantially free of gas outlets; b. introducing biomass from the feed inlet into the first end of the pyrolysis r; c. moving the biomass from the first end of the pyrolysis chamber to the second end of the pyrolysis chamber to pyrolyze the biomass and produce syngas and biochar; d. removing the biochar from the pyrolysis chamber through the biochar outlet; and W0 2016!168894 e. causing the syngas to move in a direction generally from the second end to the first end to be removed through the gas outlet, to thereby process the biomass.

In one embodiment, the method further es the step of forming a biomass plug between the feed inlet and the pyrolysis chamber.

In one embodiment, the method further es the step of forming a biochar plug at an exit of the biochar outlet.

In one embodiment, the method is a method for the continuous processing of biomass.

In certain embodiments, the pyrolysis may be carried out at a temperature of between about 40090 to about 70090.

The method may be carried out with a pressure of less than about 250kPa, preferably less than 200kPa, even more preferably less than about 150kPa, still more ably less than about 100kPa or less than about 50kPa.

Further features and advantages of the present invention will become apparent from the following detailed description.

BRIEF DESCRIPTION OF THE DRAWINGS To assist in tanding the invention and to enable a person skilled in the art to put the invention into practical effect, preferred ments of the invention will be described by way of example only with reference to the accompanying drawings, in which: FIG 1 is a plan view of the pyrolysis apparatus; FIG 2 is a process of forming a biomass plug; and FIG 3 is a process of forming a biochar plug.

DETAILED DESCRIPTION OF THE INVENTION Embodiments of the present invention reside primarily in a pyrolysis tus and a method of processing s to produce syngas and biochar.

Accordingly, the apparatus and method steps have been illustrated in concise schematic form in the drawings, showing only those specific details that are W0 68894 necessary for understanding the embodiments of the present invention, but so as not to obscure the disclosure with excessive detail that will be readily apparent to those of ordinary skill in the art having the benefit of the present description.

In this specification, adjectives such as first and second, and the like may be used solely to distinguish one element or action from another element or action without necessarily requiring or ng any actual such relationship or order. Words such as “comprises” or “includes” are intended to define a non- exclusive inclusion, such that a method or apparatus that comprises a list of elements does not include only those elements but may include other ts not expressly listed, ing elements that are inherent to such a method or apparatus.

The term “biomass”, as used herein, refers to renewable organic materials which may be used as fuels. Specific biomasses include, by way of non-limiting example, forestry ts, agricultural products, animal matter, straw, wood chips and vine clippings.

The term “centreless screw conveyor”, as used herein, refers to a mechanism that uses a rotating helical screw blade, which may be ed to as a flighting, to move granular or liquid materials along a pathway. The spiral coil is driven at one end and free at the other end and lacks the central shaft of traditional screw conveyors. The term as d herein is used in the context of centreless screw ors being used to move material through a pyrolysis chamber “centreless sis screw conveyor”, to introduce material to said chamber “centreless feed screw conveyor”, and to accept and remove pyrolyzed material from said chamber “centreless biochar screw conveyor”.

The term ‘about’, as used here, means that the amount is nominally the number following the term ‘about’ but the actual amount may vary from this precise number to an unimportant degree.

The term ‘biochar’, as used herein, can be interchanged with the term ‘charcoal’.

Referring to FIG 1 there is shown a sis apparatus. The pyrolysis W0 2016!168894 apparatus 100 comprises a sis chamber 110 having a first end 111 and a second end 112. A feed inlet 120 is located lly adjacent the first end 111 and a biochar outlet 130 is located generally adjacent the second end 112. A gas outlet 140 is in fluid communication with the hollow interior of the pyrolysis chamber 110 and is located substantially adjacent the feed inlet 120 and, hence, adjacent the first end 111.

The pyrolysis chamber 110 is preferably in the shape of a pipe or tube and has a hollow or or bore 113 along its length. The sis chamber 110 may be constructed from mild steel or other materials suitably resistant to high temperatures. In one ment, the pyrolysis r 110 may have a length which is about 8 to about 12 times greater than its diameter, preferably about 10 times its diameter. The pyrolysis chamber 110 advantageously comprises a centreless pyrolysis screw or 114 which, in the embodiment shown, extends along the length of the bore 113. The centreless pyrolysis screw or 114 is independently rotatable relative to the pyrolysis chamber 110.

The centreless pyrolysis screw conveyor 114 acts to move biomass along the pyrolysis chamber 110 from the first end 111 to the second end 112. The centreless pyrolysis screw conveyor 114 provides distinct advantages in operation over a traditional shaft screw conveyor.

Traditional screw conveyors or paddles move biomass along but do not contribute towards more dense packing of that biomass. This means that any voids or es which are typically formed within the biomass during loading are largely maintained. Furthermore, traditional screw conveyors or paddles require more energy to move material compared to the centreless screw conveyor. The less screw conveyor requires less energy because there is less friction between the centreless screw conveyor and the material being moved. This improves the efficiency of the pyrolysis tus 100. Further to this, the use of a centreless screw conveyor reduces the likelihood of material (biomass or biochar) jamming between the outside of the centreless screw conveyor and the associated wall by virtue of the material being able to tumble and fall into the void of the centreless screw or. Further to this, the rotation speed of the centreless screw conveyors can also be relatively slow and still be effective, W0 2016!168894 which also s the wear on the screw.

The present centreless pyrolysis screw conveyor 114, not being provided with a central shaft, provides more space for the constant tumbling and reforming of the biomass bed and has been found to advantageously form a more dense bed with vely few voids or es. This provides significant advantages in operation in that the dense biomass bed acts as an excellent countercurrent heat exchange system between the biomass at the first end of the pyrolysis chamber 110 and the heated syngas, and this is discussed in more detail after. In certain ments, the syngas is cooled from pyrolysis temperatures (40090-70090) to 6090 to 8090 and, at the same time, the introduced biomass is heated from ambient temperatures to drying temperatures and eventually to the pyrolysis temperature. This heat exchange therefore results in the l of moisture in the s. The dense biomass bed produced by the tumbling effect additionally provides significant advantages in terms of the filtration of oils, tars and particles from the syngas. In one embodiment, the centreless pyrolysis screw conveyor 114 forms a densely packed biomass.

The relative e of voids and cavities in the biomass es the syngas to te, in a serpentine pathway, through the densely packed biomass which achieves significant heat exchange and filtration effects, and this is discussed in more detail hereinafter. Ultimately, the present centreless pyrolysis screw conveyor 114 provides for a higher overall energy efficiency and much cleaner syngas product which can be extracted and used in subsequent operations with no or minimal further cleaning operations. The resultant biochar and syngas are of commercial quality and quantity, and do not require further cation. This results in a more efficient process with a high output of useful products. For instance, a tonne of blue gum wood chips processed through the pyrolysis apparatus 100 produces syngas with an energy density of about 5 to about 9 Mj/m3 in the amount of about 5 to about 7 Gj/tonne of biomass (dry basis), and n about 250 Kg and about 350 Kg of biochar at greater than 85% fixed carbon.

It will be iated that the dense packing of biomass is only truly W0 68894 beneficial in the portion of the pyrolysis chamber 110, closest to the first end 111, prior to pyrolysis occurring. The biomass is progressively dried and then pyrolysed as it moves through the pyrolysis zone by which point it has been reduced to about a third of its original volume and so no longer plays a role in filtration and purification of the . Therefore, in one embodiment, the centreless pyrolysis screw conveyor 114 merely extends from the first end 111 at least partially towards the second end 112 of the pyrolysis chamber 110. In certain embodiments, the centreless pyrolysis screw conveyor 114 extends from the first end 111 to at least about one third of the way along the pyrolysis chamber 110 towards the second end 112. It may be that the centreless pyrolysis screw conveyor 114 simply ends at this point and biomass is pushed further along by the constant movement of more biomass being supplied by the centreless pyrolysis screw conveyor 114. In a r embodiment, the centreless sis screw conveyor 114 extends from the first end 111 to at least about half of the way along the pyrolysis chamber 110 s the second end 112. Preferably, the centreless sis screw conveyor 114 extends substantially n the first end 111 and the second end 112. This embodiment is preferred as the advantages in packing of the biomass are obtained in the first third or so of the length of the pyrolysis chamber 110 (from the first end 111) and it is simpler in terms of construction to simply continue this conveyor design as far as is required to efficiently move the biomass through the pyrolysis zone and deliver it as close to the biochar outlet 130 as is required.

In one embodiment, the re or bore forming the centre of the centreless pyrolysis screw conveyor 114 is substantially free from any structure or device such as, for example a heating rod, gas injecting lancet or the like.

That is, the re or bore of the centreless pyrolysis screw conveyor 114 is clear and/or can be described as a void which is defined by the flights of the centreless pyrolysis screw conveyor. If a structure was d through the aperture or bore of the centreless pyrolysis screw or 114 then the advantages discussed above could not be realized to the same extent.

It will be appreciated that the location of the feed inlet 120, biochar outlet 130, and gas outlet 140 in relation to the pyrolysis chamber 110 is important to W0 2016!168894 achieve the abovementioned advantages. Further to this, the formation of the s plug 124 and biochar plug 133, discussed hereinafter, are also important to the present invention. The combination of these features result in the syngas being forced through the densely packed biomass, in the pyrolysis chamber 110, to exit through the gas outlet 140, and s in syngas substantially free of particulate matter. This densely packed biomass effectively filters the syngas of particular matter.

The pyrolysis chamber 110 is preferably a single chamber as this is more compact and utilizes fewer components. The use of fewer components s the risk of possible mechanical failures in the pyrolysis apparatus 100. In this regard, only a single pyrolysis chamber 110 is required to achieve rcurrent flow of the . However, it will be appreciated by the person skilled in the art that multiple pipes or tubes can be used as long as countercurrent flow through the dense plug of biomass is achieved.

Condensates are formed within the pyrolysis chamber. These condensates include tars and oils and can cause fouling of the pyrolysis apparatus 100, the gas outlet 140 and downstream machinery using the syngas, such as boilers or engines. A problem with prior art pyrolysis apparatus is that significant quantities of oils and tars and particulate matter remain in the syngas leaving the pyrolyser. As such, the syngas from prior art pyrolysis apparatus may be unsuitable for use in modern high efficiency boilers, gas engines or gas turbines which require very low levels of particulates, oils and tars. Such syngas requires expensive purification systems.

The present pyrolysis apparatus 100 ates this problem through the continuous countercurrent ing of the exiting syngas h the incoming densely packed s. Particulates, oils and tars are captured by the s and moved towards the pyrolysis zone. Very low levels of ulates, oils and tars remain in the syngas as it exits the pyrolysis apparatus 100 at gas outlet 140 (order of 10-100 mg/m3).

The countercurrent flow of the syngas, as previously mentioned, heats and dries the biomass as it travels toward the gas outlet 140. The syngas is effectively filtered by the biomass whilst at the same time transferring thermal W0 2016!168894 energy to the biomass. Another advantage of this countercurrent flow is that it maintains a large surface area contact with the biomass and allows for efficient thermal energy transfer.

In this regard, a heater or heating element, such as a lancet as may be used in the prior art, only results in a relatively small heat transfer surface area being created between the biomass and heat source, and does not facilitate efficient thermal energy transfer. The flow-on effects from this are slower conversion of biomass to biochar and syngas, more fouling of the sis apparatus and requiring faster rotation of the screw to ensure that the biomass is constantly being exposed to the heat source.

However, it will be appreciated that the main advantage of the present invention lies in the countercurrent flow of the syngas through the y packed biomass. In this regard, it will be appreciated that the pyrolysis apparatus 100 can include a heating t which heats the biomass, near the second end 112 of the sis chamber 110, to pyrolysis atures. In this uration, it will iated that the countercurrent flow of syngas will still be achieved and syngas substantially free of particulate matter is obtained.

In this embodiment, the heating element or g elements may e thermal energy from any electrical source. The thermal energy generated by the heating element(s) may be supplied by electricity, any other suitable energy source or from solar l . It would be advantageous to source this thermal energy from a renewable resource as it is more environmentally friendly.

The centreless pyrolysis screw conveyor 114 may be made of stainless steel and other appropriate materials as would be understood in the art. The speed at which it rotates can be controlled to move biomass through at an optimal speed, which may vary depending on the nature and moisture content of the biomass, whereby the biomass is fully pyrolysed without unnecessary onal time in the pyrolysis chamber 110.

The feed inlet 120 is generally adjacent to the first end 111 of the pyrolysis chamber 110. In one embodiment, the feed inlet 120 is only located W0 2016!168894 adjacent the first end 111. In another embodiment, the feed inlet 120 is located within a third of the length of the pyrolysis chamber 110 from the first end 111 of the pyrolysis chamber 110. In a r embodiment, the feed inlet 120 is located within a quarter of the length of the pyrolysis chamber 110 from the first end 111 of the pyrolysis chamber 110. The feed inlet 120 has a hollow interior or bore 121. The feed inlet 120 further comprises a centreless feed screw conveyor 122 along the length of the bore 121. The centreless feed screw or 122 is independently rotatable to the feed inlet 120 and is of a similar design to the centreless pyrolysis screw conveyor 114.

The rotational speed of the centreless feed screw conveyor 122 can be varied. It will be appreciated by a person skilled in the art that the rotational speed of the centreless feed screw conveyor 122 determines the rate at which biomass is uced into the pyrolysis chamber 110 and, hence, into the centreless pyrolysis screw or 114. The speed of rotation of the centreless feed screw conveyor 122 will be adjusted to fit with the speed of rotation of the centreless pyrolysis screw conveyor 114. This adjustment is preferably made through an automated system whereby adjustment of the speed of rotation of the centreless pyrolysis screw conveyor 114 to suit the biomass being provided automatically results in an appropriate adjustment in the speed of rotation of the centreless feed screw conveyor 122. Particularly, the e of biomass flow n the centreless pyrolysis screw conveyor 114 and the centreless feed screw or 122 may be maintained by sensing the torque of the centreless feed screw conveyor 122 which is sensitive to the level of biomass therein. This torque measurement is then used to fine tune the speed of delivery. In one embodiment, the rate of biomass introduction to the pyrolysis chamber 110 is controlled by stopping and restarting the rotation of the centreless feed screw conveyor 122 by sensing the torque of the centreless feed screw conveyor.

In preferred embodiments, there is a spacing in the bore 121 of the feed inlet 120 between an end of the centreless feed screw conveyor 122 adjacent the pyrolysis chamber 110, and the sis chamber 110. A particular advantage of the present ive tus is that the centreless feed screw or 122 is capable of generating a biomass plug 124 in this spacing or gap W0 2016!168894 formed between the end of the centreless feed screw conveyor 122 closest the pyrolysis chamber 110 and the point of inlet to the pyrolysis chamber 110. The lack of presence of structure of the centreless feed screw conveyor 122 in this space results in the formation of a dense biomass plug 124. This biomass plug 124 has been found to be ntially gastight and so it is an efficient means of keeping syngas within the pyrolysis apparatus 100 without the need for any additional ted apparatus components for this purpose. A key advantage over the prior art is that, since the biomass is itself being used as the gastight seal, and it is constantly renewing itself through new biomass being introduced, the pyrolysis apparatus 100 is able to operate on a continuous basis rather than a batch basis. The advantages in continuous operation are clear and this is enabled in the present apparatus 100 by the use of the less feed screw conveyor 122. It has been found that by leaving a space in the bore 121 of the feed inlet 120 between the centreless feed screw conveyor 122 and the pyrolysis r 110, the biomass plug 124 is allowed to form in this space to build up and become denser and deeper thereby improving the sealing quality. In one embodiment, the surface of the feed inlet 120 adjacent the biomass plug 124 may be roughened, marked or provided with a higher friction coating or material to increase the grip of the biomass being forced h and thereby assist in forming and maintaining the density of the biomass plug 124. In a further ment, the s plug 124 can be ed to be deeper by increasing the length of the feed inlet 120 or by having the end of the less feed screw conveyor 122 a r ce from the entrance to the pyrolysis chamber 110 and so improve the ability of the plug to form and “self-hold”. In one embodiment, a biomass plug 124 is formed in the feed inlet 120. In another embodiment, the biomass plug 124 is formed in the feed inlet 120 adjacent the pyrolysis chamber 110. In one embodiment, the s plug 124 substantially prevents the pyrolysis chamber 110 and the feed inlet 120 being in fluid communication.

It has been found that this approach to biomass plug 124 formation and maintenance requires less torque, and so energy, from the centreless feed screw conveyor 122. It also results in a more reliable seal which is less inclined to blow out due to gas build up within the pyrolysis chamber 110.

W0 2016!168894 The centreless pyrolysis screw conveyor 114 lies in a horizontal plane.

However, it will be appreciated that the pyrolysis r 110 may deviate from this plane so long as it does not materially affect the workings of the pyrolysis chamber 110. The feed inlet 120 may introduce biomass to the pyrolysis chamber 110 at any angle as the biomass plug 124 is formed by friction n the biomass with the feed inlet 120, and the absence of flights of the centreless feed screw conveyor 122, in that section. In an embodiment, the angle formed n the feed inlet 120 and the pyrolysis chamber 110 is suitably between 09 and 909, more preferably between 09 and 459 and most preferably 09 or 1809. In other words, it is most preferable to have the feed inlet 120 connected to the pyrolysis r 110 in the same plane.

In one embodiment, the feed inlet 120 may be ted to the pyrolysis chamber 110 via a transfer chute (not shown). The transfer chute assists in allowing the biomass plug 124 components to expand and fragment, and also provides a small surge chamber that ensures the entry to the centreless pyrolysis screw conveyor 114 is continuously ‘flooded’ with fresh biomass which maintains a full flighting in the centreless pyrolysis screw conveyor 114.

A biomass feed hopper 123 is in communication with the feed inlet 120.

Biomass can be introduced to the feed inlet 120 through the biomass feed hopper 123. The s is then moved to the first end 111 of the pyrolysis chamber 110 by the centreless feed screw conveyor 122. For larger ses the biomass feed hopper 123 may receive biomass material from a diminution device (not shown) to reduce the size of the biomass. Specific devices include a shredder, ng drum chopper, tub grinder and hammer mi”. Other suitable mechanisms for reducing the size of the biomass matter will be evident to a person skilled in the art. It will be appreciated that not all biomass will need to be reduced in size. To achieve the full advantages of the compacting effect in the biomass plug 124 and the gas purification in the pyrolysis r 110 it is preferable if the biomass is less than about 25 mm in diameter. This allows for ease of tumbling and ing within the biomass thereby affording appropriate density for the operations y described.

The pyrolysis chamber 110 may further comprise at least one gas W0 2016!168894 2016/050286 injection port 115. The at least one gas injection port 115 is located generally towards the second end 112 of the pyrolysis chamber 110 in the region where pyrolysis will be occurring. The at least one gas ion port 115 injects gas into the pyrolysis r 110 to initiate a minimum required level of combustion of biomass to maintain a suitable temperature range. The gas injected into the sis chamber 110 can be any gas that is e of initiating tion.

Suitable gases include oxygen or any oxygen containing gas, such as atmospheric air. ore, combustion of biomass will occur on moving from the first end 111 towards the second end 112 of the pyrolysis chamber 110 and this leads to a temperature gradient being formed between the first end 111 and the second end 112. The pyrolysis chamber 110 is insulated to prevent loss of the heat generated during pyrolysis.

The at least one gas injection port is located generally toward the second end so that a temperature gradient is formed in the pyrolysis r 110. As previously mentioned, the densely packed biomass is only truly beneficial in the portion of the pyrolysis chamber 110 closest the first end 110. If the at least one gas injection port 115 is located throughout the pyrolysis chamber 110 then the biomass will reduce in volume and not form the densely packed biomass. As such, the at least one gas injection port is located toward the second end 112 so that pyrolysis, and thus syngas tion only occurs towards the second end 112. This forces the hot syngas in a countercurrent direction. In one embodiment, the at least one gas injection port 115 is only located adjacent the second end 112. In another embodiment, the at least one gas injection port 115 is located within a third of the length of the pyrolysis chamber 110 from the second end 112 of the sis r 110. In a further embodiment, the at least one gas injection portion 115 is located within a r of the length of the pyrolysis chamber 110 from the second end 111 of the pyrolysis chamber 110.

This also results in thermal energy gradually being transferred to the biomass and a temperature gradient is formed. The temperature gradient allows pyrolysis to occur adjacent the second end 112 whilst maintaining densely packed biomass near the first end. In one embodiment, a temperature gradient is formed in the pyrolysis chamber.

W0 2016!168894 2016/050286 It will be appreciated by those skilled in the art that other s may be used to introduce gas into the pyrolysis chamber 110. Another suitable method may be the use of a lance positioned to introduce a gas into the pyrolysis chamber 110 to initiate combustion of the biomass.

The temperature at the second end 112 is ly greater than about 20090, more suitably between about 20090 and about 100090, preferably between about 40090 and about 60090, and most ably between 4509 and about 55090. It will be appreciated that the pyrolysis apparatus 100 has been described for use in pyrolysis for convenience. It will be appreciated by the person skilled in the art that the pyrolysis apparatus 100 and method described herein can be equally applied to torrefaction and gasification.

For instance, when the pyrolysis tus is applied to torrefaction, the temperature of the second end 112 is suitably greater than about 15090, more suitably between about 15090 and about 50090, ably between about 20090 and about 40090 and most preferably between 2009 and about 35090.

Alternatively, when the pyrolysis tus is used for gasification, the temperature of the second end 112 is suitably greater than about 40090, more suitably between about 50090 and about 150090, preferably between about 70090 and about 100090.

The temperature of the pyrolysis chamber 110 is monitored by multiple sensors which will feed back to a control system and control the amount of gas injected by the at least one gas injection port 115 and/or the lance, which in turn determines how much heat is generated from combustion and so the temperature of the second end 112 of the pyrolysis chamber 110.

The biochar outlet 130 is d at the second end 112 of the pyrolysis chamber 110, and further comprises a hollow interior or bore 131 and a centreless biochar screw conveyor 132. In one embodiment, the biochar outlet 130 is only located adjacent the second end 112. In another embodiment, the biochar outlet 130 is located within a third of the length of the pyrolysis chamber 110 from the second end 112 of the pyrolysis chamber 110. In a further embodiment, the biochar outlet 130 is located within a quarter of the length of the pyrolysis r 110 from the second end 112 of the pyrolysis chamber W0 2016!168894 110. The centreless r screw conveyor 132 is d along the length of bore 131 and is independently rotatable relative to the biochar outlet 130. The rotational movement of the centreless biochar screw conveyor 132 removes the biochar from the pyrolysis chamber 110 h an exit of the biochar outlet 130.

In one preferred ment, there is a spacing between an end of the centreless biochar screw conveyor 132 furthest from the pyrolysis r 110 and an exit of the biochar outlet 130. This will encourage formation of a biochar plug 133 in the space between the end of the centreless biochar screw conveyor 132 and the exit of the biochar outlet 130. All of the comments made for the feed inlet 120 apply mutatis mutandis to the biochar outlet 130 ing the approach to forming the biochar plug 133 and the optional use of an increased friction surface in the region adjacent the exit of the biochar outlet 130. The rotational speed of the centreless biochar screw conveyor 132 can be varied as described previously for the other conveyors. It will be appreciated by a person skilled in the art that the rotational speed of the centreless biochar screw conveyor 132 determines the rate at which biochar is removed from the pyrolysis chamber 110 and so will be automatically adjusted based on the rate set for the centreless pyrolysis screw conveyor 1 14. In one embodiment, a biochar plug 133 is formed in the biochar outlet 130. In r embodiment, the biochar plug 133 is formed in the space n the end of the centreless r screw conveyor 132 and the exit of the biochar outlet 130. In one ment, the r plug 133 prevents the biochar outlet 130 being in fluid communication with the external atmosphere.

The pyrolysis chamber 120 may introduce biochar to the biochar outlet 130 at any angle as the biochar plug 133 is formed by friction between the biochar with the biochar outlet 130, and the absence of flights of the centreless biochar screw conveyor 132, in that n. In an embodiment, the angle formed between pyrolysis chamber 110 and the biochar outlet 130 is suitably between 09 and 909, more preferably between 09 and 459 and most preferably 09 or 1809.

In other words it is most preferably to have the biochar outlet 130 connected to the pyrolysis chamber 110 in the same plane.

In FIG 1, the biochar outlet 130 extends across the pyrolysis chamber W0 2016!168894 110. The biochar that is formed in the second end 112 of the pyrolysis chamber 110 falls into the flights of the centreless biochar screw conveyor 132. Water or recovered condensate is sprayed onto the biochar as it travels along the biochar outlet 130 to cool and passivate the biochar and to enable the correct moisture content to form the biochar plug 133. Therefore, as the biochar travels along the biochar outlet 130, it is cooled and the re content increases so that the resultant biochar is safe to handle and store.

The gas outlet 140 has a bore 141 along its length and may be a standard gas transfer pipe or tube. The gas outlet 140 is in fluid communication with the pyrolysis chamber 110 and removes syngas from the pyrolysis chamber 110. In one ment, the gas outlet 140 and transfer chute sits within an expansion r. The expansion chamber reduces the gas ty of the syngas to age dis-entrainment of any biomass particles and condensate droplets. In one ment, the gas outlet 140 further comprises a basket of biomass that can be replaced from time to time which further ensures that no particulate matter is present in the syngas.

In one embodiment, the gas outlet 140 is located only in the area adjacent the first end 111 of the pyrolysis chamber 110. In another embodiment, the gas outlet 140 is located within a third of the length of the pyrolysis chamber 110 from the first end 111 of the sis chamber 110. In a further embodiment, the gas outlet 140 is located within a quarter of the length of the sis chamber 110 from the first end 111 of the pyrolysis chamber 110. In one embodiment, the gas outlet 140 is located substantially adjacent the first end 111 of the pyrolysis chamber 110. In one embodiment, all gas outlets in fluid communication with the pyrolysis chamber 110 are located substantially adjacent the first end.

It will be iated by the person skilled in the art that more than one gas outlet 140 can be utilized in the present invention so long as these gas outlets 140 are located as bed hereinabove. In one embodiment, the pyrolysis apparatus comprises more than one gas . It will be appreciated that the gas outlet 140 is required to be placed before the pyrolysis zone and before the densely packed biomass to achieve the desired countercurrent flow, filtering of syngas and ent thermal energy transfer.

W0 2016!168894 One advantage to the apparatus 100 is that the s does not need to be dried prior to introduction to the pyrolysis chamber 110 so biomass with higher moisture content can therefore be utilized. Much of the sensible and latent heat in the syngas is transferred to the incoming biomass, resulting in drying the biomass. The re content of the biomass which may be utilised is suitably from 0% to 70%, more suitably from 0% to 50%, preferably from about 0% to 40%, and most preferably from about 0% to 30%. As discussed usly, the drying effect is ed by the temperature gradient set up when syngas is produced adjacent the second end 112 of the pyrolysis chamber 110 such that it is caused to move s the first end 111. The syngas is, of course, at a high temperature, having just been formed from the pyrolysis of the biomass, and as it passes through the newly entering biomass it heats that incoming biomass up and causes it to lose moisture. This has the additional benefit of cooling the syngas. Due, in part, to the effective packing of the biomass towards the first end 111 the s is intimately contacted with the syngas meaning an efficient er of heat is obtained and so higher moisture content biomass materials, which would typically be overlooked, or require separate drying processes, can be utilised.

In another embodiment, the pyrolysis apparatus 100 further comprises a biochar valve 134. The biochar valve 134 may comprise one or more valves in series. The biochar valve 134 may be connected to the exit of the biochar outlet 130. In one embodiment the biochar valve 134 may be a rotary valve such as a segment rotary valve. In this embodiment, biochar exits the pyrolysis chamber 110 and is removed by the centreless biochar screw conveyor 132. Water or condensate is added to the biochar, to cool it, while it is in contact with the centreless biochar screw conveyor 132 and after being delivered to the spacing the biochar plug 133 is formed. The biochar from the biochar plug 133 then , and passes through, the biochar valve 134 and into the external here where it may be deposited onto a conveyor belt or the like. The biochar valve 134 therefore provides a countermeasure for a potential failure of the biochar plug 133. In the event that the biochar plug 133 becomes too fluid due to ive addition of water or from condensate, the biochar plug 133 may W0 2016!168894 fail to maintain the biochar outlet 130 and external atmosphere in non-fluid ication and so, in this instance, the biochar valve 134 would assist.

In one embodiment, the biochar valve 134 is a rotary valve. The rotary valve may contain several segments which are sealed and as the t rotary valve rotates the segments ensure that the biochar outlet 130 and the external atmosphere are not in fluid communication. The segment rotary valve has at least 2 ts, preferably 5 or 6. In a preferred embodiment, the biochar valve 134 is a double rotary valve.

The pyrolysis apparatus can further comprise pressure sensors in the feed inlet 120, the pyrolysis chamber 110 and biochar outlet 130. These pressure sensors can be used to monitor the pressure in each section and ensure that the biomass plug 124 and biochar plug 133 do not fail due to excessive pressure entials. The pyrolysis apparatus 100 was equipped with pressure sensors and monitored during the process. It was found that there was a re drop of n about 10 and about 50 KPa n the pyrolysis zone and the biomass entry which is indicative of syngas filtration through the densely packed biomass.

Referring to FIG 2 there is shown a diagram of the feed inlet 120. In step (a) there is shown a centreless feed screw conveyor 122 and a biomass plug 124. As the centreless feed screw conveyor 122 rotates it continuously moves biomass toward the first end 111 of the pyrolysis chamber 110. As the centreless feed screw conveyor 122 rotates it also moves and adds more s to the biomass plug 124, which is formed in the space between the end of the centreless feed screw conveyor 122 nearest the pyrolysis chamber 110 and the pyrolysis chamber 110. In step (b) there is shown the centreless feed screw conveyor 122 and the biomass plug 124 which has had further biomass added.

As the centreless feed screw conveyor 122 rotates it adds more biomass to the biomass plug 124 and it simultaneous pushes the biomass plug 124 into the first end 111 of the pyrolysis r 110. Therefore, the biomass plug 124 is continually being expanded and pushed into the pyrolysis chamber 110 whilst ensuring that the pyrolysis r 110 is not in fluid communication with the feed inlet 120 thereby preventing the escape of syngas and the entrance of W0 2016!168894 undesirable amounts of air. In step (c) there is shown the leading end of the biomass plug 124 collapsing and being removed by the less sis screw conveyor 114; a process which is repeated in continuous operation.

Referring to FIG 3 there is shown a diagram of the r outlet 130. In step (a) there is shown the biochar outlet 130, the centreless biochar screw conveyor 132 and the biochar plug 133 formed in the space between the end of the centreless biochar screw 132 furthest from the pyrolysis chamber 110 and the exit of the biochar outlet 130. As the centreless biochar screw conveyor 132 rotates it moves the biochar from pyrolysis chamber 110 and adds it to the r plug 133, and thus into the biochar valve 134. In step (b) there is shown the centreless biochar screw or 132 and the biochar plug 133 which has had more biochar added. As the centreless biochar screw conveyor 132 rotates and adds more biochar to the biochar plug 133, it simultaneously pushes the biochar plug 133 out of the exit of the biochar outlet 130 and into the biochar valve 134. The r valve 134 rotates and ensures that the biochar outlet 130 is not in fluid communication with the external atmosphere. In step (c) there is shown the leading end of the biochar plug 133 being removed through the exit of the biochar outlet 130 and into r segment of the biochar valve 134. This process is continuously repeated.

In operation, it will be appreciated that biomass material, to be processed, is loaded into the biomass feed hopper 123. It may have optionally been reduced in size prior to loading into the hopper. The biomass is then moved through the feed inlet 120 by the centreless feed screw conveyor 122. The rotational movement of the centreless feed screw conveyor 122 moves the biomass towards the first end 111 of the sis chamber 110. There may be a spacing n an end of the centreless feed screw conveyor 122 and the first end 111 of the pyrolsis chamber 110. The centreless feed screw conveyor 122 adds biomass and results in the formation of the biomass plug 124 in the feed inlet 120 adjacent the pyrolysis r 110. The s plug 124 is dense and relatively absent of large air voids to thereby substantially prevent fluid communication between the pyrolysis chamber 110 and the feed inlet 120. The centreless feed screw conveyor 122 continuously adds biomass to the biomass W0 2016!168894 plug 124 and simultaneously pushes the biomass plug 124 into the pyrolysis chamber 110. This action of adding biomass to the biomass plug 124 maintains the biomass plug 124, while also introducing biomass into the first end 111 of the pyrolysis chamber 110.

The biomass from the s plug 124 is then moved from the first end 111 to the second end 112 of the pyrolysis chamber 110 by the centreless sis screw conveyor 114. The pyrolysis chamber 110 has at least one gas ion port 115 which injects gas to initiate combustion of a small n of the biomass to provide the necessary temperature for pyrolysis. As such the pyrolysis r 110 has a temperature gradient, increasing from the first end 111 to the second end 112.

The rotational movement of the centreless pyrolysis screw conveyor 114 constantly tumbles and repacks the s to remove air voids and so a dense volume of biomass is present at the first end 111 of the pyrolysis chamber 110.

This dense volume of s acts as a filter and heat exchanger, discussed herein. The centreless pyrolysis screw conveyor 114 continuously adds new s as it is simultaneously pushing the biomass towards the second end 112. As the biomass is moved the ature increase will initially remove any volatile substances, such as hydrocarbons and moisture, from the s before pyrolysis is then initiated. This process results in biochar accumulation near the second end 112 of the pyrolysis chamber 110.

The biochar in the pyrolysis chamber 110 is then removed through the exit of the biochar outlet 130. There is a spacing between an end of the centreless biochar screw conveyor 132 and the exit of the r outlet 130.

During the exiting process, the centreless biochar screw conveyor 132 forms the biochar plug 133 as the biochar is moved towards the exit of the biochar outlet 130. The biochar plug 133 is dense and absent of large gas voids and thereby substantially prevents fluid communication between the biochar outlet 130 and the external atmosphere. Newly formed dry biochar can show pyrophoric or and as such may spontaneously ignite when exposed to air. To alleviate this problem a controlled amount of water or condensate may be added to the biochar via one or more water inlets located within the biochar outlet 130, W0 2016!168894 preferably adjacent a portion of the centreless biochar screw conveyor 132 such that r is ted with the water prior to exiting the centreless biochar screw or 132 and forming the biochar plug 133.

The syngas produced during pyrolysis is removed through the gas outlet 140. The gas outlet 140 is d adjacent to the first end 111 of the pyrolysis chamber 110 and nt to the feed inlet 120. In one embodiment, the gas outlet 140 is located substantially adjacent the feed inlet 120. It may be accommodated within an expansion chamber. The syngas is removed through the gas outlet 140 and the syngas may then be used directly as a fuel source to generate electricity and/or process heat in boilers, gas engines or gas turbines.

The syngas must travel generally from the second end 112 to the first end 111 of the pyrolysis chamber 110 to be removed by the gas outlet 140. As previously mentioned the centreless pyrolysis screw conveyor 114 forms a dense s adjacent the first end 111 of pyrolysis chamber 110. This dense biomass is substantially absent of large voids. The syngas must te through the dense biomass to the gas outlet 140 and in doing so is effectively “filtered” by the dense biomass to remove oil, tar and particulate matter. The dense biomass also acts as a heat exchanger whereby the syngas gives up most of its latent heat to dry and heat the incoming biomass. lf large voids are present then the syngas will find the path of least resistance (through the voids) and the oil, tar and particulate matter will not be removed from the syngas and the heat exchange will be less effective. The pyrolysis apparatus 100 ntially reduces or avoids this issue.

The gas outlet 140 ensures that the pyrolysis chamber 110 operates at a low pressure (<50 kPA). The pyrolyser is designed to be intrinsically safe because there is very little flammable gas present in the pyrolysis chamber 110 at any one time. The pyrolysis apparatus 100 can further comprise an automatic nitrogen purge unit. The automatic nitrogen purge unit may be placed in fluid communication with the pyrolysis chamber 110. The automatic nitrogen purge unit purges the sis chamber 110 with nitrogen to ensure that any uncontrolled tion is starved of oxygen. It will be appreciated by those skilled in the art that any gas that is able to starve a fire can be used in the purge unit. Suitable gases include nitrogen, helium, neon, argon, n, xenon or carbon dioxide.

The gas pressure of the pyrolysis tus 100 is monitored by a control system. The control system maintains the gas re at the gas outlet 140 at a slight negative pressure (20 to 100Pa) by controlling the rate at which the syngas is d from the pyrolysis apparatus 100. This results in the pressure on either side of the biomass plug 124 being similar and if there is any leakage then a small amount of air is removed with the syngas via the gas outlet, and none of the syngas is leaked into the atmosphere.

It has been shown that the present pyrolysis apparatus 100 can continuously pyrolyze biomass and continuously collect clean syngas. r to this, the present pyrolysis apparatus 100 can pyrolyze biomass with high moisture content. These advantages are possible due to the use of the various centreless screw conveyors making the biomass plug 124 and the biochar plug 133, which substantially prevent fluid ication of the sis chamber 110 with the external environment, and the densely packed incoming biomass which effectively filters and transfers heat from the existing syngas. The above description of various embodiments of the present invention is provided for purposes of description to one of ordinary skill in the related art. It is not intended to be exhaustive or to limit the invention to a single disclosed ment. As ned above, numerous alternatives and variations to the present invention will be nt to those skilled in the art of the above teaching. Accordingly, while some alternative ments have been discussed specifically, other embodiments will be apparent or relatively easily developed by those of ordinary skill in the art. Accordingly, this invention is intended to embrace all alternatives, modifications and variations of the present invention that have been discussed herein, and other embodiments that fall within the spirit and scope of the above described invention.

In a first aspect, the invention relates to a pyrolysis apparatus sing: a. a pyrolysis chamber having a first end and a second end and comprising a centreless pyrolysis screw conveyor extending from the first end at least partially towards the second end of the pyrolysis chamber and configured to form a biomass bed; b. a feed inlet adjacent the first end of the pyrolysis chamber; c. a biochar outlet adjacent the second end of the pyrolysis chamber; d. a gas outlet in fluid communication with the sis chamber and located nt the first end; and e. at least one gas injection port located adjacent the second end, wherein the feed inlet comprises a centreless feed screw conveyor and a spacing between an end of the centreless feed screw conveyor and the pyrolysis chamber, wherein the biochar outlet comprises a centreless biochar screw conveyor and a spacing n an end of the centreless biochar screw conveyor and an exit of the biochar outlet, wherein the second end of the pyrolysis chamber is free of gas outlets and n the less feed screw conveyor is configured to form a s plug in the spacing between the end of the centreless feed screw conveyor and the pyrolysis chamber.

In a second aspect, the invention relates to a pyrolysis apparatus comprising: a. a pyrolysis chamber having a first end and a second end and sing a centreless pyrolysis screw conveyor extending from the first end at least partially towards the second end of the pyrolysis chamber and configured to form a biomass bed; b. a feed inlet adjacent the first end of the pyrolysis chamber; c. a biochar outlet adjacent the second end of the pyrolysis chamber; d. a gas outlet in fluid communication with the pyrolysis chamber and located adjacent the first end, and e. at least one gas injection port located adjacent the second end, wherein the feed inlet ses a centreless feed screw conveyor and a spacing between an end of the centreless feed screw conveyor and the pyrolysis chamber, wherein the centreless feed screw conveyor is configured to form a biomass plug in the spacing between the end of the centreless feed screw conveyor and the pyrolysis chamber, wherein the biochar outlet ses a centreless biochar screw conveyor configured to form a biochar plug, and wherein the second end of the pyrolysis r is free of gas outlets.

In a third , the invention s to a method of processing biomass, including the steps of: a. providing a pyrolysis chamber comprising i. a pyrolysis chamber having a first end and a second end and sing a centreless pyrolysis screw or extending from the first end at least partially towards the second end of the pyrolysis chamber, and configured to form a biomass bed; ii. a feed inlet adjacent the first end of the pyrolysis chamber; iii. a r outlet adjacent the second end of the pyrolysis chamber; iv. a gas outlet in fluid communication with the pyrolysis chamber and located adjacent the first end, wherein the feed inlet comprises a centreless feed screw conveyor and a spacing between an end of the centreless feed screw conveyor and the pyrolysis chamber, wherein the centreless feed screw conveyor is ured to form a biomass plug in the spacing between the end of the centreless feed screw conveyor and the pyrolysis r, and the second end of the pyrolysis chamber is free of gas outlets; and v. at least one gas injection port located adjacent the second end, b. introducing biomass from the feed inlet to the first end of the pyrolysis chamber; c. moving the s from the first end of the pyrolysis chamber to the second end of the pyrolysis chamber to pyrolyze the biomass and produce syngas and biochar; d. removing the biochar from the pyrolysis chamber through the biochar outlet; and e. causing the syngas to move in a direction lly from the second end to the first end to be removed h the gas outlet, to thereby process the biomass.

Claims (16)

1. A pyrolysis apparatus comprising: a. a pyrolysis chamber having a first end and a second end and comprising a less pyrolysis screw conveyor 5 extending from the first end at least partially towards the second end of the pyrolysis chamber and configured to form a biomass bed; b. a feed inlet adjacent the first end of the pyrolysis chamber; c. a biochar outlet adjacent the second end of the pyrolysis 10 chamber; d. a gas outlet in fluid communication with the pyrolysis chamber and located adjacent the first end; and e. at least one gas injection port located adjacent the second end, 15 wherein the feed inlet comprises a centreless feed screw or and a spacing between an end of the centreless feed screw conveyor and the pyrolysis chamber, wherein the biochar outlet ses a centreless r screw conveyor and a spacing between an end of the centreless biochar screw conveyor and an exit of the biochar outlet, 20 wherein the second end of the pyrolysis chamber is free of gas outlets and wherein the centreless feed screw conveyor is ured to form a biomass plug in the spacing between the end of the centreless feed screw conveyor and the pyrolysis chamber.

2. The pyrolysis apparatus according to claim 1, n a ature 25 gradient is formed in the pyrolysis r.

3. The pyrolysis apparatus according to claim 1 or claim 2, wherein the pyrolysis apparatus further comprises a biochar valve in communication with the biochar outlet.

4. The pyrolysis apparatus according to claim 1, 2 or 3, wherein gas injected through the at least one gas injection port is selected from oxygen or atmospheric air.

5. The pyrolysis apparatus according to claim 1, 2, 3 or 4, wherein the at 5 least one gas injection port is only located adjacent the second end.

6. The pyrolysis apparatus, according to claim 1, 2, 3, 4 or 5, wherein the at least one gas injection port is only located within a third of the length of the pyrolysis chamber from the second end.

7. The pyrolysis apparatus according to claim 1, 2, 3, 4, 5 or 6, wherein the 10 centreless biochar screw conveyor is configured to form a biochar plug in the spacing n the end of the less biochar screw conveyor and the exit of the r outlet.

8. A pyrolysis apparatus comprising: a. a pyrolysis chamber having a first end and a second end and 15 comprising a centreless pyrolysis screw conveyor extending from the first end at least partially towards the second end of the pyrolysis chamber and configured to form a biomass bed; b. a feed inlet adjacent the first end of the pyrolysis chamber; c. a r outlet nt the second end of the pyrolysis chamber; 20 d. a gas outlet in fluid communication with the sis chamber and located adjacent the first end; and e. at least one gas injection port located nt the second end, wherein the feed inlet comprises a centreless feed screw conveyor and a spacing between an end of the centreless feed screw or and the 25 sis chamber, wherein the centreless feed screw conveyor is configured to form a biomass plug in the spacing between the end of the centreless feed screw conveyor and the pyrolysis chamber, wherein the biochar outlet comprises a centreless biochar screw conveyor configured to form a biochar plug, and wherein the second end of the pyrolysis chamber is free of gas outlets. 5

9. The pyrolysis apparatus according to claim 8, wherein a temperature gradient is formed in the pyrolysis chamber.

10. The pyrolysis apparatus according to claim 8 or claim 9, wherein the gas injected through the at least one gas injection port is selected from oxygen or atmospheric air. 10

11. The pyrolysis apparatus according to claim 8, 9 or 10, wherein the at least one gas injection port is only located adjacent the second end.

12. A method of processing biomass, including the steps of: a. providing a pyrolysis chamber comprising: i. a pyrolysis chamber having a first end and a second end 15 and comprising a centreless pyrolysis screw conveyor extending from the first end at least lly towards the second end of the pyrolysis chamber, and configured to form a biomass bed; ii. a feed inlet adjacent the first end of the pyrolysis chamber; 20 iii. a biochar outlet adjacent the second end of the sis chamber; iv. a gas outlet in fluid communication with the pyrolysis r and d adjacent the first end, wherein the feed inlet comprises a centreless feed screw or and a 25 g between an end of the centreless feed screw conveyor and the pyrolysis chamber, wherein the centreless feed screw or is configured to form a biomass plug in the spacing between the end of the centreless feed screw conveyor and the pyrolysis chamber, and the second end of 30 the pyrolysis r is free of gas outlets; and v. at least one gas injection port located adjacent the second end, b. introducing biomass from the feed inlet to the first end of the pyrolysis chamber; c. moving the biomass from the first end of the pyrolysis chamber to the second end of the pyrolysis chamber to pyrolyze the biomass 5 and produce syngas and biochar; d. removing the r from the pyrolysis chamber through the biochar outlet; and e. causing the syngas to move in a direction generally from the second end to the first end to be removed h the gas outlet, 10 to thereby s the biomass.

13. The method of claim 12, n a biochar plug is formed in the biochar outlet.

14. The method of claim 12 or claim 13, wherein a packed biomass is formed in the pyrolysis chamber.

15 15. The method of claim 13 or claim 14, wherein syngas is filtered by the packed biomass.

16. The method of claim 12, 13, 14 or 15, wherein the biomass is processed continually.