NO823367L - PROCEDURE FOR THE PREPARATION OF METAL SULPHIDES AND COLLECTION MIXTURES FOR USE WITH THIS - Google Patents
PROCEDURE FOR THE PREPARATION OF METAL SULPHIDES AND COLLECTION MIXTURES FOR USE WITH THISInfo
- Publication number
- NO823367L NO823367L NO823367A NO823367A NO823367L NO 823367 L NO823367 L NO 823367L NO 823367 A NO823367 A NO 823367A NO 823367 A NO823367 A NO 823367A NO 823367 L NO823367 L NO 823367L
- Authority
- NO
- Norway
- Prior art keywords
- metal
- collector
- ore
- allyl
- carbon atoms
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 30
- 229910052976 metal sulfide Inorganic materials 0.000 title claims description 9
- 239000000203 mixture Substances 0.000 title claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 18
- 238000005188 flotation Methods 0.000 claims description 15
- 239000006260 foam Substances 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000002002 slurry Substances 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
- 150000001340 alkali metals Chemical class 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- 230000001143 conditioned effect Effects 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 2
- 208000034699 Vitreous floaters Diseases 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 claims 1
- 239000004088 foaming agent Substances 0.000 description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000002932 luster Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- NFMAZVUSKIJEIH-UHFFFAOYSA-N bis(sulfanylidene)iron Chemical compound S=[Fe]=S NFMAZVUSKIJEIH-UHFFFAOYSA-N 0.000 description 1
- 229910052948 bornite Inorganic materials 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052951 chalcopyrite Inorganic materials 0.000 description 1
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 229910052961 molybdenite Inorganic materials 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- ZRPRNLNEYWYWLO-UHFFFAOYSA-N o-ethyl n-prop-2-enylcarbamothioate Chemical compound CCOC(=S)NCC=C ZRPRNLNEYWYWLO-UHFFFAOYSA-N 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- QXKXDIKCIPXUPL-UHFFFAOYSA-N sulfanylidenemercury Chemical compound [Hg]=S QXKXDIKCIPXUPL-UHFFFAOYSA-N 0.000 description 1
- WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical compound [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/014—Organic compounds containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Description
Oppfinnelsen angår en fremgangsmåte til anrikning av metallsulfidmalmer. Denne fremgangsmåte angår'spesielt en sådan prosess hvor skumfIotasjon anvendes i kombinasjon med The invention relates to a method for the enrichment of metal sulphide ores. This method particularly concerns such a process where foam flotation is used in combination with
en metallsamler innbefattende et N-all.yl-O— alkyltionokarbamat. a metal collector including an N-allyl-O-alkylthionocarbamate.
Mange betydningsfulle metaller forekommer i naturen i f orm av sulf idmalmer.. Slike malmer opptrer ..på forskjellige Many important metals occur in nature in the form of sulphide ores.. Such ores appear ..in different
'steder i verden, og på mange steder er malmforekomstene av tilstrekkelig størrelse for'utvinning ved gruvebrytnings-operasjoner, hvoretter forskjellige metoder- anvendes for ut-vinning av metallinnholdet.. places in the world, and in many places the ore deposits are of sufficient size for extraction by mining operations, after which different methods are used to extract the metal content.
Skumflotasjon er den viktigste metode for konsentrering eller anrikning av en rekke verdifulle malmmineraler. Den vesentligste fordel er at den er en forholdsvis effektiv ope-rasjon med vesentlig lavere kostnad enn mange andre prosesser. Foam flotation is the most important method for concentrating or beneficiating a number of valuable ore minerals. The most significant advantage is that it is a relatively efficient operation with significantly lower costs than many other processes.
Flotasjon er en prosess for- separering av finmalte verdifulle mineraler fra med disse forenet gangart eller avfall, eller.for separering av verdifulle komponenter fra hverandre. Flotation is a process for the separation of finely ground valuable minerals from gangue or waste combined with these, or for the separation of valuable components from each other.
Ved skumflotasjon tilveiebringes skumdannelse ved .innføringIn foam flotation, foam formation is provided by introduction
av luft i en pulp eller oppslemning. av findelt malm og vann of air in a pulp or slurry. of finely divided ore and water
inneholdende et skumdannelsesrniddel. Mineraler som har en • spesiell affinitet til luftbobler, 'stiger til overflaten i containing a foaming agent. Minerals which have a • special affinity for air bubbles, 'rise to the surface i
skummet og separeres fra dem som fuktes av. vannet. De partikler som skal separeres ved skumflotasjon, må ha en slik.. skimmed and separated from those that are wetted off. the water. The particles to be separated by foam flotation must have such a..
størrelse at de lett kan løftes av luftboblene. size that they can be easily lifted by the air bubbles.
Midler som kalles samlere anvendes i kombinasjon méd Agents called collectors are used in combination with
.flotasjon for å lette utvinningen av det ønskede mineral..flotation to facilitate the extraction of the desired mineral.
De valgte midler må selektivt kunne belegge det ønskede mine-.ral til tross for tilstedeværelse av mange andre mineralslag.; The agents chosen must be able to selectively coat the desired mineral despite the presence of many other mineral types.
Den rådende' teori angir at fIotasjonsseparasjon av ett mine-.ralslag f ra- et annet beror .på den relative fuktbarhet' av overflatene. Typisk senkes den frie overflateenergi. bety-delig gjennom adsorps jon av heteropolære overflateaktive midler. Det hydrofobe belegg som tilveiebringes på denne måte-, virker i henhold til denne forklaring som en bro,, slik at partiklene kan festes til en luftboble. Fremgangsmåten ifølge- oppfinnelsen er ikke begrenset til denne eller andre teorier for flotasjon. The prevailing theory states that flotation separation of one mineral layer from another depends on the relative wettability of the surfaces. Typically, the surface free energy is lowered. significantly through adsorption of heteropolar surfactants. The hydrophobic coating thus provided acts according to this explanation as a bridge, so that the particles can be attached to an air bubble. The method according to the invention is not limited to this or other theories of flotation.
Mange métallsulfidmalmer anrikes ved skumflotasjon under anvendelse av. en rekke forskjellige samlere. Slike sulfid- malmer innbefatter eksempelvis svovelkis (FeS2), kobberkis Many metal sulphide ores are beneficiated by foam flotation using a number of different collectors. Such sulphide ores include, for example, sulfur pyrite (FeS2), copper pyrite
(CuFeS2) , kobberglans (Cu2S) , blyglans (PbS) , sinkblende- (ZnS) , (CuFeS2), copper luster (Cu2S), lead luster (PbS), zinc blende (ZnS),
molybdenitt (MoS'2) , sinober (HgS) , kovellitt (CuS), bornitt (Cu^FeS^) og lignende, såvel som blandmalmer. molybdenite (MoS'2), cinnabar (HgS), covellite (CuS), bornite (Cu^FeS^) and the like, as well as mixed ores.
Selv om disse og andre malmer effektivt kan behandlesAlthough these and other ores can be effectively processed
for fremstilling av konsentrater med øket metallinnhold, foreligger det.likevel behov for mer■effektive samlere som gir øket utbytte av metallinnholdet under bibeholdelse av høy-gradig utbytte. I betraktning av de store mengder metallsulfider som behandles ved skumflotasjon,' kan én sådan ut-vikling medføre en vesentlig økning av den samlede mengde ' metallbestanddeler som utvinnes og gi vesentlige økonomiske fordeler, endog om .en moderat økning av utbyttet oppnås. Til-veiebringelsen av en forbedret fremgangsmåte for skumflotasjon av metallsulfider skulle oppfylle et lenge følt behov og utgjøre et vesentlig fremskritt på området. for the production of concentrates with an increased metal content, there is nevertheless a need for more efficient collectors which give an increased yield of the metal content while maintaining a high yield. Considering the large quantities of metal sulphides that are treated by foam flotation, one such development can lead to a significant increase in the total amount of metal constituents that are extracted and provide significant economic benefits, even if a moderate increase in the yield is achieved. The provision of an improved method for foam flotation of metal sulphides should fulfill a long-felt need and constitute a significant advance in the field.
I henhold til den foreliggende oppfinnelse tilveiebringes en fremgangsmåte for anrikning av en metallsulfidmalm, hvilken innbefatter maling av malmen, slik at man frem-bringer partikler'av flptérbar størrelse, oppslemning av partiklene i ét vannmedium, kondisjonering av oppslemningen According to the present invention, a method for beneficiation of a metal sulphide ore is provided, which includes grinding the ore so as to produce particles of filterable size, slurrying the particles in a water medium, conditioning the slurry
. med effektive mengder ,av skumdannelsesrniddel og metallsamler omfattende en forbindelse med strukturen . with effective amounts of foaming agent and metal aggregates comprising a connection with the structure
■ hvor .R er en alkylgruppe. med 1-6 karbonatomer, og flotéring av deønskede verdifulle malmbestanddeler ved skumflotasjon. ■ where .R is an alkyl group. with 1-6 carbon atoms, and flotation of the desired valuable ore constituents by foam flotation.
Helt overraskende gir fremgangsmåten ifølge oppfinnelsen Quite surprisingly, the method according to the invention gives
'metarikonsentråter med forbedret, konsentrasjon og forbedret utbytte sammenlignet med hva som erholdes når prosessen utfø-res under anvendelse av nær beslektede, tidligere kjente samlere. Den forbedrede konsentrasjon og det forbedrede utbytte leder til'at man oppnår større mengde av verdifullt metall ved hjelp av fremgangsmåten ifølge.oppfinnelsen og gir herigjennom vesentlige økonomiske fordeler. 'metariconcentrates with improved concentration and improved yield compared to what is obtained when the process is carried out using closely related, previously known collectors. The improved concentration and the improved yield lead to a greater amount of valuable metal being obtained by means of the method according to the invention and thereby provide significant economic advantages.
Ved utførelse av fremgangsmåten ifølge oppfinnelsen males en metallsulfidmalm som skal behandles, ..slik at man erholder partikler av flotér.bar størrelse'. I alminnelighet er det malte materiales partikkelstørrelse slik at størstedelen av partiklene er mindre enn 200 mesh (U.S. screen, 0,74 mm). When carrying out the method according to the invention, a metal sulphide ore to be treated is ground, ..so that particles of a floatable size are obtained'. In general, the particle size of the ground material is such that the majority of the particles are smaller than 200 mesh (U.S. screen, 0.74 mm).
Den malte malm beredes som en vannoppslemning inneholdende fra ca. 50 til 75 vekt% malt malm,, basert på,den samlede oppslemningsvekt, fortrinnsvis ca. 65-70 vékt% på samme basis. Den på denne måte .erholdte oppslemning kondisjoneres med skumdannelsesrniddel og samlerreagens i effektive mengder. Brenselolje.og andre skumnédtrykkere kan også anvendes'. f or regulering av skumdannelsen om så:ønskes. The ground ore is prepared as a water slurry containing from approx. 50 to 75% by weight ground ore, based on the total slurry weight, preferably approx. 65-70% by weight on the same basis. The slurry obtained in this way is conditioned with foaming agent and collecting reagent in effective quantities. Fuel oil and other foam suppressants can also be used'. for regulation of foam formation if desired.
Dén kondisjonerte oppslemning underkastes deretter kon-vensjonell skumflotasjon, og metallinnholdet utvinnes med skummet. F.lotasjbnen kan utføres i ett eller flere trinn om så. ønskes', med tilsats av mer skumdannelsesrniddel i etter-følgende, trinn om så ønskes. The conditioned slurry is then subjected to conventional foam flotation, and the metal content is recovered with the foam. The F.lotsjbn can be carried out in one or more steps if so. desired', with the addition of more foaming agent in subsequent steps if desired.
Samlerforbindelsene ifølge.foreliggende oppfinnelse har den generelle struktur The collector connections according to the present invention have the general structure
hvor R er en alkylgruppe med 1-6 karbonatomer. Forbindelser med denne struktur inkluderer N-al,lyl-0-metylti.onokarbamat, N-ailyl-O-etyltionokarbamat, N.^allyl-O-isopropyltionokarbamat, N-allyl-O-n-propyltionokarbamat, N-allyl-O-isobutyltiono-karbamat og N-allyl-0-n-amyit.ionokarbamat og lignende. where R is an alkyl group with 1-6 carbon atoms. Compounds with this structure include N-allyl-O-methylthionocarbamate, N-allyl-O-ethylthionocarbamate, N-allyl-O-isopropylthionocarbamate, N-allyl-O-n-propylthionocarbamate, N-allyl-O-isobutylthionocarbamate carbamate and N-allyl-O-n-amylite.ionocarbamate and the like.
Samlerforbindelsen anvendes■ved fremgangsmåten ifølge, oppfinnelsen i. en effektiv mengde. Med. "en effektiv, mengde" menes en mengde som gir en ønsket grad av anrikning av den ønskede metallbestanddel. Den spesifikke mengde av. samler, som anvendes med ulike metallsulfidmalmer, kan variere i høy grad. I alminnelighet er det effektive samleranvendelsesnivå en verdi pa ca. 0 , 0004.5 . til ca . 0 , 045 kg,' fortrinnsvis 0, 0027 til'0,027 kg samler pr. tonn malm. The collector compound is used in the method according to the invention in an effective amount. With. "an effective amount" means an amount which gives a desired degree of enrichment of the desired metal component. The specific amount of. collectors, which are used with different metal sulphide ores, can vary greatly. In general, the effective collector usage level is a value of approx. 0 , 0004.5 . to approx. 0.045 kg, preferably 0.0027 to 0.027 kg collector per tons of ore.
Også skumdannelsesmidlet anvendes i effektive mengder som ved konvensjonelle metoder. I alminnelighet anvendes skumdannelsesrniddel 1 en mengde på ca. 0,0045 til 0,045 kg pr. tonn- malm. Egnede skumdannelsesmidler er velkjente for fag-mannen og inkluderer eksempelvis me.tylisobutylkarbinol, 6- til • 8-karbon-alkoholer og. lignende. The foaming agent is also used in effective amounts as in conventional methods. In general, foaming agent 1 is used in an amount of approx. 0.0045 to 0.045 kg per tonnes of ore. Suitable foaming agents are well known to those skilled in the art and include, for example, methylisobutylcarbinol, 6- to • 8-carbon alcohols and. the like.
Ved fremgangsmåten ifølge oppfinnelsen kan man som metallsamler anvende visse kombinasjoner av N-allyl-0-alkyl'tiono-. In the method according to the invention, certain combinations of N-allyl-O-alkyl'thiono- can be used as metal collectors.
karbamater og andre forbindelser, forutsatt.at disse kombinasjoner ikke forringer anvendelsesegenskapene hos de angitte tioriokarbamaterSom eksempel har kombinasjoner av et alkalimetall- eller ammoniumsalt av et dialkylditiofosfat med for-•. melen carbamates and other compounds, provided that these combinations do not impair the application properties of the stated thioriocarbamates. For example, combinations of an alkali metal or ammonium salt of a dialkyldithiophosphate with for-•. the flour
hvor M er et alkalimetall- eller ammonium-ion, og R' og R", hver for seg velges fra alkylgrupper med: 2-8 karbonatomer, og visse av N-ally1-0-alkyltionokarbamatene har vist-seg å gi meget gode resultater som metallsamlere i kombinasjon med fremgangsmåten ifølge foreliggende oppfinnelse. where M is an alkali metal or ammonium ion, and R' and R", are each selected from alkyl groups with: 2-8 carbon atoms, and certain of the N-ally1-0-alkylthionocarbamates have been shown to give very good results as metal collectors in combination with the method according to the present invention.
Oppfinnelsen illustreres nærmere i nedenstående eksempler, hvor alle deler og- prosentangivelser er på vektbasis The invention is illustrated in more detail in the examples below, where all parts and percentages are by weight
. medmindre annet er angitt.. unless otherwise stated.
I nedenstående eksempler anvendes følgende generelle arbeidsmåte. - Generell arbeidsmåte. .1.. Maling i 16,5 minutter (67,5% - 0 , 074 mm)' ble utført med 0,009 kg pr. tonn av samler og 0,0136 kg pr. tonn av brenselolje nr. 2.. 2. Tp.grovfIotasjpnstrinn, henholdsvis 3 og 5 mi.nu.tter, ble utført ved den nøytrale pH-verdi hos den malte pulp,, ' pH 8,5 til 8,6..Metylisobutylkarbinol ble anvendt som skumdannelsesrniddel og en standardisert dose på 0,0127. kg pr. tonn- tii det. f ørs te grovf Iotas jons trinn- og 0 , 063 kg pr. tonn til det.andre grovfIotasjpnstrinn. 3. Alle produkter ble oppsamlet individuelt og ble under-kastet analyse. In the examples below, the following general working method is used. - General working method. .1.. Grinding for 16.5 minutes (67.5% - 0.074 mm)' was carried out with 0.009 kg per ton of collector and 0.0136 kg per tons of fuel oil No. 2. 2. Tp.grovfIotasjpnstep, respectively 3 and 5 mi.nu.tter, was carried out at the neutral pH value of the ground pulp,, ' pH 8.5 to 8.6..Methylisobutylcarbinol was used as foaming agent and a standardized dose of 0.0127. kg per tons of it. f irst rough foot Iotas ion step- and 0 , 063 kg per ton to that.other rough fIotasjpnsteps. 3. All products were collected individually and subjected to analysis.
Alle fIotasjonsf<p>rsøk ble utført i duplikat i tilfeldig rekkefølge av samme operatør. De gjennomsnittlige metallur-giske resultater ved de dupliserte forsøk angis. All fIotation trials were performed in duplicate in random order by the same operator. The average metallurgical results of the duplicate experiments are indicated.
Eksempel I Example I
Med den generelle arbeidsmåte ble N-allyl-O-isobutyl-tionokarbamat vurdert under anvendelse av Gaspé-kobbermalm •.(hovedsakelig kobberglans). ved tre anvendelsesnivåer. Resultatene angis i'Tabell I. With the general procedure, N-allyl-O-isobutyl-thionocarbamate was evaluated using Gaspé copper ore •.(mainly copper luster). at three application levels. The results are given in Table I.
Sammenligningseksempel ÅComparative example Å
Arbeidsmåten ifølge Eksempel. 1 ble anvendt med unntagelse av at.den anvendte samler var N-isopropyl-G-etylkarba-mat, en tidligere kjent samler. Resultatene angis også i Tabell I. . Resultatene i'Tabell I viser at fremgangsmåten ifølge oppfinnelsen gir høyere kobber-utbytter enn den tidligere, kjente prosess under bibeholdelse av høye konsentrasjoner. The way of working according to Example. 1 was used with the exception that the collector used was N-isopropyl-G-ethylcarbamate, a previously known collector. The results are also given in Table I. . The results in Table I show that the method according to the invention gives higher copper yields than the previously known process while maintaining high concentrations.
Eksempel 2Example 2
Den generelle arbeidsmåte ble på ny fulgt med unntagelse av at en serie N-allyl-O-alkyltionokarbamater ble vurdert hver for seg eller i visse kombinasjoner med hatriumdiisobutyl-. ditiofosfat..Siden alle ditiortokarbamatene oppviser innbyrdes forskjellig oppløseli.ghet i ditiofosfatreagenset, ble utprøv-ningen av blandingene utført ved forskjellige innhold.av bestanddelene. Resultatene angis i Tabell II. The general procedure was again followed with the exception that a series of N-allyl-O-alkylthionocarbamates were evaluated individually or in certain combinations with sodium diisobutyl-. dithiophosphate. Since all the dithioorthocarbamates show mutually different solubility in the dithiophosphate reagent, the tests of the mixtures were carried out at different contents of the components. The results are shown in Table II.
Resultatene i Tabell II viser at N-allyl-O-alkyltionokarbamater i alminnelighet ved anvendelse alene gir økninger av utbyttet med økende alkylkjédelengde. Resultatene viser også at økede utbytteverdier erholdes med blandinger av N-allyl-O-ålkyltionokarbamater og dialkylditiofosfatsalt, når metyl-, etyl- og n-propylderivater av tionokarbamatene anvendes. Andre alkylåilyltionokarbamater' i kombinasjon med dialkylditiofosfatsalt gir høyere utbytte enn de lavere alkyl-allyltionokarbamater ved anvendelse alene. The results in Table II show that N-allyl-O-alkylthiocarbamates generally, when used alone, give increases in yield with increasing alkyl chain length. The results also show that increased yield values are obtained with mixtures of N-allyl-O-alkylthiocarbamates and dialkyldithiophosphate salt, when methyl, ethyl and n-propyl derivatives of the thionocarbamates are used. Other alkylallylthiocarbamates' in combination with dialkyldithiophosphate salt give higher yields than the lower alkylallylthiocarbamates when used alone.
Claims (8)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US30985181A | 1981-10-08 | 1981-10-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO823367L true NO823367L (en) | 1983-04-11 |
Family
ID=23199942
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO823367A NO823367L (en) | 1981-10-08 | 1982-10-07 | PROCEDURE FOR THE PREPARATION OF METAL SULPHIDES AND COLLECTION MIXTURES FOR USE WITH THIS |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS5876153A (en) |
| DE (1) | DE3237231A1 (en) |
| ES (1) | ES8400149A1 (en) |
| GB (1) | GB2106804A (en) |
| IT (1) | IT1149096B (en) |
| NO (1) | NO823367L (en) |
| SE (1) | SE8205732L (en) |
| YU (1) | YU44364B (en) |
| ZA (1) | ZA827358B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4699712A (en) * | 1984-06-20 | 1987-10-13 | Thiotech, Inc. | Ore dressing method |
| ZA853831B (en) * | 1984-06-20 | 1986-01-29 | Thiotech Inc | Ore dressing method |
| GB2163068B (en) * | 1984-08-17 | 1988-09-28 | American Cyanamid Co | Neutral circuit sulfide collectors |
| GB8527214D0 (en) * | 1985-11-05 | 1985-12-11 | British Petroleum Co Plc | Separation process |
| ZA906138B (en) * | 1989-08-04 | 1991-05-29 | Broken Hill Pty Co Ltd | Ion flotation with non-ionic reagents |
| ZA918140B (en) * | 1991-10-11 | 1992-07-29 | American Cyanamid Co | Recovery of platinum group metals and gold by synergistic reaction between allylalkylthionocarbamates and dithiophosphates |
| US5599442A (en) * | 1996-06-14 | 1997-02-04 | Cytec Technology Corp. | Collector composition for flotation of activated sphalerite |
| CN108607678A (en) * | 2018-04-28 | 2018-10-02 | 西安鑫城投资有限公司 | A method of from separation molybdenum concntrate and lead concentrate in stone containing wulfenite |
| CN113441286B (en) * | 2021-06-17 | 2022-07-29 | 南京银茂铅锌矿业有限公司 | Process method beneficial to improving recovery rate of lead and silver in lead concentrate |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3288782A (en) * | 1962-07-25 | 1966-11-29 | Monsanto Co | Unsaturated hydrocarbon esters of n, nu-disubstituted thionocarbamic acids |
| US3590999A (en) * | 1969-02-13 | 1971-07-06 | Dow Chemical Co | Flotation of sulfide ores |
| US3925218A (en) * | 1974-08-01 | 1975-12-09 | American Cyanamid Co | Concentration of ore by flotation with solutions of aqueous dithiophosphates and thionocarbamate as collector |
| JPS526688A (en) * | 1975-06-24 | 1977-01-19 | Sumiyoshi Heavy Ind | Fish landing device to be used at quay |
-
1982
- 1982-08-23 GB GB08224143A patent/GB2106804A/en not_active Withdrawn
- 1982-09-22 YU YU2106/82A patent/YU44364B/en unknown
- 1982-10-05 IT IT49207/82A patent/IT1149096B/en active
- 1982-10-05 JP JP57174081A patent/JPS5876153A/en active Pending
- 1982-10-07 DE DE19823237231 patent/DE3237231A1/en not_active Ceased
- 1982-10-07 ZA ZA827358A patent/ZA827358B/en unknown
- 1982-10-07 NO NO823367A patent/NO823367L/en unknown
- 1982-10-07 SE SE8205732A patent/SE8205732L/en not_active Application Discontinuation
- 1982-10-07 ES ES516314A patent/ES8400149A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE3237231A1 (en) | 1983-04-28 |
| IT8249207A0 (en) | 1982-10-05 |
| SE8205732L (en) | 1983-04-09 |
| JPS5876153A (en) | 1983-05-09 |
| ZA827358B (en) | 1983-08-31 |
| YU210682A (en) | 1985-03-20 |
| SE8205732D0 (en) | 1982-10-07 |
| IT1149096B (en) | 1986-12-03 |
| YU44364B (en) | 1990-06-30 |
| ES516314A0 (en) | 1983-10-16 |
| GB2106804A (en) | 1983-04-20 |
| ES8400149A1 (en) | 1983-10-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4283017A (en) | Selective flotation of cubanite and chalcopyrite from copper/nickel mineralized rock | |
| RU2631743C2 (en) | Enrichment of sulphide metal ore by means of foam flotation using oxidant | |
| Phetla et al. | A multistage sulphidisation flotation procedure for a low grade malachite copper ore | |
| US5795465A (en) | Process for recovering copper from copper-containing material | |
| US5285972A (en) | Ore processing | |
| US5122289A (en) | Collector composition for use in a froth flotation process for the recovery of minerals | |
| US2919802A (en) | Method of concentrating ores | |
| NO823367L (en) | PROCEDURE FOR THE PREPARATION OF METAL SULPHIDES AND COLLECTION MIXTURES FOR USE WITH THIS | |
| CA1278111C (en) | Neutral hydrocarboxycarbonyl thionocarbamate sulfide collectors | |
| US4324654A (en) | Recovery of copper from copper oxide minerals | |
| Cilliers et al. | The flotation of fine pyrite using colloidal gas aphrons | |
| US4735783A (en) | Process for increasing the selectivity of mineral flotation | |
| O'Connor et al. | The practice of pyrite flotation in South Africa and Australia | |
| US4246096A (en) | Flotation process | |
| US3827557A (en) | Method of copper sulfide ore flotation | |
| US7150357B2 (en) | Selective recovery of minerals by flotation | |
| US4606817A (en) | Recovery of molybdenite | |
| PL202110B1 (en) | The manner of foam floatation for enrichment of ores | |
| CA1046656A (en) | Use of tetraalkylammonium halides as flotation collectors | |
| CA2258163C (en) | New collector composition for flotation of activate sphalerite | |
| CA1111155A (en) | Ore beneficiation | |
| EP0116616A1 (en) | Process for the selective separation of base metal sulfides and oxides contained in an ore. | |
| US6484883B1 (en) | Use of cupric chloride in zinc flotation | |
| US4220524A (en) | Collector agent for the recovery of metal values in sulphide ores by froth flotation | |
| US4214983A (en) | Recovery of copper from copper oxide minerals |