JPS62197496A - Liquid detergent composition improved in washing power containing alkylglycoside - Google Patents
Liquid detergent composition improved in washing power containing alkylglycosideInfo
- Publication number
- JPS62197496A JPS62197496A JP62020366A JP2036687A JPS62197496A JP S62197496 A JPS62197496 A JP S62197496A JP 62020366 A JP62020366 A JP 62020366A JP 2036687 A JP2036687 A JP 2036687A JP S62197496 A JPS62197496 A JP S62197496A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- alkyl
- alcohol
- softening
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims description 61
- 239000000203 mixture Substances 0.000 title claims description 60
- 239000007788 liquid Substances 0.000 title claims description 19
- 238000005406 washing Methods 0.000 title claims description 10
- -1 alkyl glycoside Chemical class 0.000 claims description 45
- 229930182470 glycoside Natural products 0.000 claims description 32
- 125000000217 alkyl group Chemical group 0.000 claims description 28
- 239000004744 fabric Substances 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 23
- 238000004140 cleaning Methods 0.000 claims description 22
- 239000002736 nonionic surfactant Substances 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 16
- 239000003945 anionic surfactant Substances 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 230000000694 effects Effects 0.000 claims description 12
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 10
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 10
- 150000003871 sulfonates Chemical class 0.000 claims description 7
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000012188 paraffin wax Substances 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 3
- 239000008365 aqueous carrier Substances 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 125000001165 hydrophobic group Chemical group 0.000 claims 2
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 claims 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical group [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims 1
- 125000003563 glycoside group Chemical group 0.000 claims 1
- 239000002075 main ingredient Substances 0.000 claims 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims 1
- 159000000000 sodium salts Chemical class 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 description 17
- 239000011734 sodium Substances 0.000 description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 16
- 239000000047 product Substances 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 7
- 102000004190 Enzymes Human genes 0.000 description 5
- 108090000790 Enzymes Proteins 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- 239000003760 tallow Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 229910052783 alkali metal Chemical group 0.000 description 4
- 150000001340 alkali metals Chemical group 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 150000002338 glycosides Chemical class 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 238000005282 brightening Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 239000000039 congener Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 230000013595 glycosylation Effects 0.000 description 2
- 238000006206 glycosylation reaction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 235000015067 sauces Nutrition 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical group CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 235000012545 Vaccinium macrocarpon Nutrition 0.000 description 1
- 240000001717 Vaccinium macrocarpon Species 0.000 description 1
- 235000002118 Vaccinium oxycoccus Nutrition 0.000 description 1
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 1
- XEKWJQURPPJYTC-UHFFFAOYSA-N [Cl-].CC(CCCCCCCCCCC[NH+](CCCCCCCCCCCC)CC)C Chemical compound [Cl-].CC(CCCCCCCCCCC[NH+](CCCCCCCCCCCC)CC)C XEKWJQURPPJYTC-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 230000002152 alkylating effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000021168 barbecue Nutrition 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 235000004634 cranberry Nutrition 0.000 description 1
- 229940071118 cumenesulfonate Drugs 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 1
- GFLLOMRSVVPUNQ-UHFFFAOYSA-M dimethyl-propyl-tetradecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CCC GFLLOMRSVVPUNQ-UHFFFAOYSA-M 0.000 description 1
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004453 electron probe microanalysis Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- UFZOPKFMKMAWLU-UHFFFAOYSA-N ethoxy(methyl)phosphinic acid Chemical compound CCOP(C)(O)=O UFZOPKFMKMAWLU-UHFFFAOYSA-N 0.000 description 1
- XDRMBCMMABGNMM-UHFFFAOYSA-N ethyl benzenesulfonate Chemical compound CCOS(=O)(=O)C1=CC=CC=C1 XDRMBCMMABGNMM-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- RXHDXDIEHWVFOC-UHFFFAOYSA-M ethyl-dimethyl-octadecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC RXHDXDIEHWVFOC-UHFFFAOYSA-M 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000008396 flotation agent Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 235000003084 food emulsifier Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 125000003147 glycosyl group Chemical group 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 235000019674 grape juice Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- IRHTZOCLLONTOC-UHFFFAOYSA-N hexacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCO IRHTZOCLLONTOC-UHFFFAOYSA-N 0.000 description 1
- SSILHZFTFWOUJR-UHFFFAOYSA-N hexadecane-1-sulfonic acid Chemical compound CCCCCCCCCCCCCCCCS(O)(=O)=O SSILHZFTFWOUJR-UHFFFAOYSA-N 0.000 description 1
- QKIAYRRGJHLRAQ-UHFFFAOYSA-N hexadecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 QKIAYRRGJHLRAQ-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000000411 inducer Substances 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229930190071 lycoside Natural products 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005528 methosulfate group Chemical group 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- GHKGUEZUGFJUEJ-UHFFFAOYSA-M potassium;4-methylbenzenesulfonate Chemical compound [K+].CC1=CC=C(S([O-])(=O)=O)C=C1 GHKGUEZUGFJUEJ-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- XZTJQQLJJCXOLP-UHFFFAOYSA-M sodium;decyl sulfate Chemical group [Na+].CCCCCCCCCCOS([O-])(=O)=O XZTJQQLJJCXOLP-UHFFFAOYSA-M 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ILWRPSCZWQJDMK-UHFFFAOYSA-N triethylazanium;chloride Chemical compound Cl.CCN(CC)CC ILWRPSCZWQJDMK-UHFFFAOYSA-N 0.000 description 1
- UWSCPROMPSAQOL-UHFFFAOYSA-N trimethylazanium;sulfate Chemical compound CN(C)C.CN(C)C.OS(O)(=O)=O UWSCPROMPSAQOL-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
産業上の利用分野:
本発明は、第4級アンモニウム柔軟剤化合物、陰イオン
界面活性剤と非イオン界面活性剤の存在下での洗浄効果
と柔軟化性とを改良するための有効量のアルキルグリコ
シトを含む、布帛の洗たくに用いる新規な柔軟化性洗剤
液状組成物に関する。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application: The present invention improves cleaning effectiveness and softening properties in the presence of quaternary ammonium softening compounds, anionic surfactants and nonionic surfactants. The present invention relates to a novel softening detergent liquid composition for use in washing fabrics, which contains an effective amount of alkyl glycoside to wash fabrics.
従来技術:
繊維製品に対する柔軟剤としての種々な化学物質、特に
陽イオン系第4rンモニウム化合物の使用は技術上周知
である。このような物質を洗たく操作中、特に洗たく過
程のすすぎサイクルで、柔軟化効果のために用いること
も周知である。この後者の方法は主に陽イオン性である
今まで用いられた前記第4級アンモニウム化合物が、洗
たくサイクルで用いられる主要な洗剤の1つである陰イ
オン洗剤と相客性でないという事実によって、必要とさ
れている。さらに、陽イオン洗剤化合物は非イオン洗剤
の存在下では比較的効果がない。Prior Art: The use of various chemicals, particularly cationic quaternary ammonium compounds, as softeners for textiles is well known in the art. It is also well known to use such materials for their softening effect during washing operations, particularly in the rinse cycle of the washing process. This latter method is largely due to the fact that the quaternary ammonium compounds used hitherto, which are cationic, are not compatible with anionic detergents, which are one of the main detergents used in wash cycles. is necessary. Furthermore, cationic detergent compounds are relatively ineffective in the presence of nonionic detergents.
洗たくした物が、前記第4rンモニウム化合物で処理し
た場合には、黄変または変色する傾向があることも周知
である。It is also well known that washed items tend to yellow or discolor when treated with the quaternary ammonium compounds.
前記陽イオン作用剤を布帛の洗たくに用いた場合の他の
欠点は、これが光学的増白剤の布帛への沈着を妨げて、
このような光学的増白剤を含む洗剤組成物の光学的増白
効果を減することである。Another disadvantage of using said cationic agents for washing fabrics is that they prevent the deposition of optical brighteners on the fabrics.
The objective is to reduce the optical brightening effect of detergent compositions containing such optical brighteners.
陽イオン系第4級アンモニウム静電防止柔軟化剤のさら
に他の欠点は、これが洗剤による汚れ除去を減すること
によって洗剤の洗浄性を妨げて、洗たく効果を減するこ
とである。陰イオン洗剤の存在は陽イオン性第4級アン
モニウム化合物の布帛柔軟化性を無効にする。Yet another disadvantage of cationic quaternary ammonium antistatic softeners is that they interfere with the detergency of the detergent by reducing soil removal by the detergent, reducing its cleaning effectiveness. The presence of anionic detergents negates the fabric softening properties of cationic quaternary ammonium compounds.
従って、前記第4級アンモニウム化合物はその不利な洗
浄性を打ち消すように設計された種々な化合物と組合さ
れている、または前記第4級アンモニウム柔軟剤の代り
に、洗浄効果を改良するために他の柔軟化剤が用いられ
ている。Therefore, the quaternary ammonium compounds are combined with various compounds designed to counteract their disadvantageous cleaning properties, or instead of the quaternary ammonium softeners, other compounds are used to improve the cleaning effect. Softeners are used.
洗剤、繊維柔軟剤、界面活性剤、ゲル化剤、食品乳化剤
及び滑剤として有用な高級アルキルモノグリコシドとポ
リグリコシト;及びこれらの製造法は米国特許第3.5
98,865号;第3,707,535号;第3,83
9,318号;第3,772,269号;及び第3,2
19.656号に開示されている。Higher alkyl monoglycosides and polyglycosides useful as detergents, fabric softeners, surfactants, gelling agents, food emulsifiers and lubricants; and methods for their production described in U.S. Pat. No. 3.5
No. 98,865; No. 3,707,535; No. 3,83
No. 9,318; No. 3,772,269; and No. 3,2
No. 19.656.
高級アルキルポリグリコ7ドは米国特許第3.721,
633号、ヨーロッパ特許第0.070,074号、第
0.070,075号。Higher alkyl polyglyco7ide is disclosed in U.S. Patent No. 3.721,
No. 633, European Patent Nos. 0.070,074 and 0.070,075.
第0.070,076号、第0.092.877号に示
されているように陰イオン界面活性剤と組合せてまた米
国特許第4,483,779号、第4,483,780
号、第4,483,787号、ヨーロッパ特許第0.0
75,994号、第0.075,995号。No. 0.070,076; No. 0.092.877; and in combination with anionic surfactants; and U.S. Pat.
No. 4,483,787, European Patent No. 0.0
No. 75,994, No. 0.075,995.
第0.075,996号及び第0.105,556号に
示されているように、陰イオン界面活性剤または他の非
イオン界面活性剤と組合せて種々な洗剤組成物に非イオ
ン界面活性剤として用いられて洗浄力を高めている。No. 0.075,996 and No. 0.105,556, nonionic surfactants are used in various detergent compositions in combination with anionic surfactants or other nonionic surfactants. It is used as a detergent to improve its cleaning power.
米国特許第4,493,773号;ヨーロッパ特許第0
.094,118号と第0.106,692号に示され
ているように、先行技術もアルキルポリグリコシビ、従
来の非イオン界面活性剤と陽イオン性繊維柔軟化性化合
物とを含み、洗たく中に柔軟化性と洗浄性の両方を発揮
する洗剤組成物を開示している。しかし、これらの特許
では陰イオン界面活性剤を組成物に対して不利であると
して特に除外している。US Patent No. 4,493,773; European Patent No. 0
.. No. 094,118 and No. 0.106,692, the prior art also includes alkyl polyglycosylation, conventional nonionic surfactants and cationic fiber softening compounds, and Discloses a detergent composition that exhibits both softening and detergent properties. However, these patents specifically exclude anionic surfactants as being detrimental to the composition.
米国特許!4,014,808号はアルカリ性ビルダー
、高級アルキルモノグリコシビとポリグリコシドの混合
物、非イオンエトキシレートもしくは酸形の陰イオン変
性エトキシレート、及び汚れを凝集させて浮遊フロック
にする凝集剤、ならびに任意にアルキルアリールスルホ
ン酸ナトリウムである浮遊化剤から成る、床のような硬
い表面を洗浄するための水性洗剤組成物を開示している
。US patent! No. 4,014,808 contains an alkaline builder, a mixture of higher alkyl monoglycosylates and polyglycosides, a nonionic ethoxylate or anionically modified ethoxylate in acid form, and a flocculant to flocculate the soil into floating flocs, and optionally discloses an aqueous detergent composition for cleaning hard surfaces, such as floors, comprising a flotation agent that is sodium alkylaryl sulfonate.
しかし、上記先行技術参考文献のいずれも、主要4成分
金含むすなわち第4級アンモニウム柔軟化性化合物、陰
イオン界面活性剤と非イオン界面活性剤の存在下での洗
浄効果と柔軟化性の両方を改良するための有効量のアル
キルグリコンビを含む、布帛を同時に洗浄・柔軟化する
液体洗剤組成物を開示していない。However, none of the above prior art references show both cleaning effectiveness and softening properties in the presence of a main quaternary gold-containing i.e. quaternary ammonium softening compound, an anionic surfactant and a non-ionic surfactant. does not disclose a liquid detergent composition that simultaneously cleans and softens fabrics that includes an effective amount of an alkyl glycome to improve the properties of the fabric.
発明が解決しようとする問題点:
非イオン−陰イオン界面活性剤系中に陽イオン系第4級
アンモニウム柔軟化性化合物を含む液体柔軟化性洗剤組
成にアルキルホリグリコシド界面活性剤紮加えると、洗
浄力が上昇し、これによって処理した布帛に対する柔軟
化性が増強することが今回発見された。Problem to be Solved by the Invention: When an alkyl hoglycoside surfactant is added to a liquid softening detergent composition containing a cationic quaternary ammonium softening compound in a nonionic-anionic surfactant system, It has now been discovered that the cleaning power is increased, thereby increasing the softening properties of treated fabrics.
従って、陽イオン系第4級アンモニウム柔軟化性化合物
の存在下での洗浄効果を改良した液体洗剤を提供するこ
とが、本発明の主要な目的である。It is therefore a principal object of the present invention to provide a liquid detergent with improved cleaning effectiveness in the presence of cationic quaternary ammonium softening compounds.
本発明の他の目的は、主要4成分としてのアルキルグリ
コシビ、第4級アンモニウム柔軟化性化合物、非イオン
界面活性剤と陰イオン界面活性剤を含み、洗たく過程中
に布帛を同時に洗浄・柔軟化する液体洗剤組成物を提供
することである。Another object of the present invention is to contain an alkyl glycosylation compound, a quaternary ammonium softening compound, a nonionic surfactant and an anionic surfactant as the main four components, and simultaneously wash and soften the fabric during the washing process. It is an object of the present invention to provide a liquid detergent composition that has the following properties.
本発明のさらに他の目的は、陰イオン、非イオン及び陽
イオン界面活性剤の混合物を含む洗剤組成物中にアルキ
ルグリコシドが存在することにより、洗浄性と柔軟化性
とを改良された液体洗剤組成物を提供することである。Yet another object of the invention is to provide a liquid detergent with improved detergent and softening properties due to the presence of an alkyl glycoside in a detergent composition comprising a mixture of anionic, nonionic and cationic surfactants. An object of the present invention is to provide a composition.
本発明のこの他の目的、利点及び新規な特徴は以下の説
明に部分的に述べるが、その一部は次に述べる検査に基
づいて当業者に明らかになると思われる、または本発明
の実施によって会得されると思われる。本発明の目的と
利点は特許請求の範囲で特に指摘した手段及び組合せに
よって、実現され、達成される。Other objects, advantages and novel features of the invention are set forth in part in the following description, and in part will be apparent to those skilled in the art based on examination of the following, or by practice of the invention. It seems likely that this will be achieved. The objects and advantages of the invention may be realized and attained by means of the instruments and combinations particularly pointed out in the appended claims.
問題点を解決するための手段:
ここに具体化し概略を述べた本発明によって、上記その
他の目的を達成するために、布帛法たく用の本発明の液
状洗剤組成物は主要4成分を含む、すなわち水性キャリ
ヤ中の第4級アンモニウム柔軟化性化合物、陰イオン界
面活性剤と非イオン界面活性剤の存在下での洗浄効果と
柔軟化性とを改良するための有効量のアルキルグリコシ
ドヲ含む、また本発明による増白剤効果と洗浄力とを減
することなく、布帛を同時に洗浄・柔軟化する方法は洗
たく操作の洗たくサイクル中に前記組成物によって布帛
を処理することから成る。SUMMARY OF THE INVENTION In accordance with the invention as embodied and outlined herein, in order to achieve the above and other objects, a liquid detergent composition of the invention for use in fabric washing comprises four main components: a quaternary ammonium softening compound in an aqueous carrier, an effective amount of an alkyl glycoside to improve cleaning efficacy and softening properties in the presence of anionic and nonionic surfactants; Also, a method according to the invention for simultaneously cleaning and softening fabrics without reducing brightener effectiveness and cleaning power comprises treating the fabrics with said composition during the wash cycle of the wash operation.
さらに詳しく説明すると、本発明は第4級アンモニウム
化合物による洗浄力低下を克服するために充分な量のC
1り、。アルキルモノまたはポリグリコシド約2御5
軟化性化合物約2〜8重量%,非イオン界面活性剤約8
〜25重量%と陰イオン界面活性剤約1〜12重量%と
を水性キャリヤ中に含む安定な液体柔軟化性洗剤組成物
に関する。To explain in more detail, the present invention provides a sufficient amount of carbon to overcome the reduction in detergency caused by quaternary ammonium compounds.
1. Approximately 2 to 5 alkyl mono- or polyglycosides, approximately 2-8% by weight of softening compounds, approximately 8% nonionic surfactant
The present invention relates to a stable liquid softening detergent composition comprising ~25% by weight and about 1-12% by weight of an anionic surfactant in an aqueous carrier.
アルキルグリコシドは柔軟化剤として作用し、陽イオン
界面活性剤の存在下での布帛柔軟化を強化する。アルキ
ルグリコシド9が布帛の表面を被覆する及び/または布
帛構造を変化させて柔軟化効果を与えることが考えられ
る。アルキルグリコシドが水素結合を中断させて柔軟化
効果を高めることが考えられる。アルキルグリコシドは
洗浄力に影響を与えず及び/または、柔軟化性洗剤の別
の課題である、増白剤沈着を妨げない。Alkyl glycosides act as softening agents and enhance fabric softening in the presence of cationic surfactants. It is conceivable that the alkyl glycoside 9 coats the surface of the fabric and/or changes the fabric structure to provide a softening effect. It is thought that alkyl glycosides disrupt hydrogen bonds and enhance the softening effect. Alkyl glycosides do not affect detergency and/or prevent brightener deposition, which is another problem with softening detergents.
本発明の新規な柔軟化性洗剤に用いられるアルキルグリ
コシド9は、炭素数1〜30、好ましくは炭素数8〜1
5の疎水性基1個以上と糖うジカル1〜約10個好まし
くは約1〜3個を含む親水性基1個とを有するものとし
て定義される。アルキルグリコンドは次式によって表さ
れる:
RO(R’O)、Zn
〔式中、R(dCl−c3oアルキルラジカルであり、
(R10) はエトキシ、プロポキシまたはグリセリ
ル基であり、XはO〜10の数値、好ましくは0であり
、Zは炭素数5または6の還元糖であり、nは1〜10
、好ましくは1゜0〜3の数値である〕
疎水性アルキル基は飽和または不飽和、分岐鎖または直
鎖の、好ましくは飽和直鎖の炭素数1〜30、好ましく
は炭素数8〜23の基である。適当なアルキルポリグリ
コンビは、メチル、エチル、プロピル、オクチル、ノニ
ル、テシル、ウンデシル、ドデシル、トリデシル、テト
ラデシル、ヘキサテフル、ヘプタデシル、オクタデシル
及びこれらの混合した、モノグリコシド、ジグリコシド
、トリグリコシビ、テトラグリコシド、にンタンリコシ
ド。The alkyl glycoside 9 used in the novel softening detergent of the present invention has 1 to 30 carbon atoms, preferably 8 to 1 carbon atoms.
5 and one hydrophilic group containing from 1 to about 10, preferably from about 1 to 3 sugar radicals. The alkyl glyconde is represented by the following formula: RO(R'O), Zn [wherein R(dCl-c3o alkyl radical,
(R10) is an ethoxy, propoxy or glyceryl group, X is a numerical value of O to 10, preferably 0, Z is a reducing sugar having 5 or 6 carbon atoms, and n is 1 to 10
The hydrophobic alkyl group is a saturated or unsaturated, branched or straight chain, preferably a saturated straight chain group having 1 to 30 carbon atoms, preferably 8 to 23 carbon atoms. It is the basis. Suitable alkyl polyglycosides include methyl, ethyl, propyl, octyl, nonyl, tecyl, undecyl, dodecyl, tridecyl, tetradecyl, hexateflu, heptadecyl, octadecyl and mixtures thereof, mono-, di-, tri-, and tetra-glycosides. Ntan lycoside.
ヘキサグリコシド、等である。グリコシビ単位はグルコ
ース、ガラクトース、マンノース、ラクトース及び/ま
たはフルクトースであり得る。前記グリコシドゝの製造
方法は米国特許第3,598,865号;第3,707
,535号;第3,839,318号;第3,772,
269号;第3,219,656号に開示されている。Hexaglycoside, etc. The glycosylation unit may be glucose, galactose, mannose, lactose and/or fructose. The method for producing the glycoside is described in U.S. Pat. No. 3,598,865; No. 3,707.
, No. 535; No. 3,839,318; No. 3,772,
No. 269; No. 3,219,656.
これらの特許は全て参考文献としてここに関係する。柔
軟化性洗剤にアルキルグリコシドを添加すると、洗剤の
洗浄効果は改良される。All of these patents are incorporated herein by reference. Addition of alkyl glycosides to softening detergents improves the detergent's cleaning effectiveness.
グリコシドの量は柔軟化性洗剤中に陽イオン系第4級ア
ンモニウム柔軟化剤が存在することによる洗浄力低下を
中和するほどでなければならない。The amount of glycoside should be sufficient to counteract the detergency loss due to the presence of the cationic quaternary ammonium softener in the softening detergent.
従って、グリコシビ含有景は柔軟化性洗剤の洗浄力を改
善し、組成物の約1〜30M−Ikチ、好ましくは2〜
25重量%を占める。Therefore, the glycosyl-containing powder improves the detergency of the softening detergent and improves the detergency of the composition by approximately 1-30 M-Ik, preferably 2-30 M-Ik, of the composition.
It accounts for 25% by weight.
陽イオン系第4級アンモニウム柔軟化剤は商業的に周知
であり、典型的に、窒素原子に結合した4基の中の少な
くとも1基が炭素数約10〜20のアルキル基であり、
少なくとも2基が炭素数1〜3のアルキル基であり、4
番目の基が別のC10〜C20アルキル基またはC1−
、C3アルキル基のいずれがであり、ハロゲン、アセテ
ート、メトサルフェート等のような陰イオンが存在する
第4級アンモニウム化合物を含む。典型的な第4級アン
モニウム化合物はエチルージメチルーステアリルアンモ
ニウムクロリビ、トリメチルーステアリルアンモニウム
クロリヒ、トリメチルセチルアンモニウムプロミド、ジ
メチルーエチルージラウリルアンモニウムクロリビ、ジ
メチループロピルーミリスチルアンモニウムクロリ1.
タロートリメチルアンモニウムクロリド、三水素化タロ
ージメチルアンモニウムクロリビ、ジココジメチルアン
モニウムクロリド、ジステアリルジメチルアンモニウム
クロリド9.オクタデシルトリメチルアンモニウムクロ
リビ、ドデシルトリメチル″!りはトリエチルアンモニ
ウムクロリド、及びこれらに対応するメトサルフェート
とアセテートである。他の適当な第4級アンモニウム化
合物にはデュオクワット、イミグゾリニウムクワット、
ポリエトキシル化クワット及びアミドアルコキシル化ク
ワットがある。Cationic quaternary ammonium softeners are well known commercially and typically include at least one of the four groups attached to the nitrogen atom being an alkyl group having about 10 to 20 carbon atoms;
At least two groups are alkyl groups having 1 to 3 carbon atoms, and 4
th group is another C10-C20 alkyl group or C1-
, C3 alkyl group, including quaternary ammonium compounds in which anions such as halogen, acetate, methosulfate, etc. are present. Typical quaternary ammonium compounds are ethyl-dimethyl-stearylammonium chloride, trimethyl-stearylammonium chloride, trimethylcetylammonium bromide, dimethyl-ethyl-dilauryl ammonium chloride, dimethyl-propyl-myristylammonium chloride.
Tallow trimethylammonium chloride, trihydrated tallow dimethylammonium chloride, dicocodimethylammonium chloride, distearyldimethylammonium chloride9. Octadecyltrimethylammonium chloride, dodecyltrimethyl"! is triethylammonium chloride, and its corresponding methosulfates and acetates.Other suitable quaternary ammonium compounds include duoquat, imigzoliniumquat,
There are polyethoxylated quats and amidoalkoxylated quats.
本発明の柔軟化性洗剤組成物に用いる第4級アンモニウ
ム柔軟化剤量は柔軟化性組成物の約2〜8重量%である
ことが好ましい。Preferably, the amount of quaternary ammonium softener used in the softening detergent composition of the present invention is about 2-8% by weight of the softening composition.
本発明によると、布帛洗剤として用いる非イオン界面活
性剤は商業的に周知であり、これには第1脂肪族アルコ
ールエトキシレート、第2脂肪族アルコールエトキシレ
ート、アルキルフェノールエトキシレート及びアルコー
ルーエチレンオキシピープロピレンオキシト9縮金物〔
例えば、Plura−facs (Wyanaotle
社)〕及びこれらの混合物がある。非イオン合成有機洗
剤は一般に有機脂肪族またはアルキル芳香族疎水性化合
物と親水性エチレンオキシド基との縮合生成物である。According to the present invention, nonionic surfactants for use as fabric detergents are commercially well known and include primary aliphatic alcohol ethoxylates, secondary aliphatic alcohol ethoxylates, alkylphenol ethoxylates, and alcohol-ethylene oxypropyl alcohols. Propylene oxide 9 metal product [
For example, Plura-facs (Wyanaotle
) and mixtures thereof. Nonionic synthetic organic detergents are generally condensation products of organic aliphatic or alkyl aromatic hydrophobic compounds and hydrophilic ethylene oxide groups.
窒素に付加した遊離水素を含むカルボキ7.ヒドロキン
。Carboxy containing free hydrogen added to nitrogen7. Hydroquine.
アミドまたはアミノ基を有する疎水性化合物は実際にエ
チレンオキシド9またはその多水酸化生成物(ポリエチ
レングリコール)と縮合して、非イオン洗剤を形成し得
る。さらに、ポリエテノキシ鎖の長さは疎水性要素と親
水性要素との間に望ましいバランスが得られるように調
節することができる。Hydrophobic compounds with amide or amino groups can actually be condensed with ethylene oxide 9 or its polyhydroxylated product (polyethylene glycol) to form nonionic detergents. Additionally, the length of the polyethenoxy chain can be adjusted to obtain the desired balance between hydrophobic and hydrophilic elements.
非イオン洗剤には、直鎖または分枝鎖配置の炭素数約6
〜12のアルキルフェノール1モルとエチレンオキノビ
5〜30モルとのポリエチレンオキシド縮合物、例えば
エチレンオキシド9モルと縮合シタノニルフェノール、
エチレンオキシド15モルと縮合したドデシルフェノー
ルがある。エチレンオキノビ5〜30モルと対応アルキ
ルチオフェノールとの縮合生成物も適している。Nonionic detergents contain about 6 carbon atoms in a linear or branched configuration.
A polyethylene oxide condensate of 1 mol of ~12 alkylphenol and 5 to 30 mol of ethylene oxide, such as 9 mol of ethylene oxide and fused sitanonylphenol,
There is dodecylphenol condensed with 15 moles of ethylene oxide. Also suitable are condensation products of 5 to 30 mol of ethylene oquinone with the corresponding alkylthiophenols.
エチレンオキシビ約5〜30モルと縮合した高級アルコ
ール(例えば、直鎖まf?、は分枝鎖配置の炭素数約8
〜18のアルカノール)の縮合物、例えばエチレンオキ
シド約16モルとラウリル−ミリスチルアルコールとの
縮合物も、非イオン洗剤の種類に含まれる。Higher alcohols condensed with about 5 to 30 moles of ethylene oxybi (for example, straight-chained alcohols have about 8 carbon atoms in a branched chain configuration)
Also included in the category of non-ionic detergents are condensates of about 16 moles of ethylene oxide and lauryl-myristyl alcohol.
非イオン界面活性剤の好ましい群は、例えばエチレンオ
キシピロ、5モルと縮合したC工2〜C13アルカノー
ル、エチレンオキシ)”12モルと縮合したC1□−J
C15アルカノール、エチレンオキシ白3モルと縮合し
りC14−c05アルカノール等のような、炭素数約1
0〜18の脂肪族アルコール1モルにつきエチレンオキ
シ基約r−20個を有する高級脂肪族アルコールエトキ
シレートであるNO3(101エトキシレート(She
xICo、)である。HLB (疎水性−親油性平衡
)約8〜15のEthoxamer は良好なo/w
乳化作用を及ぼすが、低いHLB 値(8未満)の
Ethoxamer は5個より少ないエチレンオキシ
基を含み、弱い乳化剤及び弱い非イオン洗剤である。こ
の非イオン界面活性剤は柔軟化性洗剤組成物中にアルキ
ルポリグリコシド含有量以上の量で、すなわち約8〜2
5重i%量で存在する。非イオン界面活性剤の全量、す
なわち非イオン界面活性剤でもあるグリコシドと上記で
定義した非イオン系アルコールエトキシレートとの合計
量はこの柔軟化性洗剤の主要流刑成分をなし、組成物の
約25〜40i量チ、好ましくは30〜40重itチを
占める。A preferred group of non-ionic surfactants are, for example, ethyleneoxypyro, C2-C13 alkanols condensed with 5 moles, C1□-J condensed with 12 moles of ethyleneoxy)
C15 alkanol, about 1 carbon number, such as C14-c05 alkanol condensed with 3 moles of ethyleneoxy white
NO3 (101 ethoxylate (She
xICo, ). Ethoxamer with HLB (hydrophobic-lipophilic balance) of about 8-15 has good o/w
Although exerting an emulsifying effect, Ethoxamer with a low HLB value (less than 8) contains fewer than 5 ethyleneoxy groups and is a weak emulsifier and a weak nonionic detergent. The nonionic surfactant is present in the softening detergent composition in an amount greater than or equal to the alkyl polyglycoside content, i.e., about 8 to 2
Present in an amount of 5% by weight. The total amount of nonionic surfactants, i.e. the total amount of glycosides which are also nonionic surfactants and nonionic alcohol ethoxylates as defined above, constitutes the main component of this softening detergent and accounts for approximately 25% of the composition. It accounts for ~40 weight units, preferably 30 to 40 weight units.
本発明の柔軟化性洗剤に用いる陰イオン洗剤は商業的に
周知であり、アルキルRンゼンスルホン酸とその塩、例
えば式:アルキルフェニル−803−M(式中、アルキ
ルは08<2□アルキルラジカル、好ましくはC10−
C18アルキルラジカルでアリ、Mは水素またはアルカ
リ金属である)で表される化合物を含む。この化合物は
周知の陰イオン洗剤の種類であり、ビデシルスルホン酸
ナトリウム、ト9デシルベンゼンスルホン酸カリウム、
ラウリルベンゼンスルホン酸ナトリウム、セチルベンゼ
ンスルホン酸ナトリウムを含む。この他には、パラフィ
ンスルホネート、アルキルサルフェート、アルコールエ
ーテルサルフェート、オレフィンスルホネート、及ヒア
ルキルフェノールエトキ7レートサルフエート(例えば
ジノニルフェノキ7ノナエトキシエタノール硫酸ナトリ
ウム)ならびに特にアルカリ金属系列の他の同等な水溶
性塩が含まれる。The anionic detergents used in the softening detergents of the present invention are commercially well known and include alkylRbenzenesulfonic acids and their salts, such as the formula alkylphenyl-803-M, where alkyl is an 08<2□alkyl radical. , preferably C10-
C18 alkyl radical, M is hydrogen or an alkali metal). This compound is a class of well-known anionic detergents, including sodium bidecylsulfonate, potassium to9decylbenzenesulfonate,
Contains sodium laurylbenzenesulfonate and sodium cetylbenzenesulfonate. In addition, paraffin sulfonates, alkyl sulfates, alcohol ether sulfates, olefin sulfonates, and hyalkylphenol ethoxy heptalate sulfates (e.g. sodium dinonylphenoxynonaethoxyethanol sulfate) as well as other equivalent water-soluble compounds, especially of the alkali metal series. Contains salt.
上記アルキルはンゼンスルホン酸とその塩の中で好まし
い化合物は、生物学的分解可能であり、特にCl0−C
2゜好ましくはC1□(15の直鎖アルキル置換基によ
って特性化されるような化合物である。このような化合
物の製造方法が通常、混合鎖長のアルキル化試薬を用い
るので、炭素鎖長が一般に平均鎖長を表すことは当然理
解される。しかし、他の方法で実質的に純粋なオレフィ
ンならびにアルキル化化合物を用いるならば、アルキル
成分が実質的に(すなわち、少なくとも99%)単一鎖
長、fすbチc、”−C12,C131c14’77’
!−BC□5であるアルキル化ベンゼンスルホネートカ
得られることは明らかである。点鎖アルキルベンゼンス
ルホネートはさらに、線状アルキル鎖中のばンゼン環の
位置によって特性化され、位置異性体(すなわち、αか
らωまで)が生成可能であり、考えられる。Among the above-mentioned alkylbenzene sulfonic acids and their salts, preferred compounds are biologically degradable, especially Cl0-C
2° is preferably a compound characterized by C1□ (15 straight chain alkyl substituents). Since processes for the preparation of such compounds typically employ mixed chain length alkylating reagents, the carbon chain length is It is understood that it generally refers to the average chain length.However, if an otherwise substantially pure olefin as well as an alkylated compound are used, the alkyl component may be substantially (i.e., at least 99%) single chain. long, fsbchic, ”-C12,C131c14'77'
! -BC□5 is clearly obtained. Point-chain alkylbenzene sulfonates are further characterized by the position of the benzene ring in the linear alkyl chain, and positional isomers (ie, α to ω) are possible and contemplated.
インゼンスルホネートの他に、トルエン、キ7レン、ト
リメチルベンゼン、エチルばンゼン、イソプロビルイン
ゼン等のようなベンゼンの低級アルキル(C1−C4)
同族体上用いることもできる。スルホネートは一般に、
陽イオンとしてアルカリ金属、アンモニウム、及び低級
アミンならびにアルカノールアミン陽イオンを含む水溶
性塩として用いられる。In addition to inzenesulfonates, lower alkyl (C1-C4) benzenes such as toluene, xylene, trimethylbenzene, ethylbanzene, isoprobylinzene, etc.
Congeners can also be used. Sulfonates are generally
It is used as a water-soluble salt containing alkali metal, ammonium, and lower amine as well as alkanolamine cations as cations.
適当な直鎖アルキルベンゼンスルホネートの例は、
n−ビデシルズンゼンスルホン酸ナトリウムn−L”デ
シルベンゼンスルホン酸ナトリウムn−テトラデシルベ
ンゼンスルホ/酸ナトリウム
n−−<ンタデシルベンゼンスルホン酸ナトリウム
n−ヘキサデフルベンゼンスルホン酸ナトリウム
及び対応する低級アルキル置換ベンゼン同族体ならびに
上記陽イオンの塩である。これらのスルホネートの混合
物も、混合物の平均鎖長がC1(1”C2□の特定要件
に従うものであるならば、線状アルキル鎖が上記化合物
よりも短いまたは長い化合物を含む混合物と共に当然用
いることができる。Examples of suitable linear alkylbenzenesulfonates include sodium n-bidecylbenzenesulfonate n-L" sodium decylbenzenesulfonate n-tetradecylbenzenesulfonate/sodium acid n--<sodium ntadecylbenzenesulfonate n-hexade Sodium flubenzenesulfonate and the corresponding lower alkyl-substituted benzene congeners and salts of the above cations. Mixtures of these sulfonates may also be used, provided that the average chain length of the mixture is C1 (1"C2□). For example, it can of course be used with mixtures containing compounds whose linear alkyl chains are shorter or longer than those mentioned above.
直鎖パラフィンスルホネートも周知の化合物群であり、
次の酸の水溶性塩(アルカリ金属、アミン、アルカノー
ルアミン及ヒアンモニウム):1−デカンスルホン酸
1−トルエンスルホン酸
1−トリデカンスルホン酸
1−テトラデカンスルホン酸
1−ば/タデカンスルホン酸
1−ヘキサデカンスルホン酸
ならびにスルホン酸基の他の位置異性体を含む。Straight-chain paraffin sulfonates are also a well-known group of compounds,
Water-soluble salts of the following acids (alkali metals, amines, alkanolamines and hyammonium): 1-decanesulfonic acid 1-toluenesulfonic acid 1-tridecanesulfonic acid 1-tetradecanesulfonic acid 1-ba/tadecanesulfonic acid 1 - Hexadecane sulfonic acid as well as other positional isomers of the sulfonic acid group.
上記パラフィンスルホネートの他に、一般範囲のC−C
アルキルC最も好ましい範囲はC1□〜C2oアルキル
)を有するスルホネートも用いることができる。In addition to the above paraffin sulfonates, the general range of C-C
Sulfonates having alkyl C (most preferably in the range C1□ to C2o alkyl) can also be used.
本発明で用いる直鎖アルキルサルフェートはCl0−c
2o の範囲を含む。特定の例はn−デシル硫酸ナト
リウム、n−)+Tデシル硫酸ナトリウム。The linear alkyl sulfate used in the present invention is Cl0-c
Includes a range of 2o. A specific example is sodium n-decyl sulfate, n-) + sodium T-decyl sulfate.
n−へキサデフル硫酸ナトリウム、n−ヘプタデシル硫
酸ナトリウム、n−オクタデシル硫酸ナトリウム、なら
びに、例えばエトキシル化アルコールサルフェートのよ
うな、エトキシル化(エチレンオキシド1〜100モル
)誘導体、及び当然上記の他の水溶性塩形成陽イオンも
含む。Sodium n-hexadeflu sulfate, sodium n-heptadecyl sulfate, sodium n-octadecyl sulfate, as well as ethoxylated (1 to 100 moles of ethylene oxide) derivatives, such as e.g. ethoxylated alcohol sulfate, and of course other water-soluble salts mentioned above. Also includes formed cations.
本発明に適切であると上記した陰イオン洗剤群には、長
鎖アルケンスルホネート、長鎖ヒドロキシアルカンスル
ホネート、ならびにジスルホネー(”を含trオレフィ
ンスルホネートが含まれる。適当なオレフィンスルホネ
ートの例には(一般的種類を単に説明するものとして)
、ドデセニル−1スルホン酸ナトリウム、テトラデセニ
ル−1スルホン酸ナトリウム、ヘキサデセニル−1スル
ホン酸ナトリウム、及びオクタデセニル−1スルホン酸
ナトリウムがある。本発明に用いる陰イオン界面活性剤
の量は非イオン界面活性剤(エトキシル化脂肪族アルコ
ール)の含有量(重量)よシも少なく、好ましくは全非
イオン界面活性剤(アルキルグリコシド9+エトキシル
化脂肪族アルコール)の関重量%未満であシ、組成物の
約1〜2重量%を占めることが好ましい。The group of anionic detergents described above as suitable for the present invention includes long chain alkenesulfonates, long chain hydroxyalkanesulfonates, and disulfones (including tr olefinsulfonates). Examples of suitable olefinsulfonates include (generally (as a mere description of the type)
, sodium dodecenyl-1 sulfonate, sodium tetradecenyl-1 sulfonate, sodium hexadecenyl-1 sulfonate, and sodium octadecenyl-1 sulfonate. The amount of anionic surfactant used in the present invention is smaller than the content (weight) of nonionic surfactant (ethoxylated fatty alcohol), preferably total nonionic surfactant (alkyl glycoside 9 + ethoxylated fatty alcohol). It is preferred that the total amount of alcohol (alcohols in the group alcohol group) is less than about 1% to 2% by weight of the composition.
本発明の柔軟化性洗剤組成物は通常の洗剤添加剤、例え
ば光学的増白剤、殺菌剤、汚れ懸濁化剤。The softening detergent composition of the present invention contains conventional detergent additives such as optical brighteners, disinfectants, soil suspending agents.
再沈着防止剤、酸化防止剤2着色剤(色素と顔料)。Anti-redeposition agent, antioxidant 2 colorants (pigments and pigments).
香料、水溶性アルコール、起泡剤2例えばキシレンスル
ホン酸カリウムトナトリウム、トルエンスルホン酸ナト
リウムとカリウム、クメンスルホネート、エチルベンゼ
ンスルホネート等のような油水性誘発物質、酵素と酵素
安定剤を、これらが組成物の洗浄力と柔軟化活性を妨げ
ないかぎり、含み得る。Fragrances, water-soluble alcohols, foaming agents, oil-water inducers such as sodium potassium xylene sulfonate, sodium and potassium toluene sulfonate, cumene sulfonate, ethylbenzene sulfonate, etc., enzymes and enzyme stabilizers, which may be added to the composition. may be included as long as it does not interfere with the detergency and softening activity of
本発明の詳細な説明
次の実施例は本発明を単に説明するものであり、本発明
を限定するものと解釈すべきではない。DETAILED DESCRIPTION OF THE INVENTION The following examples are merely illustrative of the invention and should not be construed as limiting the invention.
実施例1
柔軟化性洗剤
C1□(,5アルコール:エチレンオキシド97モル1
5チ
アルキルポリグリコント”、 C12,C13:グリ
コシト加モル(St(ley 工ndustrial
Products社)15%トリエタノールアミン
0.25チモノアルキルトリ
メチルアンモニウムクロリド18.0%C12〜C15
アルコール:エチレンオキシド加モル12チサルフエー
ト、ナトリウム
キシレンスルホン酸ナトリウム 4.
0%増白剤 0
.5 %水
十分な量1、 タロートリメチルアンモニウムクロリ
ド上記成分を均質になるまで混合して、安定な液体組成
物を形成することによって、液体洗剤を製造する。Example 1 Softening detergent C1□(,5 alcohol: ethylene oxide 97 mol 1
5-thialkyl polyglycocont", C12, C13: Glycocytomol (St(ley industrial
Products) 15% triethanolamine
0.25 Thimonoalkyltrimethylammonium chloride 18.0% C12-C15
Alcohol: 12 moles of ethylene oxide, sodium thiosulfate, sodium xylene sulfonate 4.
0% brightener 0
.. 5% water
Sufficient Quantity 1, Tallow Trimethylammonium Chloride A liquid detergent is prepared by mixing the above ingredients until homogeneous to form a stable liquid composition.
この生成物の洗浄力を、120下と70”Fの150p
111(カルシウム)水1gを含むターボトメ−ター(
tergotometer)において、柔軟化性洗剤0
.184濃度を用いて試験し、アルキルグリコシド成分
を含まない市販の洗剤製品と比較した。The cleaning power of this product is 150p below 120 and 70”F.
111 (calcium) in a turbotometer containing 1 g of water (
tergotometer), softening detergent 0
.. 184 concentration was used and compared to commercially available detergent products that do not contain alkyl glycoside components.
標準汚れ負荷した試験布片ナイロン(TFN)と綿(T
FC)、ポリエステル−綿65〜35%ズレント8(P
C)及びダク”7: 綿50:!1(DC)fxらUK
EMPA 101C1othの汚れ負荷を試験洗剤で洗
たくし、電気回転乾燥機で乾燥した。汚れた布片の反射
率を洗浄力(Rd)の尺度として読み取る。汚れ除去(
SR)は全布片に対するRa読取り値の合計であり、汚
れ除去指数(SRI)は布片数で除した総Ra読取り値
の平均値である。Standard soil loaded test fabric pieces of nylon (TFN) and cotton (T
FC), polyester-cotton 65-35% Zulent 8 (P
C) and dac”7: cotton 50:!1 (DC) fx et al. UK
The EMPA 101C1oth soil load was washed with the test detergent and dried in an electric rotary dryer. The reflectance of the soiled cloth piece is read as a measure of cleaning power (Rd). Dirt removal (
SR) is the sum of the Ra readings for all fabric pieces, and Stain Removal Index (SRI) is the average of the total Ra readings divided by the number of fabric pieces.
第1表
実施例1はDynamo 、 5oxo 、 BOLD
3 に比べてすぐれた洗浄力を示す。実施例1と液体
TIDE。Table 1 Example 1 is Dynamo, 5oxo, BOLD
Shows superior cleaning power compared to No. 3. Example 1 and liquid TIDE.
間では120下と70下において統計的有意差が認めら
れなかった。No statistically significant difference was observed between 120 and below and 70 and below.
120′Fニオケル脂汚し除去ハ綿トD/c50150
とに関して液体TIDEと同じであり、D/C50/父
に関しては大ていの競合洗剤よシも良好であった。70
下において、液体TよりEがやや良好であったが、他の
大ていの競合洗剤は実施例1に等しかった。120'F Niokel Grease Stain Removal Cotton D/c50150
It was the same as Liquid TIDE in terms of D/C50/Father and was better than most competing detergents. 70
Below, E was slightly better than Liquid T, but most other competitive detergents were equal to Example 1.
第■表
120、’Fと70下における多重しみテストは次の結
果を生じた、対照として液体TよりE2用いた。Multiple stain tests under Table 120, 'F and 70 yielded the following results, using E2 rather than Liquid T as a control.
第■表
120下
有意に良好 2 1 0有
意差なし 7 7 2有意に低
下 13 14 2070’F
有意に良好 5 3 Q
有意差なし 9 3 5有意に
低下 8 16 17120下
n布片全テノ総Ra 1407 t522
1368 t20270下
n布片全テノ総Ra 1351 1390 12
40 1215液体TよりE に比べて洗浄力の最
も有意な低下は、120下における酸素の例において生
じた。実施例1の製剤が酵素を含まないので、これは予
想されることであった。しかし、酸化可能なしみに関し
ても(グレープジュースとクランベリージュ−ス)、低
下が観察された。実施例1は、油汚れの場合に(バーベ
キューソースとフレンチトゝレッシング)、DDKに強
い汚れを示した。Table 120: Significantly better 2 1 0 No significant difference 7 7 2 Significantly lower 13 14 2070'F Significantly better 5 3 Q
No significant difference 9 3 5 Significantly decreased 8 16 17120 lower n cloth total teno total Ra 1407 t522
1368 t20270 lower n cloth piece all teno total Ra 1351 1390 12
The most significant decrease in cleaning power compared to 40 1215 liquid T than E occurred in the oxygen example below 120. This was expected since the formulation of Example 1 does not contain enzymes. However, a reduction was also observed for oxidizable stains (grape juice and cranberry juice). Example 1 showed strong staining on DDK in the case of oil stains (barbecue sauce and French dressing).
70下において、酵素しみによる洗浄力低下はかなり減
少した。これは酵素が一般に高温になると効果的になる
という事実による。70下において、実施例1は油汚れ
の場合には〔スパングラ−脂(Spangler Se
bum)/微粒子、バーRキューソース、 Rea C
r1sco ショートニング、フレンチドレッシング
〕、液体TII)Eよりも非常に効果的である。70, the reduction in detergency due to enzyme stains was considerably reduced. This is due to the fact that enzymes generally become more effective at higher temperatures. In the case of oil stains, Example 1 uses [Spangler Se
bum)/fine particles, bar R cu sauce, Rea C
r1sco shortening, French dressing], liquid TII) Much more effective than E.
BOLD3と5OLOはいずれの温度においても良好な
効果を示さなかった。BOLD3 and 5OLO did not show good effects at any temperature.
5回の柔軟化/静電気/増白剤試験は次の結果を示した
:
綿布片の蛍光を増白剤効果(Rb)の尺度として読み取
る。Five softening/static/brightener tests showed the following results: The fluorescence of the cotton fabric piece is read as a measure of brightener effectiveness (Rb).
第V表
Ra読取り値
実施例1 269.96
液体TIDE 255.44SOLO12
0,88
Dynamo 245.53BOLD3
224.56実施例1の製剤は静電気付
着防止においてBOLD3に匹敵し、5OLOよりも良
好であった。Table V Ra Reading Example 1 269.96 Liquid TIDE 255.44 SOLO12
0,88 Dynamo 245.53BOLD3
224.56 The formulation of Example 1 was comparable to BOLD3 and better than 5OLO in preventing static build-up.
実施例1は5OLOに比べて柔軟化効果においては幾ら
か劣ったが、実施例1製剤−アルキルグリコシドに比べ
ると改良された柔軟化作用を示した。Although Example 1 was somewhat inferior in softening effect compared to 5OLO, it showed improved softening effect compared to Example 1 formulation - alkyl glycoside.
実施例2
柔軟化性洗剤
Neodol 25−7121%
トフシルベンゼンスルホン酸ナトリウム
6%タロートリメチル第4級アンモニウムクロリ
ビ 4%メチルグリコシド
2%増白剤
0.4%エタノール
8チキシレンスル
ホン酸ナトリウム 5チ着
色剤 0.5
%水 充
分な量1C12へ015アルコール:エチレンオキシド
7モル実施例3
柔軟化性洗剤
Neodol 25−7 21
%トフシルベンゼンスルホン酸ナトリウム
4%タロートリメチルアンモニウムサルフェート
4%メチルグリコシド
2%増白剤
0.4チエタノール
8%着色
剤 0.5チ
水 充分な
量この洗剤を、最大柔軟化性Qlt有する対照として5
oxo を用いた61b・非汚染負荷柔軟化性テスト5
回においてテストした。この製剤の柔軟化性評価は6f
3(第1回、第3回及び第5回後の読取り値の平均値)
であり、5oloにかなり匹敵する。Example 2 Softening detergent Neodol 25-7121% Sodium tophsylbenzenesulfonate
6% tallow trimethyl quaternary ammonium chloribid 4% methyl glycoside
2% brightener
0.4% ethanol
8 Sodium thixylene sulfonate 5 Colorant 0.5
% Water Sufficient amount to 1C12 015 Alcohol: Ethylene oxide 7 moles Example 3 Softening detergent Neodol 25-7 21
%Sodium tofsylbenzenesulfonate
4% tallow trimethyl ammonium sulfate 4% methyl glycoside
2% brightener
0.4 ethanol
8% colorant 0.5 t water Sufficient amount of this detergent to serve as a control with maximum softening Qlt.
61b non-polluting load flexibility test 5 using oxo
It was tested twice. The softening property rating of this formulation is 6f.
3 (Average value of readings after 1st, 3rd and 5th reading)
, and is quite comparable to 5olo.
柔軟化性評価は1(最もゴワゴワした)〜10(最大柔
軟化性)の範囲内である。この製剤にタローアミン:1
5エチレンオキシド3チを添加すると、柔軟化性評価は
6.0 に低下する。第4級アンモニウム化合物を省略
してメチルグリコシドを6%に増加すると、柔軟化性評
価は7.2に上昇する。Softening ratings range from 1 (most stiff) to 10 (maximum softening). Tallowamine: 1 in this preparation
Addition of 5.3% ethylene oxide lowers the softening rating to 6.0. Omitting the quaternary ammonium compound and increasing the methyl glycoside to 6% increases the softening rating to 7.2.
次の第v表は5試験製品と2対照に関する5回テストの
増白結果と静電結果とを要約する。Table V below summarizes the brightening and electrostatic results of the five tests for the five test products and two controls.
上記結果はメチルグリコシドが布帛に柔軟化効果を与え
ることを示す。実験室テストは、グリコシドが液体製剤
に増白効果を与えることも示した。The above results show that methyl glycosides have a softening effect on fabrics. Laboratory tests also showed that glycosides impart a whitening effect to liquid formulations.
しかし、quatが存在しない場合には静電気抑制は達
成されない。However, in the absence of quat, static suppression is not achieved.
アルキルグリコシドを含む柔軟化性洗剤は第4級アンモ
ニウム柔軟化剤の存在による洗浄力低下を克服するのみ
でなく、柔軟化性洗剤の洗浄力と柔軟化性2!il一本
改良することが意外にも発見された。Softening detergents containing alkyl glycosides not only overcome the reduction in detergency caused by the presence of quaternary ammonium softeners, but also improve the detergency and softening properties of softening detergents! It was unexpectedly discovered that il was improved by one line.
このことはわずか2%のメチルグリコシド″ヲ含む製品
4(実施例3)がアルキルグリコシドを含まない製品1
(5,9)、 2(5,8)及び3 (6,0)
よりも大きな柔軟化性塵(6,8)を示すことによって
、第V表に明らかに認められる。同様に、製品4は第1
回、第3回及び第5回読たくサイクル後に製品1゜2及
び3よりも大きな増白効果を示し、アルキルグリコシド
ヲ含棟々い製品に比べてSRI値の増加を示した。2チ
程度の低量のアルキルグリコシドが布帛の洗たくに用い
る柔軟化性洗剤組成物の洗浄力と柔軟化性の両方の改良
に有効である。さらに、本発明の製剤は現在市販されて
いる他の界面活性剤及び/または柔軟化剤組成物に比べ
て、第1表、第■表、第■表と第v表の比較結果から分
るように、良好な洗浄・柔軟化効果を示す。This indicates that product 4 (Example 3), which contains only 2% methyl glycosides, is different from product 1, which contains no alkyl glycosides.
(5,9), 2 (5,8) and 3 (6,0)
This is clearly seen in Table V by showing the softening dust (6,8) larger than Similarly, product 4 is the first
After the third, third, and fifth reading cycles, products 1, 2, and 3 exhibited greater whitening effects and increased SRI values compared to products containing alkyl glycosides. Amounts of alkyl glycosides as low as 2% are effective in improving both the detergency and softening properties of softening detergent compositions used for washing fabrics. Furthermore, the formulations of the present invention are more effective than other surfactant and/or softener compositions currently on the market, as can be seen from the comparative results in Tables 1, 2, 3, and v. As such, it shows good cleaning and softening effects.
上記詳細な説明が単に説明のためだけに記載されるもの
であること及び本発明の精神から逸脱することなく、変
更がなされ得ることが理解されよう。It will be understood that the above detailed description is given for purposes of illustration only and that changes may be made without departing from the spirit of the invention.
(外5名)(5 other people)
Claims (17)
化合物の存在下、洗浄性および柔軟性を改良するための
有効量のアルキルグリコシド、水性キャリアー中の非イ
オン界面活性剤および陰イオン界面活性剤を含むことか
らなる、布帛を洗浄し同時に柔軟化するための液状洗剤
組成物。(1) In the presence of four main ingredients: a quaternary ammonium softener compound, an effective amount of an alkyl glycoside to improve detergency and softening properties, a nonionic surfactant in an aqueous carrier, and an anionic surfactant. A liquid detergent composition for cleaning and softening fabrics at the same time.
含有量による洗浄効果の低下を克服するために充分であ
り、組成物の約2〜25重量%を占める特許請求の範囲
第1項記載の組成物。(2) The composition of claim 1, wherein the amount of alkyl glycoside is sufficient to overcome the reduction in cleaning effectiveness due to the content of quaternary ammonium and accounts for about 2 to 25% by weight of the composition. thing.
の疎水性基1個以上と還元糖ラジカル1〜10個含有す
る親水性グリコシド基1個とを有する特許請求の範囲第
1項記載の組成物。(3) Claim 1, wherein the alkyl glycoside has one or more hydrophobic groups having 1 to 30 carbon atoms/hydrophobic group and one hydrophilic glycoside group containing 1 to 10 reducing sugar radicals. Composition.
モノグリコシドまたはポリグリコシドである特許請求の
範囲第1項記載の組成物。(4) The composition according to claim 1, wherein the alkyl glycoside is an alkyl monoglycoside or polyglycoside having 1 to 30 carbon atoms.
ルトリグリコシドである特許請求の範囲第4項記載の組
成物。(5) The composition according to claim 4, wherein the alkyl glycoside is an alkyl triglycoside having 12 to 13 carbon atoms.
る特許請求の範囲第4項記載の組成物。(6) The composition according to claim 4, wherein the alkyl glycoside is methyl monoglycoside.
4基の中の少なくとも1基がC_1_0〜C_2_0ア
ルキル基であり、少なくとも2基がC_1〜C_3アル
キル基であり、第4番目の基が別のC_1_0〜C_2
_0アルキル基またはC_1〜C_3アルキル基である
特許請求の範囲第1項記載の組成物。(7) At least one of the four groups bonded to the nitrogen atom of the quaternary ammonium compound is a C_1_0 to C_2_0 alkyl group, at least two groups are C_1 to C_3 alkyl groups, and the fourth group is another C_1_0~C_2 of
The composition according to claim 1, which is a _0 alkyl group or a C_1 to C_3 alkyl group.
量%を占める特許請求の範囲第7項記載の組成物。(8) The composition of claim 7, wherein the quaternary ammonium compound accounts for about 2 to 8% by weight of the composition.
キシレート、第2脂肪族アルコールエトキシレート、ア
ルキルフェノールエトキシレート、アルコールエチレン
オキシドプロピレンオキシド縮合物、及びこれらの混合
物から成る群から選択する特許請求の範囲第1項記載の
組成物。(9) Claims in which the nonionic surfactant is selected from the group consisting of first aliphatic alcohol ethoxylates, second aliphatic alcohol ethoxylates, alkylphenol ethoxylates, alcohol ethylene oxide propylene oxide condensates, and mixtures thereof. The composition according to item 1.
特許請求の範囲第9項記載の組成物。(10) The composition of claim 9, wherein the nonionic surfactant comprises about 8 to 5% by weight.
ドとの組合せから成る全非イオン界面活性剤含有量が組
成物の約25〜40重量%を占めて、主要洗剤成分を構
成する特許請求の範囲第9項記載の組成物。(11) The total nonionic surfactant content consisting of a combination of alcohol ethoxylate and alkyl glycoside accounts for about 25-40% by weight of the composition and constitutes the main detergent ingredient. Composition of.
エチレンオキシ基7個を有するC_1_2〜C_1_5
脂肪族アルコールである特許請求の範囲第9項記載の組
成物。(12) C_1_2 to C_1_5 in which the nonionic surfactant has 7 ethyleneoxy groups per mole of alcohol
10. The composition of claim 9, which is an aliphatic alcohol.
ネート、アルコールエーテルサルフェート、オレフィン
スルホネート、パラフィンスルホネート、アルキルサル
フェート、及びエトキシル化アルコールサルフェートか
ら成る群から選択する特許請求の範囲第1項記載の組成
物。(13) The composition of claim 1, wherein the anionic surfactant is selected from the group consisting of alkylbenzene sulfonates, alcohol ether sulfates, olefin sulfonates, paraffin sulfonates, alkyl sulfates, and ethoxylated alcohol sulfates.
剤含有量よりも少なく、約1〜12重量%量である特許
請求の範囲第13項記載の組成物。14. The composition of claim 13, wherein the anionic surfactant content is less than the nonionic surfactant content, in an amount of about 1 to 12% by weight.
エチレンオキシド3モルを含むエトキシル化C_1_2
〜C_1_5アルコールサルフェートのナトリウム塩で
ある特許請求の範囲第13項記載の組成物。(15) Ethoxylated C_1_2 where the anionic surfactant contains 3 moles of ethylene oxide per mole of alcohol
The composition according to claim 13, which is a sodium salt of ~C_1_5 alcohol sulfate.
ン酸ナトリウムである特許請求の範囲第13項記載の組
成物。(16) The composition according to claim 13, wherein the anionic surfactant is sodium dodecylbenzenesulfonate.
の範囲第1項記載の組成物によつて布帛を処理すること
から成る、増白剤効果と洗浄力とを減することのない、
布帛を同時に洗浄・柔軟化する方法。(17) without reducing the brightener effect and cleaning power, comprising treating the fabric with the composition according to claim 1 in the washing cycle of the washing operation;
A method for cleaning and softening fabrics at the same time.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US82392686A | 1986-01-30 | 1986-01-30 | |
US823926 | 1986-01-30 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62197496A true JPS62197496A (en) | 1987-09-01 |
JPH07113119B2 JPH07113119B2 (en) | 1995-12-06 |
Family
ID=25240144
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62020366A Expired - Lifetime JPH07113119B2 (en) | 1986-01-30 | 1987-01-30 | Liquid detergent composition with improved detergency containing alkyl glycosides |
Country Status (28)
Country | Link |
---|---|
JP (1) | JPH07113119B2 (en) |
KR (1) | KR950003426B1 (en) |
AR (1) | AR247588A1 (en) |
AT (1) | AT397809B (en) |
AU (1) | AU595851B2 (en) |
BE (1) | BE1002958A4 (en) |
BR (1) | BR8700392A (en) |
CH (1) | CH671963A5 (en) |
DE (1) | DE3702287A1 (en) |
DK (1) | DK167881B1 (en) |
EG (1) | EG18097A (en) |
ES (1) | ES2004081A6 (en) |
FR (1) | FR2593516B1 (en) |
GB (1) | GB2185992B (en) |
GR (1) | GR870125B (en) |
HK (1) | HK97693A (en) |
IL (1) | IL81353A (en) |
IN (1) | IN170107B (en) |
IT (1) | IT1205726B (en) |
MX (1) | MX168268B (en) |
NL (1) | NL8700231A (en) |
NO (1) | NO169661C (en) |
NZ (1) | NZ219051A (en) |
PH (1) | PH25243A (en) |
SE (1) | SE8700324L (en) |
TR (1) | TR24572A (en) |
ZA (1) | ZA87561B (en) |
ZW (1) | ZW1887A1 (en) |
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---|---|---|---|---|
IL81354A (en) * | 1986-01-30 | 1990-11-05 | Colgate Palmolive Co | Liquid detergent having improved softening properties |
AU619502B2 (en) * | 1987-11-05 | 1992-01-30 | Colgate-Palmolive Company, The | Liquid softergent formulations having improved stability and softening properties |
US4844824A (en) * | 1988-02-08 | 1989-07-04 | The Procter & Gamble Company | Stable heavy duty liquid detergent compositions which contain a softener and antistatic agent |
US5230835A (en) * | 1988-08-04 | 1993-07-27 | Kao Corporation | Mild non-irritating alkyl glycoside based detergent compositions |
DE68925390T2 (en) * | 1988-08-04 | 1996-06-05 | Kao Corp | Detergent composition |
CA2007169A1 (en) * | 1989-01-19 | 1990-07-19 | Regis Lysy | Softergent with sugar ethers as detergency boosters |
FR2666346B1 (en) * | 1990-09-05 | 1992-11-20 | Oreal | COMPOSITION FOR WASHING AND / OR COSMETIC TREATMENT WITH RINSING OF KERATINIC FIBERS, QUICK DRYING, BASED ON CATIONIC FLUORINATED COMPOUNDS AND ALKYLPOLYGLYCOSIDES. |
EP0838518B1 (en) * | 1992-09-11 | 2002-11-13 | Cognis Deutschland GmbH & Co. KG | Detergent mixtures |
DE4338113A1 (en) * | 1993-11-08 | 1995-05-11 | Henkel Kgaa | Softening detergent with alkyl glycosides |
US5466394A (en) * | 1994-04-25 | 1995-11-14 | The Procter & Gamble Co. | Stable, aqueous laundry detergent composition having improved softening properties |
DE4440620A1 (en) * | 1994-11-14 | 1996-05-15 | Henkel Kgaa | Textile softeners |
AR003724A1 (en) * | 1995-09-29 | 1998-09-09 | Procter & Gamble | STRUCTURED LIQUID LAUNDRY DETERGENT COMPOSITION, FOR HARD WORK, COMPRISING ANIONIC AND CATIONIC SURFACTANTS. |
GB9606913D0 (en) | 1996-04-02 | 1996-06-05 | Unilever Plc | Surfactant blends processes for preparing them and particulate detergent compositions containing them |
DE19629666A1 (en) | 1996-07-23 | 1998-01-29 | Henkel Kgaa | Process for the hydrophilic finishing of fibers or nonwovens |
EP0849354A1 (en) | 1996-12-20 | 1998-06-24 | Unilever Plc | Softening compositions |
GB2340843A (en) * | 1998-08-25 | 2000-03-01 | Reckitt & Colman Inc | Liquid laundry detergent compositions |
US6384010B1 (en) | 2000-06-15 | 2002-05-07 | S.C. Johnson & Son, Inc. | All purpose cleaner with low organic solvent content |
GB0106466D0 (en) | 2001-03-15 | 2001-05-02 | Unilever Plc | Fabric softening compositions |
GB0114921D0 (en) * | 2001-06-19 | 2001-08-08 | Ciba Spec Chem Water Treat Ltd | Particles containing fabric conditioner |
WO2023170120A1 (en) * | 2022-03-10 | 2023-09-14 | Unilever Ip Holdings B.V. | Concentrated fabric conditioner |
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JPS58132094A (en) * | 1981-09-28 | 1983-08-06 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Detergent composition |
JPS5925896A (en) * | 1982-05-10 | 1984-02-09 | ザ・プロクタ−・エンド・ギヤンブル・カンパニ− | Low phosphate laundry detergent composition |
JPS59145299A (en) * | 1982-10-18 | 1984-08-20 | ザ,プロクタ−,エンド,ギヤンブル,カンパニ− | Polyethylene glycol containing liquid detergent |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GR76286B (en) * | 1981-09-28 | 1984-08-04 | Procter & Gamble | |
IL81354A (en) * | 1986-01-30 | 1990-11-05 | Colgate Palmolive Co | Liquid detergent having improved softening properties |
-
1987
- 1987-01-22 IL IL81353A patent/IL81353A/en unknown
- 1987-01-23 NZ NZ219051A patent/NZ219051A/en unknown
- 1987-01-26 ZA ZA87561A patent/ZA87561B/en unknown
- 1987-01-27 PH PH34768A patent/PH25243A/en unknown
- 1987-01-27 GR GR870125A patent/GR870125B/en unknown
- 1987-01-27 IN IN53/DEL/87A patent/IN170107B/en unknown
- 1987-01-27 DE DE19873702287 patent/DE3702287A1/en not_active Withdrawn
- 1987-01-27 ZW ZW18/87A patent/ZW1887A1/en unknown
- 1987-01-28 SE SE8700324A patent/SE8700324L/en not_active Application Discontinuation
- 1987-01-28 IT IT47579/87A patent/IT1205726B/en active
- 1987-01-28 GB GB8701854A patent/GB2185992B/en not_active Expired - Lifetime
- 1987-01-28 EG EG52/87A patent/EG18097A/en active
- 1987-01-28 AU AU68053/87A patent/AU595851B2/en not_active Ceased
- 1987-01-29 NO NO870367A patent/NO169661C/en unknown
- 1987-01-29 FR FR878701079A patent/FR2593516B1/en not_active Expired - Lifetime
- 1987-01-29 AT AT0017687A patent/AT397809B/en not_active IP Right Cessation
- 1987-01-29 ES ES878700215A patent/ES2004081A6/en not_active Expired
- 1987-01-29 BR BR8700392A patent/BR8700392A/en active Search and Examination
- 1987-01-30 JP JP62020366A patent/JPH07113119B2/en not_active Expired - Lifetime
- 1987-01-30 DK DK051387A patent/DK167881B1/en active
- 1987-01-30 CH CH342/87A patent/CH671963A5/de not_active IP Right Cessation
- 1987-01-30 KR KR1019870000745A patent/KR950003426B1/en active IP Right Grant
- 1987-01-30 MX MX005112A patent/MX168268B/en unknown
- 1987-01-30 AR AR87306640A patent/AR247588A1/en active
- 1987-01-30 BE BE8700064A patent/BE1002958A4/en not_active IP Right Cessation
- 1987-01-30 TR TR87/0077A patent/TR24572A/en unknown
- 1987-01-30 NL NL8700231A patent/NL8700231A/en not_active Application Discontinuation
-
1993
- 1993-09-23 HK HK976/93A patent/HK97693A/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS565895A (en) * | 1979-06-29 | 1981-01-21 | Kao Corp | Detergent composition |
JPS58132094A (en) * | 1981-09-28 | 1983-08-06 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Detergent composition |
JPS5925896A (en) * | 1982-05-10 | 1984-02-09 | ザ・プロクタ−・エンド・ギヤンブル・カンパニ− | Low phosphate laundry detergent composition |
JPS59145299A (en) * | 1982-10-18 | 1984-08-20 | ザ,プロクタ−,エンド,ギヤンブル,カンパニ− | Polyethylene glycol containing liquid detergent |
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