NO20074411L - Process and apparatus for polymerizing ethylene - Google Patents

Process and apparatus for polymerizing ethylene

Info

Publication number
NO20074411L
NO20074411L NO20074411A NO20074411A NO20074411L NO 20074411 L NO20074411 L NO 20074411L NO 20074411 A NO20074411 A NO 20074411A NO 20074411 A NO20074411 A NO 20074411A NO 20074411 L NO20074411 L NO 20074411L
Authority
NO
Norway
Prior art keywords
ethylene
polymer particles
propane
gas
fraction
Prior art date
Application number
NO20074411A
Other languages
Norwegian (no)
Inventor
Giuseppe Penzo
Cyrus Ahmadzade-Youssefi
Rainer Karer
Ulrich Nieken
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Publication of NO20074411L publication Critical patent/NO20074411L/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/0035—Periodical feeding or evacuation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/006—Separating solid material from the gas/liquid stream by filtration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/001—Removal of residual monomers by physical means
    • C08F6/005—Removal of residual monomers by physical means from solid polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00274—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00761—Discharging
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/92—Apparatus for use in addition polymerization processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Fremgangsmåte for polymerisering av etylen eller av etylen med ytterligere 1-olefiner, hvori etylenet polymeriserer i nærvær av en katalysator i en gassfasereaktor og reaksjonsgass omfattende propan og upolymerisert etylen sirkuleres for å fjerne polymerisasjonsvarme, hvori polymerpartiklene fjernes kontinuerlig eller diskontinuerlig fra reaktoren, polymerpartiklene separeres fra hovedandelen av den samtidig fjernede gass og polymerpartiklene avgasses, gassen befris for medrevne fine partikler og separeres fra en lavtkokende fraksjon omfattende etylen eller fra en høytkokende fraksjon inneholdende ytterligere 1-olefiner eller alkaner med fra 4 til 12 karbonatomer i et første separasjonstrinn, en propanfraksjon separeres i et andre separeringstrinn og denne propanfraksjon anvendes for deavgassing av polymerpartikler fjernet fra reaktoren, idet mengdeandelen av etylen i propanfraksjonen er mindre enn 1 mol% og mengeandelen av 1-olefiner og alkaner med fra 4 til 12 karbonatomer i propanfraksjonen er mindre enn 4 mol%, i hvert tilfelle basert på den totale propanfraksjon.Videre beskrives et apparat for gjennomføring av fremgangsmåten. På denne måte muliggjøres en høy varmefjerning fra reaktoren, tilfredsstillende avgassing av de uttatte polymerpartikler og gjenvinning av reaksjonsgassen tømt ut sammen med polymerpartiklene og også gassen anvendt for avgassing av polymerpartiklene.Process for polymerizing ethylene or of ethylene with additional 1-olefins, wherein the ethylene polymerizes in the presence of a catalyst in a gas phase reactor and reaction gas comprising propane and unpolymerized ethylene is circulated to remove polymerization heat, wherein the polymer particles are continuously or discontinuously removed from the reactor. the major portion of the co-removed gas and polymer particles are degassed, the gas is liberated from entrained fine particles and separated from a low boiling fraction comprising ethylene or from a high boiling fraction containing additional 1-olefins or alkanes having from 4 to 12 carbon atoms in a first separation step, a propane fraction is separated in a second separation step and this propane fraction is used for the degassing of polymer particles removed from the reactor, the amount of ethylene in the propane fraction being less than 1 mol% and the amount of 1-olefins and alkanes having from 4 to 12 carbon atoms in propane the action is less than 4 mol%, in each case based on the total propane fraction. Furthermore, an apparatus for carrying out the process is described. In this way a high heat removal from the reactor is enabled, satisfactory degassing of the extracted polymer particles and recovery of the reaction gas emptied out together with the polymer particles and also the gas used for degassing the polymer particles.

NO20074411A 2005-02-04 2007-08-29 Process and apparatus for polymerizing ethylene NO20074411L (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102005005506A DE102005005506A1 (en) 2005-02-04 2005-02-04 Polymerization of ethylene optionally with 1-olefins involves polymerizing ethylene in presence of catalyst to form polymer particles and circulating unpolymerized ethylene to remove heat of polymerization
US65618505P 2005-02-25 2005-02-25
PCT/EP2006/000783 WO2006082007A1 (en) 2005-02-04 2006-01-30 Process and apparatus for the polymerization of ethylene

Publications (1)

Publication Number Publication Date
NO20074411L true NO20074411L (en) 2007-10-31

Family

ID=36709737

Family Applications (1)

Application Number Title Priority Date Filing Date
NO20074411A NO20074411L (en) 2005-02-04 2007-08-29 Process and apparatus for polymerizing ethylene

Country Status (22)

Country Link
US (1) US7582723B2 (en)
EP (1) EP1853635B1 (en)
JP (1) JP2008528776A (en)
KR (1) KR101222265B1 (en)
CN (1) CN100537609C (en)
AR (1) AR054728A1 (en)
AT (1) ATE402961T1 (en)
AU (1) AU2006210053A1 (en)
BR (1) BRPI0607244B1 (en)
CA (1) CA2592333A1 (en)
DE (2) DE102005005506A1 (en)
EG (1) EG24418A (en)
ES (1) ES2308718T3 (en)
IL (1) IL183737A0 (en)
MX (1) MX2007009396A (en)
MY (1) MY138311A (en)
NO (1) NO20074411L (en)
PL (1) PL1853635T3 (en)
RU (1) RU2394842C2 (en)
TW (1) TW200630389A (en)
WO (1) WO2006082007A1 (en)
ZA (1) ZA200706446B (en)

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EP2123682A1 (en) * 2008-05-20 2009-11-25 INEOS Manufacturing Belgium NV Olefin polymerisation process
CN102666443B (en) * 2009-10-16 2014-09-03 沙索技术有限公司 Separation of components from a multi-component hydrocarbon stream which includes ethylene
BR112013000533B1 (en) * 2010-07-09 2020-04-22 Univation Tech Llc process for recovering hydrocarbons from a polymerization ventilation gas and system for recovering hydrocarbons from a polymerization ventilation gas
WO2012175469A1 (en) 2011-06-21 2012-12-27 Basell Polyolefine Gmbh Method and apparatus for discharging a polymer from a gas-phase reactor
KR101378892B1 (en) * 2011-07-14 2014-04-04 주식회사 엘지화학 Method of preparing polyolefin resin
RU2608615C2 (en) * 2011-10-17 2017-01-23 Инеос Юроуп Аг Control over polymers degassing process
CN104684941B (en) * 2012-10-02 2017-10-03 英尼奥斯欧洲股份公司 Method for improving polyplant operation
EP2743279A1 (en) 2012-12-11 2014-06-18 Basell Polyolefine GmbH Process for treating polyolefin particles obtained by gas-phase polymerization
EP2743278A1 (en) 2012-12-11 2014-06-18 Basell Polyolefine GmbH Process for degassing and buffering polyolefin particles obtained by olefin polymerization
RU2016138019A (en) * 2014-02-26 2018-03-29 Инеос Юроуп Аг METHOD OF POLYMERIZATION AND POLYMERIZATION INSTALLATION INCLUDING A DEGASATION SECTION
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US10626195B2 (en) 2015-11-18 2020-04-21 Basell Polyolefine Gmbh Polymerization process with a partial shutdown phase
WO2017102303A1 (en) * 2015-12-15 2017-06-22 Sabic Global Technologies B.V. Olefin polymerization process
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EP3418310B1 (en) * 2017-06-23 2020-04-08 Borealis AG Process and apparatus for removing polymer material from a gas-solids olefin polymerization reactor
EP3438133A1 (en) * 2017-08-04 2019-02-06 Basell Polyolefine GmbH Polymerization process including discharging polyolefin particles from a gas-phase polymerization reactor
CN108854859B (en) * 2018-07-27 2023-08-18 中化蓝天霍尼韦尔新材料有限公司 Suspension gas-liquid phase reaction device and operation method
EP3898709A1 (en) * 2018-12-18 2021-10-27 Basell Polyolefine GmbH Gas-phase process for preparing ethylene polymers
CN112745435B (en) * 2019-10-31 2022-07-12 中国石油化工股份有限公司 Process for converting polymer slurry into polymer solution and process for producing butyl rubber
US11820841B2 (en) * 2020-01-28 2023-11-21 Exxonmobil Chemical Patents Inc. Reducing accumulation of C6+ hydrocarbon components in polyolefin gas-phase reactors
EP4046981A4 (en) 2020-09-07 2023-06-28 LG Chem, Ltd. Method for preparing oligomer
KR20220104418A (en) 2021-01-18 2022-07-26 주식회사 엘지화학 Method for preparing oligomer
CN115246903B (en) * 2021-04-28 2023-09-12 中国石油化工股份有限公司 Continuous solution polymerization process
JP2024007084A (en) * 2022-07-05 2024-01-18 住友化学株式会社 Polyolefin production apparatus and polyolefin production method

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Also Published As

Publication number Publication date
BRPI0607244B1 (en) 2016-05-31
EP1853635B1 (en) 2008-07-30
TW200630389A (en) 2006-09-01
BRPI0607244A2 (en) 2010-03-23
PL1853635T3 (en) 2009-01-30
DE102005005506A1 (en) 2006-08-10
EP1853635A1 (en) 2007-11-14
JP2008528776A (en) 2008-07-31
ES2308718T3 (en) 2008-12-01
RU2007129830A (en) 2009-02-10
WO2006082007A1 (en) 2006-08-10
KR20070116221A (en) 2007-12-07
ZA200706446B (en) 2008-06-25
MX2007009396A (en) 2007-09-25
KR101222265B1 (en) 2013-01-15
EG24418A (en) 2009-05-25
MY138311A (en) 2009-05-29
IL183737A0 (en) 2007-09-20
AR054728A1 (en) 2007-07-11
US20080177012A1 (en) 2008-07-24
AU2006210053A1 (en) 2006-08-10
CN101107273A (en) 2008-01-16
DE602006002026D1 (en) 2008-09-11
CN100537609C (en) 2009-09-09
ATE402961T1 (en) 2008-08-15
WO2006082007A8 (en) 2007-08-30
CA2592333A1 (en) 2006-08-10
RU2394842C2 (en) 2010-07-20
US7582723B2 (en) 2009-09-01

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