NO831063L - Fremgangsmaate for stabilisering av polymerer. - Google Patents
Fremgangsmaate for stabilisering av polymerer.Info
- Publication number
- NO831063L NO831063L NO831063A NO831063A NO831063L NO 831063 L NO831063 L NO 831063L NO 831063 A NO831063 A NO 831063A NO 831063 A NO831063 A NO 831063A NO 831063 L NO831063 L NO 831063L
- Authority
- NO
- Norway
- Prior art keywords
- polymer
- sulfur
- stated
- mixture
- containing compound
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 50
- 229920000642 polymer Polymers 0.000 title claims description 40
- 230000000087 stabilizing effect Effects 0.000 title description 6
- 150000001875 compounds Chemical class 0.000 claims description 23
- -1 polyethylene Polymers 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 17
- 229910052717 sulfur Inorganic materials 0.000 claims description 16
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 15
- 239000011593 sulfur Substances 0.000 claims description 15
- 230000003647 oxidation Effects 0.000 claims description 14
- 238000007254 oxidation reaction Methods 0.000 claims description 14
- 230000001590 oxidative effect Effects 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 12
- 239000004743 Polypropylene Substances 0.000 claims description 9
- 229920001155 polypropylene Polymers 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- 150000002978 peroxides Chemical class 0.000 claims description 5
- 239000000326 ultraviolet stabilizing agent Substances 0.000 claims description 5
- 125000004434 sulfur atom Chemical group 0.000 claims description 3
- 239000002243 precursor Substances 0.000 description 23
- 239000012963 UV stabilizer Substances 0.000 description 18
- 239000004594 Masterbatch (MB) Substances 0.000 description 12
- 239000003963 antioxidant agent Substances 0.000 description 9
- 239000003381 stabilizer Substances 0.000 description 9
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- 229920000098 polyolefin Polymers 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000010790 dilution Methods 0.000 description 6
- 239000012895 dilution Substances 0.000 description 6
- 150000002019 disulfides Chemical class 0.000 description 6
- 230000006641 stabilisation Effects 0.000 description 5
- 238000011105 stabilization Methods 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 4
- 238000007792 addition Methods 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 239000012990 dithiocarbamate Substances 0.000 description 3
- 150000004659 dithiocarbamates Chemical class 0.000 description 3
- 239000012991 xanthate Substances 0.000 description 3
- 150000003751 zinc Chemical class 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 150000002432 hydroperoxides Chemical class 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 150000002815 nickel Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 description 1
- SPTHWAJJMLCAQF-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene;hydrogen peroxide Chemical class OO.CC(C)C1=CC=CC=C1C(C)C SPTHWAJJMLCAQF-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- JLZIIHMTTRXXIN-UHFFFAOYSA-N 2-(2-hydroxy-4-methoxybenzoyl)benzoic acid Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O JLZIIHMTTRXXIN-UHFFFAOYSA-N 0.000 description 1
- YHCGGLXPGFJNCO-UHFFFAOYSA-N 2-(2H-benzotriazol-4-yl)phenol Chemical class OC1=CC=CC=C1C1=CC=CC2=C1N=NN2 YHCGGLXPGFJNCO-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000006701 autoxidation reaction Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- HVSYRUKKSFWIKV-UHFFFAOYSA-K dioxido-sulfanylidene-sulfido-lambda5-phosphane nickel(3+) Chemical class [Ni+3].[O-]P([O-])([S-])=S HVSYRUKKSFWIKV-UHFFFAOYSA-K 0.000 description 1
- 125000004119 disulfanediyl group Chemical group *SS* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 125000004404 heteroalkyl group Chemical group 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/5398—Phosphorus bound to sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8208828 | 1982-03-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO831063L true NO831063L (no) | 1983-09-26 |
Family
ID=10529281
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO831063A NO831063L (no) | 1982-03-25 | 1983-03-24 | Fremgangsmaate for stabilisering av polymerer. |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0090555B1 (es) |
| JP (1) | JPS58174424A (es) |
| KR (1) | KR860001035B1 (es) |
| AU (1) | AU1269683A (es) |
| BR (1) | BR8301488A (es) |
| CA (1) | CA1201546A (es) |
| CS (1) | CS241140B2 (es) |
| DE (1) | DE3367111D1 (es) |
| ES (1) | ES8502142A1 (es) |
| FI (1) | FI831033L (es) |
| GB (1) | GB2117779B (es) |
| IN (1) | IN161007B (es) |
| NO (1) | NO831063L (es) |
| ZA (1) | ZA831958B (es) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3264257A (en) * | 1963-07-10 | 1966-08-02 | Stauffer Chemical Co | Poly-alpha-olefin compositions containing organophosphorus compounds as stabilizers |
-
1983
- 1983-03-17 DE DE8383301495T patent/DE3367111D1/de not_active Expired
- 1983-03-17 GB GB08307400A patent/GB2117779B/en not_active Expired
- 1983-03-17 EP EP83301495A patent/EP0090555B1/en not_active Expired
- 1983-03-21 ZA ZA831958A patent/ZA831958B/xx unknown
- 1983-03-21 CA CA000424053A patent/CA1201546A/en not_active Expired
- 1983-03-22 AU AU12696/83A patent/AU1269683A/en not_active Abandoned
- 1983-03-23 BR BR8301488A patent/BR8301488A/pt unknown
- 1983-03-24 NO NO831063A patent/NO831063L/no unknown
- 1983-03-24 JP JP58049679A patent/JPS58174424A/ja active Pending
- 1983-03-24 ES ES520975A patent/ES8502142A1/es not_active Expired
- 1983-03-24 KR KR1019830001186A patent/KR860001035B1/ko active
- 1983-03-25 FI FI831033A patent/FI831033L/fi not_active Application Discontinuation
- 1983-03-25 IN IN363/CAL/83A patent/IN161007B/en unknown
- 1983-03-25 CS CS832084A patent/CS241140B2/cs unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FI831033A0 (fi) | 1983-03-25 |
| KR840004134A (ko) | 1984-10-06 |
| KR860001035B1 (ko) | 1986-07-28 |
| ZA831958B (en) | 1984-04-25 |
| CA1201546A (en) | 1986-03-04 |
| CS208483A2 (en) | 1985-07-16 |
| CS241140B2 (en) | 1986-03-13 |
| ES520975A0 (es) | 1984-12-16 |
| EP0090555A2 (en) | 1983-10-05 |
| IN161007B (es) | 1987-09-12 |
| ES8502142A1 (es) | 1984-12-16 |
| JPS58174424A (ja) | 1983-10-13 |
| GB8307400D0 (en) | 1983-04-27 |
| BR8301488A (pt) | 1983-12-06 |
| EP0090555B1 (en) | 1986-10-22 |
| EP0090555A3 (en) | 1984-02-29 |
| FI831033L (fi) | 1983-09-26 |
| DE3367111D1 (en) | 1986-11-27 |
| GB2117779B (en) | 1985-09-11 |
| AU1269683A (en) | 1983-09-29 |
| GB2117779A (en) | 1983-10-19 |
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