NO169661B - Liquid detergent mixture for simultaneous cleaning and softening of fabrics - Google Patents
Liquid detergent mixture for simultaneous cleaning and softening of fabrics Download PDFInfo
- Publication number
- NO169661B NO169661B NO870367A NO870367A NO169661B NO 169661 B NO169661 B NO 169661B NO 870367 A NO870367 A NO 870367A NO 870367 A NO870367 A NO 870367A NO 169661 B NO169661 B NO 169661B
- Authority
- NO
- Norway
- Prior art keywords
- alkyl
- mixture
- softening
- mixture according
- alcohol
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 69
- 239000003599 detergent Substances 0.000 title claims description 57
- 239000007788 liquid Substances 0.000 title claims description 21
- 239000004744 fabric Substances 0.000 title claims description 18
- 238000004140 cleaning Methods 0.000 title claims description 13
- -1 alkyl glycoside Chemical class 0.000 claims description 42
- 229930182470 glycoside Natural products 0.000 claims description 28
- 238000005406 washing Methods 0.000 claims description 27
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- 239000002736 nonionic surfactant Substances 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000003945 anionic surfactant Substances 0.000 claims description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 7
- 125000001165 hydrophobic group Chemical group 0.000 claims description 6
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 125000003563 glycoside group Chemical group 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 239000008365 aqueous carrier Substances 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical group [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 claims description 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims 1
- 159000000000 sodium salts Chemical class 0.000 claims 1
- 229910021653 sulphate ion Inorganic materials 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 description 18
- 230000000694 effects Effects 0.000 description 14
- 239000000047 product Substances 0.000 description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 102000004190 Enzymes Human genes 0.000 description 6
- 108090000790 Enzymes Proteins 0.000 description 6
- 125000002091 cationic group Chemical group 0.000 description 6
- 150000002338 glycosides Chemical group 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 230000002087 whitening effect Effects 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- 239000007844 bleaching agent Substances 0.000 description 5
- 239000002979 fabric softener Substances 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical group 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 3
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 3
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 230000002152 alkylating effect Effects 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 235000021168 barbecue Nutrition 0.000 description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- QKIAYRRGJHLRAQ-UHFFFAOYSA-N hexadecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 QKIAYRRGJHLRAQ-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 235000015067 sauces Nutrition 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical compound COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- KVGOXGQSTGQXDD-UHFFFAOYSA-N 1-decane-sulfonic-acid Chemical compound CCCCCCCCCCS(O)(=O)=O KVGOXGQSTGQXDD-UHFFFAOYSA-N 0.000 description 1
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 description 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical class CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229920002257 Plurafac® Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical class [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 240000001717 Vaccinium macrocarpon Species 0.000 description 1
- 235000012545 Vaccinium macrocarpon Nutrition 0.000 description 1
- 235000002118 Vaccinium oxycoccus Nutrition 0.000 description 1
- XEKWJQURPPJYTC-UHFFFAOYSA-N [Cl-].CC(CCCCCCCCCCC[NH+](CCCCCCCCCCCC)CC)C Chemical compound [Cl-].CC(CCCCCCCCCCC[NH+](CCCCCCCCCCCC)CC)C XEKWJQURPPJYTC-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 235000004634 cranberry Nutrition 0.000 description 1
- VQZHOOBGYXKMLU-UHFFFAOYSA-N decyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 VQZHOOBGYXKMLU-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- GFLLOMRSVVPUNQ-UHFFFAOYSA-M dimethyl-propyl-tetradecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CCC GFLLOMRSVVPUNQ-UHFFFAOYSA-M 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004453 electron probe microanalysis Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- UFZOPKFMKMAWLU-UHFFFAOYSA-N ethoxy(methyl)phosphinic acid Chemical compound CCOP(C)(O)=O UFZOPKFMKMAWLU-UHFFFAOYSA-N 0.000 description 1
- XDRMBCMMABGNMM-UHFFFAOYSA-N ethyl benzenesulfonate Chemical compound CCOS(=O)(=O)C1=CC=CC=C1 XDRMBCMMABGNMM-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000005194 ethylbenzenes Chemical class 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 239000008396 flotation agent Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000003084 food emulsifier Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 235000015201 grapefruit juice Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- IRHTZOCLLONTOC-UHFFFAOYSA-N hexacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCO IRHTZOCLLONTOC-UHFFFAOYSA-N 0.000 description 1
- SSILHZFTFWOUJR-UHFFFAOYSA-N hexadecane-1-sulfonic acid Chemical compound CCCCCCCCCCCCCCCCS(O)(=O)=O SSILHZFTFWOUJR-UHFFFAOYSA-N 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- RVVIPWANIHIUDD-UHFFFAOYSA-M icosyl-dimethyl-octadecylazanium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC RVVIPWANIHIUDD-UHFFFAOYSA-M 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 238000010412 laundry washing Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 235000013310 margarine Nutrition 0.000 description 1
- 239000003264 margarine Substances 0.000 description 1
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- TWBKZBJAVASNII-UHFFFAOYSA-N pentadecane-1-sulfonic acid Chemical compound CCCCCCCCCCCCCCCS(O)(=O)=O TWBKZBJAVASNII-UHFFFAOYSA-N 0.000 description 1
- CAOVKIWLIMUXEU-UHFFFAOYSA-N pentadecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 CAOVKIWLIMUXEU-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- HSJXWMZKBLUOLQ-UHFFFAOYSA-M potassium;2-dodecylbenzenesulfonate Chemical compound [K+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HSJXWMZKBLUOLQ-UHFFFAOYSA-M 0.000 description 1
- BGHJOVPDUCMEAT-UHFFFAOYSA-M potassium;phenylmethanesulfonate Chemical class [K+].[O-]S(=O)(=O)CC1=CC=CC=C1 BGHJOVPDUCMEAT-UHFFFAOYSA-M 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- ZIGVUIYVPLQEAL-UHFFFAOYSA-M sodium;2-tetradecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O ZIGVUIYVPLQEAL-UHFFFAOYSA-M 0.000 description 1
- XZTJQQLJJCXOLP-UHFFFAOYSA-M sodium;decyl sulfate Chemical compound [Na+].CCCCCCCCCCOS([O-])(=O)=O XZTJQQLJJCXOLP-UHFFFAOYSA-M 0.000 description 1
- HHURSJAUVYNJBT-UHFFFAOYSA-M sodium;heptadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCCOS([O-])(=O)=O HHURSJAUVYNJBT-UHFFFAOYSA-M 0.000 description 1
- GGHPAKFFUZUEKL-UHFFFAOYSA-M sodium;hexadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCOS([O-])(=O)=O GGHPAKFFUZUEKL-UHFFFAOYSA-M 0.000 description 1
- NWZBFJYXRGSRGD-UHFFFAOYSA-M sodium;octadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCOS([O-])(=O)=O NWZBFJYXRGSRGD-UHFFFAOYSA-M 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- MYOWBHNETUSQPA-UHFFFAOYSA-N tetradecane-1-sulfonic acid Chemical compound CCCCCCCCCCCCCCS(O)(=O)=O MYOWBHNETUSQPA-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- GTSMGKYOGFOSAR-UHFFFAOYSA-N tridecane-1-sulfonic acid Chemical compound CCCCCCCCCCCCCS(O)(=O)=O GTSMGKYOGFOSAR-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000005199 trimethylbenzenes Chemical class 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
Description
Foreliggende oppfinnelse vedrører nye flytende vaskemiddelblandinger hvor den tilstedeværende mengde av alkylglykosid virker til å forbedre vaskestyrken og mykningsegenskapene og er tilstrekkelig til å oppveie reduksjonen i vaskestyrke på grunn av den tilstedeværende mengde av kvaternær ammoniumforbindelse, samt anvendelse av en slik flytende vaskemiddelblanding for samtidig rengjøring og mykning av stoffer. The present invention relates to new liquid detergent mixtures where the amount of alkyl glycoside present acts to improve washing strength and softening properties and is sufficient to offset the reduction in washing strength due to the amount of quaternary ammonium compound present, as well as the use of such a liquid detergent mixture for simultaneous cleaning and softening of substances.
Anvendelsen av forskjellige og uensartede kjemiske stoffer og særlig kationiske kvaternære ammoniumforbindelser som myknere for tekstilprodukter er svært godt kjent innen teknikken. Det er også godt kjent å anvende slike stoffer på grunn av mykningsvirkningene under tøyvaskingen og særlig i skylleperioden av vaskeprosessen. Denne sistnevnte teknikk er blitt nødvendiggjort på grunn av det faktum at de tidligere nevnte, hittil anvendte kvaternære forbindelser som hoved-sakelig er kationiske av natur, ikke er forenlige med de anioniske vaskemidler, en av hovedvaskemiddeltypene som brukes i vaskeperioden. Videre er kationiske kvaternære forbindelser forholdsvis ineffektive i nærvær av ikke-ioniske vaskemidler. The use of different and disparate chemical substances and in particular cationic quaternary ammonium compounds as plasticizers for textile products is very well known in the art. It is also well known to use such substances because of the softening effects during the laundry and especially during the rinsing period of the washing process. This latter technique has been necessitated by the fact that the previously mentioned, hitherto used quaternary compounds which are mainly cationic in nature, are not compatible with the anionic detergents, one of the main types of detergents used in the washing period. Furthermore, cationic quaternary compounds are relatively ineffective in the presence of non-ionic detergents.
Det er også velkjent at det er en tilbøyelighet for vaskede tøyartikler å gulne eller misfarges når de behandles med de tidligere nevnte kvaternære forbindelser. It is also well known that there is a tendency for washed articles of clothing to yellow or discolor when treated with the aforementioned quaternary compounds.
En annen ulempe forbundet med bruken av de kationiske midler i vaskingen av stoffer, er innvirkningen på avsetning på stoffer av optisk hvitemiddel, og derved reduksjon av optisk hvithetsvirkning av en vaskemiddelblanding som inneholder det optiske hvitemiddel. Another disadvantage associated with the use of the cationic agents in the washing of fabrics is the effect on the deposition of optical whitening agent on fabrics, thereby reducing the optical whitening effect of a detergent mixture containing the optical whitening agent.
Nok en annen ulempe ved de antistatiske mykningsmidler av kationisk kvaternær ammoniumtype, er innvirkningen på ren-gjøringsegenskapene til vaskemidlet ved at smussfjerningen Yet another disadvantage of the antistatic softeners of the cationic quaternary ammonium type is the effect on the cleaning properties of the detergent in that the soil removal
som bevirkes av vaskemidlet reduseres, noe som resulterer i nedsatt vaskeeffektivitet. Tilstedeværelsen av det anioniske vaskemiddelstoff opphever i stor grad de stoffmyknende egenskaper til de kationiske kvaternære ammoniumforbindelser. caused by the detergent is reduced, resulting in reduced washing efficiency. The presence of the anionic detergent substance largely negates the fabric softening properties of the cationic quaternary ammonium compounds.
Følgelig har de tidligere nevnte kvaternære midler blitt kombinert med flere forbindelser utformet for å motvirke de ugunstige egenskaper med hensyn til vaskevirkning, eller de kvaternære mykningsmidler er blitt erstattet av andre mykningsmidler for å forbedre rengjøringsstyrken. Accordingly, the previously mentioned quaternary agents have been combined with several compounds designed to counteract the unfavorable properties with respect to detergency, or the quaternary softeners have been replaced by other softeners to improve cleaning power.
Høyerealkylmono- og -polyglykosider som kan brukes som vaskemidler, tekstilmyknene, overflateaktive midler, gel-danningsmidler, matvareemulgatorer og smøremidler, og fremgangsmåter for fremstilling av disse er blitt beskrevet i US patentskrifter nr. 3 598 865, 3 707 535, 3 839 318, 3 772 269 og 3 219 656. Higher alkyl mono- and -polyglycosides which can be used as detergents, fabric softeners, surfactants, gel-forming agents, food emulsifiers and lubricants, and methods for the production of these have been described in US Patents Nos. 3,598,865, 3,707,535, 3,839,318, 3,772,269 and 3,219,656.
Høyerealkylpolyglykosider er blitt brukt som ikke-ioniske overflateaktive midler i en rekke vaskemiddelblandinger sammen med anioniske overflateaktive midler, slik som vist US patentskrift nr. 3 721 633, europeiske patentskrifter nr. 70.074, 70.075, 70.076 og 92.877, og sammen med et anionisk og et annet ikke-ionisk overflateaktivt middel slik som vist i US patentskrifter nr. 4 483 779, 4 483 780 og 4 483 787, Higher alkyl polyglycosides have been used as nonionic surfactants in a variety of detergent compositions together with anionic surfactants, as shown in US Patent No. 3,721,633, European Patent Nos. 70,074, 70,075, 70,076 and 92,877, and together with an anionic and a other nonionic surfactant as shown in US Patent Nos. 4,483,779, 4,483,780 and 4,483,787,
og i europeiske patentskrifter nr. 75.994, 75.995, 75.996 og 105.556, hvordet det fåes god vaskeeffekt. and in European patent documents no. 75,994, 75,995, 75,996 and 105,556, whereby a good washing effect is obtained.
I den tidligere kjente teknikk er det også beskrevet vaskemiddelblandinger som inneholder et alkylpolyglykosid, In the prior art, detergent mixtures containing an alkyl polyglycoside are also described,
et konvensjonelt ikke-ionisk overflateaktivt middel og en kationisk tøymyknende forbindelse, hvorved det fåes både myknende og vaskeaktive egenskaper under tøyvasking, slik som vist i US patentskrift nr. 4 493 773 og europeiske patentskrifter nr. 94.118 og 106.692. Ifølge disse patentskriftene utelates imidlertid uttrykkelig anioniske overflateaktive midler ettersom disse er skadelige for blandingen. a conventional non-ionic surface-active agent and a cationic fabric softening compound, whereby both softening and detergent-active properties are obtained during laundry washing, as shown in US Patent No. 4,493,773 and European Patent Nos. 94,118 and 106,692. However, according to these patents, anionic surfactants are expressly omitted as these are harmful to the mixture.
US patentskrift nr. 4 014 808 beskriver en vandig vaskemiddelblanding for rengjøring av hårde overflater, slik som gulv, som inneholder alkaliske byggere, en blanding av høyere-alkylmono- og -polyglykosider, et ikke-ionisk ethoxylat eller hvilket som helst anionisk modifisert ethoxylat i syreform, US Patent No. 4,014,808 discloses an aqueous detergent composition for cleaning hard surfaces, such as floors, containing alkaline builders, a mixture of higher alkyl mono- and polyglycosides, a nonionic ethoxylate or any anionic modified ethoxylate in acid form,
og et kationisk flokkuleringsmiddel, slik sqm polydiallyldi-methylammoniumklorid, som får tilgrising til å agglomerere i små partikler som flyter opp, og eventuelt et flotasjons-middel som er natriumalkylarylsulfonat. and a cationic flocculating agent, such as sqm polydiallyldimethylammonium chloride, which causes fouling to agglomerate into small particles which float up, and optionally a flotation agent which is sodium alkylaryl sulphonate.
Det beskrives imidlertid ikke i noen av de nevnte litteratursteder en flytende myknings- og vaskemiddelblanding for samtidig rengjøring og mykning av stoffer som inneholder fire vesentlige bestanddeler, en virksom mengde av et alkylglykosid for å forbedre vaskestyrken og mykningsegenskapene i nærvær av en myknende kvaternær ammoniumforbindelse og anioniske og ikke-ioniske overflateaktive midler. However, none of the aforementioned literature sources describe a liquid softener and detergent mixture for simultaneous cleaning and softening of fabrics containing four essential components, an effective amount of an alkyl glycoside to improve wash strength and softening properties in the presence of a softening quaternary ammonium compound and anionic and nonionic surfactants.
Det er nå blitt oppdaget at tilsetningen av et overflateaktivt alkylpolyglykosid til en flytende myknings- og vaskemiddelblanding som inneholder en myknende kationisk kvaternær forbindelse i en blanding av ikke-ionisk og anionisk overflateaktivt middel forsterker vaskeeffekten og gir økte mykningsegenskaper til stoffer behandlet med denne. Følgelig er det et primært formål ved foreliggende oppfinnelse å tilveiebringe en flytende vaskemiddelblanding med forbedret ren-gjøringsstyrke i nærvær av myknende kationiske kvaternære ammoniumforbindelser. It has now been discovered that the addition of an alkylpolyglycoside surfactant to a liquid softener and detergent mixture containing a softening cationic quaternary compound in a mixture of nonionic and anionic surfactant enhances the washing effect and provides increased softening properties to fabrics treated with it. Accordingly, it is a primary object of the present invention to provide a liquid detergent composition with improved cleaning power in the presence of softening cationic quaternary ammonium compounds.
Et annet formål ved oppfinnelsen er å tilveiebringe Another object of the invention is to provide
en flytende vaskemiddelblanding som samtidig renser og mykner stoffer under vaskeprosessen, som inneholder et alkylglykosid, en myknende kvaternær ammoniumforbindelse, et ikke-ionisk overflateaktivt middel og et anionisk overflateaktivt middel som de fire vesentlige bestanddeler. a liquid detergent mixture that simultaneously cleans and softens fabrics during the washing process, containing an alkyl glycoside, a softening quaternary ammonium compound, a non-ionic surfactant and an anionic surfactant as the four essential ingredients.
Nok et annet formål ved oppfinnelsen er å tilveiebringe en flytende myknings- og vaskemiddelblanding med forbedrede rengjørings- og mykningsegenskaper på grunn av tilstedeværelsen av et alkylglykosid i en vaskemiddelblanding som inneholder en blanding av anioniske, ikke-ioniske og kationiske overflateaktive midler. Yet another object of the invention is to provide a liquid softener and detergent composition with improved cleaning and softening properties due to the presence of an alkyl glycoside in a detergent composition containing a mixture of anionic, nonionic and cationic surfactants.
Foreliggende oppfinnelse vedrører således en flytende vaskemiddelblanding hvor den tilstedeværende mengde av alkylglykosid virker til å forbedre vaskestyrken og mykningsegenskapene og er tilstrekkelig til å oppveie reduksjonen i vaskestyrke på grunn av den tilstedeværende mengde av kvaternær ammoniumforbindelse, som er kjennetegnet ved at den inneholder fire grunnbestanddeler: 1-30 vekt% av et alkylglykosid med én eller flere hydrofobe grupper som inneholder 1-30 carbonatomer pr. hydrofob gruppe, og en hydrofil glykosidgruppe som inneholder 1- 10 reduserende saccharidradikaler; 2- 8 vekt% av en myknende, kvaternær ammoniumforbindelse hvor minst én av de fire gruppene som er bundet til nitrogenatomet, er en C10~C20 <a>lkY19ruPPe'°9 minst to av gruppene er C.-C, alkylgrupper og den fjerde gruppe kan enten være en annen C10~C20 alkvl9ruPPe eller en C1~C3 alkylgruppe; The present invention thus relates to a liquid detergent mixture where the amount of alkyl glycoside present acts to improve the washing strength and the softening properties and is sufficient to offset the reduction in washing strength due to the amount of quaternary ammonium compound present, which is characterized by the fact that it contains four basic components: 1 -30% by weight of an alkyl glycoside with one or more hydrophobic groups containing 1-30 carbon atoms per hydrophobic group, and a hydrophilic glycoside group containing 1-10 reducing saccharide radicals; 2-8% by weight of a softening, quaternary ammonium compound where at least one of the four groups bound to the nitrogen atom is a C10~C20 <a>lkY19ruPPe'°9 at least two of the groups are C.-C, alkyl groups and the fourth group can be either another C10~C20 alkyl group or a C1~C3 alkyl group;
1-12 vekt% av et anionisk, overflateaktivt middel; og 8-25 vekt% av et ikke-ionisk, overflateaktivt middel valgt fra gruppen bestående av ethoxylater av primære, alifat- 1-12% by weight of an anionic surfactant; and 8-25% by weight of a nonionic surfactant selected from the group consisting of ethoxylates of primary, aliphatic
iske alkoholer, ethoxylater av sekundære, alifatiske alkoholer, ethoxylater av alkylfenoler, ethylenoxyd/propylenoxyd-kondensater av alkoholer og blandinger derav; isic alcohols, ethoxylates of secondary aliphatic alcohols, ethoxylates of alkylphenols, ethylene oxide/propylene oxide condensates of alcohols and mixtures thereof;
i en vandig bærer, eventuelt sammen med konvensjonelle tøy-vaskingsadditiver. Videre vedrører oppfinnelsen anvendelse av en slik vaskemiddelblanding for samtidig rengjøring og mykning av stoffer. in an aqueous carrier, optionally together with conventional laundry detergent additives. Furthermore, the invention relates to the use of such a detergent mixture for simultaneous cleaning and softening of substances.
Alkylglykosidene virker som et mykningsmiddel og forsterker stoffmykning i nærvær av kationiske overflateaktive midler.Det antas at alkylglykosidene tildekker overflaten av stoffet og/eller endrer stoffstrukturen, slik at det fåes mykningsfordeler. Det antas at alkylglykosidene kan bryte opp hydrogenbinding og derved øke mykningsegenskaper. Alkylglykosidene virker ikke inn på vaskeeffekten og/eller avsetningen av hvitemiddel, noe som er et annet problem ved myknings- og vaskemidler. The alkyl glycosides act as a softening agent and enhance fabric softening in the presence of cationic surfactants. It is assumed that the alkyl glycosides cover the surface of the fabric and/or change the fabric structure, so that softening benefits are obtained. It is believed that the alkyl glycosides can break up hydrogen bonding and thereby increase softening properties. The alkyl glycosides do not affect the washing effect and/or the deposition of bleach, which is another problem with fabric softeners and detergents.
Alkylglykosidene som benyttes i foreliggende nye vaskemiddelblanding, er definert ved at de har én eller flere hydrofobe grupper som inneholder 1-30 carbonatomer pr. hydrofob gruppe, og fortrinnsvis 8-15 carbonatomer, og en hydrofil glykosidgruppe som inneholder 1 - 10, og fortrinnsvis fra 1 til 3 reduserende saccharidradikaler. Alkylglykosidene kan re-presenteres ved hjelp av følgende formel: R0(R'0) Z , hvor The alkyl glycosides used in the present new detergent mixture are defined in that they have one or more hydrophobic groups containing 1-30 carbon atoms per hydrophobic group, and preferably 8-15 carbon atoms, and a hydrophilic glycoside group containing 1-10, and preferably from 1 to 3 reducing saccharide radicals. The alkyl glycosides can be represented by the following formula: R0(R'0) Z , where
x n x n
R er et C^-C^q alkylradikal, (R'0) er en ethoxy-, propoxy-eller glycerylgruppe, x har en tallverdi fra 0 til 10,.og fortrinnsvis 0, Z er et reduserende saccharid som inneholder 5 eller 6 carbonatomer, og n har en tallverdi på 1 - 10 og fortrinnsvis 1,0 - 3. Den hydrofobe alkylgruppe kan være mettet eller umettet, forgrenet eller rettkjedet, fortrinnsvis mettet og rettkjedet, og inneholde 1-30 carbonatomer, fortrinnsvis 8-23 carbonatomer. Egnede alkylpolyglykosider omfatter methyl, ethyl, propyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, hexadecyl, octadecylog bland-dinger derav, monoglykosider, diglykosider, triglykosider, tetraglykosider, pentaglykosider, hexaglykosider, etc. Glyko-sidenhetene kan være glukose, galaktose, mannose, laktose og/ eller fruktose. Fremgangsmåter for fremstilling av de nevnte glykosider er beskrevet i US patentskrifter nr. 3 598 865, 3 707 535, 3 839 318, 3 772 269 og 3 219 656. Tilsetningen av alkylglykosidet til myknings- og vaskemidler forbedrer ren-gjøringsstyrken. Glykosidmengden bør være tilstrekkelig til å. motvirke tapet i vaskeeffekt på grunn av tilstedeværelsen av de kationiske kvaternære ammonium-mykningsmidler i myknings- og vaskemidlet. Følgelig forbedrer glykosidinnholdet vaskeeffekten i myknings- og vaskemiddelblandingen og utgjør 1 til 30 vekt%, og fortrinnsvis 2 til 25 vekt%, av blandingen. R is a C^-C^q alkyl radical, (R'O) is an ethoxy, propoxy or glyceryl group, x has a numerical value from 0 to 10, and preferably 0, Z is a reducing saccharide containing 5 or 6 carbon atoms, and n has a numerical value of 1 - 10 and preferably 1.0 - 3. The hydrophobic alkyl group can be saturated or unsaturated, branched or straight-chain, preferably saturated and straight-chain, and contain 1-30 carbon atoms, preferably 8-23 carbon atoms. Suitable alkyl polyglycosides include methyl, ethyl, propyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, hexadecyl, octadecylog mixtures thereof, monoglycosides, diglycosides, triglycosides, tetraglycosides, pentaglycosides, hexaglycosides, etc. The glycoside units can be glucose, galactose, mannose, lactose and/or fructose. Methods for producing the aforementioned glycosides are described in US Patent Nos. 3,598,865, 3,707,535, 3,839,318, 3,772,269 and 3,219,656. The addition of the alkyl glycoside to softeners and detergents improves cleaning power. The amount of glycoside should be sufficient to counteract the loss in washing effect due to the presence of the cationic quaternary ammonium softeners in the softener and detergent. Accordingly, the glycoside content improves the washing effect of the softener and detergent mixture and constitutes 1 to 30% by weight, and preferably 2 to 25% by weight, of the mixture.
De myknende, kvaternære ammoniumforbindelser er kommersielt velkjente og omfatter kvaternære ammoniumforbindelser hvor minst én av de fire gruppene bundet til nitrogenatomet er en alkylgruppe med 10-20 carbonatomer, og minst to av gruppene bundet til nitrogenatomet er alkylgrupper som inneholder 1-3 carbonatomer, og den fjerde- gruppe kan være enten en annen cio~C20 alkylgruppe eller en C-^- C^ alkylgruppe, og hvor det er tilstede et anion, slik som halogen, acetat, methosulfat, etc. Typiske kvaternære ammoniumforbindelser er ethyl-dimethyl-distearyl-ammoniumklorid, trimethyl-stearyl-ammoniumklorid, trimethylcetyl-ammoniumbromid, dimethyl-ethyl-dilauryl-ammoniumklorid, dimethyl-propyl-myristyl-ammoniumklorid, talg-trimethyl-ammoniumklorid, (dihydrogenert talg)-dimethy1-ammoniumklorid, dikokos-dimethyl-ammoniumklorid, di-steary1-dimethy1-ammoniumklorid, disteary1-dimethy1-ammoniumklorid, octadecyl-trimethy1-ammoniumklorid, dodecyl-trimethyl-eller -triethylammoniumklorid, og de tilsvarende methosul-fater og acetater. The softening quaternary ammonium compounds are commercially well known and include quaternary ammonium compounds where at least one of the four groups attached to the nitrogen atom is an alkyl group of 10-20 carbon atoms, and at least two of the groups attached to the nitrogen atom are alkyl groups containing 1-3 carbon atoms, and the quaternary group can be either another cio~C20 alkyl group or a C-^-C^ alkyl group, and where an anion is present, such as halogen, acetate, methosulfate, etc. Typical quaternary ammonium compounds are ethyl-dimethyl-distearyl- ammonium chloride, trimethyl-stearyl-ammonium chloride, trimethylcetyl-ammonium bromide, dimethyl-ethyl-dilauryl-ammonium chloride, dimethyl-propyl-myristyl-ammonium chloride, tallow-trimethyl-ammonium chloride, (dihydrogenated tallow)-dimethyl-1-ammonium chloride, dicocos-dimethyl-ammonium chloride, di -steary1-dimethy1-ammonium chloride, disteary1-dimethy1-ammonium chloride, octadecyl-trimethy1-ammonium chloride, dodecyl-trimethyl-or -triethylammonium chloride, and the equivalent the methosulphates and acetates.
Andre egnede kvaternære forbindelser omfatter "duo-quats", polyethoxylerte "quats" og amidoalkoxylerte "quats". Other suitable quaternary compounds include "duo-quats", polyethoxylated "quats" and amido-alkylated "quats".
Mengden av de kvaternære ammoniumforbindelsene som benyttes i foreliggende vaskemiddelblanding, er 2 - 8 vekt% The amount of the quaternary ammonium compounds used in the present detergent mixture is 2 - 8% by weight
av vaskemiddelblandingen. of the detergent mixture.
I overensstemmelse med oppfinnelsen er de ikke-ioniske overf lateaktive midler for bruk i vaskemiddelblandingen kommersielt velkjente og omfatter ethoxylatene av primære alifatiske alkoholer, ethoxylatene av sekundære alifatiske alkoholer, ethoxylatene av alkylfenol og ethylenoxyd/propylenoxyd-kon-densatene av alkoholer, slik som Plurafac<®>, og blandinger derav. De ikke-ioniske syntetiske organiske vaskemidler er vanligvis kondensasjonsproduktet av en organisk alifatisk eller alkylaromatisk hydrofob forbindelse og hydrofile ethylenoxydgrupper. Praktisk talt hvilken som helst hydrofob forbindelse som har en carboxyl-, hydroxyl-, amid- eller amin-gruppe med fritt hydrogenatom bundet til nitrogenatornet, kan kondenseres med ethylenoxyd eller med polyhydratiseringspro-duktet derav, polyethylenglycol, hvorved det fåes et ikke-ionisk overflateaktivt middel. Videre kan lengden av poly-ethenoxykjeden reguleres for å oppnå den ønskede likevekt mellom de hydrofobe og hydrofile elementer. In accordance with the invention, the nonionic surfactants for use in the detergent composition are commercially well known and include the ethoxylates of primary aliphatic alcohols, the ethoxylates of secondary aliphatic alcohols, the ethoxylates of alkylphenol and the ethylene oxide/propylene oxide condensates of alcohols, such as Plurafac< ®>, and mixtures thereof. The nonionic synthetic organic detergents are usually the condensation product of an organic aliphatic or alkylaromatic hydrophobic compound and hydrophilic ethylene oxide groups. Practically any hydrophobic compound that has a carboxyl, hydroxyl, amide or amine group with a free hydrogen atom attached to the nitrogen atom can be condensed with ethylene oxide or with its polyhydration product, polyethylene glycol, whereby a nonionic surfactant is obtained medium. Furthermore, the length of the poly-ethenoxy chain can be regulated to achieve the desired equilibrium between the hydrophobic and hydrophilic elements.
De ikke-ioniske vaskemidler omfatter polyethylenoxyd-kondensatet av 1 mol alkylfenol som inneholder fra 6 til 12 carbonatomer i en rettkjedet eller forgrenet konfigurasjon med 5-30 mol ethylenoxyd, f.eks. nonylfenol kondensert med 9 mol ethylenoxyd, dodecylfenol kondensert med 15 mol ethylenoxyd. Kondensasjonsprodukter av de tilsvarende alkylthio-fenoler med 5 - 30 mol ethylenoxyd er også egnet. The nonionic detergents comprise the polyethylene oxide condensate of 1 mole of alkylphenol containing from 6 to 12 carbon atoms in a straight chain or branched configuration with 5-30 moles of ethylene oxide, e.g. nonylphenol condensed with 9 mol ethylene oxide, dodecylphenol condensed with 15 mol ethylene oxide. Condensation products of the corresponding alkylthiophenols with 5 - 30 mol of ethylene oxide are also suitable.
Også inkludert i den ikke-ioniske vaskemiddelklasse er kondensasjonsproduktene av en høyere alkohol (f.eks. en alkanol som inneholder 8-18 carbonatomer i en rettkjedet eller forgrenet konfigurasjon) kondensert med 5-30 mol ethylenoxyd, f.eks. lauryl-myristyl-alkohol kondensert med ca. 16 mol ethylenoxyd. Also included in the nonionic detergent class are the condensation products of a higher alcohol (eg, an alkanol containing 8-18 carbon atoms in a straight-chain or branched configuration) condensed with 5-30 moles of ethylene oxide, e.g. lauryl-myristyl alcohol condensed with approx. 16 moles of ethylene oxide.
En foretrukket gruppe ikke-ioniske overflateaktive midler er "Neodol"-ethoxylatene, som er høyere alifatiske alkoholethoxylater med 5-20 ethylenoxydgrupper pr. mol alifatisk alkohol som inneholder 10 - 18 carbonatomer, slik som C]_ 2~^ 13 alkan°l kondensert med 6,5 mol ethylenoxyd, Ci2-C15 alkan°l kondensert med 12 mol ethylenoxyd, A preferred group of nonionic surfactants are the "Neodol" ethoxylates, which are higher aliphatic alcohol ethoxylates with 5-20 ethylene oxide groups per moles of aliphatic alcohol containing 10 - 18 carbon atoms, such as C]_ 2~^ 13 alkane°l condensed with 6.5 moles of ethylene oxide, Ci2-C15 alkane°l condensed with 12 moles of ethylene oxide,
C^-C^t- alkanol kondensert med 13 mol ethylenoxyd og lignende. C^-C^t- alkanol condensed with 13 moles of ethylene oxide and the like.
- Ethoxamerer med en HLB (hydrofob/lipofil-likevekt)- verdi på - Ethoxamers with an HLB (hydrophobic/lipophilic balance) value of
8-15 gir god O/W-emulgering, mens ethoxamerer med lave HLB-verdier (under 8) inneholder mindre enn 5 ethylenoxygrupper og er dårlige emulgatorer og dårlige ikke-ioniske vaskemidler. Dette ikke-ioniske overflateaktive middel er til stede i myknings- og vaskemiddelblandingen i en mengde som er lik med 8-15 give good O/W emulsification, while ethoxamers with low HLB values (below 8) contain less than 5 ethyleneoxy groups and are poor emulsifiers and poor nonionic detergents. This nonionic surfactant is present in the fabric softener and detergent mixture in an amount equal to
eller større enn alkylpolyglykosidinnholdet, og utgjør 8-25 vekt%. Den totale mengde ikke-ionisk overflateaktivt middel, nemlig glykosidet, som også er et ikke-ionisk overflateaktivt middel, og de ikke-ioniske alkoholethoxylater som er definert ovenfor, utgjør hovedvaskemiddelbestanddelen i vaskemiddelblandingen, 25 - 40 vekt% og fortrinnsvis 30 - 40 vekt% av blandingen. or greater than the alkyl polyglycoside content, and amounts to 8-25% by weight. The total amount of nonionic surfactant, namely the glycoside, which is also a nonionic surfactant, and the nonionic alcohol ethoxylates defined above constitute the main detergent component of the detergent composition, 25-40% by weight and preferably 30-40% by weight of the mixture.
De anioniske overflateaktive midler som benyttes i vaskemiddelblandingen ifølge oppfinnelsen, er kommersielt velkjente og omfatter alkylbenzensulfonsyre og salter derav, f.eks. forbindelser med formelen alkyl-fenyl-SO^-M, hvor alkyl er et alkylradikal med cq~ C22' °^ fortrinnsvis C]lø~C18' °<9>The anionic surfactants used in the detergent mixture according to the invention are commercially well known and include alkylbenzenesulfonic acid and salts thereof, e.g. compounds with the formula alkyl-phenyl-SO^-M, where alkyl is an alkyl radical with cq~ C22' °^ preferably C]lø~C18' °<9>
M er hydrogen eller et alkalimetall, forbindelser som utgjør en velkjent klasse anioniske vaskemidler og omfatter natrium-dodecylbenzensulfonat, kaliumdodecylbenzensulfonat, natrium-laurylbenzensulfonat, natriumcetylbenzensulfonat. Andre omfatter alkansulfonater, alkylsulfater, alkoholethersulfater, olefinsulfonater og alkylfenolethoxylatsulfåtene (f.eks. natriumdinonylfenoxynonaethoxyethanolsulfat), og andre ekviva-lente vannoppløselige salter, særlig av alkalimetallserien. M is hydrogen or an alkali metal, compounds which constitute a well-known class of anionic detergents and include sodium dodecylbenzenesulfonate, potassium dodecylbenzenesulfonate, sodium laurylbenzenesulfonate, sodium cetylbenzenesulfonate. Others include alkane sulfonates, alkyl sulfates, alcohol ether sulfates, olefin sulfonates and the alkylphenol ethoxylate sulfates (eg sodium dinonylphenoxynonaethoxyethanol sulfate), and other equivalent water-soluble salts, especially of the alkali metal series.
Blant de ovenfor angitte alkylbenzensulfonsyrer og salter derav, omfatter foretrukne forbindelser de som er bio-logisk nedbrytbare og som spesielt er kjennetegnet ved en rettkjedet alkylsubstituent med ciø~C22°9 fortrinnsvis fra C12~ C15' Det skal selvfølgelig forståes at carbonkjedelengden generelt utgjør en gjennomsnittskjedelengde ettersom det ved fremgangsmåten for fremstilling av slike produkter vanligvis anvendes alkyleringsreagenser med blandet kjedelengde. Det er imidlertid klart at praktisk talt rene olefiner samt alkyleringsforbindelser som brukes i andre teknikker, kan gi og gir alkylerte benzensulfonater hvor alkylresten i det vesentlige (dvs. minst 99%) er av én kjedelengde, dvs. Among the above-mentioned alkylbenzenesulfonic acids and salts thereof, preferred compounds include those which are biologically degradable and which are particularly characterized by a straight-chain alkyl substituent with C1~C22°9 preferably from C12~C15' It should of course be understood that the carbon chain length generally constitutes an average chain length since alkylating reagents with mixed chain length are usually used in the process for the production of such products. However, it is clear that practically pure olefins as well as alkylating compounds used in other techniques can and do give alkylated benzene sulphonates where the alkyl residue is essentially (i.e. at least 99%) of one chain length, i.e.
C12' C13' C14 eller C15* De rettkjedede alkylbenzensulfonater er videre kjennetegnet ved benzenringens stilling i det rettkjedede alkylradikal, idet hvilke som helst av stillingsiso-merene (dvs. a tilu3) kan brukes og er ment å skulle være om-fattet. C12' C13' C14 or C15* The straight-chain alkylbenzenesulfonates are further characterized by the position of the benzene ring in the straight-chain alkyl radical, any of the positional isomers (ie a tilu3) can be used and are meant to be included.
I tillegg til benzensulfonatene kan man også anvende In addition to the benzene sulphonates, one can also use them
de laverealkyl(C^-C^)analoger av benzen, slik som toluen, xylen, trimethylbenzenene, ethylbenzenene, isopropylbenzen og lignende. Sulfonatene anvendes generelt i den vannoppløselige saltform som omfatter som kation, alkalimetallene, ammonium og lavere amin, og alkanolaminkationer. the lower alkyl (C₁-C₂) analogues of benzene, such as toluene, xylene, the trimethylbenzenes, the ethylbenzenes, isopropylbenzene and the like. The sulphonates are generally used in the water-soluble salt form which includes, as cation, the alkali metals, ammonium and lower amine, and alkanolamine cations.
Eksempler på egnede rettkjedede alkylbenzensulfonater omfatter: natrium-n-decylbenzensulfonat Examples of suitable straight chain alkylbenzenesulfonates include: sodium n-decylbenzenesulfonate
natrium-n-dodecylbenzensulfonat sodium n-dodecylbenzenesulfonate
natrium-n-tetradecylbenzensulfonat sodium n-tetradecylbenzenesulfonate
natrium-n-pentadecylbenzensulfonat sodium n-pentadecylbenzenesulfonate
natrium-n-hexadecylbenzensulfonat sodium n-hexadecylbenzenesulfonate
og de tilsvarende laverealkylsubstituerte homologer av benzen, samt saltene av kationene som det tidligere er henvist til. Blandinger av disse sulfonater kan selvfølgelig også brukes sammen med blandinger som kan omfatte forbindelser hvor den rettkjedede alkylrest er mindre eller større enn det som her er angitt, forutsatt den gjennomsnittlige kjedelengde i blandingen samsvarer med de bestemte krav på c^q-C22*and the corresponding lower alkyl substituted homologues of benzene, as well as the salts of the cations previously referred to. Mixtures of these sulfonates can of course also be used together with mixtures that may include compounds where the straight-chain alkyl residue is smaller or larger than what is stated here, provided that the average chain length in the mixture corresponds to the specific requirements for c^q-C22*
De rettkjedede alkansulfonater er også velkjente The straight chain alkanesulfonates are also well known
grupper forbindelser og omfatter vannoppløselige salter (alkalimetall, amin, alkanolamin og ammonium) av: groups of compounds and includes water-soluble salts (alkali metal, amine, alkanolamine and ammonium) of:
1-decansulfonsyre 1-decanesulfonic acid
1-dodecansulfonsyre 1-dodecanesulfonic acid
1-tridecansulfonsyre 1-tridecanesulfonic acid
1-tetradecansulfonsyre 1-tetradecanesulfonic acid
1-pentadecansulfonsyre 1-pentadecanesulfonic acid
1-hexadecansulfonsyre 1-hexadecanesulfonic acid
samt andre stillingsisomerer av sulfonsyregruppen. as well as other positional isomers of the sulfonic acid group.
I tillegg til alkansulfonatene som er illustrert ovenfor, kan det brukes andre med det generelle område C]_q-<~22 a^-ky-'--rester, idet det mest foretrukne område er fra C,- til C20*In addition to the alkanesulphonates illustrated above, others with the general range of C]_q-<~22 a^-ky-'- residues may be used, the most preferred range being from C1- to C20*
De rettkjedede alkylsulfater som det er tenkt på ved foreliggende oppfinnelse, omfatter området ciø~C20* Bestemte eksempler omfatter natrium-n-decylsulfat, natrium-n-dodecyl-sulfat, natrium-n-hexadecylsulfat, natrium-n-heptadecylsulfat, natrium-n-octadecylsulfat og de ethoxylerte (1 - 100 mol ethylenoxyd) derivater, slik som de ethoxylerte alkoholsulfater, og selvfølgelig de øvrige vannoppløselige saltdannende kationer som er nevnt ovenfor. The straight-chain alkyl sulfates that are contemplated by the present invention comprise the range ciø~C20* Certain examples include sodium-n-decyl sulfate, sodium-n-dodecyl sulfate, sodium-n-hexadecyl sulfate, sodium-n-heptadecyl sulfate, sodium-n -octadecyl sulfate and the ethoxylated (1 - 100 mol ethylene oxide) derivatives, such as the ethoxylated alcohol sulfates, and of course the other water-soluble salt-forming cations mentioned above.
Inkludert i gruppen av anioniske vaskemidler som er blitt beskrevet ovenfor som egnet i foreliggende oppfinnelse, er olefinsulfåtene, inkludert langkjedede alkensulfonater, langkjedede hydroxyalkansulfonater, samt disulfonater. Eksempler på egnede olefinsulfonater som kun er illustrerende for den generelle klasse, er natrium-dodecenyl-l-sulfonat, natrium-tetradecenyl-l-sulfonanat, natrium-hexadecenyl-l-sulfonat, Included in the group of anionic detergents that have been described above as suitable in the present invention are the olefin sulfates, including long-chain alkenesulfonates, long-chain hydroxyalkanesulfonates, as well as disulfonates. Examples of suitable olefin sulfonates which are only illustrative of the general class are sodium dodecenyl-l-sulfonate, sodium tetradecenyl-l-sulfonate, sodium hexadecenyl-l-sulfonate,
og natrium-octadecenyl-l-sulfonat. Mengden av anionisk overflateaktivt middel som benyttes i foreliggende blanding, er mindre enn vektinnholdet av ikke-ionisk (ethoxylert alifatisk alkohol) overflateaktivt middel, og fortrinnsvis mindre enn 50 vekt% av den totale mengde .. ikke-ionisk overf lateaktivt middel (alkylglykosid pluss ethoxylert alifatisk alkohol) og utgjør 1-12 vekt% av blandingen. and sodium octadecenyl-1-sulfonate. The amount of anionic surfactant used in the present mixture is less than the weight content of nonionic (ethoxylated aliphatic alcohol) surfactant, and preferably less than 50% by weight of the total amount of .. nonionic surfactant (alkylglycoside plus ethoxylated aliphatic alcohol) and make up 1-12% by weight of the mixture.
Den flytende vaskemiddelblanding ifølge foreliggende oppfinnelse kan også omfatte konvensjonelle tøyvaskingsaddi-tiver, slik som optiske hvitemidler, germicider, smussopp-slemmende midler, anti-redeponeringsmidler, antioxydanter, fargegivende stoffer (fargestoffer og pigmenter), parfyme og vannoppløselige alkoholer, skumforsterkere, hydrotrope forbindelser, slik som natrium- og kaliumxylensulfonater, natrium- og kaliumtoluensulfonater, cumensulfonater, ethyl-benzensulfonat og lignende. Enzymer og enzymstabilisatorer, forutsatt at de ikke virker inn på blandingens vaskeeffekt og mykningsaktivitet. The liquid detergent mixture according to the present invention can also include conventional laundry additives, such as optical brighteners, germicides, dirt-repelling agents, anti-redeposition agents, antioxidants, coloring substances (dyes and pigments), perfume and water-soluble alcohols, foam enhancers, hydrotropic compounds, such as sodium and potassium xylene sulphonates, sodium and potassium toluene sulphonates, cumene sulphonates, ethyl benzene sulphonate and the like. Enzymes and enzyme stabilizers, provided they do not affect the washing effect and softening activity of the mixture.
Følgende eksempler illustrerer oppfinnelsen nærmere. The following examples illustrate the invention in more detail.
Eksempel 1 Example 1
Myknings- og vaskemiddel Softener and detergent
15% C]_2~ci5 alkohol: 7 mol ethylenoxyd 15% C]_2~ci5 alcohol: 7 moles of ethylene oxide
15% alkylpolyglykosid, ci2~13<:3> m°l glykosid 15% alkyl polyglycoside, ci2~13<:3> m°l glycoside
0,25% triethanolamin 0.25% triethanolamine
8,0% monoalkyltrimethylammoniumklorid 8.0% monoalkyltrimethylammonium chloride
12% Cj2-15 <a>lkohol:3 mol ethylenoxyd- 12% Cj2-15 <a>alcohol:3 mol ethyleneoxyd-
sulfat, natriumsalt sulfate, sodium salt
4,0% natrium-xylensulfonat 4.0% sodium xylene sulfonate
0,5% hvitemiddel 0.5% bleach
Q.S. vann Q.S. water
^ talg-trimethyl-ammoniumklorid. ^ tallow-trimethyl-ammonium chloride.
Det flytende vaskemiddel fremstilles ved å blande de ovenfor nevnte bestanddeler inntil homogenitet, hvorved det fåes en stabil flytende blanding. The liquid detergent is prepared by mixing the above-mentioned ingredients until homogeneity, whereby a stable liquid mixture is obtained.
Våskeeffekten til dette produktet ble testet i et tergo-tometer som inneholdt 1 liter vann med 150 ppm kalsium ved 49°C og 21°C og med en konsentrasjon på 0,18% myknings- og vaskemiddel, og det ble sammenlignet med kommersielle vaske-middelprodukter som ikke inneholder alkylglykosidbestanddelen. En stoffmengde med standard tilsmussede prøvestykker av "Test Fabric" nylon (TFN) og bomull (TFC), en 65/35% blanding av polyester/bomull (PC) og 50/50% dacron/bomull (DC) og EMPA The washing performance of this product was tested in a tergotometer containing 1 liter of water with 150 ppm calcium at 49°C and 21°C and with a concentration of 0.18% softener and detergent, and it was compared to commercial detergents. intermediate products that do not contain the alkylglycoside component. A fabric load of standard soiled samples of "Test Fabric" nylon (TFN) and cotton (TFC), a 65/35% blend of polyester/cotton (PC) and 50/50% dacron/cotton (DC) and EMPA
101 stoffprøve ble vasket med testvaskemidlene og tørket i elektriske tromme1tørkere. Reflektans for de tilsmussede prøvestykker ble avlest som et mål for vaskeeffekt (Rd). Smussfjerningen (SR) er summen av Rd-avlesningene på alle prøve-stykkene, og smussfjerningstallet (SRI) er gjennomsnittet av de samlede Rd-avlesninger dividert på antallet stoffprøver. 101 fabric samples were washed with the test detergents and dried in electric tumble dryers. Reflectance of the soiled test pieces was read as a measure of washing effect (Rd). The soil removal (SR) is the sum of the Rd readings on all the test pieces, and the soil removal number (SRI) is the average of the total Rd readings divided by the number of fabric samples.
Eksempel 1 viser utmerket vaskeeffekt for Dynamo<®>, Solo og Bold® 3.Ingen statistisk signifikant forskjell med hensyn til vaskeeffekt ble observert mellom eksempel 1 og Example 1 shows excellent washing effect for Dynamo<®>, Solo and Bold® 3. No statistically significant difference with regard to washing effect was observed between example 1 and
flytende Tide<®> ved 4 9°C og 21°C. liquid Tide<®> at 4 9°C and 21°C.
Fjerning av hudfettsmuss ved 49°C var lik med flytende Tide<®> på bomull og D/C 50/50, og bedre enn de fleste konkur-renter på D/C 50/50. Ved 21°C var flytende Tide<®> litt bedre, mens de fleste andre konkurrentene var like med produktet Removal of skin grease at 49°C was equal to liquid Tide<®> on cotton and D/C 50/50, and better than most competitors on D/C 50/50. At 21°C liquid Tide<®> was slightly better, while most other competitors were equal to the product
ifølge eksempel 1. according to example 1.
En flerflekktest ved 49°C og 20°C ga følgende resultater under anvendelse av flytende Tide<®> som kontroll. A multi-spot test at 49°C and 20°C gave the following results using liquid Tide<®> as a control.
Man fikk de største tap i vaskeeffekt sammenlignet med flytende Tide<®> i tilfellet med enzym ved 49°C. Dette var å forvente ettersom blandingen ifølge eksempel 1 ikke inneholder noen enzymer. Tap ble imidlertid også iakttatt med de oxyder-bare flekker (saft fra grapefrukt og saft fra tranebær). I eksempel 1 fikk man store gevinster for DDK i tilfellet med oljeholdig smuss (grillsaus og fransk dressing). The greatest losses in washing efficiency were obtained compared to liquid Tide<®> in the case of enzyme at 49°C. This was to be expected as the mixture according to example 1 does not contain any enzymes. However, loss was also observed with the oxidizable stains (grapefruit juice and cranberry juice). In example 1, large gains were made for DDK in the case of oily dirt (barbecue sauce and French dressing).
Ved 21°C var tap på grunn av enzymflekker betydelig re-dusert. Dette skyldes det faktum at enzymer generelt er mer effektive ved høyere temperaturer. Ved 21°C er produktet ifølge eksempel 1 et mye mer effektivt vaskemiddel enn flytende Tide<® >i tilfellet med oljeholdig smuss (Spangler hudfett/dråper, grillsaus, "Red Crisco" margarin og fransk dressing). At 21°C, losses due to enzyme spots were significantly reduced. This is due to the fact that enzymes are generally more effective at higher temperatures. At 21°C, the product according to example 1 is a much more effective detergent than liquid Tide<® >in the case of oily dirt (Spangler skin fat/drops, barbecue sauce, "Red Crisco" margarine and French dressing).
Bold<®> 3 og SOLO virket ikke bedre ved noen temperatur. Bold<®> 3 and SOLO did not perform better at any temperature.
Den fem perioders test av mykning/statisk elektrisitet/ hvitgjøring ga følgende resultater: The five period softening/static/whitening test gave the following results:
Fluorescens på bomullsprøvene ble avlest som et mål Fluorescence on the cotton samples was read as a measure
for effektivitet som hvitgjøringsmiddel (Rb). for effectiveness as a bleaching agent (Rb).
Blandingen ifølge eksempel 1 var lik med Bold<®> 3 når det gjelder å regulere statisk vedheng og bedre enn SOLO. Blandingen ifølge eksempel 1 ble bedømt til å være noe mindre effektiv med hensyn til mykning sammenlignet med SOLO, men oppviste forbedret mykning sammenlignet med blandingen ifølge eksempel 1 uten alkylglykosidet. The mixture according to example 1 was equal to Bold<®> 3 in controlling static cling and better than SOLO. The mixture of Example 1 was judged to be somewhat less effective in terms of softening compared to SOLO, but showed improved softening compared to the mixture of Example 1 without the alkyl glycoside.
Eksempel 2 Example 2
Myknings- og vaskemiddel Softener and detergent
21% "Neodol 25-7" 21% "Neodol 25-7"
6% natrium-dodecylbenzensulfonat 6% sodium dodecylbenzene sulfonate
4% talg-trimethyl-(kvaternært) ammoniumsulfat 2% methylglukosid 4% tallow-trimethyl-(quaternary) ammonium sulfate 2% methylglucoside
0,4% hvitemiddel 0.4% bleach
8% ethanol 8% ethanol
5% natrium-xylensulfonat 5% sodium xylene sulfonate
0,5% fargestoff 0.5% dye
Q.S. vann Q.S. water
^ C12~<C>15 <a>lkon°l:7 mol ethylenoxyd. ^ C12~<C>15 <a>lkon°l:7 mol ethylene oxide.
Eksempel 3 Example 3
Myknings- og vaskemiddel Softener and detergent
21% "Neodol 25-7" 21% "Neodol 25-7"
4% natrium-dodecylbenzensulfonat 4% sodium dodecylbenzenesulfonate
4% talg-trimethyl-ammoniumsulfat 4% tallow-trimethyl-ammonium sulfate
2% methylglykosid 2% methylglycoside
0,4% hvitemiddel 0.4% bleach
8% ethanol 8% ethanol
5% natrium-xylensulfonat 5% sodium xylene sulfonate
0,5% fargestoff 0.5% dye
Q.S. vann Q.S. water
Denne blanding ble testet i en fem perioders mykhets-test med 2,7 kg rent tøy under anvendelse av SOLO som kontroll med den høyeste mykhet (10). Mykhetsbedømmelsen av denne blanding som var 6,8 (gjennomsnittet av disse avlesningene etter 1., 3. og 5. periode), holder fint mål med SOLO. Myk-hetsbedømmelsen ligger innenfor et område på 1 (det hardeste) til 10 (det mykeste). Tilsetning av 3% av et talgamin:15 ethylenoxyd til denne blandingen reduserer mykhetsbedømmelsen til 6,0. Utelatelse av den kvaternære forbindelse og økning av methylglykosidinnholdet til 6%, øker mykhetsbedømmelsen til 7,2. This blend was tested in a five period softness test with 2.7 kg of clean laundry using SOLO as the highest softness control (10). The softness rating of this mixture which was 6.8 (the average of these readings after the 1st, 3rd and 5th periods) measures up nicely with the SOLO. The softness rating lies within a range of 1 (the hardest) to 10 (the softest). Adding 3% of a tallow:15 ethylene oxide to this mixture reduces the softness rating to 6.0. Omitting the quaternary compound and increasing the methylglycoside content to 6% increases the softness rating to 7.2.
Følgende tabell IV oppsummerer resultatene med hensyn til hvitgjøring og statisk elektrisitet ved den fem perioders test på fem testprodukter og to kontroller. The following Table IV summarizes the whitening and static results of the five period test on five test products and two controls.
Resultatene ovenfor indikerer at methylglykosid gir mykningsfordeler til stoff. Laboratorietestene indikerer også at glukosidet gir hvitgjøringsfordeler i flytende blandinger. I fravær av kvaternær forbindelse oppnåes det imidlertid ingen kontroll av statisk elektrisitet. The above results indicate that methylglycoside provides softening benefits to fabric. The laboratory tests also indicate that the glucoside provides whitening benefits in liquid mixtures. In the absence of a quaternary compound, however, no control of static electricity is achieved.
Myknings- og vaskemidlene som inneholder et alkylglykosid ble uventet funnet ikke bare å overvinne reduksjonen av vaskeeffekt på grunn av tilstedeværelsen av det kvaternære mykningsmiddel, men har også forbedret vaskeeffekten og mykningsegenskapene til myknings- og vaskemiddelblandingen. Dette er klart vist i tabell V ved produkt 4 som inneholder bare 2% methylglykosid, blandingen ifølge eksempel 3 oppviser en større grad av mykhet (6,8) enn produktene 1 (5,9), 2 (5,8) og 3 (6,0) som ikke inneholder noe alkylglykosid. Likeledes oppviser produkt 4 en større hvithetsgrad etter 1., 3. og 5. vaske-periode enn produktene 1, 2 og 3, samt økt SRI-verdi sammenlignet med produktene som ikke inneholder noe alkylglykosid. The fabric softeners and detergents containing an alkyl glycoside were unexpectedly found not only to overcome the reduction in washing performance due to the presence of the quaternary softener, but also to have improved the washing performance and softening properties of the fabric softener and detergent mixture. This is clearly shown in table V by product 4 which contains only 2% methylglycoside, the mixture according to example 3 exhibits a greater degree of softness (6.8) than products 1 (5.9), 2 (5.8) and 3 ( 6.0) which does not contain any alkyl glycoside. Likewise, product 4 shows a greater degree of whiteness after the 1st, 3rd and 5th washing period than products 1, 2 and 3, as well as an increased SRI value compared to the products that do not contain any alkyl glycoside.
Så små mengder som 2% alkylglykosid er effektive når det Amounts as small as 2% alkyl glycoside are effective when that
gjelder å forbedre både vaskeeffekten og mykningsegenskapene til en myknings- og vaskemiddelblanding anvendt ved vasking av stoffer. I tillegg oppviser foreliggende blandinger bedre rengjørings- og mykningsstyrke enn andre overflateaktive midler og/eller myknerblandinger som for tiden er på markedet, slik det er vist ved hjelp av sammenligningsresultatene i applies to improving both the washing effect and the softening properties of a softening and detergent mixture used when washing fabrics. In addition, the present compositions exhibit better cleaning and softening power than other surfactant and/or softener compositions currently on the market, as shown by the comparative results in
tabellene I, II, IV og V. tables I, II, IV and V.
Claims (11)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US82392686A | 1986-01-30 | 1986-01-30 |
Publications (4)
Publication Number | Publication Date |
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NO870367D0 NO870367D0 (en) | 1987-01-29 |
NO870367L NO870367L (en) | 1987-07-31 |
NO169661B true NO169661B (en) | 1992-04-13 |
NO169661C NO169661C (en) | 1992-07-22 |
Family
ID=25240144
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO870367A NO169661C (en) | 1986-01-30 | 1987-01-29 | Liquid detergent mixture for simultaneous cleaning and softening of fabrics |
Country Status (28)
Country | Link |
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JP (1) | JPH07113119B2 (en) |
KR (1) | KR950003426B1 (en) |
AR (1) | AR247588A1 (en) |
AT (1) | AT397809B (en) |
AU (1) | AU595851B2 (en) |
BE (1) | BE1002958A4 (en) |
BR (1) | BR8700392A (en) |
CH (1) | CH671963A5 (en) |
DE (1) | DE3702287A1 (en) |
DK (1) | DK167881B1 (en) |
EG (1) | EG18097A (en) |
ES (1) | ES2004081A6 (en) |
FR (1) | FR2593516B1 (en) |
GB (1) | GB2185992B (en) |
GR (1) | GR870125B (en) |
HK (1) | HK97693A (en) |
IL (1) | IL81353A (en) |
IN (1) | IN170107B (en) |
IT (1) | IT1205726B (en) |
MX (1) | MX168268B (en) |
NL (1) | NL8700231A (en) |
NO (1) | NO169661C (en) |
NZ (1) | NZ219051A (en) |
PH (1) | PH25243A (en) |
SE (1) | SE8700324L (en) |
TR (1) | TR24572A (en) |
ZA (1) | ZA87561B (en) |
ZW (1) | ZW1887A1 (en) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IL81354A (en) * | 1986-01-30 | 1990-11-05 | Colgate Palmolive Co | Liquid detergent having improved softening properties |
AU619502B2 (en) * | 1987-11-05 | 1992-01-30 | Colgate-Palmolive Company, The | Liquid softergent formulations having improved stability and softening properties |
US4844824A (en) * | 1988-02-08 | 1989-07-04 | The Procter & Gamble Company | Stable heavy duty liquid detergent compositions which contain a softener and antistatic agent |
US5230835A (en) * | 1988-08-04 | 1993-07-27 | Kao Corporation | Mild non-irritating alkyl glycoside based detergent compositions |
DE68925390T2 (en) * | 1988-08-04 | 1996-06-05 | Kao Corp | Detergent composition |
CA2007169A1 (en) * | 1989-01-19 | 1990-07-19 | Regis Lysy | Softergent with sugar ethers as detergency boosters |
FR2666346B1 (en) * | 1990-09-05 | 1992-11-20 | Oreal | COMPOSITION FOR WASHING AND / OR COSMETIC TREATMENT WITH RINSING OF KERATINIC FIBERS, QUICK DRYING, BASED ON CATIONIC FLUORINATED COMPOUNDS AND ALKYLPOLYGLYCOSIDES. |
EP0838518B1 (en) * | 1992-09-11 | 2002-11-13 | Cognis Deutschland GmbH & Co. KG | Detergent mixtures |
DE4338113A1 (en) * | 1993-11-08 | 1995-05-11 | Henkel Kgaa | Softening detergent with alkyl glycosides |
US5466394A (en) * | 1994-04-25 | 1995-11-14 | The Procter & Gamble Co. | Stable, aqueous laundry detergent composition having improved softening properties |
DE4440620A1 (en) * | 1994-11-14 | 1996-05-15 | Henkel Kgaa | Textile softeners |
AR003724A1 (en) * | 1995-09-29 | 1998-09-09 | Procter & Gamble | STRUCTURED LIQUID LAUNDRY DETERGENT COMPOSITION, FOR HARD WORK, COMPRISING ANIONIC AND CATIONIC SURFACTANTS. |
GB9606913D0 (en) | 1996-04-02 | 1996-06-05 | Unilever Plc | Surfactant blends processes for preparing them and particulate detergent compositions containing them |
DE19629666A1 (en) | 1996-07-23 | 1998-01-29 | Henkel Kgaa | Process for the hydrophilic finishing of fibers or nonwovens |
EP0849354A1 (en) | 1996-12-20 | 1998-06-24 | Unilever Plc | Softening compositions |
GB2340843A (en) * | 1998-08-25 | 2000-03-01 | Reckitt & Colman Inc | Liquid laundry detergent compositions |
US6384010B1 (en) | 2000-06-15 | 2002-05-07 | S.C. Johnson & Son, Inc. | All purpose cleaner with low organic solvent content |
GB0106466D0 (en) | 2001-03-15 | 2001-05-02 | Unilever Plc | Fabric softening compositions |
GB0114921D0 (en) * | 2001-06-19 | 2001-08-08 | Ciba Spec Chem Water Treat Ltd | Particles containing fabric conditioner |
WO2023170120A1 (en) * | 2022-03-10 | 2023-09-14 | Unilever Ip Holdings B.V. | Concentrated fabric conditioner |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS598392B2 (en) * | 1979-06-29 | 1984-02-24 | 花王株式会社 | cleaning composition |
JPS58132094A (en) * | 1981-09-28 | 1983-08-06 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Detergent composition |
GR76286B (en) * | 1981-09-28 | 1984-08-04 | Procter & Gamble | |
DE3365810D1 (en) * | 1982-05-10 | 1986-10-09 | Procter & Gamble | Low phosphate laundry detergent compositions |
JPS59145299A (en) * | 1982-10-18 | 1984-08-20 | ザ,プロクタ−,エンド,ギヤンブル,カンパニ− | Polyethylene glycol containing liquid detergent |
IL81354A (en) * | 1986-01-30 | 1990-11-05 | Colgate Palmolive Co | Liquid detergent having improved softening properties |
-
1987
- 1987-01-22 IL IL81353A patent/IL81353A/en unknown
- 1987-01-23 NZ NZ219051A patent/NZ219051A/en unknown
- 1987-01-26 ZA ZA87561A patent/ZA87561B/en unknown
- 1987-01-27 PH PH34768A patent/PH25243A/en unknown
- 1987-01-27 GR GR870125A patent/GR870125B/en unknown
- 1987-01-27 IN IN53/DEL/87A patent/IN170107B/en unknown
- 1987-01-27 DE DE19873702287 patent/DE3702287A1/en not_active Withdrawn
- 1987-01-27 ZW ZW18/87A patent/ZW1887A1/en unknown
- 1987-01-28 SE SE8700324A patent/SE8700324L/en not_active Application Discontinuation
- 1987-01-28 IT IT47579/87A patent/IT1205726B/en active
- 1987-01-28 GB GB8701854A patent/GB2185992B/en not_active Expired - Lifetime
- 1987-01-28 EG EG52/87A patent/EG18097A/en active
- 1987-01-28 AU AU68053/87A patent/AU595851B2/en not_active Ceased
- 1987-01-29 NO NO870367A patent/NO169661C/en unknown
- 1987-01-29 FR FR878701079A patent/FR2593516B1/en not_active Expired - Lifetime
- 1987-01-29 AT AT0017687A patent/AT397809B/en not_active IP Right Cessation
- 1987-01-29 ES ES878700215A patent/ES2004081A6/en not_active Expired
- 1987-01-29 BR BR8700392A patent/BR8700392A/en active Search and Examination
- 1987-01-30 JP JP62020366A patent/JPH07113119B2/en not_active Expired - Lifetime
- 1987-01-30 DK DK051387A patent/DK167881B1/en active
- 1987-01-30 CH CH342/87A patent/CH671963A5/de not_active IP Right Cessation
- 1987-01-30 KR KR1019870000745A patent/KR950003426B1/en active IP Right Grant
- 1987-01-30 MX MX005112A patent/MX168268B/en unknown
- 1987-01-30 AR AR87306640A patent/AR247588A1/en active
- 1987-01-30 BE BE8700064A patent/BE1002958A4/en not_active IP Right Cessation
- 1987-01-30 TR TR87/0077A patent/TR24572A/en unknown
- 1987-01-30 NL NL8700231A patent/NL8700231A/en not_active Application Discontinuation
-
1993
- 1993-09-23 HK HK976/93A patent/HK97693A/en unknown
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