NO982240L - Process for oxidizing organic substrates in the presence of metal complexes of tetra-, penta- and hexacoridinated ligands, as well as oxidation catalysts containing these - Google Patents
Process for oxidizing organic substrates in the presence of metal complexes of tetra-, penta- and hexacoridinated ligands, as well as oxidation catalysts containing theseInfo
- Publication number
- NO982240L NO982240L NO982240A NO982240A NO982240L NO 982240 L NO982240 L NO 982240L NO 982240 A NO982240 A NO 982240A NO 982240 A NO982240 A NO 982240A NO 982240 L NO982240 L NO 982240L
- Authority
- NO
- Norway
- Prior art keywords
- metal complex
- hexacoridinated
- penta
- ligands
- tetra
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/16—Peroxy compounds the —O—O— group being bound between two carbon atoms not further substituted by oxygen atoms, i.e. peroxides
- C07C409/18—Peroxy compounds the —O—O— group being bound between two carbon atoms not further substituted by oxygen atoms, i.e. peroxides at least one of the carbon atoms belonging to a ring other than a six-membered aromatic ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
- B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B41/00—Formation or introduction of functional groups containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
- C07C45/294—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with hydrogen peroxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/385—Saturated compounds containing a keto group being part of a ring
- C07C49/417—Saturated compounds containing a keto group being part of a ring polycyclic
- C07C49/423—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system
- C07C49/453—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system having three rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
- B01J2531/72—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/56—Ring systems containing bridged rings
- C07C2603/58—Ring systems containing bridged rings containing three rings
- C07C2603/70—Ring systems containing bridged rings containing three rings containing only six-membered rings
- C07C2603/74—Adamantanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Selektiv oksidasjonsprosess for organiske substrater ved å bringe substratene i berøring med et oksidasjons- middel utvalgt, fra hydroperoksd der og/eller hyd^ogen- peroksid i nærvær av en katalysator som inneholder et metallkompleks av minst en multikoordinerende nitroge- nert ligand, kjennetegnet ved at det molare metallkom- pleks/peroksid-forhold ligger mellom l og 10"10, idet temperaturen er lavere enn 120°C, og tnetallkomplekset har den generelle formel: [LxMyXj"Yq, hvor M betyr et mangan- eller jernatom i oksidert tilstand, X er en bro mellom metaller, Y er et motion, x og y er > l, O < u < 3, z er ladningen av metallkcmplekset, q = z/ladningen av Y, og L er en ligand med formel: RjA^N- (CH2)r-NAr2R2, hvor A^ og Ar3 er rettkjedede C^- til C6- karbonkjeder, forbundet med en nitrogenert hetero- cyklus, Rt og R2 er hydrogen eller en C^-Cs-alkylkjede som valgfritt kan være forbundet med en nitrogenert heterocyklus, og 2 < r <. 4.Selective oxidation process for organic substrates by contacting the substrates with an oxidizing agent selected, from hydroperoxide there and / or hydrogen peroxide in the presence of a catalyst containing a metal complex of at least one multi-coordinating nitrogenous ligand, characterized in that the molar metal complex / peroxide ratio is between 1 and 10 "10, the temperature being lower than 120 ° C, and the metal complex having the general formula: [LxMyXj" Y X is a bridge between metals, Y is a motion, x and y are> l, O <u <3, z is the charge of the metal complex, q = z / the charge of Y, and L is a ligand of the formula: R - (CH 2) r -NaR 2 R 2, where A 1 and Ar 3 are straight chain C 1 - to C 6 carbon chains linked by a nitrogenated hetero cycle, R t and R 2 are hydrogen or a C 1 a nitrogenized heterocycle, and 2 <r <. 4.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9513580A FR2741340B1 (en) | 1995-11-16 | 1995-11-16 | PROCESS FOR OXIDIZING ORGANIC SUBSTRATES IN THE PRESENCE OF METAL COMPLEXES OF TETRA-, PENTA- AND HEXACOORDINANTS AND OXIDATION CATALYSTS CONTAINING THEM |
PCT/FR1996/001804 WO1997018035A1 (en) | 1995-11-16 | 1996-11-15 | Oxidation process of organic substrates in the presence of metal complexes of tetra-, penta- and hexacoordinating ligands, and oxidation catalysts containing them |
Publications (2)
Publication Number | Publication Date |
---|---|
NO982240D0 NO982240D0 (en) | 1998-05-15 |
NO982240L true NO982240L (en) | 1998-07-16 |
Family
ID=9484620
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO982240A NO982240L (en) | 1995-11-16 | 1998-05-15 | Process for oxidizing organic substrates in the presence of metal complexes of tetra-, penta- and hexacoridinated ligands, as well as oxidation catalysts containing these |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0914205A1 (en) |
JP (1) | JP2000500151A (en) |
AU (1) | AU7628996A (en) |
CA (1) | CA2235764A1 (en) |
FR (1) | FR2741340B1 (en) |
NO (1) | NO982240L (en) |
WO (1) | WO1997018035A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69817832T2 (en) * | 1998-11-10 | 2004-10-07 | Unilever Nv | Bleaching and oxidation catalyst |
ES2223108T3 (en) * | 1998-11-10 | 2005-02-16 | Unilever N.V. | DETERGENT WHITENING COMPOSITIONS. |
US6573409B1 (en) | 1999-07-02 | 2003-06-03 | The Nutrasweet Company | Process for the preparation of 3,3-dimethylbutanal |
JP2005194244A (en) * | 2004-01-09 | 2005-07-21 | Shigenobu Yano | Zinc ion fluorescence sensor |
WO2013183591A1 (en) * | 2012-06-06 | 2013-12-12 | 保土谷化学工業株式会社 | Method for producing adamantanetriol |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4326084A (en) * | 1979-10-11 | 1982-04-20 | E. I. Du Pont De Nemours And Company | Process for producing a mixture containing cyclohexanol and cyclohexanone from cyclohexane |
US4459427A (en) * | 1981-10-31 | 1984-07-10 | The British Petroleum Company P.L.C. | Process for the conversion of an alkane to a mixture of an alcohol and a ketone |
FR2573087B1 (en) * | 1984-11-09 | 1987-07-10 | Inst Francais Du Petrole | METHOD OF SOFTENING OIL CUTTINGS CARRIED OUT IN THE ABSENCE OF AN ALKALINE COMPOUND |
US5990363A (en) * | 1987-01-02 | 1999-11-23 | Sun Company, Inc. | Method for oxidizing alkanes using novel porphyrins synthesized from dipyrromethanes and aldehydes |
FR2692499B1 (en) * | 1992-06-22 | 1994-08-26 | Atochem Elf Sa | Process for delignification and bleaching of a lignocellulosic material. |
US5329024A (en) * | 1993-03-30 | 1994-07-12 | National Starch And Chemical Investment Holding Corporation | Epoxidation of olefins via certain manganese complexes |
-
1995
- 1995-11-16 FR FR9513580A patent/FR2741340B1/en not_active Expired - Fee Related
-
1996
- 1996-11-15 AU AU76289/96A patent/AU7628996A/en not_active Abandoned
- 1996-11-15 JP JP9518635A patent/JP2000500151A/en active Pending
- 1996-11-15 CA CA002235764A patent/CA2235764A1/en not_active Abandoned
- 1996-11-15 WO PCT/FR1996/001804 patent/WO1997018035A1/en not_active Application Discontinuation
- 1996-11-15 EP EP96939124A patent/EP0914205A1/en not_active Withdrawn
-
1998
- 1998-05-15 NO NO982240A patent/NO982240L/en unknown
Also Published As
Publication number | Publication date |
---|---|
JP2000500151A (en) | 2000-01-11 |
NO982240D0 (en) | 1998-05-15 |
FR2741340A1 (en) | 1997-05-23 |
EP0914205A1 (en) | 1999-05-12 |
FR2741340B1 (en) | 1997-12-26 |
AU7628996A (en) | 1997-06-05 |
CA2235764A1 (en) | 1997-05-22 |
WO1997018035A1 (en) | 1997-05-22 |
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