NO954122L - Process of polymerization or copolymerization of propylene in liquid polymer, solid catalytic component and process of its preparation - Google Patents

Process of polymerization or copolymerization of propylene in liquid polymer, solid catalytic component and process of its preparation

Info

Publication number
NO954122L
NO954122L NO954122A NO954122A NO954122L NO 954122 L NO954122 L NO 954122L NO 954122 A NO954122 A NO 954122A NO 954122 A NO954122 A NO 954122A NO 954122 L NO954122 L NO 954122L
Authority
NO
Norway
Prior art keywords
polymerization
propylene
catalytic component
copolymerization
preparation
Prior art date
Application number
NO954122A
Other languages
Norwegian (no)
Other versions
NO954122D0 (en
Inventor
Corinne Gomez-Journaud
Jean-Michel Brusson
Roger Spitz
Original Assignee
Appryl Snc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Appryl Snc filed Critical Appryl Snc
Publication of NO954122D0 publication Critical patent/NO954122D0/en
Publication of NO954122L publication Critical patent/NO954122L/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/61—Pretreating the metal or compound covered by group C08F4/60 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/612—Pretreating with metals or metal-containing compounds
    • C08F4/614—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6143—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/61—Pretreating the metal or compound covered by group C08F4/60 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/612—Pretreating with metals or metal-containing compounds
    • C08F4/616—Pretreating with metals or metal-containing compounds with silicon or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Det beskrives en fremgangsmåte ved polymerisasjon eller kopolymerisasjon av propylen i flytende pro- pylen i nærvær av en kokatalysator og av en fast katalytisk komponent oppnådd etter ha vært plassert i kontakt med a. en fast forbindelse inneholdende atomer av magnesium, halogen og av et overgangsmetall b. en organisk aluminiumsforbindelse (b) c. en dialkoksysilan med formel R^SiCOR3) (OR*) der R3 og R4 står for hydrokarbongrupper inneholdende fra 1-12 karbonatomer, fortrinnsvis metyl eller etyl, og R1 og R2 står for hydrokarbongrupper, i det minste en av gruppene R1 og R2 inneholder minst tre karbon- atomer. Det beskrives også en ny fast katalytisk kompo- nent for polymerisasjon av olefiner og en fremgangs- måte for dens fremstilling.There is disclosed a process of polymerization or copolymerization of propylene in liquid propylene in the presence of a cocatalyst and of a solid catalytic component obtained after being placed in contact with a. A solid compound containing atoms of magnesium, halogen and of a transition metal b an organic aluminum compound (b) c. a dialkoxysilane of formula R (SiCOR3) (OR *) wherein R3 and R4 represent hydrocarbon groups containing from 1 to 12 carbon atoms, preferably methyl or ethyl, and R1 and R2 represent hydrocarbon groups, in the at least one of the groups R1 and R2 contains at least three carbon atoms. A new solid catalytic component for the polymerization of olefins is also described and a process for its preparation.

NO954122A 1994-02-18 1995-10-17 Process of polymerization or copolymerization of propylene in liquid polymer, solid catalytic component and process of its preparation NO954122L (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9401883 1994-02-18
PCT/FR1995/000147 WO1995022568A1 (en) 1994-02-18 1995-02-08 Method for polymerising or copolymerising propylene in liquid propylene, solid catalytic component, and method for making same

Publications (2)

Publication Number Publication Date
NO954122D0 NO954122D0 (en) 1995-10-17
NO954122L true NO954122L (en) 1995-10-17

Family

ID=9460233

Family Applications (1)

Application Number Title Priority Date Filing Date
NO954122A NO954122L (en) 1994-02-18 1995-10-17 Process of polymerization or copolymerization of propylene in liquid polymer, solid catalytic component and process of its preparation

Country Status (8)

Country Link
EP (1) EP0702701A1 (en)
JP (1) JPH08509263A (en)
KR (1) KR960701907A (en)
CN (1) CN1123552A (en)
CA (1) CA2160806A1 (en)
FI (1) FI954937A (en)
NO (1) NO954122L (en)
WO (1) WO1995022568A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5058401B2 (en) * 1999-10-19 2012-10-24 出光興産株式会社 Olefin polymerization catalyst, process for producing olefin polymer, and olefin polymer
JP4505085B2 (en) * 1999-10-19 2010-07-14 出光興産株式会社 Olefin polymerization catalyst, process for producing olefin polymer, and olefin polymer
JP5058400B2 (en) * 1999-10-19 2012-10-24 出光興産株式会社 Propylene-based block copolymer production method and propylene-based block copolymer
JP2001302718A (en) * 2000-04-24 2001-10-31 Idemitsu Petrochem Co Ltd Catalyst for vapor phase polymerization, method for vapor phase polymerization using the same, and olefin polymer
US6689849B1 (en) 2000-04-24 2004-02-10 Idemitsu Petrochemical Co., Ltd. Catalyst for bulk polymerization, catalyst for vapor phase polymerization, method of polymerization using these, and olefin polymer obtained with these

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5842604A (en) * 1981-09-08 1983-03-12 Ube Ind Ltd Polymerization of alpha-olefin
US4442276A (en) * 1982-02-12 1984-04-10 Mitsui Petrochemical Industries, Ltd. Process for polymerizing or copolymerizing olefins
FR2669915B1 (en) * 1990-11-29 1993-01-29 Atochem MAGNESIUM CHLORIDE PARTICLES WITH POLYHEDRAL STRUCTURE, CATALYTIC COMPONENT SUPPORTED ON THESE PARTICLES, METHODS OF MANUFACTURING THESE PRODUCTS AND POLYOLEFINS OBTAINED FROM THIS CATALYTIC COMPONENT.
JPH04272907A (en) * 1991-02-27 1992-09-29 Mitsubishi Petrochem Co Ltd Production of olefin polymer
JP3355657B2 (en) * 1992-08-10 2002-12-09 東ソー株式会社 Method for producing polyolefin

Also Published As

Publication number Publication date
FI954937A0 (en) 1995-10-17
EP0702701A1 (en) 1996-03-27
NO954122D0 (en) 1995-10-17
JPH08509263A (en) 1996-10-01
KR960701907A (en) 1996-03-28
CA2160806A1 (en) 1995-08-24
CN1123552A (en) 1996-05-29
FI954937A (en) 1995-10-17
WO1995022568A1 (en) 1995-08-24

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