NO314691B1 - Fremgangsmåte og reaktor for fremstilling av hydrogen og syntesegass - Google Patents

Fremgangsmåte og reaktor for fremstilling av hydrogen og syntesegass Download PDF

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Publication number
NO314691B1
NO314691B1 NO20002378A NO20002378A NO314691B1 NO 314691 B1 NO314691 B1 NO 314691B1 NO 20002378 A NO20002378 A NO 20002378A NO 20002378 A NO20002378 A NO 20002378A NO 314691 B1 NO314691 B1 NO 314691B1
Authority
NO
Norway
Prior art keywords
hydrogen
gas
reactor
reformed
stream
Prior art date
Application number
NO20002378A
Other languages
English (en)
Norwegian (no)
Other versions
NO20002378L (no
NO20002378D0 (no
Inventor
Erling Rytter
Original Assignee
Statoil Asa I & K Ir Pat
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Statoil Asa I & K Ir Pat filed Critical Statoil Asa I & K Ir Pat
Priority to NO20002378A priority Critical patent/NO314691B1/no
Publication of NO20002378D0 publication Critical patent/NO20002378D0/no
Priority to DE60131471T priority patent/DE60131471T2/de
Priority to EP01928258A priority patent/EP1441981B1/de
Priority to AT01928258T priority patent/ATE378287T1/de
Priority to US10/275,227 priority patent/US20030171442A1/en
Priority to PCT/NO2001/000183 priority patent/WO2001085608A1/en
Priority to AU2001255116A priority patent/AU2001255116A1/en
Publication of NO20002378L publication Critical patent/NO20002378L/no
Publication of NO314691B1 publication Critical patent/NO314691B1/no

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405Purification by membrane separation
    • C01B2203/041In-situ membrane purification during hydrogen production
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/047Composition of the impurity the impurity being carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0475Composition of the impurity the impurity being carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0495Composition of the impurity the impurity being water
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/061Methanol production
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/062Hydrocarbon production, e.g. Fischer-Tropsch process
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/068Ammonia synthesis
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005Arrangement or shape of catalyst
    • C01B2203/1011Packed bed of catalytic structures, e.g. particles, packing elements
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1082Composition of support materials
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1241Natural gas or methane
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/142At least two reforming, decomposition or partial oxidation steps in series
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
NO20002378A 2000-05-05 2000-05-05 Fremgangsmåte og reaktor for fremstilling av hydrogen og syntesegass NO314691B1 (no)

Priority Applications (7)

Application Number Priority Date Filing Date Title
NO20002378A NO314691B1 (no) 2000-05-05 2000-05-05 Fremgangsmåte og reaktor for fremstilling av hydrogen og syntesegass
DE60131471T DE60131471T2 (de) 2000-05-05 2001-05-03 Reaktor zur reformierung von erdgas und gleichzeitige herstellung von wasserstoff
EP01928258A EP1441981B1 (de) 2000-05-05 2001-05-03 Reaktor zur reformierung von erdgas und gleichzeitige herstellung von wasserstoff
AT01928258T ATE378287T1 (de) 2000-05-05 2001-05-03 Reaktor zur reformierung von erdgas und gleichzeitige herstellung von wasserstoff
US10/275,227 US20030171442A1 (en) 2000-05-05 2001-05-03 Method and reactor for reformation of natural gas and simultaneous production of hydrogen
PCT/NO2001/000183 WO2001085608A1 (en) 2000-05-05 2001-05-03 Method and reactor for reformation of natural gas and simultaneous production of hydrogen
AU2001255116A AU2001255116A1 (en) 2000-05-05 2001-05-03 Method and reactor for reformation of natural gas and simultaneous production ofhydrogen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NO20002378A NO314691B1 (no) 2000-05-05 2000-05-05 Fremgangsmåte og reaktor for fremstilling av hydrogen og syntesegass

Publications (3)

Publication Number Publication Date
NO20002378D0 NO20002378D0 (no) 2000-05-05
NO20002378L NO20002378L (no) 2001-11-06
NO314691B1 true NO314691B1 (no) 2003-05-05

Family

ID=19911109

Family Applications (1)

Application Number Title Priority Date Filing Date
NO20002378A NO314691B1 (no) 2000-05-05 2000-05-05 Fremgangsmåte og reaktor for fremstilling av hydrogen og syntesegass

Country Status (7)

Country Link
US (1) US20030171442A1 (de)
EP (1) EP1441981B1 (de)
AT (1) ATE378287T1 (de)
AU (1) AU2001255116A1 (de)
DE (1) DE60131471T2 (de)
NO (1) NO314691B1 (de)
WO (1) WO2001085608A1 (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2846958B1 (fr) * 2002-11-13 2005-08-26 N Ghy Valorisation de l'oxygene pour la production d'hydrogene a partir d'hydrocarbures avec sequestration de co2
CN100564495C (zh) * 2003-03-18 2009-12-02 凯洛格·布朗及鲁特有限公司 制氢用自热转化器-转化交换器布置
US7166643B2 (en) * 2004-03-08 2007-01-23 Chevron U.S.A. Inc. Hydrogen recovery from hydrocarbon synthesis processes
BR112014002629A2 (pt) 2011-08-04 2017-05-02 A Stuart Martin forno de arco de plasma e aplicações
CN102530859B (zh) * 2011-12-29 2013-11-06 武汉凯迪工程技术研究总院有限公司 一种外热型微波等离子气化炉及合成气生产方法
US9359558B2 (en) 2012-11-29 2016-06-07 General Electric Company Carbon to liquids system and method of operation
US20140364654A1 (en) * 2013-06-10 2014-12-11 Unitel Technologies, Inc. Dimethyl ether (dme) production process
US10066275B2 (en) 2014-05-09 2018-09-04 Stephen L. Cunningham Arc furnace smeltering system and method

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3278268A (en) * 1962-08-15 1966-10-11 Engelhard Ind Inc Method for hydrogen production
IT1272532B (it) * 1993-08-27 1997-06-23 Snam Progetti Processo di ossidazione parziale catalitica del gas naturale per ottenere gas di sintesi e formaldeide
US5965010A (en) * 1997-07-15 1999-10-12 Niagara Mohawk Power Corporation Electrochemical autothermal reformer
NO319681B1 (no) * 1998-09-16 2005-09-05 Statoil Asa Fremgangsmate for fremstilling av en H2-rik gass og en CO2-rik gass ved hoyt trykk
DK173897B1 (da) * 1998-09-25 2002-02-04 Topsoe Haldor As Fremgangsmåde til autotermisk reforming af et carbonhydridfødemateriale indeholdende højere carbonhydrider

Also Published As

Publication number Publication date
US20030171442A1 (en) 2003-09-11
EP1441981B1 (de) 2007-11-14
DE60131471T2 (de) 2008-10-02
AU2001255116A1 (en) 2001-11-20
WO2001085608A1 (en) 2001-11-15
NO20002378L (no) 2001-11-06
ATE378287T1 (de) 2007-11-15
NO20002378D0 (no) 2000-05-05
EP1441981A1 (de) 2004-08-04
DE60131471D1 (de) 2007-12-27

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CHAD Change of the owner's name or address (par. 44 patent law, par. patentforskriften)

Owner name: STATOIL ASA, NO

CHAD Change of the owner's name or address (par. 44 patent law, par. patentforskriften)

Owner name: STATOIL PETROLEUM AS, NO

MK1K Patent expired