NZ204184A - Polyester compositions containing talc and ovenware manufactured therefrom - Google Patents
Polyester compositions containing talc and ovenware manufactured therefromInfo
- Publication number
- NZ204184A NZ204184A NZ204184A NZ20418483A NZ204184A NZ 204184 A NZ204184 A NZ 204184A NZ 204184 A NZ204184 A NZ 204184A NZ 20418483 A NZ20418483 A NZ 20418483A NZ 204184 A NZ204184 A NZ 204184A
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- New Zealand
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- weight
- talc
- ovenware
- parts
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Electric Ovens (AREA)
- Polyesters Or Polycarbonates (AREA)
- Cookers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
<div class="application article clearfix" id="description">
<p class="printTableText" lang="en">New Zealand Paient Spedficaiion for Paient Number £04184 <br><br>
204184 <br><br>
Priority Date(s): .... ?.4".V.?!•?,........ <br><br>
Complete Specification Filed: <br><br>
Class: <br><br>
..$klW/o# <br><br>
Pubficstion Date: ?£!". j??{\... <br><br>
P.O. Journal, No: *2. t.Z. <br><br>
NO DRAWIN <br><br>
if* ^ <br><br>
J5»5w^ r ' l°HAYl98f <br><br>
NZ No <br><br>
NEW ZEALAND Patents Act, 1953 COMPLETE SPECIFICATION <br><br>
"IMPROVED PLASTIC OVENWARE CONTAINING.TALC. <br><br>
.1 <br><br>
We, DART INDUSTRIES INC, a Corporation organised and existing under the laws of the State of Delaware, United States of run- Sabers fv)<rftUbrcok lu^ojs <br><br>
Americ:ar of -8480 Bcvorly Doul-cvcird j—feoe jUtgoiLoEf Caliluiim •9004 9', United States of America, do hereby declare the invention for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement <br><br>
_ l - (Followed by 1A.) <br><br>
IMPROVED PLASTIC OVENWARE <br><br>
CONTAINING TALC <br><br>
ABSTRACT <br><br>
Permanent ovenware capable of repeated use in both conventional thermal and microwave ovens fabricated from wholly aromatic polyester compositions and, more particularly, from oxybenz-oyl polyester compositions containing up to about 60% of talc having present a minimum content of material decomposable at elevated temperatures. <br><br>
BACKGROUND OF THE INVENTION <br><br>
It is known that certain plastic materials have found some application in the ovenware field. For example, polymethyl-pentene has been used for injection molded trays which can be used in the preparation of foods. Polysulfone has also been employed in food handling applications. However, no satisfactory material has been found possessing utility over the wide ranges of conditions and of demands which are encountered in the provision of cook-in containers, or ovenware, which can be used in either thermal ovens or microwave ovens. <br><br>
In addition to the obvious necessity for a material which can withstand the temperatures met in the heat source used for cooking, a material must provide a unique combination of a number of other characteristics before ovenware fabricated from the material can be successfully employed in the preparation of food. The material must have good electrical properties. It must be able to undergo severe thermal shocks in that ovenware prepared l <br><br>
from it must be capable of going from conditions of extreme cold to high temperatures in relatively brief periods of time. The material must have good hardness and impact strength and possess high tensile and flexural strength. It must also be resistant to boiling water, food acids and fats and to adverse effects from immersion in detergents. / 'i 1 '* • , <br><br>
f'V <br><br>
- 1A - Ssi <br><br>
204184 <br><br>
In the area of food related properties the material must inpart to the ovenware fabricated from it resistance to staining by a wide variety of foodstuffs. It must provide a surface affording good antistick properties, ready releasability for the food which it contains. It must not emit or give off any volatile matter and it must not have any extractable constituent. And in addition to meeting all of the foregoing requirements, articles prepared from it must present a pleasing and generally uniform appearance in order to be marketable. <br><br>
Accordingly, the present invention provides a moulding composition comprising from 35% to p^>y^ weight of a wholly aromatic polyester and from 1% to 60% by weight of a talc which has a weight loss on ignition of not more than 6% by weight at 950°C andnot more than 2% by weight at 800°C, such that during moulding at elevated temperatures said composition is not blistered,, bubbled or cracked. <br><br>
Ovenware meeting the stringent demands of the cook-in container market is provided by fabricating ovenware articles from such composition and, in a preferred embodiment upon oxybenzoyl polyesters. <br><br>
The wholly aromatic polyesters employed in accordance with the present invention may consist of combinations of repeating units of one or more of the following formulae: <br><br>
oc <br><br>
CO <br><br>
V <br><br>
VI <br><br>
where x is-O-, -S-, - |l - , -NH-, or-SO_- and n is 0 or 1 and the total 1 C <br><br>
of the integers p+q+r+s+t+uin the moieties present is from about 3 to about 800. t** ■ <br><br>
- 2 - <br><br>
,AUe®kiS? <br><br>
Aoq-i-ju. <br><br>
Combinations of the above units include union o£(Jrajtfi.84 carbonyl group of Formulae I, II, IV and V with the oxy group of Formulae I, III, IV and VI. In the most general combination all units of the above formulae can be present in a single copolymer. The simplest embodiment would be homopolymers of units I or IV. Other combinations include mixtures of units II and III, II and VI, III and V, V and VI, and I and IV. <br><br>
The location of the functional groups are preferably in the para, (1,4) positions. They can also be located in ortho (1,2) position to each other. With respect to the naphthalene moiety, the most desirable locations of the functional groups are 1,4; 1,5 and 2,6. Such groups can also be in the ortho position to each other. <br><br>
The symbols p, q, r, s, t and u are integers and indicate the number of moieties present in the polymer. The total (p+q+r+s+t+u) can vary from 3 to 800 and, when present, the ratio of q/r, q/u, t/r, t/u, q + t/r, q + t/r + u and t/r + u can vary from about 10/11 to about 11/10 with the most preferable ratio being 10/10. <br><br>
Exemplary of materials from which the moieties of Formula I may be obtained are p-hydroxybenzoic acid and esters such as phenyl-p-hydroxybenzoate, p-acetoxybenzoic acid and isobutyl-p-acetoxybenzoate. Those from which the moiety of Formula II is derivable include terephthalic acid, isophthalic acid, diphenyl terephthalate, diethyl isophthalate, methylethyl terephthalate and the isobutvl half ester of terephthalic acid. Among the compounds from which the moiety of Formula III results are p,p'-biphenol; 4,4'-dihydroxybenzophenone; resorcinol and hydroquinone. Inspection will show which of these materials are also suitable for supplying the moieties of Formulae VI - VIII. <br><br>
Examples of monomers represented by Formula IV are 2-hvdroxy-6-naphthoic acid; 6-hydroxy-l-naphthoic acid; 5-acetoxy-1-naphthoic acid and phenyl 5-hydroxy-l-naphthoate. Monomers rep <br><br>
204184 <br><br>
resenting Formula V include 1,4-naphthalenedicarboxylic acid; 1,5-naphthalenedicarboxylic acid and 2,6-naphthalenedicarboxylic acid. The diphenyl esters or dicarbonyl chlorides of these acids can also be used. Examples of monomers representative of Formula VI are 1,4-dihydroxynaphthalene; 2,6-diacetoxynaphthalene and 1,5-dihydroxynaphthalene. <br><br>
Particularly preferred for use in the practice of the present invention are plastic materials based upon oxybenzoyl polyesters. <br><br>
A preferred class of oxybenzoyl polyesters are copoly- <br><br>
r VII, <br><br>
esters of recurring units of Formulae]VIII and IX: <br><br>
(VIII) <br><br>
VII <br><br>
-< p <br><br>
(IX) <br><br>
wherein x is -0 or -S02~; m is 0 or 1; n is 0 or 1; g:r = 10:15 to 15:10; p:q = 1:100 to 100:1; p + q + r = 3 to 600 and preferably 20 to 200. The carbonyl groups of the moiety of Formula VII or VIII are linked to the oxy groups of a moiety of Formula VII or IX; the oxy groups of the moiety of Formula VII or IX are linked to the carbonyl groups of the moiety of Formula VII or VIII. <br><br>
Another group of aromatic polyesters which can be employed are the aromatic polyesters containing recurring units of the 2,6—dicarboxynaphthalene moiety and/or the p-oxybenzoyl moiety and symmetrical dioxy aryl moiety, and variations thereof. Such polyesters are disclosed in U.S. Patents Nos. 4,067,852; 4,083,829; 4,130,545; 4,161,470; 4,184,996; 4,219,461; 4,224,433; 4,238,598; 4,238,599; 4,256,624; 4,265,802; 4,279,803, 4,318,841 and^ 4,318,842. <br><br>
ft <br><br>
204184 <br><br>
The preferred copolyesters are those of recurring units of Formula X: <br><br>
(X) <br><br>
.!_/~\_L0^ ^-i-o -J u.-l <br><br>
The synthesis of these polyesters is described in detail in U.S. Pat. No. 3,637,595, entitled "P-Oxybenzoyl Copolyesters", the disclosure of which is incorporated herein by reference. <br><br>
The polyesters useful in the present invention can also be chemically modified by various means such as by inclusion in the polyester of monofunctional reactants such as benzoic acid or tri- or higher functional reactants such as trimesic acid. The benzene rings in these polyesters are preferably unsubstituted but can be substituted with non-interfering substituents. <br><br>
The oxybenzoyl polyesters useful in the present invention can be employed with various fillers of types and in amounts which either promote or at a minimum do not materially affect the desired properties. Examples of suitable fillers include among others glass fibers, milled glass, polytetrafluoroethylene, pigments and fillers and combinations thereof. <br><br>
While the ovenware prepared from compositions comprising the oxybenzoyl polyesters and the various fillers recited above meet most of the general requirements recited earlier, they do not have the- uniform, pleasing appearance necessary to a commercially marketable product. In addition, it has been observed that many of the fillers create excess bubbling in the ovenware products at elevated temperatures. <br><br>
It has been found in accordance with the present inven- <br><br>
l tion that a uniform and pleasing appearance can be imparted to the :c>venware articles and the undesirable bubbling suppressed or min-jlnized by the inclusion in the oxybenzoyl compositions from which they are molded of talc which contains a minimum amount of mater <br><br>
- 5 - <br><br>
204184 <br><br>
ials decomposable at elevated temperatures, e.g. up to about 800°C, such as magnesium carbonate. Among such talcs are talcs which are of high purity, are selectively combined from various ores or have been calcined or subjected to acid treatment. <br><br>
These talcs which are employed according to the present invention are characterized by a low weight loss on ignition, a low iron content analyzed as iron oxide and a closely controlled particle size. <br><br>
The weight loss on ignition of the suitable talcs is not more than about 6% at 950°C and is 2% or less at 800°C. <br><br>
The iron content analyzed as iron oxide (¥020^) will be not more than about 1% and that of the particularly preferred talcs will be not more than about 0.6% and may be less. <br><br>
Experiments and tests carried out have demonstrated quite conclusively that it is essential to use such talc in order to realize the objectives of the present invention. The use of other forms of talc do not provide satisfactory properties in the finished molded product. However, such other forms of talc can be employed in conjunction with the specified talcs in amounts of from about 0.05% to about 20% of the required forms of talc. <br><br>
The talcs containing the minimum amount of decomposable material will be present in amounts of from about 1% to about 60% based on the total composition weight with the preferred range being from about 35% to about 55%. <br><br>
Rutile titanium dioxide can also be employed in conjunction with the talc material, including mixtures of highly refined talcs and other talc. The rutile titanium dioxide will be present in a proportion of from about 2% to about 20% based on the weight of the total composition. The preferred range is from about 5% to about 15%. <br><br>
10 <br><br>
1 ^ <br><br>
20 <br><br>
25 <br><br>
30 <br><br>
204184 <br><br>
In the molding compositions of the present invention, <br><br>
iby weight the resin will generally comprise from about 35% to about 85%[and the total inerts from about 65% to about 15%. For optimum results, the inerts will comprise from about 4 0% to about 55% of the molding compositions. The inerts will comprise up to about 55% of highly refined talc and from about 0 to about 10% of titanium dioxide. <br><br>
While all of the resins hereinbefore described are suitable for use in the present invention, it is preferred to employ the resin in which the dibasic acid, the hydroxy aromatic acid and the aromatic diol are present in the molar proportions of about 1:2:1. Other molar proportions can be employed and resins have been used in which the molar proportions of, illustratively, tereph thalic acid, p-hydroxybenzoic acid and biphenol are 1:3:1, 1:5:1, 1:7:1 and 1:3.5:1. Physical blends of resins in which various proportions of reactants have been employed are also suitable for use. <br><br>
The composition of the present invention can be prepared by extrusion in accordance with generally known practice. For example, a twin screw extruder can be employed with addition of the polymer, selected talc and titanium dioxide at the feed throat and with addition of the glass roving at both the vent and feed i throat. <br><br>
The compositions so prepared can then be injection molded according to general practice using techniques familiar to the injection molding field. <br><br>
The invention is further illustrated by the following examples in which all parts and percentages are by weight unless otherwise indicated. These nonlimiting examples are illustrative of certain embodiments designed to teach those skilled in the art how to practice the invention and to represent the best mode contemplated for carrying out the invention. <br><br>
EXAMPLE 1 <br><br>
This example illustrates the synthesis of a copolyester useful in the present invention. <br><br>
- 7 - <br><br>
The following quantities of the following ingredient; are combined as indicated. <br><br>
Quantity <br><br>
Item <br><br>
Ingredient <br><br>
Grams <br><br>
Moles <br><br>
A <br><br>
P-hydroxybenzoic Acid <br><br>
138 <br><br>
1 <br><br>
B <br><br>
Phenyl Acetate <br><br>
170 <br><br>
1.25 <br><br>
C <br><br>
Therminol 77 <br><br>
500 <br><br>
— <br><br>
D <br><br>
Diphenyl Terephthalate <br><br>
318 <br><br>
1 <br><br>
E <br><br>
Hydrogen Chloride <br><br>
— <br><br>
— <br><br>
F <br><br>
Hydroquinone <br><br>
Ill <br><br>
1.01 <br><br>
G <br><br>
Therminol 77 <br><br>
500 <br><br>
Items A-D are charged to a four-necked, round bottom flask fitted.with a thermometer, a stirrer, a combined nitrogen and HCl inlet and an outlet connected to a condenser. Nitrogen is passed slowly through the inlet. The flask and its contents are heated to 18 0°C whereupon HCl is bubbled through the reaction mixture. The outlet head temperature is kept at 110°-12 0°C by external heating during the p-hydroxybenzoic acid, phenyl acetate ester exchange reaction. <br><br>
The flask and its contents are stirred at 180°C for 6 hours whereupon the HCl is shut off, the outlet head temperature raised to 180°-190°C and the mixture stirred at 220°C for 3.5 hours. Up to this point, 159 grams of distillate are collected in the condenser. Item F is then added and the temperature gradually increased from 220°C to 320°C over a period of 10 hours (10°C/hr). Stirring is continued at 320°C for 16 hours and then for three additional hours at 340°C to form a slurry. The total amount of distillate, consisting of phenol, acetic acid and phenyl acetate, amounts to 384g. Item G is added and the reaction mixture permitted to cool to 70°C. Acetone (750 ml) is added and the slurry filtered, the solids are extracted in a Soxhlet with acetone to remove items C and G. The solids are dried in vacuo at 110°C overnight whereupon the resultant copolyester (320g, 89.2% of theory) <br><br>
is recovered as a granular powder. <br><br>
- 8 - <br><br>
10 <br><br>
15 <br><br>
20 <br><br>
204184 <br><br>
EXAMPLE 2 <br><br>
518 parts of isophthalic acid, 1,557 parts of terephthalic acid, 5,175 parts of para-hydroxybenzoic acid, 6,885 parts of acetic anhydride and 2,325 parts of p,p'-bisphenol are mixed together and refluxed for 17 hours, at a temperature of about 180°C, after which the reflux condenser is replaced with a distilling head and the temperature is raised to 345°C over a period of 1 and 1/4 hours. The reaction mixture is stirred throughout the heating period, being particularly actively mixed during the period in which the temperature is being raised to 345°C. The yield of polymer is 8,020 parts and 8,010 parts of distillate are recovered. The contents of the reaction vessel are removed, cooled and ground to particle sizes in the 20 to 160 mesh range, U.S. Standard Sieve Series. The resin made is of a molecular weight in the 5,000 -20,000 range, with an average weight in about the middle of such range. The product is estimated to be about 50% crystalline. <br><br>
The resin particles are held under vacuum illustratively at an elevated temperature at an absolute pressure of about 100 mm of mercury for eight hours and recovered as a granular powder. <br><br>
EXAMPLE 3 <br><br>
The following quantities of the following ingredients are combined as indicated. <br><br>
Quantity <br><br>
Item A B C D <br><br>
Ingredient <br><br>
Grams <br><br>
Moles <br><br>
Terephthalic Acid P-Hydroxybenzoic Acid p,p'-biphenol Acetic Anhydride <br><br>
291 1.75 <br><br>
483 3.50 <br><br>
325 1.75 <br><br>
755 7.40 <br><br>
Items A-D are heated to 145°C and refluxed overnight. ,The reflux condenser is removed and a distilling head put in place, "JPhe mixture is heated with stirring at a rate of 20°C/hour to <br><br>
I <br><br>
300°C and the contents of the reactor removed. At this point, <br><br>
^ - 9 - <br><br>
304184 <br><br>
about 92-94% of the theoretical acetic acid is collected. The pre-polymer is ground up and advanced as in Example 2, employing a temperature of about 250-375°C. <br><br>
EXAMPLE 4 <br><br>
Quantity <br><br>
Item A B C D E F <br><br>
Ingredient <br><br>
P-Hydroxybenzoic Acid Terephthaloyl Chloride Trimesic Acid Therminol 66 p,p'-biphenol Acetic Anhydride <br><br>
Grams 276.0 203 8.4 1274 186 224 .6 <br><br>
Moles (2.00) 1.0 0.040 <br><br>
1.0 2.2 <br><br>
Items A-D are heated to 130°C and held one hour. The reaction is exothermic and care is taken to maintain temperature at 130°C. The contents are then heated at 1556C for one hour and 180°C for 4 hours. The mixture is then cooled to 150°C and item E added whereby the temperature is further reduced to 140°C. Item F is then added. This mixture is then refluxed one hour at 155°C and the reflux condenser replaced by a distillation column. While distilling the acetic acid formed, the contents of the reactor are heated to 330°C and held 3 hours. The suspended polymer is cooled to 250°C and the mixture passed through a filter. The solid material is worked with trichloroethylene to remove the heat transfer fluid. The dried powder is advanced further in vacuum as in Example 2. <br><br>
EXAMPLES 5, 6 AND 7 <br><br>
The procedure of Example 3 is repeated employing the quantities of the ingredients indicated. '»/ <br><br>
£* <br><br>
L''«***;.■ <br><br>
204184 <br><br>
Quantity in Moles <br><br>
Item A B C D <br><br>
Ingredient <br><br>
Terephthalic Acid p-Hydroxybenzoic Acid p,p'-biphenol Acetic Anhydride <br><br>
Ex. 5 1 3 1 <br><br>
Ex. <br><br>
Ex. 7 <br><br>
1 1 <br><br>
4 5 <br><br>
1 1 <br><br>
•A#' <br><br>
c t <br><br>
EXAMPLE 8 <br><br>
268 parts of biphenol, 396 parts of para-hydroxybenzoic acid, 693.40 parts of acetic anhydride and 238 parts of terephthalic acid are admixed and heated to a temperature of 315°C over a period of 5 hours at a 30°C per hour rate of rise for the temperature. The reaction mixture is stirred throughout the heating period. When the temperature of 315°C is reached, the polymer contents are removed from the reaction vessel and ground to a particle size in the 20 to 200 mesh range, U.S. Standard Sieve Series. The resin particles are incrementally advanced in an oven to a temperature of 354°C over a period of 16 hours and recovered as a granular powder. <br><br>
EXAMPLE 9 <br><br>
A molding composition was prepared from the polymer of Example 8 by extruding a mixture of 257.5 parts of the polymer of Example 8, 30 parts of rutile titanium dioxide and 212.5 parts of a high purity talc having the platy structure of natural talc, a loss on ignition of 2% weight percent, an iron content analyzed as Fe2C>2 of 0.5% and a particle size distribution in which over 9 5% of the particles are less than 40 microns. <br><br>
The resulting blend was injection molded to provide molded bowls of a uniform, pleasing appearance which showed no cracking or blistering at minimum temperatures of about 260°C. <br><br>
Certain of the molded articles were subjected to a stain test in which a dollop of barbecue sauce was placed on the bottom f the molded container. The container was then placed in a 350°F <br><br>
- 11 - <br><br></p>
</div>
Claims (18)
1. A moulding composition comprising from 35% to 85%'by weight of a wholly aromatic polyester and from 2% to 60% by weight of a talc which has a weight loss on ignition of not more than 6% by weight at 950°C and not more than 2% by weight at 800°C, such that during moulding at elevated temperatures said composition is not blistered, bubbled or cracked.<br><br>
2. A composition according to claim 1, comprising an iron content analyzed as iron oxide of not more than 1% by weight.<br><br>
3. A composition according to claim 1 or claim 2, containing from 2% to 20% by weight of rutile titanium dioxide.<br><br>
4. A composition according to claim 3 wherein the amount of rutile titanium dioxide is from 5% by weight to 15% by weight.<br><br>
5. A composition according to any one of the preceding claims wherein the amount of talc is from 35% by weight to 55% by weight.<br><br>
6. A composition according to any one of the preceding claims wherein the talc is selected from high purity talc, highly refined talc, calcined talc and acid-treated talc.<br><br>
7. A composition according to any one of the preceding claims wherein the aromatic polyester is an oxybenzoyl polyester.<br><br>
8. A composition according to claim 7 wherein the oxybenzoyl polyester contains one or more recurrent moieties selected from groups of the following formulae:<br><br> II<br><br> - 13 -<br><br> 204184<br><br> V<br><br> \ r vK<br><br> —* r «—<br><br> III<br><br> •J •<br><br> IV<br><br> -oc<br><br> VI<br><br> o ft where X is -0-, -S-, -C-, -NH-,or -S02~ and n is O or 1 and the total of the integers p+q+r+s+t+uin the moieties present is from 3 to 800.<br><br>
9. A composition according to claim 8 in which the ratio °f q/r, q/u, t/r, t/u, q + ^/r + u and t/r + u, when present,<br><br> is substantially €rom 10/11 .to 11/10.<br><br>
10. A composition according to claim 9 in v;hich the ratio is 10/10.<br><br>
11. A composition according to claim 8,9 or 10 wherein p + q + r = 20 to 200.<br><br>
12. A composition according to claim 7 wherein the r of oxybenzoyl polyester has recurring units of each! formulae VII, VIII and IX:<br><br> O<br><br> 9 V£-4-<br><br> -*p<br><br> VII<br><br> VIII<br><br> - 14 -<br><br> /ft* %<br><br> !.. ■«><br><br> f 11 AU6198&,<br><br> "//<br><br> 204,194<br><br> -.ohQ^<«>„-0V<br><br> XX<br><br> wherein x is -0- or -SC^-; m is 0 or 1; n is 0 or 1, q:r = 10:15 to 15:10; p:q = 1:100 to 100:1;<br><br> p + q + r = 3 to 600; the carbonvl groups of the moiety of formula VII or VIII are linked to the oxy groups of the moiety of formula VII or IX: and the oxy groups of the moiety of formula VII or IX are linked to the carbonyl groups of the moiety of formula VII or VIII.<br><br>
13, A composition according to claim 7 wherein the oxybenzoyl polyester has recurring units of the formula:<br><br> - -K> <-o-Q-?-o-€X>'<br><br>
14. A composition according to claim 1 substantially as described with reference to any one of Examples 9 to 18.<br><br>
15. Ovenware comprising a moulded article of a moulding composition as claimed in any one of the preceding claims.<br><br>
16. A process of preparing food in permanent cook-in ovenware capable of repeated usage which comprises placing the food in ovenware as claimed in claim 15 and heating the food to serving temperature.<br><br>
17, A process according to claim 16 wherein the heat source is thermal.<br><br>
18. a process according to source is microwave.<br><br> claim 16 wherein the heat<br><br> 2041 $4<br><br> -19. A composition according to claim 1, substantially as hereinbefore described.<br><br> DART INDUSTRIES INC By Their Attorneys HENRY HUGHES LIMITED<br><br> 16 -<br><br> </p> </div>
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US40176582A | 1982-07-26 | 1982-07-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
NZ204184A true NZ204184A (en) | 1986-10-08 |
Family
ID=23589142
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NZ204184A NZ204184A (en) | 1982-07-26 | 1983-05-10 | Polyester compositions containing talc and ovenware manufactured therefrom |
Country Status (27)
Country | Link |
---|---|
JP (1) | JPS5936154A (en) |
KR (1) | KR840005473A (en) |
AT (1) | AT395519B (en) |
AU (1) | AU561068B2 (en) |
BE (1) | BE896763A (en) |
BR (1) | BR8302838A (en) |
CA (1) | CA1228688A (en) |
CH (1) | CH663141A5 (en) |
DE (1) | DE3326733A1 (en) |
DK (1) | DK338983A (en) |
ES (1) | ES524426A0 (en) |
FI (1) | FI831780L (en) |
FR (1) | FR2537149B1 (en) |
GB (1) | GB2124236B (en) |
GR (1) | GR77516B (en) |
IE (1) | IE54564B1 (en) |
IT (1) | IT1173669B (en) |
LU (1) | LU84809A1 (en) |
MA (1) | MA19812A1 (en) |
NL (1) | NL8302500A (en) |
NO (1) | NO832187L (en) |
NZ (1) | NZ204184A (en) |
PH (1) | PH19608A (en) |
PL (1) | PL243165A1 (en) |
PT (1) | PT77078B (en) |
SE (1) | SE8304131L (en) |
ZA (1) | ZA833395B (en) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4503168A (en) * | 1983-05-25 | 1985-03-05 | Union Carbide Corporation | Cookware made from polyarylethersulfone |
JPH062812B2 (en) * | 1984-04-17 | 1994-01-12 | 三菱化成株式会社 | Method for producing copolyester |
US4563508A (en) * | 1984-05-18 | 1986-01-07 | Dart Industries, Inc. | Injection moldable aromatic polyesters compositions and method of preparation |
JPS61315A (en) * | 1984-06-12 | 1986-01-06 | 住友化学工業株式会社 | Oven wear |
JPS61316A (en) * | 1984-06-13 | 1986-01-06 | 住友化学工業株式会社 | Oven wear |
JPS61199821A (en) * | 1985-03-01 | 1986-09-04 | 住友化学工業株式会社 | Plastic oven wear having non-stickiness |
JPH0638520B2 (en) * | 1986-02-03 | 1994-05-18 | ポリプラスチックス株式会社 | Light emitting device |
JPH0610255B2 (en) * | 1986-06-03 | 1994-02-09 | ユニチカ株式会社 | Method for producing liquid crystalline polyester |
JPH0739533B2 (en) * | 1986-12-10 | 1995-05-01 | ポリプラスチックス株式会社 | Liquid crystalline polyester resin composition |
FR2634215A1 (en) * | 1988-07-13 | 1990-01-19 | Rhone Poulenc Chimie | MOLDING COMPOSITIONS BASED ON THERMOTROPIC POLYMERS REINFORCED BY MINERAL CHARGES |
JP2736906B2 (en) * | 1988-11-30 | 1998-04-08 | 日本石油化学株式会社 | Method for blending thermoplastic wholly aromatic polyester resin composition |
NL8901535A (en) * | 1989-06-17 | 1991-01-16 | Stamicarbon | POLYMER COMPOSITION. |
JP2884362B2 (en) * | 1990-04-20 | 1999-04-19 | 日本石油化学株式会社 | Cooking table for induction cooker |
GB2313378B (en) * | 1996-05-22 | 2001-01-31 | Courtaulds Plc | A container or part thereof for packaging |
FR2768075B1 (en) * | 1997-09-05 | 1999-11-12 | Auxerroise De Distribution Sia | PROCESS FOR MANUFACTURING NUMBER OF ARTIFICIAL SHELLS OF SNAIL AND SHELLS OBTAINED THEREBY |
DE102006051723A1 (en) * | 2006-10-30 | 2008-05-08 | Zwilling J. A. Henckels Aktiengesellschaft | Pot for use on a stove and / or in an oven |
JP5869983B2 (en) | 2012-08-02 | 2016-02-24 | ポリプラスチックス株式会社 | Liquid crystalline resin composition |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3849362A (en) * | 1973-09-04 | 1974-11-19 | Carborundum Co | Incorporation of fillers in insoluble,infusible oxybenzoyl polymers |
JPS5128141A (en) * | 1974-09-03 | 1976-03-09 | Asahi Chemical Ind | MUKIJUTENZAIGANJUSENJOHORIESUTERUJUSHISOSEIBUTSU NO SEIZOHO |
US4080359A (en) * | 1975-07-18 | 1978-03-21 | Mitsubishi Petrochemical Co., Ltd. | Talc containing polyolefin compositions |
JPS5259653A (en) * | 1975-11-12 | 1977-05-17 | Teijin Ltd | Heat treatment of polyester composition |
US4067852A (en) * | 1976-05-13 | 1978-01-10 | Celanese Corporation | Melt processable thermotropic wholly aromatic polyester containing polybenzoyl units |
US4124561A (en) * | 1976-12-06 | 1978-11-07 | General Electric Company | Reinforced thermoplastic polyester compositions having improved shatter resistance |
US4244859A (en) * | 1977-11-15 | 1981-01-13 | Teijin Limited | Aromatic polyester composition |
US4140669A (en) * | 1977-12-30 | 1979-02-20 | General Electric Company | Warp-resistant reinforced thermoplastic compositions comprising polyester resins, talc and silica |
JPS54142260A (en) * | 1978-04-28 | 1979-11-06 | Toray Ind Inc | Polyester composition |
JPS5512102A (en) * | 1978-07-10 | 1980-01-28 | Teijin Ltd | Heat treatment of polyester resin molded article |
US4219629A (en) * | 1978-11-09 | 1980-08-26 | Dart Industries Inc. | P-Oxybenzoyl copolyesters comprising thiodiphenol components and having improved flexibility and solubility in organic solvents |
JPS5594930A (en) * | 1979-01-10 | 1980-07-18 | Sumitomo Chem Co Ltd | Preparation of aromatic polyester by improved bulk polymerization process |
US4219461A (en) * | 1979-04-23 | 1980-08-26 | Celanese Corporation | Polyester of 6-hydroxy-2-naphthoic acid, para-hydroxy benzoic acid, aromatic diol, and aromatic diacid capable of readily undergoing melt processing |
BR8008657A (en) * | 1979-05-01 | 1981-03-31 | Gen Electric | THERMOPLASTIC MOLDING COMPOSITION AND PROCESS |
US4256624A (en) * | 1979-07-02 | 1981-03-17 | Celanese Corporation | Polyester of 6-hydroxy-2-naphthoic acid, aromatic diol, and aromatic diacid capable of undergoing melt processing |
IE50008B1 (en) * | 1979-09-10 | 1986-01-22 | Dart Ind Inc | Improvements in or relating to plastics ovenware |
US4322333A (en) * | 1979-11-05 | 1982-03-30 | General Electric Company | Reinforced PBT-copolyaromatic/aliphatic block copolyesters |
US4265802A (en) * | 1980-01-04 | 1981-05-05 | Celanese Corporation | Polyester of para-hydroxy benzoic acid, 1,4-bis(para-carboxyphenoxy) benzene, aromatic diol and aromatic diacid capable of undergoing melt processing |
US4460735A (en) * | 1980-07-03 | 1984-07-17 | Celanese Corporation | Blend of polycarbonate and wholly aromatic polyester |
-
1983
- 1983-05-06 IE IE1046/83A patent/IE54564B1/en not_active IP Right Cessation
- 1983-05-09 CA CA000427699A patent/CA1228688A/en not_active Expired
- 1983-05-10 NZ NZ204184A patent/NZ204184A/en unknown
- 1983-05-11 ZA ZA833395A patent/ZA833395B/en unknown
- 1983-05-12 AU AU14496/83A patent/AU561068B2/en not_active Ceased
- 1983-05-17 LU LU84809A patent/LU84809A1/en unknown
- 1983-05-17 BE BE0/210787A patent/BE896763A/en not_active IP Right Cessation
- 1983-05-19 FI FI831780A patent/FI831780L/en not_active Application Discontinuation
- 1983-05-25 FR FR8308632A patent/FR2537149B1/en not_active Expired
- 1983-05-30 BR BR8302838A patent/BR8302838A/en unknown
- 1983-06-09 MA MA20034A patent/MA19812A1/en unknown
- 1983-06-09 AT AT0211283A patent/AT395519B/en not_active IP Right Cessation
- 1983-06-16 NO NO832187A patent/NO832187L/en unknown
- 1983-06-23 GR GR71762A patent/GR77516B/el unknown
- 1983-07-04 GB GB08318051A patent/GB2124236B/en not_active Expired
- 1983-07-05 PH PH29178A patent/PH19608A/en unknown
- 1983-07-13 NL NL8302500A patent/NL8302500A/en not_active Application Discontinuation
- 1983-07-19 CH CH3954/83A patent/CH663141A5/en not_active IP Right Cessation
- 1983-07-21 PT PT77078A patent/PT77078B/en unknown
- 1983-07-21 JP JP58132039A patent/JPS5936154A/en active Pending
- 1983-07-21 IT IT22179/83A patent/IT1173669B/en active
- 1983-07-25 PL PL24316583A patent/PL243165A1/en unknown
- 1983-07-25 SE SE8304131A patent/SE8304131L/en not_active Application Discontinuation
- 1983-07-25 KR KR1019830003426A patent/KR840005473A/en not_active Application Discontinuation
- 1983-07-25 DK DK338983A patent/DK338983A/en not_active Application Discontinuation
- 1983-07-25 DE DE19833326733 patent/DE3326733A1/en active Granted
- 1983-07-26 ES ES524426A patent/ES524426A0/en active Granted
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