FR2741340B1 - PROCESS FOR OXIDIZING ORGANIC SUBSTRATES IN THE PRESENCE OF METAL COMPLEXES OF TETRA-, PENTA- AND HEXACOORDINANTS AND OXIDATION CATALYSTS CONTAINING THEM - Google Patents

PROCESS FOR OXIDIZING ORGANIC SUBSTRATES IN THE PRESENCE OF METAL COMPLEXES OF TETRA-, PENTA- AND HEXACOORDINANTS AND OXIDATION CATALYSTS CONTAINING THEM

Info

Publication number
FR2741340B1
FR2741340B1 FR9513580A FR9513580A FR2741340B1 FR 2741340 B1 FR2741340 B1 FR 2741340B1 FR 9513580 A FR9513580 A FR 9513580A FR 9513580 A FR9513580 A FR 9513580A FR 2741340 B1 FR2741340 B1 FR 2741340B1
Authority
FR
France
Prior art keywords
hexacoordinants
penta
tetra
metal complexes
catalysts containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9513580A
Other languages
French (fr)
Other versions
FR2741340A1 (en
Inventor
Laurent Fraisse
Jean Jacques Girerd
Frederic Perie
Alain Rabion
David Tetard
Jean Baptiste Verlhac
Alexander Nivorozhkin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe National Elf Aquitaine
Original Assignee
Societe National Elf Aquitaine
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR9513580A priority Critical patent/FR2741340B1/en
Application filed by Societe National Elf Aquitaine filed Critical Societe National Elf Aquitaine
Priority to JP9518635A priority patent/JP2000500151A/en
Priority to EP96939124A priority patent/EP0914205A1/en
Priority to CA002235764A priority patent/CA2235764A1/en
Priority to AU76289/96A priority patent/AU7628996A/en
Priority to PCT/FR1996/001804 priority patent/WO1997018035A1/en
Publication of FR2741340A1 publication Critical patent/FR2741340A1/en
Application granted granted Critical
Publication of FR2741340B1 publication Critical patent/FR2741340B1/en
Priority to NO982240A priority patent/NO982240L/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/16—Peroxy compounds the —O—O— group being bound between two carbon atoms not further substituted by oxygen atoms, i.e. peroxides
    • C07C409/18—Peroxy compounds the —O—O— group being bound between two carbon atoms not further substituted by oxygen atoms, i.e. peroxides at least one of the carbon atoms belonging to a ring other than a six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C07C45/294—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with hydrogen peroxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C07C49/417—Saturated compounds containing a keto group being part of a ring polycyclic
    • C07C49/423—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system
    • C07C49/453—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system having three rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/58—Ring systems containing bridged rings containing three rings
    • C07C2603/70—Ring systems containing bridged rings containing three rings containing only six-membered rings
    • C07C2603/74—Adamantanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
FR9513580A 1995-11-16 1995-11-16 PROCESS FOR OXIDIZING ORGANIC SUBSTRATES IN THE PRESENCE OF METAL COMPLEXES OF TETRA-, PENTA- AND HEXACOORDINANTS AND OXIDATION CATALYSTS CONTAINING THEM Expired - Fee Related FR2741340B1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR9513580A FR2741340B1 (en) 1995-11-16 1995-11-16 PROCESS FOR OXIDIZING ORGANIC SUBSTRATES IN THE PRESENCE OF METAL COMPLEXES OF TETRA-, PENTA- AND HEXACOORDINANTS AND OXIDATION CATALYSTS CONTAINING THEM
EP96939124A EP0914205A1 (en) 1995-11-16 1996-11-15 Oxidation process of organic substrates in the presence of metal complexes of tetra-, penta- and hexacoordinating ligands, and oxidation catalysts containing them
CA002235764A CA2235764A1 (en) 1995-11-16 1996-11-15 Oxidation process of organic substrates in the presence of metal complexes of tetra-, penta- and hexacoordinating ligands, and oxidation catalysts containing them
AU76289/96A AU7628996A (en) 1995-11-16 1996-11-15 Oxidation process of organic substrates in the presence of metal complexes of tetra-, penta- and hexacoordinating ligands, and oxidation catalysts containing them
JP9518635A JP2000500151A (en) 1995-11-16 1996-11-15 Method of oxidizing an organic substrate in the presence of a metal complex having tetradentate, pentadentate and hexadentate ligands and an oxidation catalyst containing the complex
PCT/FR1996/001804 WO1997018035A1 (en) 1995-11-16 1996-11-15 Oxidation process of organic substrates in the presence of metal complexes of tetra-, penta- and hexacoordinating ligands, and oxidation catalysts containing them
NO982240A NO982240L (en) 1995-11-16 1998-05-15 Process for oxidizing organic substrates in the presence of metal complexes of tetra-, penta- and hexacoridinated ligands, as well as oxidation catalysts containing these

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9513580A FR2741340B1 (en) 1995-11-16 1995-11-16 PROCESS FOR OXIDIZING ORGANIC SUBSTRATES IN THE PRESENCE OF METAL COMPLEXES OF TETRA-, PENTA- AND HEXACOORDINANTS AND OXIDATION CATALYSTS CONTAINING THEM

Publications (2)

Publication Number Publication Date
FR2741340A1 FR2741340A1 (en) 1997-05-23
FR2741340B1 true FR2741340B1 (en) 1997-12-26

Family

ID=9484620

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9513580A Expired - Fee Related FR2741340B1 (en) 1995-11-16 1995-11-16 PROCESS FOR OXIDIZING ORGANIC SUBSTRATES IN THE PRESENCE OF METAL COMPLEXES OF TETRA-, PENTA- AND HEXACOORDINANTS AND OXIDATION CATALYSTS CONTAINING THEM

Country Status (7)

Country Link
EP (1) EP0914205A1 (en)
JP (1) JP2000500151A (en)
AU (1) AU7628996A (en)
CA (1) CA2235764A1 (en)
FR (1) FR2741340B1 (en)
NO (1) NO982240L (en)
WO (1) WO1997018035A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19605688A1 (en) * 1996-02-16 1997-08-21 Henkel Kgaa Transition metal complexes as activators for peroxygen compounds
DE69817832T2 (en) * 1998-11-10 2004-10-07 Unilever Nv Bleaching and oxidation catalyst
DE69825166T2 (en) * 1998-11-10 2004-11-25 Unilever N.V. Washing and bleaching compositions
US6573409B1 (en) 1999-07-02 2003-06-03 The Nutrasweet Company Process for the preparation of 3,3-dimethylbutanal
JP2005194244A (en) * 2004-01-09 2005-07-21 Shigenobu Yano Zinc ion fluorescence sensor
JP5593002B2 (en) * 2012-06-06 2014-09-17 保土谷化学工業株式会社 Method for producing adamantanetriols

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4326084A (en) * 1979-10-11 1982-04-20 E. I. Du Pont De Nemours And Company Process for producing a mixture containing cyclohexanol and cyclohexanone from cyclohexane
US4459427A (en) * 1981-10-31 1984-07-10 The British Petroleum Company P.L.C. Process for the conversion of an alkane to a mixture of an alcohol and a ketone
FR2573087B1 (en) * 1984-11-09 1987-07-10 Inst Francais Du Petrole METHOD OF SOFTENING OIL CUTTINGS CARRIED OUT IN THE ABSENCE OF AN ALKALINE COMPOUND
US5990363A (en) * 1987-01-02 1999-11-23 Sun Company, Inc. Method for oxidizing alkanes using novel porphyrins synthesized from dipyrromethanes and aldehydes
FR2692499B1 (en) * 1992-06-22 1994-08-26 Atochem Elf Sa Process for delignification and bleaching of a lignocellulosic material.
US5329024A (en) * 1993-03-30 1994-07-12 National Starch And Chemical Investment Holding Corporation Epoxidation of olefins via certain manganese complexes

Also Published As

Publication number Publication date
JP2000500151A (en) 2000-01-11
FR2741340A1 (en) 1997-05-23
NO982240L (en) 1998-07-16
AU7628996A (en) 1997-06-05
EP0914205A1 (en) 1999-05-12
WO1997018035A1 (en) 1997-05-22
NO982240D0 (en) 1998-05-15
CA2235764A1 (en) 1997-05-22

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