NZ332747A - Improved rotational moulding process - Google Patents

Abstract

A method for rotational moulding of articles, including the step of rotationally moulding a mixture of particulate plastics material comprising at least one thermoplastics material having a first particle size and a second thermoplastics material having a larger particle size wherein, in use, said first thermoplastic material fuses to form an outer skin (5) and subsequently said second thermoplastics material fuses to form an inner skin (6) bonded to the outer skin of a resultant moulded article. The method may also include the step of incorporating a quantity of rollable moulded reinforcing elements (7) in the mould with said first and second thermoplastics materials, wherein the reinforcing elements are located in a spaced array thereby forming bridges between opposed inner skin surfaces as they expand. Articles, such as a shipping pallet, rotationally moulded using the method are also disclosed.

Description

WO 97/38839 , PCT/AU97/00224 TITLE Improved Rotational Moulding Process FIELD OF THE INVENTION This invention relates to rotational moulding of plastics articles and in 5 particular to the manufacture of moulded plastics "articles having an outer skin and an inner core BACKGROUND TO THE INVENTION Rotational moulding of thermoplastics material is a convenient and cost effective method for the manufacture of a wide variety of articles, 10 ranging in size from domestic containers and toys to large liquid storage tanks.

Rotational moulding processes are characterised by low capital costs for moulds and other apparatus when con'pared with injection moulding processes for example.., The'y are further characterised by relatively short 15 setup times, the capacity for economic low volume manufacturing and immense flexibility in product size range Typical thermoplastics matenals employed in rotational moulding processes are the polyolefins, including polyethylene and polypropylene, polyvinyl-chloride, polycarbonates, nylon, and acrylobutadiene-styrenes 20 (ABS) In this respect virtually any thermoplastic resins are suitable for use in rotational moulding, including copolymers materials and mixtures of compatible resins 59 PCT/AU97/00224 2 Products produced by rotational moulding are generally characterised by good strength and structural integnty, abrasion resistance, weather resistance including UV stability, wide colour range, selectable surface finish from high gloss to matt and textured, chemical resistance and environmental stress crack resistance (ESCR) Although generally satisfactory for most purposes, in certain applications rotationally moulded products lack stiffness, impact resistance (particularly at low temperatures), and load bearing capacity (particularly at elevated temperatures) These deficiencies generally arise from the relatively low wall thickness of products pioduced by rotational moulding which are inherently due to thermal conductivity and cost constraints Growing environmental concerns over the disposal of plastics waste has focussed the need for recycling of plastics materials reclaimed subsequent to use by domestic or industrial consumers. One of the major difficulties in recycling such reclaimed plastics is contamination Contamination can anse from inadequate sorting of polymenc species which is difficult to achieve by unskilled manual labour and virtually impossible to automate Mixtures of plastics species are difficult to process due to differing melt temperatures and viscosities as well as inherent chemical incompatibility Other sources of contamination, apart from dirt and dust, are paper and plastics film labels, non-plastics container seals and incompletely discharged contents of such containers WO 97/38839 PCT/AU97/00224 A method for manufacturing products using reclaimed plastics, typically polyolefins, employs an injection extrusion process whereby granulated plastics waste is subjected to working under high shear conditions in an extruder The compounded plastics issuing from the 5 extruder is pumped directly, under screw pressure, into a shaped t o!!ow die and allowed to cool, in a manner similar to injection moulding The injection extrusion of reclaimed plastics is generally used to produce articles such as plank members for outdoor seating, tree and shrub surrounds, garden edging, man-hole covers and pits for underground utilities 10 or shipping pallets The articles are characterised by high mass, bulky shape, limited colour range, poor chemical resistance, poor ESCR and UV resistance along with inferior mechanical properties The surface of such articles is uneven or porous and thus difficult to keep clean Textured finishes, as required for slip resistance on man-hole covers, are difficult to 15 reproduce These characteristics of reclaimed plastics products result from contamination and chemical incompatibility problems and the use of a dark pigment, usually black brown or grey, to mask unsightly flow marks from inadequately blended plastics of differing colours and viscosities A large 20 amount of expensive pigment must be added to achieve even a reasonable colour finish The applicant's Australian Patent Application No 40440/95 describes a method for the manufacture of moulded plastics articles which combines WO 97/38839 PCT/AU97/00224 4 certain advantages of conventional rotational moulding with certain advantages of injected cores to selectively overcome disadvantages of each process The applicant's earlier method comprises a two cycle method of first 5 rotationally moulding a thin walled hollow body and secondly introducing into the core of said hollow body a flowable mass of plastics material, preferably reclaimed plastics matenal, to occupy substantially the entire volume of the core of said hollow b^dy This method is particularly suited to producing relatively large thin walled objects such as buoyancy modules or liquid 10 storage tanks Whilst suitable for thin walled objects, the applicant's earlier method consumes a large amount of reclaimed plastics in the production of articles that have a core volume commensurate with the overall size of the article, thus resulting in a high mass product 15 Consequently there is a need for an improved method which incorporates the benefits of the double skin structure of the prior art method but utilises less material to produce articles that are lighter in weight whilst maintaining their structural integrity Furthermore it would be advantageous if the method required only a single cycle rotational moulding process, rather 20 than the prior art two cycle method of forming the outer skin followed by introducing the flowable reclaimed plastics matenal to form the core The improved method is suited to the production of bulky articles, such as pallets, lids for industrial waste bins and tanks, covers for utility •CT/Au 97/002 24 RECEIVED 0 - *333 ;5 ;access ways, pits (eg for underground cable or conduit systems), or structural members such as wall, roof, or flooi panels OBJECT OF THE INVENTION ;It is an object of the present invention to provide an improved 5 rotational moulding method that overcomes at least some of the disadvantages of prior art moulding methods ;It is a further object of the invention to provide an improved rotational moulding method for producing composite products that have the advantages of virgin thermoplastics without some of the disadvantages of 10 mixed reclaimed plastics incorporated therein ;Further objects will be evident from the following description DISCLOSURE OF THE INVENTION ;In one form, although it need not be the only or indeed the broadest form, the invention resides in a method for rotational moulding of articles, 15 including the step of rotationally moulding a mixture of particulate plastics material comprising at least one thermoplastics material having a first particle size and a second thermoplastics material comprised of reclaimed plastics material and having a larger particle size wherein, in use, said first thermoplastic material fuses to form an outer skin and subsequently said 20 second thermoplastics material fuses to form an inner skin bonded to the outer skin of a resultant moulded article ;The melt temperature of the second thermoplastics material may be higher than the melt temperature of the first thermoplastics material ;AMENDED SHEET IPEA/AU ;»cr/\u 97/00^24 ;RECEIVED T" ;6 ;In preference the first thermoplastics material is homopolymeric ;The second thermoplastics material may be a mixture of polymeric species ;5 Preferably the second thermoplastics material includes a quantity of thermosetting polymeric material ;In preference the second thermoplastics matenal includes a quantity of foaming agent ;The decomposition temperature of the foaming agent is preferably 10 greater than the melt temperature of the second thermoplastics material ;Preferably the second thermoplastics material includes a quantity of filler material ;If required particles of the second thermoplastics material may include an adhesion .resistant coating to reduce adhesion between the second 15 thermoplastics material and the first thermoplastics material during the fusing of the outer skin ;In a further form of the invention the method may also include the step of incorporating a quantity of rollable moulded reinforcing elements in the mould with said first and second thermoplastics materials, wherein the 20 reinforcing elements are located in a spaced array thereby forming bridges between opposed inner skin surfaces as they expand amended sheet ;•PEA/AU ;WO 97/38839 PCT/AU97/00224 ;Suitably, the reinforcing elements are larger than the particle size of the second thermoplastics material ;The reinforcing elements may be generally spherical or generally cylindrical ;5 Preferably the reinforcing elements are mechanically engaged between the opposed inner skin surfaces ;In preference, the reinforcing elements are at least partially fused to said opposed inner skin surfaces ;The reinforcing elements may include an adhesion resistant coating, 10 such as talc, to reduce adhesion between the reinforcing elements and the first and second thermoplastics materials during the fusing of said skins ;If required, the resnforcing elements may include an adhesion resistant additive to reduce adhesion ' stween the reinforcing elements and the first and second thermoplastics materials during the fusing of said skins 15 Suitably, the adhesion resistant additive may be selected from one of a soap, such as calcium stearate or the like, a silicone oil or a suitable plasticiser ;The reinforcing elements may be of a solid, hollow or foamed construction ;20 Preferably the reinforcing elements may be comprised of virgin or reclaimed plastics material ;If required, the reinforcing elements may be comprised of ceramics material ;332747 ;8 ;In a yet further form of the invention the method may also include the step of incorporating a reinforcement structure at predetermined locations in the mould with said first and second thermoplastics materials ;The reinforcement structure may be constructed of plastics or metallic material or a combination of both ;Preferably the reinforcement structure comprises steel or aluminium mesh ;If required the reinforcing structure may comprise angle or channel profiled members ;In a still further form, the invention resides in an article manufactured using the improved rotational moulding method disclosed herein above ;The article may comprise a shipping pallet, man-hole cover, tank lid, utility pit cover or the like ;The article may comprise a structural member, such as a wall panel, floor panel, roof panel or the like ;In another form, the invention resides in a rotationally moulded shipping pallet manufactured using the improved rotational moulding method disclosed herein above having a supporting surface and a series of leg means depending therefrom, wherein said surface includes a plurality of recesses which are arranged to locate pallets relative to one another when two or more are stacked ;Preferably the leg means comprise rails depending from opposite ends of the pallet and a central rail extending congruentiy to said end rails ;WO 97/38839 PCT/AU97/00224 ;9 ;Preferably the rails include a series of depending lugs which cooperate with said plurality of recesses BRIEF DETAILS OF THE DRAWINGS ;To assist in understanding the invention preferred embodiments will 5 now be descnbed with reference to the following figures in which ;FIG 1 is a perspective view of a shipping pallet manufactured in accordance with an embodiment of the invention ;FIG 2 is a partial elevational cross-section of the shipping pallet illustrated in FIG 1 ;10 FIG 3 is a partial elevational cross-section of a structural panel made in accordance with another embodiment of the invention ;FIG 4 is an isometnc view of an alternative embodiment of a shipping pallet manufactured in accordance with the invention ;FIG 5 is a front elevation of the shipping pallet shown in FIG 4 15 DETAILED DESCRIPTION OF THE DRAWINGS ;In the drawings, like reference numerals refer to like parts Referring to FIG 1, the shipping pallet 1 of the embodiment comprises a deck 2, and rails 3 thereby providing a raised portion 4 facilitating insertion of the tines of a fork-lift truck or similar transportation means 20 FIG 2 is a schematic cross-section illustrating the construction of the pallet 1, which comprises an outer skin 5, a foamed inner skin 6, spaced reinforcing members 7 in the form of foamed macro-spheres and residual ;/38839 PCT/AU97/00224 ;10 ;voids 8 The random spaced array of reinforcing members forms a bridging layer 9 between opposed inner surfaces of the inner skin 6 ;In the embodiment the outer skin layer 5 is formed from a virgin polyolefin, typically an opaque polyethylene, which can provide a smooth or textured surface as required The outer skin may also be coloured as desired, of food handling grade and UV resistant. The inner foamed skin 6 is also formed from a polyolefin, but typically of mixed reclaimed plastic which has been pre-extruded in granular form and incorporates a chemical foaming or blowing agent ;The bridging layer 9 comprises Tollable reinforcing elements in the form of balls or macro-spheres The reinforcing elements are pre-formed by rotational or injection moulding, typically also from reclaimed plastics In the embodiment the reinforcing elements are foamed polyolefin, but may alternatively be of solid or hollow construction The balls are of a diameter appropnate to the gap between the opposed inner skin surfaces, in this case around 50 mm In other embodiments the reinforcing elements may be of any appropnate reliable shape, such as cylindrical pellets, and alternatively formed by extrusion or other suitable process ;The rotational moulding process uses a mould formed to the desired outer shape of the pallet Shipping pallets are generally 1200 mm square by about 140 mm deep The ingredients are initially introduced into the mould, as follows ;9 PCT/AU97/00224 ;11 ;(a) approximately 5 kg of virgin polyethylene in the form of powder or micro-pellets averaging 0 5 mm in diameter, the polyethylene having a melting point of approximately 160 degC, ;(b) approximately 10 kg of mixed reclaimed polyolefin plastics in the form of pre-extruded pellets averaging 3 mm in diameter, the reclaimed plastics having a melting point in the approximate range of 165 to 220 degC, the foaming agent incorporated into the pellets having a decomposition temperature of approximately 220 degC, and ;(c) approximately 3 kg of pre-moulded balls of reclaimed foamed polyolefin, 50 mm in diameter ;The rotational moulding apparatus (not shown) can be any of the known forms, but would preferably be an oven type machine with computer process control providing, inter alia, precise control of the oven temperature and the rotation and oscillation speeds of a two-axis mould drive rig The mould is sealed after the ingredients are loaded and the following process steps effected by the rotational moulding apparatus, during which time the mould is rotated and oscillated at pre-selected speeds ;(I) The oven is heated to a temperature of 300 degC and held for a period of 5 minutes, so as to fuse the polyethylene powder and lay down the outer skin on the inward facing walls of the mould The finer powder or micro-pellets separate from the larger inner skin foamable pellets under the tumbling action within the slowly rotating mould This effect leads to the preferential laying down of the outer skin, ;PCT/AU97/00224 ;12 ;which may be assisted by the addition of talc surface coating on the pre-extruded pellets to slow the tendancy of the pellets to adhere to the virgin plastics material whilst it melts onto the mould surface ;(II) The oven is then elevated to a temperature of 320 degC and held for a period of 5 minutes, so as to melt and fuse the reclaimed plastics pellets thereby forming the inner skin on the inward facing surface of the outer skin layer ;(III) During the preceding steps, the pre-moulded balls roll around inside the mould while the outer and inner skin layers are laid down in the mould The balls are surface coated with talc in the embodiment, to slow or minimise them adhering prematurely to either skin ;(IV) The oven is further elevated to a temperature of 360 degC for a period of 3 minutes to effect decomposition of the blowing agent, which expands the volume of the inner skin This expansion traps the balls between, and in some instances partially embeds them in, the inward facing surfaces of the inner skin. ;(V) Cooling the mould to a temperature of at least 50 degC for a period of 10 minutes, typically by quenching the mould with water to i ;cool and solidify the skins on the inside of the mould ;(VI) The cooling step tends to effect a slight shrinkage of the product from the inward facing walls of the mould, which eases release when the mould is finally opened The process produces a ;9 ;WO 97/38839 PCT/AU97/00224 ;13 ;pallet having a double skinned wall and a spaced array of reinforcing elements in the form of foamed balls ;It should be noted that the oven temperature refers to the ambient temperature within the oven, whereas the temperature within the mould itself 5 will be somewhat lower due to heat transfer effects However the temperature gradient within the mould generally assists the process ;The selection of appropriately graded particle or granule size for the plastics materials comprising the skins, so as to take advantage of the separation effected by the mould tumbling action, allows all ingredients to be 10 loaded into the mould and the product manufactured using a single rotational moulding cycle ;This effect may be enhanced by appropnate selection of the melt temperature and melt flow, as measured by the melt flow index (MFI), for the plastics matenals See for example the melt temperatures set out above in 15 relation to the preferred embodiment Similar enhancement may be achieved by the selection of mould rotation speeds for each step ;The provision of a spaced array of reinforcing members, wnether in the form of balls or cylindncal pellets, provides improved strength and rigidity for the finished product without the weight penalty associated with solid or 20 semi-solid cores It is to be noted that, in other embodiments of the invention where there is a product requirement for slimmer walls, the reinforcing elements may be omitted because the plastics material for the inner skin can ;3327*7 14 be chosen such that opposing surfaces of the inner skin touch one another after foaming The use of employ reclaimed plastics material for the inner skin avoids any need for adding pigments during the pre-extrusion process, because it is hidden by the opaque outer skin Similarly the reclaimed plastics need not be pre-sorted by colour Although principally constituted from reclaimed polyolefins, granulated sciap plastics such as thermosetting polymers may be incorporated into the inner skin material, because the pre-extrusion process partially homogenises the reclaimed plastics The second thermoplastics material can include organic or inorganic filler material An example of a suitable inorganic filler material is talc, whilst the organic filler matenal could be cellulosic including recycled newspapers, rice or peanut hulls FIG 3 shows a schematic cross-section of a building panel made using a further embodiment of the invention In cases where panels require additional strength for use in building applications or the like, reinforcing means in the form of metallic mesh, for example, may be incorporated into the mould as part of the rotational moulding process The building panel 10 includes an outer skin 11, an inner skin 12, a spaced array of macro-spheres 13 forming a bridging layer 14 between inward facing surfaces of the inner skin Substantially encapsulated in the inner skin is a prefabricated aluminium mesh 15 97/38839 PCT/AU97/00224 During assembly of the mould for the building panel, tho mesh members are located therein and spaced therefrom by aluminium or thermosetting plastics spacers 16 The spacing and quantity of reclaimed plastics material for the inner skin is chosen so as to substantially > encapsulate the mesh, thereby enhancing the mechanical properties of the finished panel In alternative embodiments requiring additional rigidity, the i reinforcing means may be comprised of angle or channel profiled members FIG 4 shows another embodiment of a shipping pallet 17, which includes a deck 18 and, in addition to the end rails 19, a central support rail D 20 The central rail provides additional support for the deck thereby resulting in an improved ioad carrying capacity In order to facilitate stacking of empty pallets, the deck 18 includes a plurality of recesses 21 in its upper surface The recess are arranged to cooperate with lugs 22 disposed on the lower surface of the rails, as depicted in FIG 5 5 The recess and lug combination is but one arrangement which could be used in this application One alternative might include providing slots in the upper surface of the deck, which slots are arranged to cooperate with the end and central rails, omitting the lugs entirely In another alternative, the rails might be replaced by a series depending legs which cooperate with 10 enlarged recesses provided in the deck of the pallet The composite products constructed in accordance with the invention exhibit the advantages of high grade polyolefins without the disadvantages of reclaimed plastics materials WO 97/38839 PCT/AU97/00224 16 Throughout the specification the aim has been to describe the preferred embodiments of the invention without limiting the invention to any one embodiment or specific collection of features 17

Claims (2)

1 A method for rotational moulding of articles, including the step of rotationally moulding a mixture of particulate plastics material comprising at least one thermoplast'cs material having a first particle size and a second 5 thermoplastics matenal comprised of reclaimed plastics matenal and having a larger particle size wherein, in use, said first thermoplastic material fuses to form an outer skin and subsequently said second thermoplastics material fuses to form an inner skin bonded to the outer skin of a resultant moulded article 10 2 A method for rotational moulding of articles as claimed in claim 1 wherein the melt temperature of the second thermoplastics material is higher than the melt temperature of the first thermoplastics material 3 A method for rotational moulding of articles as claimed in either claim 1 or claim 2 wherein the first thermoplastics material is homopolymeric 15 4 A method for rotational moulding of articles as claimed in either claim 1 or claim 2 wherein the second thermoplastics material is a mixture of polymeric species 5 A method for rotational moulding of articles as claimed in any one of claims 1 to 4 wherein the second thermoplastics material includes a quantity 20 of thermosetting polymeric material 6 A method for rotational moulding of articles as claimed in any one of claims 1 to 5 wherein the second thermoplastics material includes a quantity of foaming agent AMENDED SHEET tPEA/AU 332747 18 7 A method for rotational moulding of articles as claimed in claim 6 wherein the foaming agent has a decomposition temperature greater than the melt temperature of the second thermoplastics material 8 A method for rotational moulding of articles as claimed in any one of claims 1 to 7 wherein the second thermoplastics material includes a quantity of filler material 9 A method for rotational moulding of articles as claimed in any one of claims 1 to 8 wherein particles of the second thermoplastics material includes an adhesion resistant coating to reduce adhesion between the second thermoplastics material and the first thermoplastics material during the fusing of the outer skin 10 A method for rotational moulding of articles as claimed in any one of the preceding claims, further including the step of incorporating a quantity of Tollable moulded reinforcing elements in the mould with said first and second thermoplastics material, wherein the reinforcing elements are located in a spaced array thereby forming bridges between opposed inner skin surfaces as they expand 11 A method for rotational moulding of articles as claimed in claim 10 wherein the reinforcing elements are larger than the particle size of the second thermoplastics material 12 A method for rotational moulding of articles as claimed in claim 10 or claim 11 wherein the reinforcing elements are substantially spherical or substantially cylindrical 19 13 A method for rotational moulding of articles as claimed in any one of claims 10 to 12 wherein the reinforcing elements are mechanically engaged between the opposed inner skin surfaces 14 A method for rotational moulding of articles as claimed in claim 13 5 wherein the reinforcing elements are at least partially fused to said opposed inner skin surfaces 15 A method for rotational moulding of articles as claimed in any one of claims 10 to 14 wherein the reinforcing elements include an adhesion resistant coating to reduce adhesion between the reinforcing elements and 10 the first and second thermoplastics matenals during the fusing of said skins 16 A method for rotational moulding of articles as claimed in any one of claims 10 to 15 wherein the reinforcing elements include an adhesion resistant additive to reduce adhesion between the reinforcing elements and the first and second thermoplastics materials during the fusing of said skins 15 17 A method for rotational moulding of articles as claimed in claim 16 wherein the adhesion resistant additive is selected from one of a soap, a silicone oil or a suitable plasticiser 18 A method for rotational moulding of articles as claimed in any one of claims 10 to 17 wherein the reinforcing elements are of a solid, hollow or 20 foamed construction 19 A method for rotational moulding of articles as claimed in any one of claims 10 to 18 wherein the reinforcing elements are comprised of virgin or reclaimed plastics material WiML)ED SHEET IPEA/AU *cr"vu 97/00224 RECEIVED Q 7 ■■ " 20 20 A method for rotational moulding of articles as claimed in any one of claims 10 to 17 wherein the reinforcing elements are comprised of ceramics material 21 A method for rotational moulding of articles as claimed in any one of 5 the preceding claims further including the step of incorporating a reinforcement structure at predetermined locations in the mould with said first and second thermoplastics materials 22 A method for rotational moulding of articles as claimed in claim 21 wherein the reinforcement structure is constnjcted of plastics material or 10 metallic material or a combination of both materials 23 A method for rotational moulding of articles as claimed in claim 21 wherein the reinforcement structure comprises steel or aluminium mesh 24 A method for rotational moulding of articles as claimed in any one of claims 21 to 23 wherein the reinforcing structure compnses angle or channel 15 profiled members 25 An article manufactured using the rotational moulding method claimed in any one or more of the preceding claims

2.6 A shipping pallet, man-hole cover, tank lid, utility pit cover or like article when manufactured using the rotational moulding method claimed in 20 any one or more of claims 1 to 24 27 A structural member, such as a wall panel, floor panel, roof panel or the like when manufactured using the rotational moulding method claimed in any one or more of claims 1 to 24 SHEET 'PEA/AU PFrEiVF0 0 7 :-V! 1S33 21 28 A rotationally moulded shipping pallet manufactured using the rotational moulding method claimed in any one or more of claims 1 to 24, having a supporting surface and a senes of leg means depending therefrom, wherein said surface includes a plurality of recesses which are arranged to locate pallets relative to one another when two or more are stacked 29 A rotationally moulded shipping pallet as claimed in claim 28 wherein the leg means comprise rails depending from opposite ends of the pallet and a central rail extending congruently to said end rails 30 A rotationally moulded shipping pallet as claimed in claim 29 wherein the rails include a series of depending lugs which cooperate with said plurality of recesses END OF CLAIMS «OED sheet PEA/AU