NO743704L - - Google Patents
Info
- Publication number
- NO743704L NO743704L NO743704A NO743704A NO743704L NO 743704 L NO743704 L NO 743704L NO 743704 A NO743704 A NO 743704A NO 743704 A NO743704 A NO 743704A NO 743704 L NO743704 L NO 743704L
- Authority
- NO
- Norway
- Prior art keywords
- sealing
- parts
- dispersions
- weight
- finely divided
- Prior art date
Links
- 239000000853 adhesive Substances 0.000 claims description 36
- 230000001070 adhesive effect Effects 0.000 claims description 34
- 150000001875 compounds Chemical class 0.000 claims description 33
- 238000007789 sealing Methods 0.000 claims description 31
- 239000006185 dispersion Substances 0.000 claims description 29
- 239000008187 granular material Substances 0.000 claims description 29
- 239000006260 foam Substances 0.000 claims description 26
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 239000000654 additive Substances 0.000 claims description 13
- 239000000945 filler Substances 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 238000004040 coloring Methods 0.000 claims description 7
- 239000000049 pigment Substances 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 5
- 239000000565 sealant Substances 0.000 claims description 4
- 229920000965 Duroplast Polymers 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- 238000009413 insulation Methods 0.000 description 9
- 229920003023 plastic Polymers 0.000 description 9
- 239000004033 plastic Substances 0.000 description 9
- 230000004888 barrier function Effects 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- -1 polyethylene Polymers 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 229920006327 polystyrene foam Polymers 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000011505 plaster Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000008240 homogeneous mixture Substances 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- 229920005830 Polyurethane Foam Polymers 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 125000005396 acrylic acid ester group Chemical group 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000006261 foam material Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012875 nonionic emulsifier Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 239000011496 polyurethane foam Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004638 Duroplast Substances 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 125000005263 alkylenediamine group Chemical group 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000002969 artificial stone Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001870 copolymer plastic Polymers 0.000 description 1
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000002984 plastic foam Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000004639 urea-formaldehyde foam Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/34—Filling pastes
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/66—Sealings
Description
Isolerende klebe-, tetnings- ogInsulating adhesive, sealing and
sparkelmasser.putty compounds.
Gjenstand for oppfinnelsen er isolerende klebe-, tetnings-og sparkelmasser av vandige filmdannende dispersjoner og eventuelt vanlige fyllstoffer, mykgjorende og/eller farvegivende tilsetninger som inneholder findelte skumstoffgranulater. Subject matter of the invention are insulating adhesive, sealing and troweling compounds of aqueous film-forming dispersions and possibly common fillers, softening and/or coloring additives which contain finely divided foam granules.
Oppfinnelsen beskjeftiger seg videre med en fremgangsmåte for fremstilling av disse isolerende klebe-, tetnings- og sparkelmasser, såvel som med deres anvendelse for avtetting og isolering av overflater av forskjellig art og av fuger. The invention further deals with a method for producing these insulating adhesive, sealing and putty compounds, as well as with their use for sealing and insulating surfaces of various types and joints.
I IN
Fremstillingen og anvendelsen av skumstoffer er kjent. Det osterrikske patent nr. 232.260 beskriver en fremgangsmåte for fremstilling av skumstoff-fyllegemer av polystyrol som kan anvendes for utfylling av hulrom i bygg, ved transportgods, The production and use of foams is known. The Austrian patent no. 232,260 describes a method for the production of foam fillers from polystyrene which can be used for filling cavities in buildings, for transport goods,
i byggeelementer og som fyllmiddel i stengulv eller sement-belegg. in building elements and as a filler in stone floors or cement coatings.
. Det tyske patentskrift nr. 1.266.680 beskriver en fremgangsmåte for fremstilling av lette byggedeler, som inneholder små polystorolskumstoffdeler sammen med hydrauliske bindemidler og vandige dispersjoner av polyepoksydforbindelser som inneholder - et herdemiddel med eventuelt vanlige tilsetningsstoffer, som deretter formes og herdes ut på vanlig måte. Ved dette dreier det seg ikke om en isolerende klebe- eller sparkelmasse, som er lagringsdyktig over et langts tidsrom, men om en hydraulisk avbindende blanding for fremstilling av kunststener, som anvendes som formede elementer. Skumstoffer som sådanne i plater eller båndform anvendes f. eks. i industrien som isolerings- og sperremateriale mot inn-virkning av varme og kulde eller for isolering mot lyd. Således er det f.eks. vanlig å klebe polystyrolskumplater på plane'flater eller anbringe polyetylenskumsnorer på steder som skal isoleres. For isolering av ikke plane eller komplisert formede deler eller - —underlag må forformede skumstoffmaterialer stykkes opp for å oppnå 'en virksom beskyttelsesvirkning. Ved dette er et betyde-lig oppbud av tid og omkostninger ikke til å unngå. . The German patent document no. 1,266,680 describes a method for the production of lightweight construction parts, which contain small polystyrene foam parts together with hydraulic binders and aqueous dispersions of polyepoxide compounds which contain - a hardener with possibly common additives, which then shaped and cured in the usual way. This does not involve an insulating adhesive or putty compound, which is capable of being stored over a long period of time, but about a hydraulic binding mixture for the production of artificial stones, which are used as shaped elements. Foam materials as such in sheets or strip form are used, e.g. in industry as insulation and barrier material against the effects of heat and cold or for insulation against sound. Thus, it is e.g. it is common to stick polystyrene foam sheets on flat surfaces or to place polyethylene foam cords in places to be insulated. For insulation of non-planar or complicatedly shaped parts or substrates, preformed foam materials must be cut up to achieve an effective protective effect. In this way, a considerable increase in time and costs cannot be avoided.
Oppgave for foreliggende oppfinnelse var det å finne isolerende sparkel- og klebemidler som uten vanskelighet lar seg enkelt tilpasse forekommende ujevnheter og som lett og billig kan påfores, og således unngå de foran beskrevne ulemper. The task of the present invention was to find insulating fillers and adhesives which can easily be adapted to existing irregularities and which can be applied easily and cheaply, thus avoiding the disadvantages described above.
Denne oppgave ble på overraskende måte lost med isolerende klebe-, tetnings- eller sparkelmasser på basis av filmdannende vandige dispersjoner og eventuelt vanlige mykningsmidler, pigmenter, fyllstoffer, farvegivende substanser, additiver og tilsetningsmidler, som erkarakterisert vedat dispersjonene i tillegg innholder findelte skumstoffgranulater. This task was surprisingly solved with insulating adhesive, sealing or putty compounds based on film-forming aqueous dispersions and possibly common softeners, pigments, fillers, coloring substances, additives and additives, which are characterized by the fact that the dispersions also contain finely divided foam granules.
De isolerende klebe-, tetnings- og sparkelmasser ifolge oppfinnelsen kan uten vanskelighet påfores på alle plane og ikke plane flater eller også på komplekst formede deler eller i fu-, ger ved sproytepåforing og gir etter torking fastheftende isolerings- og sperresjikt. De isolerende klebe-, tetnings- og sparkelmasser ifolge oppfinnelsen muliggjor således å stille et ubegrenset lagringsdyktig produkt til disposisjon, som som sproyteklar masse lar seg tilpasse uten vanskelighet enhver onsket form. Alt etter den onskede forarbeidelseskonsistens kan den sproyteferdige, isolerende klebe-, tetnings- og sparkelmasse fremstilles stabilt eller selvnivellerende. The insulating adhesive, sealing and putty compounds according to the invention can be applied without difficulty on all flat and non-flat surfaces or also on complexly shaped parts or in joints by spray application and after drying provide an adherent insulating and barrier layer. The insulating adhesive, sealing and putty compounds according to the invention thus make it possible to provide an unlimited storable product, which, as a ready-to-spray mass, can be adapted without difficulty to any desired shape. Depending on the desired processing consistency, the ready-to-spray, insulating adhesive, sealing and putty compound can be made stable or self-levelling.
Overraskende var videre at den isolerende klebe-, tetnings-It was also surprising that the insulating adhesive, sealing
og sparkelmasse skiller seg vesentlig med hensyn til isolerings- og sperrevirkning fra de hittil vanlige produkter, ja oppnår ved en sperrings- og is<p>leringsvirkning - alt etter innhol-det av de tilsatte skumstoffgranulater - nesten virkningen for vanlig kunststoffskum. and putty compound differs significantly in terms of insulation and barrier effect from the hitherto usual products, and even achieves a barrier and insulation effect - depending on the content of the added foam granules - almost the effect of ordinary plastic foam.
Samtidig tillater den isolerende klebe-, tetnings- og sparkelmasse etter oppfinnelsen også anvendelsen som klebe-, sperre-henh. tetningsstoff, som samtidig har lyd- og varmeisolerende egenskaper. Videre ligger en særlig fordel ved klebe-, tetnings-og sparkelmasser ifolge oppfinnelsen i at også fuktige eller våte flater kan behandles med den. At the same time, the insulating adhesive, sealing and putty compound according to the invention also allows its use as an adhesive, blocking attachment. sealant, which at the same time has sound and heat insulating properties. Furthermore, a particular advantage of adhesive, sealing and putty compounds according to the invention lies in the fact that damp or wet surfaces can also be treated with it.
De findelte skumstoffgranulater etter oppfinnelsen kan bestå såvel av termoplastharpikser som også av duroplastharpikser eller av blandinger av disse to. Ved dette anvendes etter en særlig utforelsesform for isolerende klebe-, tetnings- og sparkelmassene ifolge oppfinnelsen findelte skumstoffgranulater , hvis partikler har en diameter på fortrinnsvis 0,8 til 8 mm og en bulkvekt på fortrinnsvis mellom 10 og 150 g/l. The finely divided foam granules according to the invention can consist both of thermoplastic resins and also of duroplast resins or of mixtures of these two. In this case, according to a particular embodiment of the insulating adhesive, sealing and putty compounds according to the invention, finely divided foam granules are used, the particles of which have a diameter of preferably 0.8 to 8 mm and a bulk weight of preferably between 10 and 150 g/l.
I IN
i in
Mengden ligger fortrinnsvis mellom 2 og 15 deler på basis av dispersjonens totalvekt. The quantity is preferably between 2 and 15 parts based on the total weight of the dispersion.
Den videre oppgave ved oppfinnelsen, å finne en fremgangsmåte for fremstilling av isolerende klebe-, tetnings- og sparkelmasser, ble på overraskende måte lost ved en fremgangsmåte for fremstilling av isolerende klebe- og sparkelmasser på basis av filmdannende, vandige dispersjoner og eventuelt vanlige mykgjo-ringsmidler, pigmenter, fyllstoffer, farvegivende substanser, additiver og tilsetningsmidler, som erkarakterisert vedat dispersjonene også inneholder findelte skumstoffgranulater. The further task of the invention, to find a method for the production of insulating adhesive, sealing and putty compounds, was solved in a surprising way by a method for the production of insulating adhesive and putty compounds on the basis of film-forming, aqueous dispersions and possibly ordinary soft- ringing agents, pigments, fillers, coloring substances, additives and additives, which are characterized in that the dispersions also contain finely divided foam granules.
Endelig beskjeftiger oppfinnelsen seg med anvendelsen av isolerende klebe-, tetnings- og sparkelmasser for avtetning og isolering av overflater og fuger. Finally, the invention deals with the use of insulating adhesives, sealants and fillers for sealing and insulating surfaces and joints.
De kan anvendes som flytende sperre- eller utbedrings- eller klebemidler for mange anvendelsesområder innen industrien. They can be used as liquid barrier or repair or adhesive agents for many areas of application within industry.
De isolerende klebe-, tetnings- og sparkelmasser etter oppfinnelsen inneholder filmdannende, vandige dispersjoner. The insulating adhesive, sealing and putty compounds according to the invention contain film-forming, aqueous dispersions.
Disse utvinnes på kjent måte etter vanlige fremgangsmåter enten ved emulsjonspolymerisasjon eller ved etterfolgende emulgering av polymerer. F.eks. kan homo- og blandingspolymerer av vinyl-estere, vinylhydrokarboner, akrylsyreesterer, metakrylsyre-estere o.s.v., som kan være modifisert og variert på mange må-ter, anvendes. Andre plaster, som f.eks. polyesterplaster, polyuretanplast, alkydplast, celluloseplast og andre kan likeledes på vanlig måte ved hjelp av egnede emulgeringsmidler overfores til dispersjoner. Anvendes herdbare polyaddukter, som f.eks. epoksydplaster eller polyuretanplaster i dispersjons-form, så kan vanlige herdemidler tilsettes de isolerende klebe-, tetnings- og sparkelmasser kort for deres forarbeidelse. Dispersjonene kan anvendes enkeltvis eller i blanding med hverandre. Ved behov kan mindre deler av andre plaste^ som f.eks. vannopp-loselige aminoplaster eller feno plaster samtidig anvendes. These are extracted in a known manner according to usual methods either by emulsion polymerization or by subsequent emulsification of polymers. E.g. homo- and mixed polymers of vinyl esters, vinyl hydrocarbons, acrylic acid esters, methacrylic acid esters, etc., which can be modified and varied in many ways, can be used. Other plasters, such as polyester plastics, polyurethane plastics, alkyd plastics, cellulose plastics and others can likewise be converted into dispersions in the usual way by means of suitable emulsifiers. Curable polyadducts are used, such as e.g. epoxy plaster or polyurethane plaster in dispersion form, then ordinary hardeners can be added to the insulating adhesive, sealing and putty compounds shortly before their processing. The dispersions can be used individually or in a mixture with each other. If necessary, smaller parts of other plastics, such as e.g. water-soluble aminoplasts or pheno plasters are used at the same time.
Også anvendelsen av dispersjoner av flammehemmende plaster er mulig. The use of dispersions of flame retardant plaster is also possible.
Den midlere partikkelstorrelse eller diameter for de dispergerte, filmdannende plaster kan variere innenfor vide grenser. Som regel ligger de mellom ca. 0,03 og 20 mikron. The average particle size or diameter of the dispersed, film-forming plasters can vary within wide limits. As a rule, they lie between approx. 0.03 and 20 microns.
Totalmengden av dispergerte partikler i dispersjonen ligger i avhengighet av filmdanningen og fremstillingsmåten vanligvis mellom 40 og 60 vektsprosent. The total quantity of dispersed particles in the dispersion is, depending on the film formation and the method of production, usually between 40 and 60 percent by weight.
Eventuelt kan de isolerende klebe-, tetnings- og sparkelmasser ifolge oppfinnelsen inneholde mykningsmidler, som f.eks. ftal-syreester, fosforsyreester, adipinsyre-glykolester, epoksy-derte oljer og fettarter og lignende. Pigmenter som findelte metalloksyder, fyllstoffer med vilkårlig partikkel storrelse som kalsiumkarbonat, glimmer, talkum, kvartsmel, bariumsulfat kan være inneholdt. Utover dette kan de isolerende klebe-, tetnings-og sparkelmasser ifolge oppfinnelsen også inneholde metallpul-ver og fiberformede, forsterkende materialer av glass, natur-eller syntetiske fibre, kunststoffer eller asbest. Optionally, the insulating adhesive, sealing and putty compounds according to the invention may contain softening agents, such as e.g. phthalic acid ester, phosphoric acid ester, adipic acid glycol ester, epoxidized oils and fats and the like. Pigments such as finely divided metal oxides, fillers of arbitrary particle size such as calcium carbonate, mica, talc, quartz flour, barium sulphate may be contained. In addition to this, the insulating adhesive, sealing and putty compounds according to the invention can also contain metal powders and fibre-shaped, reinforcing materials of glass, natural or synthetic fibres, plastics or asbestos.
Ved behov kan vanlige farvegivende substanser, som f.eks. titandioksyd, jernoksyd, kromoksyd eller organiske farvende pigmenter medanvendes. If necessary, common coloring substances, such as e.g. titanium dioxide, iron oxide, chromium oxide or organic coloring pigments are also used.
Vanlige additiver, som f.eks. aktivatorer, katalysatorer, akse-leratorer, herdemidler og lignende, såvel som tilsetningsmidler Common additives, such as activators, catalysts, accelerators, curing agents and the like, as well as additives
som f.eks. ildsikringsmidler, fortetningsmidler, stabiliserings-midler, antiskummidler og andre kan være inneholdt etter behov. like for example. fire retardants, sealants, stabilizers, antifoams and others may be contained as required.
De anvendte findelte skumstoffgranulater kan ha åpne porer The finely divided foam granules used may have open pores
eller lukkede celler, alt etter art og fremstillingsmåte. Det kan anvendes såvel termoplastiske og/eller duroplastiske plaster. Som eksempel kan nevnes: polykondensater som aminopla-. ster eller fenoplaster, polyesterplaster, polyaddukter som epoksydforbindelser, polyuretaner og homo- og kopolymerisat-plaster, som akrylplaster, metakrylplaster, polydiener, poly- or closed cells, depending on the type and method of manufacture. Both thermoplastic and/or duroplastic plasters can be used. Examples include: polycondensates such as aminopla-. sters or phenoplasts, polyester plastics, polyadducts such as epoxy compounds, polyurethanes and homo- and copolymer plastics, such as acrylic plastics, methacrylic plastics, polydienes, poly-
olefiner, polystyrol, polyvinylesterplaster og cellulosederi-vater som f.eks.nitrocellulose, celluloseacetobutyrat, såvel som naturlig og syntetisk kautsjukk. olefins, polystyrene, polyvinyl ester plasters and cellulose derivatives such as nitrocellulose, cellulose acetobutyrate, as well as natural and synthetic rubber.
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De findelte skumstoffgranulater fremstilles på kjent måte. F.eks. kan et polystyrolskumgranulat fremstilles ved at man polymeriserer■styrol i vandig suspensjon i nærvær av esemidler som flyktige, flytende hydrokarboner, og behandler det perle-formede, esemiddalholdige polystyrol med vanndamp. Slik fremstilt findelt polystyrolskumgranulat har fortrinnsvis en partikkeldiameter på 0,1 til 4 mm. The finely divided foam granules are produced in a known manner. E.g. a polystyrene foam granulate can be produced by polymerizing styrene in aqueous suspension in the presence of blowing agents such as volatile, liquid hydrocarbons, and treating the bead-shaped, blowing agent-containing polystyrene with steam. Finely divided polystyrene foam granules produced in this way preferably have a particle diameter of 0.1 to 4 mm.
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Kjente skumstoffer som f.eks. polyuretanskum kan findeles med egnede apparater til onsket storrelse. Måten for fremstillingen av skumstoffgranulater er uten innflytelse på isolerings- Known foams such as e.g. Polyurethane foam can be shredded with suitable equipment to the desired size. The method of production of foam granules has no influence on the insulation
og sperrevirkningen for isolerings-, klebe-, tetnings- og sparkelmassene ifolge oppfinnelsen. Også blandinger av forskjellige skumstoffgranulater kan anvendes. De enkelte partikler for skumstoffgranulater har en diameter på 0,1 til 12 mm i avhengighet av det anvendte råstoff og fremstillingsmåten. Fortrinnsvis anvendes skumstoffgranulater hvis partikkeldiameter ligger mellom 0,8 og 8 mm. Bulkvekten for skumstoffgranulatene er likeledes avhengig av arten av plasten og fremstillingsmåten. and the barrier effect for the insulation, adhesive, sealing and putty compounds according to the invention. Mixtures of different foam granules can also be used. The individual particles for foam granules have a diameter of 0.1 to 12 mm, depending on the raw material used and the manufacturing method. Foam granules whose particle diameter is between 0.8 and 8 mm are preferably used. The bulk weight of the foam granules also depends on the nature of the plastic and the method of production.
Som regel ligger den mellom 5 og 300 g pr. liter, hvorved fortrinnsvis en bulkvekt mellom 10 og 150 g pr. liter gir fordel-aktige resultater. As a rule, it is between 5 and 300 g per litres, whereby preferably a bulk weight between 10 and 150 g per liter gives beneficial results.
Mengden av skumstoffgranulat er 1 til 25 deler, fortrinnsvisThe amount of foam granules is 1 to 25 parts, preferably
2 til 15 deler basert på dispersjonens totalvekt.2 to 15 parts based on the total weight of the dispersion.
,Ved anvendelsen av forskjellige skumstoffgranulater med forskjellige diametre, forskjellig form og forskjellig bulkvekt er man i stand til, alt etter den onskede forarbeidelseskonsistens for de isolerende klebe-, tetnings- og sparkelmasser ifolge oppfinnelsen, å innstille produktet stabilt til selvnivellerende. Ved tilsetning av egnede emulgeringsmidler, mykningsmidler, såper og fyllstoffer får man et produkt som er ubegrenset lagringsdyktig og har oppfinnelsesmessige fordeler. ,By using different foam granules with different diameters, different shapes and different bulk weights, it is possible, depending on the desired processing consistency for the insulating adhesive, sealing and putty compounds according to the invention, to set the product stably to self-leveling. By adding suitable emulsifiers, softeners, soaps and fillers, you get a product that can be stored indefinitely and has inventive advantages.
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Homogene blandinger av enkeltbestanddeler for de isolerende klebe-, tetnings- og sparkelmasser ifolge oppfinnelsen lar seg enkelt fremstille ved kortvarig blanding i de vanlige disper-geringsmaskiner. Hensiktsmessig anvender man dispersjonen.og rorer inn i denne etter behov det passende mykningsmiddel. Skum-stof f granulatene kan som sådanne eller blandet med fyll- og tilsetningsstoffer innarbeides i dispersjonen. Man får et homogent enhetslig produkt, som er ubegrenset lagringsdyktig og ikke har noen tendens til avsetning. Homogeneous mixtures of individual components for the insulating adhesive, sealing and putty compounds according to the invention can be easily prepared by short-term mixing in the usual dispersing machines. Appropriately, the dispersion is used and the appropriate plasticizer is stirred into it as needed. Foaming material f the granules can be incorporated into the dispersion as such or mixed with fillers and additives. You get a homogeneous, uniform product, which can be stored indefinitely and has no tendency to settle.
Påforingen av de isolerende klebe-, tetnings- og sparkelmasser etter oppfinnelsen skjer på vanlig måte ved sproytning, borsting, påvalsing og lignende med egnet utstyr. Etter påforingen er en lufttorking tilstrekkelig. Ved behov kan det dog torkes under The application of the insulating adhesive, sealing and putty compounds according to the invention takes place in the usual way by spraying, brushing, rolling and the like with suitable equipment. After application, air drying is sufficient. If necessary, however, it can be dried underneath
tilforsel av varme.supply of heat.
Anvendelsen av de isolerende klebe- og sparkelmasser ifolge oppfinnelsen som tetnings-, isolerings-, sperre-, reparasjons-og klebemiddel har stor anvendelsesbredde i industrien. Det kan f.eks. anvendes for varme- og lydisolering i byggeindustrien såvel som.. ved skips- og båtbygning, som også i automobilindustrien. The use of the insulating adhesive and putty compounds according to the invention as a sealing, insulating, barrier, repair and adhesive agent has a wide range of applications in industry. It can e.g. used for heat and sound insulation in the construction industry as well as... in ship and boat building, as well as in the automotive industry.
De etterfølgende eksempler skal forklare de isolerende klebe-og. sparkelmasser etter oppfinnelsen uten å begrense disse. De. angitte deler er vektsdeler. The following examples will explain the insulating adhesives. fillers according to the invention without limiting these. The. parts given are parts by weight.
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EKSEMPEL 1EXAMPLE 1
A) I 43 vektsdeler av en 48%'s vandig dispersjon av et akryl-syreester-blandingspolymerisat av 75 % etylakrylat, 20 % rnetyl-metakrylat, 2 % metakrylsyre og 3 % N- ((3-met akryl amidoetyl) - N,N<1->etylenurea og en partikkelstorrelse på 0^15 mikron rores inn 1,5 vektsdeler av et ikke-ionogent emulgeringsmiddel bestående av et etylenoksydaddukt av en fettalkohol i mol-forholdet 18 til 1. Denne blanding tilsettes porsjonsvis 7,0 vektsdeler A) In 43 parts by weight of a 48% aqueous dispersion of an acrylic acid ester mixture polymerizate of 75% ethyl acrylate, 20% methyl methacrylate, 2% methacrylic acid and 3% N- ((3-met acrylic amidoethyl)-N, N<1->ethylene urea and a particle size of 0^15 microns are stirred into 1.5 parts by weight of a non-ionic emulsifier consisting of an ethylene oxide adduct of a fatty alcohol in the molar ratio 18 to 1. This mixture is added portionwise 7.0 parts by weight
av et flytende polyisobutylen av mol-vekt ca. 3000 under god omroring. of a liquid polyisobutylene of molar weight approx. 3000 under good stirring.
B) 34 vektsdeler kritt og 4 vektsdeler talkum såvel som 5 vektsdeler titandioksyd av Rutiltype blandes, med 3 vektsdeler polystyrolskumstoffgranulat med lukkede celler, som som kule-aktig granulat oppviser en bulkvekt på 20 g/l og hvis partikler har en diameter på ca. 6 mm og som ble impregnert med 1,5 B) 34 parts by weight of chalk and 4 parts by weight of talc as well as 5 parts by weight of titanium dioxide of the Rutile type are mixed with 3 parts by weight of polystyrene foam granules with closed cells, which as ball-like granules have a bulk weight of 20 g/l and whose particles have a diameter of approx. 6 mm and which was impregnated with 1.5
vektsdeler av en 30%'s opplosning av ammoniumsaltet av en lavviskos polyakrylsyre. parts by weight of a 30% solution of the ammonium salt of a low viscosity polyacrylic acid.
Produkt B ble rort inn porsjonsvis i produkt A i tvangsblanderen inntil en homogen blanding oppnås. Hensiktsmessig anvendes produkt A etter en modningstid på 24 til 48 timer. Product B was mixed in portions into product A in the forced mixer until a homogeneous mixture is obtained. Appropriately, product A is used after a maturation period of 24 to 48 hours.
Produktet ifolge oppfinnelsen kan påfores ved hjelp av sprøyte-pistoler med en dysebredde på 2,5 mm og et trykk på 2 ato. Ved påforingen av dette produkt på et koldtvannsror av jern med en sjikttykkelse på ca. 30 mm oppnår man etter torkingen et isolerings- og sperresjikt, som isolerer roret fremragende mot The product according to the invention can be applied using spray guns with a nozzle width of 2.5 mm and a pressure of 2 ato. When applying this product to a cold-water iron rudder with a layer thickness of approx. 30 mm, after drying, an insulating and barrier layer is obtained, which insulates the rudder excellently against
det omgivende murverk og puss som skal påfores senere. the surrounding brickwork and plaster to be applied later.
EKSEMPEL 2EXAMPLE 2
A) I 40 vektsdeler av en i handelen vanlig vandig lateks på naturkautsjukk-basis med 40%<1>s torrstoffinnhold og en midlere partikkelstorrelse på 3 - 15 mikron rores inn 1,5 vektsdeler av et ikke-ionogent emulgeringsmiddel bestående av et alkylen- A) 1.5 parts by weight of a non-ionic emulsifier consisting of an alkylene-
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oksydaddukt av en fettsyre i mol-forholdet 12 til 1. Denne blanding tilsettes porsjonsvis 8,0 vektsdeler av et flytende polyisobutylen med mol-vekten ca. 10.000 under god omroring.. B) I 50 vektsdeler kvartsmel med kornstorrelsen 6 til 40 mikron tilsettes 5 vektsdeler polyetylenskumstoffgranulat med en bulkvekt på 80 g/ l og en partikkeldiameter på 1 til 8 mm, som ble impregnert med 1,5 vektsdeler av en 30%'s vandig opplosning av ammoniumsaltet av en lavviskos polyakrylsyre. oxide adduct of a fatty acid in the molar ratio of 12 to 1. To this mixture is added in portions 8.0 parts by weight of a liquid polyisobutylene with a molar weight of approx. 10,000 under good stirring.. B) In 50 parts by weight of quartz flour with a grain size of 6 to 40 microns, 5 parts by weight of polyethylene foam granules with a bulk weight of 80 g/l and a particle diameter of 1 to 8 mm are added, which was impregnated with 1.5 parts by weight of a 30 %'s aqueous solution of the ammonium salt of a low viscosity polyacrylic acid.
Produkt B rores porsjonsvis inn i produkt A i tvangsblanderen, inntil en homogen blanding oppnås. Product B is stirred portionwise into product A in the forced mixer, until a homogeneous mixture is achieved.
Produktet ifolge oppfinnelsen innfores i hulrom mellom tre, dorsarg og betongferdigdeler og lufttorkes. The product according to the invention is introduced into the cavity between wood, dorsarg and concrete precast parts and is air-dried.
Man oppnår en befestigelse av dorsargen ved samtidig avtetning?sperring og isolering mellom dor og veggelement. A fixing of the door frame is achieved by simultaneous sealing?blocking and insulation between the door and the wall element.
EKSEMPEL 3EXAMPLE 3
Til 45 vektsdeler av en 46%'s dispersjon av et blandingspoly-merisat av 60% etylakrylat, 39% metylmetakrylat og 1% akryl-syre og med en partikkelstorrelse på ca. 0,4 mikron tilsettes 18 vektsdeler ureaformaldehyd-skumstoffgranulat med en korn-storrelse på ca. 1,67 mm, som er fordispergert i 36 vektsdeler vann,som inneholder 0,9 vektsdeler fuktningsmiddel (benzyleter av den tertiære oktylfenoksypoly-(20)-atoksyalkanol og 0,1 vektsdel av et antiskumningsmiddel, i en blander og homogeniseres. To 45 parts by weight of a 46% dispersion of a mixed polymer of 60% ethyl acrylate, 39% methyl methacrylate and 1% acrylic acid and with a particle size of approx. 0.4 micron, 18 parts by weight of urea formaldehyde foam granules with a grain size of approx. 1.67 mm, which is predispersed in 36 parts by weight of water, containing 0.9 parts by weight of wetting agent (benzyl ether of the tertiary octylphenoxypoly-(20)-ethoxyalkanol and 0.1 part by weight of an antifoam agent, in a mixer and homogenized.
Man får et homogent produkt som påfores et betongunderlag i en sjikttykkelse på 4 mm. You get a homogeneous product that is applied to a concrete substrate in a layer thickness of 4 mm.
Etter torkingen får man et isoleringssjikt som beskytter ut-merket mot varme og kulde såvel som mot fuktighet og som etter behov kan overtrekkes med vanlige malingsmidler. After drying, you get an insulating layer that provides excellent protection against heat and cold as well as against moisture, and which can be coated with ordinary paint as needed.
EKSEMPEL 4EXAMPLE 4
I 62 vektsdeler av en 60%'s vandig dispersjon av en polyepoksyd-forbindelse av pentaerytrid og epiklorhydrin, fremstilt ved dispergering av en blanding av polyepoksydforbindelsen med 10 deler av et emulgeringsmiddel bestående av 70 deler av et addukt av 20 mol etylenoksyd i laurylalkohol og 30 deler av et triatanolaminsalt av dodecylbenzensulfosyre i vann som inneholder 4 deler polyvinylalkohol rores inn 18 vektsdeler kritt og In 62 parts by weight of a 60% aqueous dispersion of a polyepoxide compound of pentaerythride and epichlorohydrin, prepared by dispersing a mixture of the polyepoxide compound with 10 parts of an emulsifier consisting of 70 parts of an adduct of 20 moles of ethylene oxide in lauryl alcohol and 30 parts of a triethanolamine salt of dodecylbenzenesulfonic acid in water containing 4 parts of polyvinyl alcohol are stirred into 18 parts by weight of chalk and
. 8 vektsdeler titandioksyd-rutil-pigment og til denne blanding innblandes 12 vektsdeler av et polyuretanskumstoffgranulat med . 8 parts by weight of titanium dioxide-rutile pigment and 12 parts by weight of a polyurethane foam granulate with
en kbrnstorrelse mellom 1,4 og 3,3 mm. og en bulkvekt på 120 g/l porsjonsvis og homogeniseres. a carbon size between 1.4 and 3.3 mm. and a bulk weight of 120 g/l in portions and homogenized.
s pp
Man får et flytedyktig produkt, som etter tilsetning av 8 vektsdeler alkylendiamin lar seg herde kort for anvendelsen som iso-ler ingsmiddel mot lyd i automobilindustrien på overflater i sjikttykkelser på 0,5 til 3 mm. A flowable product is obtained, which after the addition of 8 parts by weight of alkylenediamine can be cured briefly for use as an insulating agent against sound in the automotive industry on surfaces in layer thicknesses of 0.5 to 3 mm.
Claims (7)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19732351820 DE2351820A1 (en) | 1973-10-16 | 1973-10-16 | INSULATING ADHESIVE, SEALING AND FILLER COMPOUNDS |
Publications (1)
Publication Number | Publication Date |
---|---|
NO743704L true NO743704L (en) | 1975-05-12 |
Family
ID=5895545
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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NO743704A NO743704L (en) | 1973-10-16 | 1974-10-15 |
Country Status (11)
Country | Link |
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AT (1) | AT330326B (en) |
BE (1) | BE820990A (en) |
DE (1) | DE2351820A1 (en) |
DK (1) | DK539374A (en) |
ES (1) | ES430992A1 (en) |
FI (1) | FI300674A (en) |
FR (1) | FR2247520A1 (en) |
GB (1) | GB1478412A (en) |
NL (1) | NL7413510A (en) |
NO (1) | NO743704L (en) |
SE (1) | SE7412951L (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2817200C2 (en) * | 1978-04-20 | 1982-10-14 | Basf Ag, 6700 Ludwigshafen | Thermal insulation layer based on foam particles, binders and processing aids |
CA1124501A (en) * | 1978-06-20 | 1982-06-01 | Arthur D. Jordan, Jr. | Plasticizer combination of alkylene oxide-alkyl phenol adduct and carboxylic acid ester, and caulking composition |
DE3010863C2 (en) * | 1980-03-21 | 1983-05-26 | MC-Bauchemie Müller GmbH & Co, Chemische Fabrik, 4300 Essen | Material for freshening up and / or tinting, as well as for preserving the joints of tile or tile coverings of all kinds |
DE3404271A1 (en) * | 1984-02-03 | 1985-08-08 | Mannesmann AG, 4000 Düsseldorf | FINE GRAIN BLEND |
DE102012104769A1 (en) | 2012-06-01 | 2013-12-05 | Hardy Schulze | Paints, substrates for application together with a binder on surfaces, and methods of making a paint to reduce or prevent the formation of mold |
-
1973
- 1973-10-16 DE DE19732351820 patent/DE2351820A1/en active Pending
-
1974
- 1974-10-11 BE BE149462A patent/BE820990A/en unknown
- 1974-10-14 AT AT823374A patent/AT330326B/en not_active IP Right Cessation
- 1974-10-14 ES ES430992A patent/ES430992A1/en not_active Expired
- 1974-10-15 GB GB4466974A patent/GB1478412A/en not_active Expired
- 1974-10-15 SE SE7412951A patent/SE7412951L/ not_active Application Discontinuation
- 1974-10-15 NO NO743704A patent/NO743704L/no unknown
- 1974-10-15 NL NL7413510A patent/NL7413510A/en unknown
- 1974-10-15 DK DK539374A patent/DK539374A/da not_active Application Discontinuation
- 1974-10-15 FI FI3006/74A patent/FI300674A/fi unknown
- 1974-10-16 FR FR7434810A patent/FR2247520A1/fr not_active Withdrawn
Also Published As
Publication number | Publication date |
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ATA823374A (en) | 1975-09-15 |
NL7413510A (en) | 1975-04-18 |
GB1478412A (en) | 1977-06-29 |
AT330326B (en) | 1976-06-25 |
FR2247520A1 (en) | 1975-05-09 |
SE7412951L (en) | 1975-04-17 |
DE2351820A1 (en) | 1975-04-17 |
DK539374A (en) | 1975-06-16 |
ES430992A1 (en) | 1977-02-01 |
BE820990A (en) | 1975-02-03 |
FI300674A (en) | 1975-04-17 |
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