NO812406L - Fremgangsmaate for elektrokjemisk fremstilling av organiske forbindelser. - Google Patents
Fremgangsmaate for elektrokjemisk fremstilling av organiske forbindelser.Info
- Publication number
- NO812406L NO812406L NO812406A NO812406A NO812406L NO 812406 L NO812406 L NO 812406L NO 812406 A NO812406 A NO 812406A NO 812406 A NO812406 A NO 812406A NO 812406 L NO812406 L NO 812406L
- Authority
- NO
- Norway
- Prior art keywords
- electrolysis
- stated
- reaction
- carried out
- group
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 25
- 150000002894 organic compounds Chemical class 0.000 title claims description 4
- 239000000126 substance Substances 0.000 title description 2
- 239000003054 catalyst Substances 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 238000005868 electrolysis reaction Methods 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 230000015572 biosynthetic process Effects 0.000 claims description 11
- 229910052763 palladium Inorganic materials 0.000 claims description 10
- 238000003786 synthesis reaction Methods 0.000 claims description 9
- 239000000758 substrate Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229910002804 graphite Inorganic materials 0.000 claims description 7
- 239000010439 graphite Substances 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 229910052707 ruthenium Inorganic materials 0.000 claims description 5
- 238000007327 hydrogenolysis reaction Methods 0.000 claims description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- 239000013543 active substance Substances 0.000 claims description 3
- 150000001491 aromatic compounds Chemical class 0.000 claims description 3
- 239000010406 cathode material Substances 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 229910052703 rhodium Inorganic materials 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- 238000005984 hydrogenation reaction Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 229910000510 noble metal Inorganic materials 0.000 claims 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 25
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 21
- 239000000203 mixture Substances 0.000 description 19
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 11
- 150000001242 acetic acid derivatives Chemical class 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 239000008096 xylene Substances 0.000 description 11
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 10
- 238000006137 acetoxylation reaction Methods 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- BQWKGDOXTCKIMG-UHFFFAOYSA-N (2,3,4,6-tetramethylphenyl) acetate Chemical compound CC(=O)OC1=C(C)C=C(C)C(C)=C1C BQWKGDOXTCKIMG-UHFFFAOYSA-N 0.000 description 6
- BFIMMTCNYPIMRN-UHFFFAOYSA-N 1,2,3,5-tetramethylbenzene Chemical compound CC1=CC(C)=C(C)C(C)=C1 BFIMMTCNYPIMRN-UHFFFAOYSA-N 0.000 description 6
- QUMXDOLUJCHOAY-UHFFFAOYSA-N 1-Phenylethyl acetate Chemical compound CC(=O)OC(C)C1=CC=CC=C1 QUMXDOLUJCHOAY-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
- 229940022663 acetate Drugs 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 229940115425 methylbenzyl acetate Drugs 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- AQMMQXVLQRGYRO-UHFFFAOYSA-N (2,3,5,6-tetramethylphenyl) acetate Chemical compound CC(=O)OC1=C(C)C(C)=CC(C)=C1C AQMMQXVLQRGYRO-UHFFFAOYSA-N 0.000 description 3
- SBOSLJVYJPZJNH-UHFFFAOYSA-N (2,5-dimethylphenyl) acetate Chemical compound CC(=O)OC1=CC(C)=CC=C1C SBOSLJVYJPZJNH-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 3
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- KFTICBQPDRQGKB-UHFFFAOYSA-N (2,4,5-trimethylphenyl)methyl acetate Chemical compound CC(=O)OCC1=CC(C)=C(C)C=C1C KFTICBQPDRQGKB-UHFFFAOYSA-N 0.000 description 2
- KCLWUNIWBXUMQO-UHFFFAOYSA-N (2,4,6-trimethylphenyl) acetate Chemical compound CC(=O)OC1=C(C)C=C(C)C=C1C KCLWUNIWBXUMQO-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229940007550 benzyl acetate Drugs 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 235000011056 potassium acetate Nutrition 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- YYEROYLAYAVZNW-UHFFFAOYSA-N 2-methyl-2-phenylpropanoic acid Chemical compound OC(=O)C(C)(C)C1=CC=CC=C1 YYEROYLAYAVZNW-UHFFFAOYSA-N 0.000 description 1
- 241001269524 Dura Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- QBKMWJRMLACRJD-UHFFFAOYSA-N benzhydryl acetate Chemical compound C=1C=CC=CC=1C(OC(=O)C)C1=CC=CC=C1 QBKMWJRMLACRJD-UHFFFAOYSA-N 0.000 description 1
- 238000010349 cathodic reaction Methods 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000006198 methoxylation reaction Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 150000003613 toluenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT23441/80A IT1132194B (it) | 1980-07-15 | 1980-07-15 | Processo elettrochimico per la sintesi di composti organici |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO812406L true NO812406L (no) | 1982-01-18 |
Family
ID=11207109
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO812406A NO812406L (no) | 1980-07-15 | 1981-07-13 | Fremgangsmaate for elektrokjemisk fremstilling av organiske forbindelser. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4544450A (sv) |
| JP (1) | JPS5751271A (sv) |
| AT (1) | AT371151B (sv) |
| BE (1) | BE889625A (sv) |
| CH (1) | CH650277A5 (sv) |
| DE (1) | DE3127975C2 (sv) |
| DK (1) | DK311881A (sv) |
| FR (1) | FR2486968B1 (sv) |
| GB (1) | GB2080335B (sv) |
| IT (1) | IT1132194B (sv) |
| NL (1) | NL8103367A (sv) |
| NO (1) | NO812406L (sv) |
| SE (1) | SE8104359L (sv) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4666570A (en) * | 1984-10-30 | 1987-05-19 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing aromatic compound with functional groups |
| US5306411A (en) * | 1989-05-25 | 1994-04-26 | The Standard Oil Company | Solid multi-component membranes, electrochemical reactor components, electrochemical reactors and use of membranes, reactor components, and reactor for oxidation reactions |
| US5296106A (en) * | 1992-01-21 | 1994-03-22 | The United States Of America As Represented By The Secretary Of The Navy | Electrified microheterogeneous catalysis |
| US5282936A (en) * | 1992-01-21 | 1994-02-01 | The United States Of America As Represented By The Secretary Of The Navy | Decomposition of halogenated and polyhalogenated organic materials by electrified microheterogeneous catalysis |
| US5288371A (en) * | 1992-01-21 | 1994-02-22 | The United States Of America As Represented By The Secretary Of The Navy | Oxidation of organic materials by electrified microheterogeneous catalysis |
| DE19944990A1 (de) * | 1999-09-20 | 2001-03-22 | Basf Ag | Verfahren zur elektrolytischen Umwandlung von organischen Verbindungen |
| DE19944989A1 (de) | 1999-09-20 | 2001-03-22 | Basf Ag | Verfahren zur elektrolytischen Umwandlung von Furanderivaten |
| US6620305B2 (en) * | 2001-04-10 | 2003-09-16 | Cornell Development Corporation Llc | Method and apparatus for electrochemical cells with improved anti-fouling characteristics |
| US9534306B2 (en) | 2012-01-23 | 2017-01-03 | Macdermid Acumen, Inc. | Electrolytic generation of manganese (III) ions in strong sulfuric acid |
| US10260000B2 (en) | 2012-01-23 | 2019-04-16 | Macdermid Acumen, Inc. | Etching of plastic using acidic solutions containing trivalent manganese |
| US9752241B2 (en) | 2012-01-23 | 2017-09-05 | Macdermid Acumen, Inc. | Electrolytic generation of manganese (III) ions in strong sulfuric acid using an improved anode |
| WO2014077957A1 (en) * | 2012-11-15 | 2014-05-22 | Macdermid Acumen, Inc. | Electrolytic generation of manganese (iii) ions in strong sulfuric acid |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1953951A1 (de) * | 1969-10-27 | 1971-05-06 | Duerkes Geb Bliedtner | Verfahren zur Herstellung von Hydrochinon |
| US4024032A (en) * | 1975-03-31 | 1977-05-17 | Hooker Chemicals & Plastics Corporation | Electrochemical acyloxylation of certain aromatic compounds |
| US4101392A (en) * | 1976-12-22 | 1978-07-18 | Monsanto Company | Process for electrolytic oxidative methyl-methyl coupling of cresol salts |
| US4119941A (en) * | 1977-08-08 | 1978-10-10 | The United States Of America As Represented By The Secretary Of The Navy | Acoustic coupler |
| US4318783A (en) * | 1978-11-30 | 1982-03-09 | Bayer Aktiengesellschaft | Process for the preparation of optionally substituted benzaldehyde dialkyl acetals |
-
1980
- 1980-07-15 IT IT23441/80A patent/IT1132194B/it active
-
1981
- 1981-06-24 GB GB8119541A patent/GB2080335B/en not_active Expired
- 1981-07-08 AT AT0302181A patent/AT371151B/de not_active IP Right Cessation
- 1981-07-09 FR FR8113558A patent/FR2486968B1/fr not_active Expired
- 1981-07-13 DK DK311881A patent/DK311881A/da not_active Application Discontinuation
- 1981-07-13 NO NO812406A patent/NO812406L/no unknown
- 1981-07-13 CH CH4580/81A patent/CH650277A5/it not_active IP Right Cessation
- 1981-07-14 SE SE8104359A patent/SE8104359L/sv unknown
- 1981-07-14 JP JP56108932A patent/JPS5751271A/ja active Pending
- 1981-07-14 BE BE0/205407A patent/BE889625A/fr not_active IP Right Cessation
- 1981-07-15 NL NL8103367A patent/NL8103367A/nl not_active Application Discontinuation
- 1981-07-15 DE DE3127975A patent/DE3127975C2/de not_active Expired
-
1983
- 1983-06-30 US US06/509,863 patent/US4544450A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| FR2486968A1 (fr) | 1982-01-22 |
| IT8023441A0 (it) | 1980-07-15 |
| CH650277A5 (it) | 1985-07-15 |
| DE3127975C2 (de) | 1984-07-05 |
| DE3127975A1 (de) | 1982-05-06 |
| AT371151B (de) | 1983-06-10 |
| IT1132194B (it) | 1986-06-25 |
| ATA302181A (de) | 1982-10-15 |
| BE889625A (fr) | 1982-01-14 |
| JPS5751271A (en) | 1982-03-26 |
| DK311881A (da) | 1982-01-16 |
| GB2080335A (en) | 1982-02-03 |
| SE8104359L (sv) | 1982-01-16 |
| FR2486968B1 (fr) | 1986-01-31 |
| US4544450A (en) | 1985-10-01 |
| GB2080335B (en) | 1983-09-21 |
| NL8103367A (nl) | 1982-02-01 |
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