KR960700206A - MEHTOD FOR OLIGOMERIZATION OF OLEFINS AND OLEFIN MIXTURES - Google Patents

MEHTOD FOR OLIGOMERIZATION OF OLEFINS AND OLEFIN MIXTURES

Info

Publication number
KR960700206A
KR960700206A KR1019950702710A KR19950702710A KR960700206A KR 960700206 A KR960700206 A KR 960700206A KR 1019950702710 A KR1019950702710 A KR 1019950702710A KR 19950702710 A KR19950702710 A KR 19950702710A KR 960700206 A KR960700206 A KR 960700206A
Authority
KR
South Korea
Prior art keywords
olefin
olefins
mixture
catalyst
oligomer
Prior art date
Application number
KR1019950702710A
Other languages
Korean (ko)
Inventor
카파넨 미카
할메 에르키
코스키미스 살메
Original Assignee
타파니 알로
네스테 오와이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 타파니 알로, 네스테 오와이 filed Critical 타파니 알로
Publication of KR960700206A publication Critical patent/KR960700206A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/20—Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/12—Fluorides
    • C07C2527/1213—Boron fluoride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Lubricants (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

본 발명은 올레핀 및 올레핀 혼합물, 특히 6-20개의 탄소 원자 또는 부텐 또는 이들 상기 올레핀의 혼합물을 포함하는 긴 사슬 탄화수소 혼합물을 BF3/촉매 복합체에 의해 올리고머화시키는 방법에 관한 것으로 촉매는 물, C2-C10의 모노알콜 또는 C2-C10의 모노 카르복실산이다. 특히 바람직한 촉매의 예로는 펜탄올 및 n-발레르산이다. BF3는 기체 상태로 올리고머화 반응기로 도입되고, 반응기는 가압된다, 이 경우, 단량체 혼합물은 올리고머화되고 생성물은 진정한 공-올리고머 형태이며, 생성물 반응성을 증가시키는 이중결합을 포함하고 올리고머가 중간체로서 사용될 필요가 있다.The present invention relates to a process for oligomerizing olefins and olefin mixtures, in particular long chain hydrocarbon mixtures comprising 6-20 carbon atoms or butenes or mixtures of these olefins by BF3 / catalyst complex, wherein the catalyst is water, C 2- C 10 monoalcohol or C 2 -C 10 mono carboxylic acid. Examples of particularly preferred catalysts are pentanol and n-valeric acid. BF 3 is introduced into the oligomerization reactor in the gas phase, and the reactor is pressurized, in which case the monomer mixture is oligomerized and the product is in the form of a true co-oligomer, which contains double bonds which increase product reactivity and the oligomer as intermediate Need to be used.

Description

올레핀 및 올레핀 혼합물의 올리고머화 방법(MEHTOD FOR OLIGOMERIZATION OF OLEFINS AND OLEFIN MIXTURES)MEHTOD FOR OLIGOMERIZATION OF OLEFINS AND OLEFIN MIXTURES

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

제1도 내지 제3도는 각각 본 발명에 따른 실시예들에 대한 질량 분석도이다.1 to 3 are mass spectrograms for embodiments according to the present invention, respectively.

Claims (10)

올레핀 또는 올레핀 혼합물을 BF3및 촉매로 부터 미리 제조한 BF3및 촉매로 이루어진 복합체와 접촉시키거나 또는 촉매 및 올레핀 또는 올레핀 혼합물을 포함하는 반응 챔버로 BF3가스를 공급함으로서 접촉시키는 것을 특징으로 하는 올레핀 또는 올레핀 혼합물을 올리고머화하는 방법.An olefin or olefin mixture, comprising a step of contacting by BF 3 and from the catalyst to advance in contact with the prepared consisting of a BF 3 and catalyst complex, or supplying a BF 3 gas to a reaction chamber containing the catalyst and the olefin, or olefin mixture Process for oligomerizing olefins or olefin mixtures. 제1항에 있어서, 올레핀이 1-20개의 탄소원자를 포함하는 알파-올레핀인 것을 특징으로 하는 방법.The method of claim 1 wherein the olefin is an alpha-olefin comprising 1-20 carbon atoms. 제2항에 있어서, 올레핀이 1-부텐 또는 C6-C20올레핀을 포함하는 혼합물인 것을 특징으로 하는 방법.The process of claim 2 wherein the olefin is a mixture comprising 1-butene or C 6 -C 20 olefins. 제2항에 있어서, 올레핀 혼합물이 1-부텐 및/또는 2-부텐, 즉 소위 라피네이트 Ⅱ 스트림을 포함하는 탄화수소 혼합물인 것을 특징으로 하는 방법.3. Process according to claim 2, characterized in that the olefin mixture is a hydrocarbon mixture comprising 1-butene and / or 2-butene, ie a so-called raffinate II stream. 제2항에 있어서, 올레핀 및 올레핀 혼합물이 C6-C20알파-올레핀 또는 이러한 올레핀을 포함하는 혼합물인 것을 특징으로 하는 방법.The method of claim 2 wherein the olefin and olefin mixture are C 6 -C 20 alpha-olefins or a mixture comprising such olefins. 제1항 내지 4항 중 어느 한 항에 있어서, 사용된 촉매가 C2-C10,모노카르복실산, 바람직하게는 아세트산, n-발레르산, 또는 n-옥탄산인 것을 특징으로 하는 방법.The process according to claim 1, wherein the catalyst used is C 2 -C 10, monocarboxylic acid, preferably acetic acid, n-valeric acid, or n-octanoic acid. 제1항 내지 4항 중 어느 한 항에 있어서, 사용된 촉매가 C2-C10,모노알콜, 바람직하게는 펜탄올인 것을 특징으로 하는 방법.Process according to any of the preceding claims, characterized in that the catalyst used is C 2 -C 10, monoalcohol, preferably pentanol. 점성도가 라피네이트 Ⅱ만으로 부터 얻어지는 올리고머 보다 더 높으며, 그 구조가 공-올리고머 형태인 것을 특징으로 하는 하나 이상의 올레핀 단량체로 부터 제1항 내지 7항 중 어느 한 항에 따른 방법으로 제조되는 올리고머.An oligomer prepared by the process according to any one of claims 1 to 7, characterized in that the viscosity is higher than the oligomers obtained only from raffinate II, the structure of which is in the form of a co-oligomer. 연료 또는 윤활제내의 용매, 예컨데 윤활제 및 연료에의 첨가제, 표면 활성제와 같은 사용가능한 화학물질의 제조를 위한 출발물질 및 공정 보조제로서 제8항에 따른 올리고머를 사용하는 방법.Use of the oligomers according to claim 8 as starting materials and process aids for the preparation of usable chemicals such as solvents in fuels or lubricants, for example lubricants and additives to fuels, surface active agents. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950702710A 1992-12-31 1993-12-15 MEHTOD FOR OLIGOMERIZATION OF OLEFINS AND OLEFIN MIXTURES KR960700206A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI925969 1992-12-31
FI925969A FI93828C (en) 1992-12-31 1992-12-31 Method for oligomerization of olefin mixtures, oligomer prepared by the method and its use
PCT/FI1993/000540 WO1994015895A1 (en) 1992-12-31 1993-12-15 Method for oligomerization of olefins and olefin mixtures

Publications (1)

Publication Number Publication Date
KR960700206A true KR960700206A (en) 1996-01-19

Family

ID=8536504

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950702710A KR960700206A (en) 1992-12-31 1993-12-15 MEHTOD FOR OLIGOMERIZATION OF OLEFINS AND OLEFIN MIXTURES

Country Status (8)

Country Link
EP (1) EP0677033A1 (en)
JP (1) JPH08505848A (en)
KR (1) KR960700206A (en)
CA (1) CA2152669A1 (en)
CZ (1) CZ166895A3 (en)
FI (1) FI93828C (en)
NO (1) NO952606L (en)
WO (1) WO1994015895A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI95239C (en) * 1993-08-31 1996-01-10 Neste Oy Process for oligomerization of aromatic and alicyclic hydrocarbons containing olefinic group with boron trifluoride catalyst
CN113522191B (en) * 2020-04-20 2022-11-15 中国石油化工股份有限公司 Apparatus and method for producing polyalphaolefins
FI129793B (en) 2021-06-15 2022-08-31 Neste Oyj Process and apparatus for producing poly-alpha-olefins

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4263465A (en) * 1979-09-10 1981-04-21 Atlantic Richfield Company Synthetic lubricant
US4434309A (en) * 1982-06-18 1984-02-28 Texaco Inc. Oligomerization of predominantly low molecular weight olefins over boron trifluoride in the presence of a protonic promoter
FI90231C (en) * 1991-08-02 1994-01-10 Neste Oy Method for oligomerization of 1-butene

Also Published As

Publication number Publication date
CZ166895A3 (en) 1995-12-13
NO952606L (en) 1995-08-17
JPH08505848A (en) 1996-06-25
FI925969A (en) 1994-07-01
CA2152669A1 (en) 1994-07-21
NO952606D0 (en) 1995-06-29
FI93828B (en) 1995-02-28
FI925969A0 (en) 1992-12-31
EP0677033A1 (en) 1995-10-18
FI93828C (en) 1995-06-12
WO1994015895A1 (en) 1994-07-21

Similar Documents

Publication Publication Date Title
JP3178928B2 (en) Production of Synthetic Oil from Vinylidene Olefin and α-Olefin
US3876720A (en) Internal olefin
GB1378449A (en) Oligomerization of olefins with boron trifluoride
KR940019666A (en) Process for preparing α-olefin oligomer and α-olefin oligomer composition
US3592869A (en) Olefin oligomerization
NO20033414L (en) Olefinoligomerisasjon
CA2001802A1 (en) Olefin oligomers functional fluid using internal olefins
KR960041140A (en) Method and apparatus for converting olefinic C4 oil into polyisobutene and propylene
KR850000364A (en) Process for producing premium gasoline by polymerization of C₄ fraction
JPS5492901A (en) Dimerization of isobutene-containing butenes
KR930023067A (en) Catalyst composition for alkylation of hydrocarbons and hydrocarbon alkylation method
ES2124903T3 (en) PROCEDURE FOR SULPHONING INTERNAL OLEFINS.
KR900012870A (en) Nickel Catalyst Substitution Reaction
US4254294A (en) Polymerization reactions in the presence of a catalyst containing aluminum oxide, boron oxide and halogen
US4110410A (en) Oligomerization of olefins
US3483268A (en) Dimerisation process
JPS56169630A (en) Preparation of fluid for lubricating oil
US3527839A (en) Ethylene oligomerization
KR960700206A (en) MEHTOD FOR OLIGOMERIZATION OF OLEFINS AND OLEFIN MIXTURES
GB1357632A (en) Process for the manufacture of higher olefins
US3927137A (en) Method of preparing nonconjugated diolefins
US2286184A (en) Process for producing paraffinic hydrocarbons
RU2002110125A (en) Oligomerization of olefins
US4463212A (en) Selective oligomerization of olefins
US3527838A (en) Ethylene oligomerization

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid