NO952606L - Process for oligomerizing olefins and olefin mixtures - Google Patents

Process for oligomerizing olefins and olefin mixtures

Info

Publication number
NO952606L
NO952606L NO952606A NO952606A NO952606L NO 952606 L NO952606 L NO 952606L NO 952606 A NO952606 A NO 952606A NO 952606 A NO952606 A NO 952606A NO 952606 L NO952606 L NO 952606L
Authority
NO
Norway
Prior art keywords
mixtures
olefins
oligomer
cocatalyst
olefin mixtures
Prior art date
Application number
NO952606A
Other languages
Norwegian (no)
Other versions
NO952606D0 (en
Inventor
Mika Kapanen
Erkki Halme
Salme Koskimies
Original Assignee
Neste Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Neste Oy filed Critical Neste Oy
Publication of NO952606D0 publication Critical patent/NO952606D0/en
Publication of NO952606L publication Critical patent/NO952606L/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/14Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/20Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06Halogens; Compounds thereof
    • C07C2527/08Halides
    • C07C2527/12Fluorides
    • C07C2527/1213Boron fluoride
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Lubricants (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Oligomerisering av olefiner eller ole- finblandinger, spesielt langkjedede hydrokarbon-blandinger inneholdende 6-20 karbonatomer, butener eller blandinger av disse olefiner, ved hjelp av et BF3/- kokatalysator-kompleks hvor kokataly- satoren er vann, C2.10-monoalkohol eller C2_10-monokarboksylsyre. Særlig fore- trukne kokatalysatorer er pentanol og n- valeriansyre. BF3 mates i gassformig tilstand til oligomeriseringsreaktoren som trykksettes med denne. Monomerbland- inger som oligomeriseres blir en sann ko-oligomer og den inneholder også dob- beltbindinger som øker produkt-reaktivi- teten, hvilket er nødvendig når oligo- meren anvendes som mellomprodukt.Oligomerization of olefins or olefin mixtures, especially long chain hydrocarbon mixtures containing 6-20 carbon atoms, butenes or mixtures of these olefins, by means of a BF3 / cocatalyst complex wherein the cocatalyst is water, C2.10 monoalcohol or C2-10 -monokarboksylsyre. Particularly preferred cocatalysts are pentanol and n-valeric acid. BF3 is fed in gaseous state to the oligomerization reactor which is pressurized therewith. Monomer mixtures that are oligomerized become a true co-oligomer and it also contains double bonds which increase product reactivity, which is necessary when the oligomer is used as an intermediate.

NO952606A 1992-12-31 1995-06-29 Process for oligomerizing olefins and olefin mixtures NO952606L (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI925969A FI93828C (en) 1992-12-31 1992-12-31 Method for oligomerization of olefin mixtures, oligomer prepared by the method and its use
PCT/FI1993/000540 WO1994015895A1 (en) 1992-12-31 1993-12-15 Method for oligomerization of olefins and olefin mixtures

Publications (2)

Publication Number Publication Date
NO952606D0 NO952606D0 (en) 1995-06-29
NO952606L true NO952606L (en) 1995-08-17

Family

ID=8536504

Family Applications (1)

Application Number Title Priority Date Filing Date
NO952606A NO952606L (en) 1992-12-31 1995-06-29 Process for oligomerizing olefins and olefin mixtures

Country Status (8)

Country Link
EP (1) EP0677033A1 (en)
JP (1) JPH08505848A (en)
KR (1) KR960700206A (en)
CA (1) CA2152669A1 (en)
CZ (1) CZ166895A3 (en)
FI (1) FI93828C (en)
NO (1) NO952606L (en)
WO (1) WO1994015895A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI95239C (en) * 1993-08-31 1996-01-10 Neste Oy Process for oligomerization of aromatic and alicyclic hydrocarbons containing olefinic group with boron trifluoride catalyst
CN113522191B (en) * 2020-04-20 2022-11-15 中国石油化工股份有限公司 Apparatus and method for producing polyalphaolefins
FI129793B (en) 2021-06-15 2022-08-31 Neste Oyj Process and apparatus for producing poly-alpha-olefins

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4263465A (en) * 1979-09-10 1981-04-21 Atlantic Richfield Company Synthetic lubricant
US4434309A (en) * 1982-06-18 1984-02-28 Texaco Inc. Oligomerization of predominantly low molecular weight olefins over boron trifluoride in the presence of a protonic promoter
FI90231C (en) * 1991-08-02 1994-01-10 Neste Oy Method for oligomerization of 1-butene

Also Published As

Publication number Publication date
CZ166895A3 (en) 1995-12-13
JPH08505848A (en) 1996-06-25
FI925969A (en) 1994-07-01
CA2152669A1 (en) 1994-07-21
NO952606D0 (en) 1995-06-29
FI93828B (en) 1995-02-28
FI925969A0 (en) 1992-12-31
EP0677033A1 (en) 1995-10-18
KR960700206A (en) 1996-01-19
FI93828C (en) 1995-06-12
WO1994015895A1 (en) 1994-07-21

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