NO326665B1 - Fremgangsmate for fremstilling av vannholdige hydroksylaminopplosninger som er i det vesentlige frie for metallioner - Google Patents
Fremgangsmate for fremstilling av vannholdige hydroksylaminopplosninger som er i det vesentlige frie for metallioner Download PDFInfo
- Publication number
- NO326665B1 NO326665B1 NO20004076A NO20004076A NO326665B1 NO 326665 B1 NO326665 B1 NO 326665B1 NO 20004076 A NO20004076 A NO 20004076A NO 20004076 A NO20004076 A NO 20004076A NO 326665 B1 NO326665 B1 NO 326665B1
- Authority
- NO
- Norway
- Prior art keywords
- hydroxylamine solution
- metal ions
- treatment
- cation exchanger
- hydroxylamine
- Prior art date
Links
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 229910021645 metal ion Inorganic materials 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title abstract description 6
- 150000001768 cations Chemical class 0.000 claims abstract description 40
- 230000002378 acidificating effect Effects 0.000 claims abstract description 11
- 239000000243 solution Substances 0.000 claims description 62
- 150000001450 anions Chemical class 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 13
- 239000003381 stabilizer Substances 0.000 claims description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 238000004821 distillation Methods 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910001413 alkali metal ion Inorganic materials 0.000 description 4
- -1 ammonium ions Chemical class 0.000 description 4
- 229920001429 chelating resin Polymers 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 229910001415 sodium ion Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 239000008139 complexing agent Substances 0.000 description 3
- 239000003456 ion exchange resin Substances 0.000 description 3
- 229920003303 ion-exchange polymer Polymers 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- 238000005349 anion exchange Methods 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000005341 cation exchange Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical group OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002443 hydroxylamines Chemical group 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/14—Hydroxylamine; Salts thereof
- C01B21/1481—Purification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19806578A DE19806578A1 (de) | 1998-02-17 | 1998-02-17 | Verfahren zur Herstellung wäßriger, im wesentlichen metallionenfreier Hydroxylaminlösungen |
| PCT/EP1999/000993 WO1999042434A2 (de) | 1998-02-17 | 1999-02-16 | Verfahren zur herstellung wässriger, im wesentlichen metallionenfreier hydroxylaminlösungen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20004076D0 NO20004076D0 (no) | 2000-08-15 |
| NO20004076L NO20004076L (no) | 2000-08-15 |
| NO326665B1 true NO326665B1 (no) | 2009-01-26 |
Family
ID=7858040
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20004076A NO326665B1 (no) | 1998-02-17 | 2000-08-15 | Fremgangsmate for fremstilling av vannholdige hydroksylaminopplosninger som er i det vesentlige frie for metallioner |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6524545B1 (zh) |
| EP (1) | EP1056713B1 (zh) |
| JP (1) | JP4285904B2 (zh) |
| KR (1) | KR100564191B1 (zh) |
| CN (1) | CN1269727C (zh) |
| AT (1) | ATE243674T1 (zh) |
| AU (1) | AU756907B2 (zh) |
| CA (1) | CA2321032C (zh) |
| DE (2) | DE19806578A1 (zh) |
| ES (1) | ES2203081T3 (zh) |
| IL (1) | IL137647A (zh) |
| MY (1) | MY120796A (zh) |
| NO (1) | NO326665B1 (zh) |
| TR (1) | TR200002384T2 (zh) |
| TW (1) | TW460407B (zh) |
| WO (1) | WO1999042434A2 (zh) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19936594A1 (de) | 1999-08-04 | 2001-02-08 | Basf Ag | Verfahren zur Herstellung von hochreinen stabilisierten Hydroxylaminlösungen |
| JP4582602B2 (ja) * | 2000-03-24 | 2010-11-17 | ビーエーエスエフ ソシエタス・ヨーロピア | ヒドロキシルアミン水溶液およびその製造方法 |
| US6432752B1 (en) * | 2000-08-17 | 2002-08-13 | Micron Technology, Inc. | Stereolithographic methods for fabricating hermetic semiconductor device packages and semiconductor devices including stereolithographically fabricated hermetic packages |
| JP4578885B2 (ja) * | 2003-08-13 | 2010-11-10 | 昭和電工株式会社 | ヒドロキシルアミンの製造方法 |
| WO2005016817A2 (en) | 2003-08-13 | 2005-02-24 | Showa Denko K. K. | Process for producing hydroxylamine |
| US7396519B2 (en) * | 2004-01-26 | 2008-07-08 | San Fu Chemical Company, Ltd. | Preparation of a high purity and high concentration hydroxylamine free base |
| JP4578999B2 (ja) * | 2005-02-10 | 2010-11-10 | 昭和電工株式会社 | ヒドロキシルアミンの製造方法 |
| JP4578998B2 (ja) * | 2005-02-10 | 2010-11-10 | 昭和電工株式会社 | ヒドロキシルアミンの製造方法 |
| CN115427392A (zh) * | 2020-04-08 | 2022-12-02 | 陶氏环球技术有限责任公司 | 有机胺纯化方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL6914306A (zh) * | 1969-09-20 | 1971-03-23 | ||
| JPS4914640B1 (zh) * | 1970-08-25 | 1974-04-09 | ||
| JPS5534764B2 (zh) | 1972-06-02 | 1980-09-09 | ||
| FR2243904B1 (zh) * | 1973-09-14 | 1976-06-18 | Commissariat Energie Atomique | |
| US4202765A (en) * | 1977-10-28 | 1980-05-13 | Allied Chemical Corporation | Hydroxylamine purification via cation exchange |
| US4147623A (en) * | 1977-10-28 | 1979-04-03 | Allied Chemical Corporation | Hydroxylamine purification via ion exclusion |
| DE3607998A1 (de) * | 1986-03-11 | 1987-09-17 | Basf Ag | Verfahren zur aufarbeitung von hydroxylamin oder dessen salze enthaltenden abwaessern |
| DE3608495A1 (de) * | 1986-03-14 | 1987-09-17 | Basf Ag | Verfahren zur herstellung von waessrigen loesungen von hydroxylamin |
| US5266290A (en) * | 1992-07-10 | 1993-11-30 | Thiokol Corporation | Process for making high purity hydroxylammonium nitrate |
| HRP960601B1 (en) * | 1995-12-20 | 2001-12-31 | Basf Ag | Process for separating medium boiling substances from a mixture of low, medium and high boiling substances |
| US5788946A (en) * | 1997-07-16 | 1998-08-04 | Ashland Inc. | Purification of hydroxylamine |
| US5872295A (en) * | 1998-02-13 | 1999-02-16 | Concept Sciences, Inc. | Purification of hydroxylamine |
-
1998
- 1998-02-17 DE DE19806578A patent/DE19806578A1/de not_active Withdrawn
-
1999
- 1999-02-12 TW TW088102275A patent/TW460407B/zh not_active IP Right Cessation
- 1999-02-13 MY MYPI99000533A patent/MY120796A/en unknown
- 1999-02-16 AT AT99908908T patent/ATE243674T1/de active
- 1999-02-16 AU AU28343/99A patent/AU756907B2/en not_active Ceased
- 1999-02-16 IL IL13764799A patent/IL137647A/en not_active IP Right Cessation
- 1999-02-16 CN CNB998050792A patent/CN1269727C/zh not_active Expired - Lifetime
- 1999-02-16 KR KR1020007008924A patent/KR100564191B1/ko active IP Right Grant
- 1999-02-16 JP JP2000532387A patent/JP4285904B2/ja not_active Expired - Lifetime
- 1999-02-16 DE DE59906097T patent/DE59906097D1/de not_active Expired - Lifetime
- 1999-02-16 CA CA002321032A patent/CA2321032C/en not_active Expired - Fee Related
- 1999-02-16 TR TR2000/02384T patent/TR200002384T2/xx unknown
- 1999-02-16 ES ES99908908T patent/ES2203081T3/es not_active Expired - Lifetime
- 1999-02-16 EP EP99908908A patent/EP1056713B1/de not_active Expired - Lifetime
- 1999-02-16 WO PCT/EP1999/000993 patent/WO1999042434A2/de active IP Right Grant
- 1999-02-16 US US09/622,170 patent/US6524545B1/en not_active Expired - Lifetime
-
2000
- 2000-08-15 NO NO20004076A patent/NO326665B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE19806578A1 (de) | 1999-08-19 |
| WO1999042434A3 (de) | 1999-10-21 |
| AU756907B2 (en) | 2003-01-23 |
| NO20004076D0 (no) | 2000-08-15 |
| CN1297422A (zh) | 2001-05-30 |
| IL137647A (en) | 2004-08-31 |
| TR200002384T2 (tr) | 2000-12-21 |
| CN1269727C (zh) | 2006-08-16 |
| EP1056713B1 (de) | 2003-06-25 |
| CA2321032C (en) | 2008-05-06 |
| TW460407B (en) | 2001-10-21 |
| DE59906097D1 (de) | 2003-07-31 |
| JP2002503633A (ja) | 2002-02-05 |
| MY120796A (en) | 2005-11-30 |
| CA2321032A1 (en) | 1999-08-26 |
| ATE243674T1 (de) | 2003-07-15 |
| AU2834399A (en) | 1999-09-06 |
| JP4285904B2 (ja) | 2009-06-24 |
| WO1999042434A2 (de) | 1999-08-26 |
| IL137647A0 (en) | 2001-10-31 |
| ES2203081T3 (es) | 2004-04-01 |
| US6524545B1 (en) | 2003-02-25 |
| KR100564191B1 (ko) | 2006-03-27 |
| KR20010078694A (ko) | 2001-08-21 |
| EP1056713A2 (de) | 2000-12-06 |
| NO20004076L (no) | 2000-08-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM1K | Lapsed by not paying the annual fees |