NO883125L - COATING COMPOSITIONS FOR TEXTILES. - Google Patents
COATING COMPOSITIONS FOR TEXTILES.Info
- Publication number
- NO883125L NO883125L NO88883125A NO883125A NO883125L NO 883125 L NO883125 L NO 883125L NO 88883125 A NO88883125 A NO 88883125A NO 883125 A NO883125 A NO 883125A NO 883125 L NO883125 L NO 883125L
- Authority
- NO
- Norway
- Prior art keywords
- approx
- water
- soluble polymer
- weight
- amount
- Prior art date
Links
- 239000008199 coating composition Substances 0.000 title claims description 25
- 239000004753 textile Substances 0.000 title description 9
- 239000000463 material Substances 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 16
- 229920003169 water-soluble polymer Polymers 0.000 claims description 16
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 15
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 15
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 15
- 239000003082 abrasive agent Substances 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 7
- 150000004676 glycans Chemical class 0.000 claims description 7
- 229920001282 polysaccharide Polymers 0.000 claims description 7
- 239000005017 polysaccharide Substances 0.000 claims description 7
- 238000007639 printing Methods 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Chemical class 0.000 claims description 5
- 229920002125 Sokalan® Chemical class 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 239000004584 polyacrylic acid Chemical class 0.000 claims description 5
- 229920002451 polyvinyl alcohol Chemical class 0.000 claims description 5
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Chemical class 0.000 claims description 3
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 claims description 3
- 229920001277 pectin Chemical class 0.000 claims description 3
- 239000001814 pectin Chemical class 0.000 claims description 3
- 235000010987 pectin Nutrition 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 239000000976 ink Substances 0.000 description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
- -1 polyethylene Polymers 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000004698 Polyethylene Substances 0.000 description 9
- 229920000573 polyethylene Polymers 0.000 description 9
- 239000000975 dye Substances 0.000 description 8
- 238000003384 imaging method Methods 0.000 description 7
- 239000000835 fiber Substances 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 4
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 3
- 229910021486 amorphous silicon dioxide Inorganic materials 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 238000010894 electron beam technology Methods 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 229920002907 Guar gum Polymers 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000004775 Tyvek Substances 0.000 description 2
- 229920000690 Tyvek Polymers 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Chemical class 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920000569 Gum karaya Polymers 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 241000934878 Sterculia Species 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 229940023476 agar Drugs 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 239000000420 anogeissus latifolia wall. gum Substances 0.000 description 1
- 239000000305 astragalus gummifer gum Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Chemical class 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Chemical class 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- 235000019314 gum ghatti Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/08—Organic compounds
- D06M10/10—Macromolecular compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Foreliggende oppfinnelse vedrører en fremgangsmåte for modifisering av overflaten til et syntetisk, fibrøst arkmateriale ved påføring på arkmaterialets overflate av en beleggsammensetning som kan motta merking med blyant, blekk og trykkeutstyr. The present invention relates to a method for modifying the surface of a synthetic, fibrous sheet material by applying to the surface of the sheet material a coating composition that can receive marking with pencil, ink and printing equipment.
Arkmaterialer fremstilt fra fibrer av syntetiske polymerer, slik som polyetylen- og polypropylenfiber, anvendes ofte som erstatning for papir i gjenbrukbare postkonvolutter og lig-nende artikler som krever en høy grad av motstandsevne overfor slitasje. Slike slitasjemotstandsdyktige papir-erstatninger har blitt begrenset av det faktum at slike syntetiske papirmaterialer ikke er mottagelige for å bli skrevet på med blyanter eller blekkpenner eller trykket på med konvensjonelle trykningsmedia, tydeligvis fordi deres overflater har tilbøyelighet til å være glatte og hydrofobe og mangle enhver kjemisk funksjonalitet som ville ha tendens til å samvirke med blekk og fargestoffer benyttet ved skriving og trykning. Sheet materials made from fibers of synthetic polymers, such as polyethylene and polypropylene fibers, are often used as a substitute for paper in reusable postal envelopes and similar articles that require a high degree of resistance to wear. Such wear-resistant paper substitutes have been limited by the fact that such synthetic paper materials are not amenable to being written on by pencils or ink pens or printed on by conventional printing media, apparently because their surfaces tend to be smooth and hydrophobic and lack any chemical functionality that would tend to interact with inks and dyes used in writing and printing.
Et forsøk på å takle dette problemet er beskrevet i US patent 4.092.457, som beskriver et fibrøst arkmateriale for forbedret offset-trykking, som består av minst en del poly-olefinfibrer, hvori en hydrofil komponent slik som polyvinylalkohol har blitt inkorporert ved polymerblanding eller podningspolymerisasjon før fibrene spinnes. Arkmaterialet behandles med en vannoppløselig polymer slik som polyvinylalkohol og polyakrylamid, samt med en vandig emulsjon av en polymer av høy molekylvekt slik som vinylacetat. Beleggsammensetningen tørkes deretter ved oppvarming. Behandling av arkmateriale, enten med en vannoppløselig polymer alene eller en vandig polymeremulsjon alene, gir ikke den effekt som forventes i nevnte patent. An attempt to deal with this problem is described in US patent 4,092,457, which describes a fibrous sheet material for improved offset printing, which consists of at least a portion of polyolefin fibers, into which a hydrophilic component such as polyvinyl alcohol has been incorporated by polymer mixing or graft polymerization before the fibers are spun. The sheet material is treated with a water-soluble polymer such as polyvinyl alcohol and polyacrylamide, as well as with an aqueous emulsion of a high molecular weight polymer such as vinyl acetate. The coating composition is then dried by heating. Treatment of sheet material, either with a water-soluble polymer alone or an aqueous polymer emulsion alone, does not produce the effect expected in the aforementioned patent.
Det ville være ønskelig å tilveiebringe en fremgangsmåte for modifisering av overflaten av et syntetisk, fibrøst arkmateriale ved påføring på arkmaterialet av en vannoppløselig beleggsammensetning som er herdbar ved bestråling alene for dannelse av et vannuoppløselig overflatebelegg som er mer mottagelig for merking med blyant, blekk og trykningsutstyr. It would be desirable to provide a method of modifying the surface of a synthetic fibrous sheet material by applying to the sheet material a water-soluble coating composition that is curable by irradiation alone to form a water-insoluble surface coating that is more amenable to marking with pencil, ink and printing equipment .
Ifølge foreliggende oppfinnelse er det tilveiebragt en frem-gangamåte for modifisering av overflaten av et syntetisk, fibrøst arkmateriale ved påføring på dets overflate av en beleggsammensetning innbefattende en vannoppløselig polymer, og denne fremgangsmåten er kjennetegnet ved at den vann-oppløselige polymer som er fotouoppløselig, har en molekylvekt fra ca. 10.000 til ca. 5 millioner, og er valgt fra gruppen besående av polysakkarider og alifatiske derivater av polysakkarider, polyvinylalkohol , polyakrylsyre, pektin og polyetylenoksyd. According to the present invention, a method is provided for modifying the surface of a synthetic, fibrous sheet material by applying to its surface a coating composition including a water-soluble polymer, and this method is characterized in that the water-soluble polymer, which is photo-insoluble, has a molecular weight from approx. 10,000 to approx. 5 million, and is selected from the group consisting of polysaccharides and aliphatic derivatives of polysaccharides, polyvinyl alcohol, polyacrylic acid, pectin and polyethylene oxide.
Den vannoppløselige polymeren har fortrinnsvis en molekylvekt fra ca. 500.000 til ca. 2 millioner, og er en hydroksyalkylcellulose, slik som hydroksyetyl- eller hydroksypropylcellulose, et aminoetylderivat av hydroksyetyl- eller hydroksypropylcellulose, en hydrofobt modifisert hydroksyetyl- eller hydroksypropylcellulose, eller karboksymetyl-cellulose. Mest foretrukket er hydroksypropylcellulose, hydroksypropylcellulose modifisert med fra ca. 1 til ca. 10 vekt-5é aminoetylgrupper, og hydroksypropylcellulose modifisert med fra ca. 0,1 til c. 2 vekt-# av en alkylkjede med 16 karbonatomer. The water-soluble polymer preferably has a molecular weight from approx. 500,000 to approx. 2 million, and is a hydroxyalkyl cellulose, such as hydroxyethyl or hydroxypropyl cellulose, an aminoethyl derivative of hydroxyethyl or hydroxypropyl cellulose, a hydrophobically modified hydroxyethyl or hydroxypropyl cellulose, or carboxymethyl cellulose. Most preferred is hydroxypropyl cellulose, hydroxypropyl cellulose modified with from approx. 1 to approx. 10 wt-5é aminoethyl groups, and hydroxypropyl cellulose modified with from approx. 0.1 to c. 2 wt # of an alkyl chain of 16 carbon atoms.
Andre egnede vannoppløselige polysakkarider innbefatter naturlige og syntetiske polymerer slik som guargummi og deres alifatiske derivater slik som karboksymetyl- og hydroksypropyl-modifisert guargummi, agar, karagengummi, gummi arabikum, ghattigummi, karayagummi, tragantgummi, Johannesbrødgummi , xantangummi og pektin, alle med molekylvekt fra ca. 20.000 til ca. 500.000, og fortrinnsvis fra 80.000 til ca. 400.000. Andre nyttige vannoppløselige polymerer er polyvinylalkohol, polyakrylsyre og polyetylen oksyd, alle med molekylvekt fra ca. 10.000 til ca. 2.000.000, og fortrinnsvis fra ca. 100.000 til ca. 1.000.000. Other suitable water-soluble polysaccharides include natural and synthetic polymers such as guar gum and their aliphatic derivatives such as carboxymethyl- and hydroxypropyl-modified guar gum, agar, carrageenan gum, gum arabic, ghatti gum, karaya gum, tragacanth gum, locust bean gum, xanthan gum and pectin, all with molecular weights from about . 20,000 to approx. 500,000, and preferably from 80,000 to approx. 400,000. Other useful water-soluble polymers are polyvinyl alcohol, polyacrylic acid and polyethylene oxide, all with molecular weights from approx. 10,000 to approx. 2,000,000, and preferably from approx. 100,000 to approx. 1,000,000.
Generelt, jo høyere molekylvekten til en gitt vannoppløselig polymer er, desto kortere er varigheten av herdebehandlingen som skal til for å oppnå et vandig, uoppløselig belegg. En beleggsammensetning omfattende hydroksypropylcellulose med gjennomsnittlig molekylvekt på 1.000.000 krever f.eks. bare ca. 15% av den f otoeksponering som skal til for en slik sammensetning som benytter hydroksypropylcellulose med en gjennomsnittlig molekylvekt på 60.000. Likeledes gir en beleggsammensetning som benytter polyakrylsyre med gjennomsnittlig molekylvekt på 4.000.000 akseptable vannuoppløselige belegg; når en slik sammensetning som benytter polyakrylsyre av gjennomsnittlig molekylvekt på 300.000, bestråles i samme tidsperiode og på samme måte oppnås et uakseptabelt belegg som ikke er vannuoppløselig. In general, the higher the molecular weight of a given water-soluble polymer, the shorter the duration of curing required to achieve an aqueous, insoluble coating. A coating composition comprising hydroxypropyl cellulose with an average molecular weight of 1,000,000 requires e.g. only approx. 15% of the photo exposure required for such a composition that uses hydroxypropyl cellulose with an average molecular weight of 60,000. Likewise, a coating composition using polyacrylic acid with an average molecular weight of 4,000,000 provides acceptable water-insoluble coatings; when such a composition using polyacrylic acid of average molecular weight of 300,000 is irradiated for the same period of time and in the same way an unacceptable coating is obtained which is not water insoluble.
Herding av foreliggende fotouoppløselige beleggsammensetninger kan konvensjonelt foretas ved behandling med ultrafiolett lys, elektronstråler eller korona-utladning. Eksponeringstid kan variere fra ca. 0,5 sek. til ca. 5 min. Den foretrukne eksponeringstid kan variere betraktelig, avhengig av slike parametrer som den spesielle vannoppløselige forbindelsen som benyttes i den fotouoppløselige beleggsammensetning, og molekylvekten til den vannoppløselige forbindelsen. Andre faktorer innbefatter herdemetode og mengden og/eller typen av ultrafiolett-transparent abrasivmaterlale som benyttes. Curing of the present photo-insoluble coating compositions can conventionally be carried out by treatment with ultraviolet light, electron beams or corona discharge. Exposure time can vary from approx. 0.5 sec. to approx. 5 min. The preferred exposure time can vary considerably, depending on such parameters as the particular water-soluble compound used in the photo-insoluble coating composition, and the molecular weight of the water-soluble compound. Other factors include curing method and the amount and/or type of ultraviolet-transparent abrasive material used.
I foreliggende fremgangsmåte omfatter beleggsammensetningen også fortrinnsvis et ultrafiolett-transparent abrasiv-materiale av partikkelstørrelse mindre enn ca. 0,05 mm (50 pm), som forbedrer evnen til å akseptere merking med blyant eller blekk, i motsetning til trykking med fargestoffer. Et hvilket som helst partikkelformlg abrasivmaterlale av den nødvendige partikkelstørrelsen, og som har i det minste delvis ultrafiolett-transparens, er egnet i foreliggende f oruoppløsel ige beleggsammensetninger. Si 1 islumdioksyd er det foretrukne abrasivmaterialet delvis p.g.a. dets hardhet og utmerkede ultrafiolett-transparens-egenskaper. Andre egnede abrasivmaterialer er partikler av glass, kalsiumkarbonat, aluminiumhydroksyd, sinkoksyd, titandioksyd, kalsiumkarbonat og magnesiumoksyd. In the present method, the coating composition also preferably comprises an ultraviolet-transparent abrasive material of particle size smaller than approx. 0.05 mm (50 pm), which improves the ability to accept marking with pencil or ink, as opposed to printing with dyes. Any particulate form of abrasive material of the required particle size, and having at least partial ultraviolet transparency, is suitable in the present insoluble coating compositions. Si 1 islum dioxide is the preferred abrasive material partly because its hardness and excellent ultraviolet transparency properties. Other suitable abrasive materials are particles of glass, calcium carbonate, aluminum hydroxide, zinc oxide, titanium dioxide, calcium carbonate and magnesium oxide.
Mengden av vannoppløselig forbindelse som benyttes og vekt-prosentforholdet for vannoppløselig forbindelse til abrasivmaterialet kan begge variere avhengig av slike parametrer som de spesifikke vannoppløselige forbindelsene og de abrasive stoffene som benyttes, spesielt den spesielle syntetiske, flberholdige tekstiloverflaten som skal belegges, og som er ytterligere beskrevet nedenfor, graden av mottagelighet for avbildning med blyant, blekkpenn, trykkmateriale eller fargestoff som er ønsket på tekstiloverflaten, og de spesifikke sluttanvendelser som er påtenkt for det således belagte, syntetiske, flberholdige tekstilmaterialet. The amount of water-soluble compound used and the weight-percentage ratio of water-soluble compound to the abrasive material can both vary depending on such parameters as the specific water-soluble compounds and abrasives used, particularly the particular synthetic fiber-containing textile surface to be coated, which is further described below, the degree of receptivity to imaging with pencil, ink pen, printing material or dye desired on the textile surface, and the specific end uses contemplated for the thus coated synthetic fibrous textile material.
Beleggsammensetninger ifølge foreliggende oppfinnelse innbefatter fortrinnsvis fra ca. 0,1 til ca. 5 vekt-% av den vannoppløselige polymeren, og opptil 1 vekt-56 av abrasivmaterialet. Mer foretrukket inneholder beleggsammensetnin-gene fra ca. 0,3 til ca. 2 vekt-# av den vannoppløselige polymeren, og fra ca. 0,05 til ca. 0,5 vekt-# av abrasivmaterialet. Coating compositions according to the present invention preferably include from approx. 0.1 to approx. 5% by weight of the water-soluble polymer, and up to 1% by weight of the abrasive material. More preferably, the coating compositions contain from approx. 0.3 to approx. 2 wt-# of the water-soluble polymer, and from approx. 0.05 to approx. 0.5 wt-# of the abrasive material.
Vann er den foretrukne bæreren i foreliggende oppfinnele for uoppløselige beleggsammensetninger, men overflateaktive mid-ler eller organiske ko-oppløsningsmidler, f.eks. aceton, kan benyttes som belegningshjelpemidler avhengig av aktuelle sluttresultater som belegningsgrad- og tykkelse. Water is the preferred carrier in the present invention for insoluble coating compositions, but surfactants or organic co-solvents, e.g. acetone, can be used as coating aids depending on the relevant end results such as coating degree and thickness.
Ikke-vevede og vevede syntetiske flberholdige arkmaterialer er egnede substrater for foreliggende beleggsammensetninger. Foretrukne er spinnebundede ikke-vevede stoffer omfattende polyetylen- eller polypropylenfibrer, slik som er kommersielt tilgjengelige fra E. I. du Pont de Nemours som Tyvek- og Typar-kvaliteter, respektivt. Andre eksempler på syntetiske flberholdige materialer egnet som substrater for foreliggende beleggsammensetnninger, innbefatter vevede eller Ikke-vevede materialer fremstilt fra polyolefiner, og halogenerte derivater av polyolefiner, polyester, polyacetyl, polyamid, poly-akrrylat eller —metakrylat, og silikonfibrer. Nonwoven and woven synthetic fibrous sheet materials are suitable substrates for the present coating compositions. Preferred are spunbond nonwovens comprising polyethylene or polypropylene fibers, such as are commercially available from E. I. du Pont de Nemours as Tyvek and Typar grades, respectively. Other examples of synthetic fibrous materials suitable as substrates for the present coating compositions include woven or non-woven materials made from polyolefins, and halogenated derivatives of polyolefins, polyester, polyacetyl, polyamide, polyacrylate or methacrylate, and silicone fibers.
Følgende eksempler illustrerer mer fullstendig oppfinnelsens foretrukne utførelser. The following examples more fully illustrate the preferred embodiments of the invention.
Eksempel 1Example 1
Dette eksempelet demonstrerer en foretrukket beleggsammensetning ifølge oppfinnelsen og spesielt dens enestående foto-følsomme egenskaper som er ansvarlig når det gjelder å gl syntetiske flberholdige tekstilmaterialer forbedret blyant-og blekkpenn-avbildnlngsmottagelighet. This example demonstrates a preferred coating composition of the invention and in particular its unique photo-sensitive properties responsible for glazing synthetic fibrous textile materials with improved pencil and ink pen imaging receptivity.
En fotouoppløselig beleggsammensetning fremstilles ved dis-pergering av 0,25 g (0,14 vekt-56) amorft silisiumdioksyd av en partikkelstørrelse mindre enn ca. 0,01 mm (10 >im), (Illi-nois Minerals IMSIL A-15), en oppløsning av 1,0 g (0,56 vekt-5é) hydroksypropylcellulose modifisert med 5 vekt-5é aminoetylgrupper (Hercules' Klucel® 6) i 139 ml vann og 55 ml aceton. A photo-insoluble coating composition is prepared by dispersing 0.25 g (0.14 wt-56) of amorphous silicon dioxide of a particle size smaller than approx. 0.01 mm (10 µm), (Illinois Minerals IMSIL A-15), a solution of 1.0 g (0.56 wt-5é) hydroxypropyl cellulose modified with 5 wt-5é aminoethyl groups (Hercules' Klucel® 6 ) in 139 ml of water and 55 ml of acetone.
En lapp av splnnebundet polyetylen-tekstilmateriale (Du Pont's Tyvek) dyppes deretter i den ovenfor beskrevne beleggsammensetning, tørkes i 1 time ved 60°C i en ovn med tvungen luftsirkulasjon og eksponeres i 2 sek. for bestrålingen fra en høytrykk-mikrobølgekvikksølvlampe. Lappen vaskes deretter i 1 time I en vann/aceton-blanding med vektprosentforhold 76/24 for å bestemme beleggsammensetnlngens motstandsevne overfor oppløsning, og deretter med hensyn til blyant- og blekkpenn-avbildnlngsmottagelighet. A patch of spunbonded polyethylene textile material (Du Pont's Tyvek) is then dipped in the coating composition described above, dried for 1 hour at 60°C in a forced air oven and exposed for 2 seconds. for the irradiation from a high-pressure microwave mercury lamp. The patch is then washed for 1 hour in a 76/24 weight percent water/acetone mixture to determine the coating composition's resistance to dissolution, and then for pencil and ink pen imaging receptivity.
Skriving på den fotoeksponerte siden av lappen med en nr. 2 grafittblyant og vanlig blekkpenn resulterte i bildekvalitet som var sammenlignbar med den oppnådd ved skriving på et stykke vanlig skrivepapir. En lapp preparert på samme måte, ikke eksponert for bestråling, ga etter vasking omtrent samme ikke-avbildningsmottagelighet for blyant og blekkpenn som observert på et ubehandlet lappmaterlale. Writing on the photoexposed side of the note with a No. 2 graphite pencil and regular ink pen resulted in image quality comparable to that obtained by writing on a piece of regular writing paper. A patch prepared in the same manner, not exposed to irradiation, gave after washing about the same non-imaging receptivity to pencil and ink pen as observed on an untreated patch material.
Eksempler 2- 4Examples 2-4
Eksemplene 2-4 illustrerer ytterligere foretrukne utførelser ifølge oppfinnelsen. Examples 2-4 illustrate further preferred embodiments according to the invention.
I eksempel 2 dispergeres 0,5 g (0,1 vekt-5^) IMSIL A-15 amorft silisiumdioksyd i en oppløsning av 2,0 g (0,4 vekt-Sé) hydroksypropylcellulose (Hercules<*>Klucel® H) i 500ml vann. ;En lapp av spinnebundet polyetylen-tekstilmateriale belegges deretter i ovennevnte sammensetning, fotoeksponeres som i eksempel 1, med unntagelse av at det anvendes en eksponeringstid på 5 sek., og vaskes ytterligere som angitt i eksempel 1. Som i eksempel 1 er blyant- og blekkpenn-avbildningsmotage-ligheten til det behandlede lappmaterlale sammenlignbar med den som oppnås ved skriving på vanlig skrivepapir. ;I eksempel 3 dispergeres 0,15 g (0,09 vekt-£) IMSIL A-15 amorft silisiumdioksyd i en oppløsning av 0,6 g (0,36 vekt-%) hydroksyetylcellulose med 0,55 vekt-£ modifikasjon med en 16-karbonkjede (Hercules Incorporated WSP D-330 ) I 125 ml vann og 51 ml aceton. ;Et spinnebundet polyetylen-lappmateriale belegges og behandles som i eksempel 1. Som før er blyant- og blekkpenn-avbildningsmottageligheten sammenlignbar med den oppnådd ved skriving på vanlig skrivepapir. ;I eksempel 4 dispergres 0,5 g (0,3 vekt-#) IMSIL A-15 amorft sllisiumdioksyd i en oppløsning av 2,0 g (1,2 vekt-#) modifisert hydroksypropylcellulose (inneholdende 0,3 vekt-$ til-føyede 16-karbonkjeder) i 125 ml vann og 51 ml aceton. ;Et spinnebundet polyetylen-lappmateriale behandles deretter som i eksempel 1, med unntagelse av at det anvendes en 30 sekunders fotoeksponerIng. Blyant- og blekkpenn-avbildnlngs-mottagel igheten til det således behandlede lappmaterialet er sammenlignbar med den oppnådd ved skriving på vanlig skrivepapir. ;Eksempel 5;Dette eksempel illustrerer ytterligere en utførelse ifølge oppfinnelsen hvorved det anvendes en korona-utladningskilde istedenfor ultrafiolett lys, for å fremstille en foto-uoppløselig beleggsammensetning ifølge foreliggende oppfinnelse . ;181,4 g (0,1 vekt-*) IMSIL A-15 amorft sllisiumdioksyd dispergeres i en oppløsning av 725,8 g (0,4 vekt-#) hydroksypropylcellulose i 181,4 kg vann. In Example 2, 0.5 g (0.1 wt-5^) of IMSIL A-15 amorphous silica is dispersed in a solution of 2.0 g (0.4 wt-Sé) of hydroxypropyl cellulose (Hercules<*>Klucel® H) in 500ml water. ;A patch of spun-bonded polyethylene textile material is then coated in the above-mentioned composition, photoexposed as in example 1, with the exception that an exposure time of 5 sec. is used, and further washed as indicated in example 1. As in example 1, pencil and the ink pen imageability of the treated patch material comparable to that achieved by writing on ordinary writing paper. In Example 3, 0.15 g (0.09 wt-£) of IMSIL A-15 amorphous silica is dispersed in a solution of 0.6 g (0.36 wt-%) hydroxyethyl cellulose with 0.55 wt-£ modification with a 16-carbon chain (Hercules Incorporated WSP D-330 ) In 125 ml of water and 51 ml of acetone. A spunbonded polyethylene patch material is coated and processed as in Example 1. As before, the pencil and ink pen imaging receptivity is comparable to that obtained by writing on ordinary writing paper. In Example 4, 0.5 g (0.3 wt-#) of IMSIL A-15 amorphous silicon dioxide is dispersed in a solution of 2.0 g (1.2 wt-#) of modified hydroxypropyl cellulose (containing 0.3 wt-$ to -added 16-carbon chains) in 125 ml of water and 51 ml of acetone. A spun bonded polyethylene patch material is then treated as in Example 1, with the exception that a 30 second photoexposure is used. The pencil and ink pen imaging receptivity of the patch material thus treated is comparable to that obtained by writing on ordinary writing paper. ;Example 5;This example further illustrates an embodiment according to the invention whereby a corona discharge source is used instead of ultraviolet light, to produce a photo-insoluble coating composition according to the present invention. ;181.4 g (0.1 wt-*) of IMSIL A-15 amorphous silicon dioxide is dispersed in a solution of 725.8 g (0.4 wt-#) of hydroxypropyl cellulose in 181.4 kg of water.
En lapp av spinnebundet polyetylen-tekstilmateriale belegges deretter med ovennevnte sammensetning og tørkes i 1 time i en 70°C ovn med tvungen luftsirkulasjon, og føres deretter under en 200 watt korona-behandlingsanordning ved en hastighet på 21,3 m/min. og i en avstand på 1,6 mm fra kilden. Lappmaterialet blir videre vasket i 1 time i en blanding av 176 ml vann og 76 ml aceton, og tørkes i 1 time ved 70°C som beskrevet i eksemplene ovenfor. Blyant- og blekkpenn-avbildnlngsmottagel Igheten for det således behandlede lappmaterialet er sammenlignbar med den oppnådd ved skriving på vanlig skrivepapir. A patch of spunbonded polyethylene textile material is then coated with the above composition and dried for 1 hour in a 70°C forced air oven and then passed under a 200 watt corona treatment device at a speed of 21.3 m/min. and at a distance of 1.6 mm from the source. The patch material is further washed for 1 hour in a mixture of 176 ml of water and 76 ml of acetone, and dried for 1 hour at 70°C as described in the examples above. Pencil and ink pen image reception The quality of the patch material treated in this way is comparable to that obtained by writing on ordinary writing paper.
Eksempel 6Example 6
Dette eksempel Illustrerer ytterligere en utførelse ifølge oppfinnelsen hvor elektronstrålebehandling benyttes istedenfor ultrafiolett lys eller korona-utladning for å fremstille en fotouoppløselig beleggsammensetning ifølge oppfinnelsen. This example further illustrates an embodiment according to the invention where electron beam treatment is used instead of ultraviolet light or corona discharge to produce a photo-insoluble coating composition according to the invention.
En lapp av spinnebundet polyetylen belegges med sammensetningen som benyttet 1 eksempel 5 og tørkes i en ovn med tvungen luftssirkulasjon i 1 time ved 75°C og eksponeres deretter overfor 0,5 megarad av 0,2 MEV-elektroner fra en kommersielt tilgjengelig elektronstråleenhet. Lappen vaskes deretter i 200 ml vann i 1 time fulgt av tørking i 1 time ved 75°C i en ovn med tvungen luftsirkulasjon. Blyant- og blekkpenn-avbildningsmottageligheten for det således behandlede lappmaterialet finnes å være sammenlignbar med den oppnådd ved skriving på vanlig skrivepapir, som beskrevet i eksemplene ovenfor. A patch of spunbonded polyethylene is coated with the composition used in Example 5 and dried in a forced air oven for 1 hour at 75°C and then exposed to 0.5 megarads of 0.2 MEV electrons from a commercially available electron beam unit. The patch is then washed in 200 ml of water for 1 hour followed by drying for 1 hour at 75°C in an oven with forced air circulation. The pencil and ink pen imaging receptivity of the patch material thus treated is found to be comparable to that obtained by writing on ordinary writing paper, as described in the examples above.
Eksempel 7Example 7
Dette eksempelet illustrerer ytterligere et aspekt ved oppfinnelsen hvorved den fotouoppløselige beleggsammensetningen forbedrer fargestoffmottagelighet hos syntetiske flberholdige tekstilmaterialer. This example further illustrates an aspect of the invention whereby the photo-insoluble coating composition improves dye receptivity of synthetic fiber-containing textile materials.
En behandlet lapp av spinnebundet polyetylen fremstilles og fotoeksponeres som illustrert i eksempel 2 ovenfor, og om-røres deretter i 70 min. ved 67°C I et fargestoffbad bestående av 12 g tonfarge av RIT-kvalitet og fargestoff oppløst i 214 ml vann. Etter fjerning av badet og skylling i vann i 30 min. viser det seg at lappmaterialet har utmerket fargestoff retensjon . En kontroll-lapp som er farget uten forut gående behandling, viser vesentlig ingen fargestoffretensjon etter vasking som beskrevet ovenfor. A treated patch of spunbonded polyethylene is prepared and photoexposed as illustrated in Example 2 above, and then stirred for 70 min. at 67°C In a dye bath consisting of 12 g of RIT-quality toner and dye dissolved in 214 ml of water. After removing the bath and rinsing in water for 30 min. it turns out that the patch material has excellent dye retention. A control patch dyed without prior treatment shows essentially no dye retention after washing as described above.
Claims (11)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7696887A | 1987-07-23 | 1987-07-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO883125D0 NO883125D0 (en) | 1988-07-13 |
| NO883125L true NO883125L (en) | 1989-01-24 |
Family
ID=22135315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO88883125A NO883125L (en) | 1987-07-23 | 1988-07-13 | COATING COMPOSITIONS FOR TEXTILES. |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0300370B1 (en) |
| JP (1) | JPS6433277A (en) |
| CA (1) | CA1328088C (en) |
| DE (1) | DE3872082T2 (en) |
| NO (1) | NO883125L (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0262234A (en) * | 1988-08-29 | 1990-03-02 | Komatsu Seiren Kk | Ultraviolet reflecting cloth |
| JPH089832B2 (en) * | 1990-05-24 | 1996-01-31 | 東レ株式会社 | Polyester fiber coated cloth and method for producing the same |
| GB9508409D0 (en) * | 1995-04-25 | 1995-06-14 | Sinclair Animal & Household Ca | House dust mite allergen control |
| US6380336B1 (en) | 1998-03-24 | 2002-04-30 | Nano-Tex, Llc | Copolymers and oil-and water-repellent compositions containing them |
| CA2324949A1 (en) * | 1998-03-24 | 1999-09-30 | Avantgarb, Llc | Modified textile and other materials and methods for their preparation |
| CN100506927C (en) | 2005-03-21 | 2009-07-01 | 刘景春 | Method for preparing nano-structural film with straggling effect for multiple substances and use thereof |
| KR101730475B1 (en) * | 2016-07-08 | 2017-04-27 | 주식회사 만경 | Environmentally friendly composition for coating on synthetic fabric and the manufacturing method of the same and coating method on the fabric using the same |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3878019A (en) * | 1970-05-19 | 1975-04-15 | Ici Ltd | Process of producing spot bonded non-woven webs using ultra-violet radiation |
| US4092457A (en) * | 1973-03-24 | 1978-05-30 | Kanzaki Paper Manufacturing Co., Ltd. | Method for the production of a synthetic fiber paper having an improved printability for offset printing and the product thereof |
| US4097646A (en) * | 1974-08-22 | 1978-06-27 | Copyer Co., Ltd. | Electrostatic recording material having a dielectric copolymer coated layer |
| JPS6130258B2 (en) * | 1974-12-27 | 1986-07-12 | Canon Kk | |
| DE2802135C3 (en) * | 1978-01-19 | 1982-01-14 | Felix Schoeller jr. GmbH & Co KG, 4500 Osnabrück | Process for the production of an electrostatic recording material |
| JPH0651432B2 (en) * | 1985-06-17 | 1994-07-06 | 花王株式会社 | Method for producing plastic film for thermal transfer recording medium |
| US4764395A (en) * | 1985-11-06 | 1988-08-16 | Ciba-Geigy Corporation | Process for finishing a textile fabric with a radiation crosslinkable compound |
-
1988
- 1988-06-20 CA CA000569854A patent/CA1328088C/en not_active Expired - Fee Related
- 1988-07-13 NO NO88883125A patent/NO883125L/en unknown
- 1988-07-14 EP EP88111345A patent/EP0300370B1/en not_active Expired - Lifetime
- 1988-07-14 DE DE8888111345T patent/DE3872082T2/en not_active Expired - Lifetime
- 1988-07-22 JP JP63183430A patent/JPS6433277A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| NO883125D0 (en) | 1988-07-13 |
| EP0300370A3 (en) | 1990-02-07 |
| CA1328088C (en) | 1994-03-29 |
| DE3872082D1 (en) | 1992-07-23 |
| EP0300370A2 (en) | 1989-01-25 |
| DE3872082T2 (en) | 1992-12-03 |
| EP0300370B1 (en) | 1992-06-17 |
| JPS6433277A (en) | 1989-02-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Kan et al. | Using atmospheric pressure plasma for enhancing the deposition of printing paste on cotton fabric for digital ink-jet printing | |
| US6319558B1 (en) | Process for manufacture of superabsorbent-coated yarn | |
| EP0177111A2 (en) | Method of treating textiles | |
| Ferrero et al. | Ultraviolet curing for surface modification of textile fabrics | |
| US20130130018A1 (en) | Method for coating with dispersions of active ingredients coated in a polymer layer | |
| NO883125L (en) | COATING COMPOSITIONS FOR TEXTILES. | |
| Chattopadhyay et al. | Improvement in properties of cotton fabric through synthesized nano-chitosan application | |
| KR19990007271A (en) | Coating composition for recording material and manufacturing method of recording material using same | |
| Gawish et al. | Grafting of 2‐(dimethlamino) ethyl methacrylate onto gamma irradiated polypropylene fabric | |
| Rollins et al. | Location of some typical vinyl polymers within radiation‐grafted cotton fibers: An electron microscopical survey | |
| DE10084234T5 (en) | transfer sheets | |
| DE69319738T2 (en) | FLOCCLE FOR ELECTROSTATIC FIBER TRANSPLANTATION | |
| EP3056549B1 (en) | Colorant composition and uses thereof | |
| US6425927B1 (en) | Aqueous composition for finishing fibrous material for a thermal transfer printing process | |
| Kan et al. | Ink-jet printing for Plasma-treated Cotton Fabric with Biomaterial | |
| WO2015018982A1 (en) | Dye-receiving materials and uses thereof in printing and dyeing | |
| GB1561798A (en) | Recovery of sizes from woven fabrics | |
| Luiken et al. | Radiation curable coatings and pigment binders for textile substrates | |
| JP2005501977A (en) | Fabric printing substrate | |
| DE2406343A1 (en) | EQUIPMENT MATERIAL AND ITS USE | |
| JP3546529B2 (en) | Inkjet recording medium | |
| Needles et al. | Vapor‐phase grafting of methyl acrylate on fiber surfaces treated with aqueous dispersions of metal oxides | |
| Hashem et al. | Innovative scouring for cotton‐based textiles | |
| JP2007075131A (en) | Deodorant material and deodorant sheet | |
| Tsukada et al. | The preparation of poly [N (n‐butoxymethyl) methacrylamide] grafted silk fibers by polymerization using a low pH system |