NO167013B - Fremgangsmaate ved bekjempelse av sopp som skader treverk - Google Patents
Fremgangsmaate ved bekjempelse av sopp som skader treverk Download PDFInfo
- Publication number
- NO167013B NO167013B NO860755A NO860755A NO167013B NO 167013 B NO167013 B NO 167013B NO 860755 A NO860755 A NO 860755A NO 860755 A NO860755 A NO 860755A NO 167013 B NO167013 B NO 167013B
- Authority
- NO
- Norway
- Prior art keywords
- wood
- fungi
- damage
- dimethyl
- tridecyl
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 4
- 239000002023 wood Substances 0.000 claims abstract description 23
- YTOPFCCWCSOHFV-UHFFFAOYSA-N 2,6-dimethyl-4-tridecylmorpholine Chemical compound CCCCCCCCCCCCCN1CC(C)OC(C)C1 YTOPFCCWCSOHFV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 241000233866 Fungi Species 0.000 claims abstract description 13
- 230000002538 fungal effect Effects 0.000 claims abstract description 11
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- 206010061217 Infestation Diseases 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000013543 active substance Substances 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 229920001817 Agar Polymers 0.000 description 5
- 239000008272 agar Substances 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000010409 ironing Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- YTOPFCCWCSOHFV-RTBURBONSA-N (2r,6r)-2,6-dimethyl-4-tridecylmorpholine Chemical compound CCCCCCCCCCCCCN1C[C@@H](C)O[C@H](C)C1 YTOPFCCWCSOHFV-RTBURBONSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XGWIJUOSCAQSSV-XHDPSFHLSA-N (S,S)-hexythiazox Chemical compound S([C@H]([C@@H]1C)C=2C=CC(Cl)=CC=2)C(=O)N1C(=O)NC1CCCCC1 XGWIJUOSCAQSSV-XHDPSFHLSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000094558 Antrodia sinuosa Species 0.000 description 2
- 241000221198 Basidiomycota Species 0.000 description 2
- 241001600095 Coniophora puteana Species 0.000 description 2
- 241001492300 Gloeophyllum trabeum Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 241000222355 Trametes versicolor Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003171 wood protecting agent Substances 0.000 description 2
- KEUPLGRNURQXAR-UHFFFAOYSA-N (4-chlorophenyl) acetate Chemical compound CC(=O)OC1=CC=C(Cl)C=C1 KEUPLGRNURQXAR-UHFFFAOYSA-N 0.000 description 1
- PLMBMEXGGQWUDS-UHFFFAOYSA-N 1-[2-[2-(2,4-dichlorophenyl)-1,3-dioxolan-2-yl]ethyl]-1,2,4-triazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CCN2N=CN=C2)OCCO1 PLMBMEXGGQWUDS-UHFFFAOYSA-N 0.000 description 1
- DPGXTUOZQHBZRC-UHFFFAOYSA-N 1-[2-[2-(2,4-dichlorophenyl)-4-ethyl-1,3-dioxolan-2-yl]ethyl]-1,2,4-triazole Chemical compound O1C(CC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CCN1N=CN=C1 DPGXTUOZQHBZRC-UHFFFAOYSA-N 0.000 description 1
- FBGKAFRWBNEYTR-UHFFFAOYSA-N 1-[2-[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]ethyl]-1,2,4-triazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CCN1N=CN=C1 FBGKAFRWBNEYTR-UHFFFAOYSA-N 0.000 description 1
- RULKYXXCCZZKDZ-UHFFFAOYSA-N 2,3,4,5-tetrachlorophenol Chemical compound OC1=CC(Cl)=C(Cl)C(Cl)=C1Cl RULKYXXCCZZKDZ-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 241000235349 Ascomycota Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241001600093 Coniophora Species 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- QTDRLOKFLJJHTG-UHFFFAOYSA-N Furmecyclox Chemical compound C1=C(C)OC(C)=C1C(=O)N(OC)C1CCCCC1 QTDRLOKFLJJHTG-UHFFFAOYSA-N 0.000 description 1
- 244000162269 Lentinus lepideus Species 0.000 description 1
- 235000017066 Lentinus lepideus Nutrition 0.000 description 1
- 241000318230 Merulius Species 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 241001581437 Polystictus Species 0.000 description 1
- 241000221535 Pucciniales Species 0.000 description 1
- 244000082988 Secale cereale Species 0.000 description 1
- 241001674251 Serpula lacrymans Species 0.000 description 1
- APQHKWPGGHMYKJ-UHFFFAOYSA-N Tributyltin oxide Chemical compound CCCC[Sn](CCCC)(CCCC)O[Sn](CCCC)(CCCC)CCCC APQHKWPGGHMYKJ-UHFFFAOYSA-N 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 150000003931 anilides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- 239000011093 chipboard Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229940120693 copper naphthenate Drugs 0.000 description 1
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- QQQYTWIFVNKMRW-UHFFFAOYSA-N diflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC=C(Cl)C=C1 QQQYTWIFVNKMRW-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000001034 iron oxide pigment Substances 0.000 description 1
- 229960002809 lindane Drugs 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- DECZQJJTUZWGMA-UHFFFAOYSA-N methyl-(2-propoxyphenyl)carbamic acid Chemical compound CCCOC1=CC=CC=C1N(C)C(O)=O DECZQJJTUZWGMA-UHFFFAOYSA-N 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000002780 morpholines Chemical class 0.000 description 1
- AKBZLSDTRZFLRP-UHFFFAOYSA-N n-cyclohexylnitrous amide Chemical class O=NNC1CCCCC1 AKBZLSDTRZFLRP-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000006916 nutrient agar Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000003032 phytopathogenic effect Effects 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- JUEAPPHORMOWPK-UHFFFAOYSA-M tributylstannyl benzoate Chemical compound CCCC[Sn](CCCC)(CCCC)OC(=O)C1=CC=CC=C1 JUEAPPHORMOWPK-UHFFFAOYSA-M 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/343—Heterocyclic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/36—Aliphatic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyrrole Compounds (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
- Photometry And Measurement Of Optical Pulse Characteristics (AREA)
Description
Foreliggende oppfinnelse vedrører en fremgangsmåte ved bekjempelse av sopp som skader treverk.
Det erkjent fra tysk off.skrift 1.164.152 å anvende substituerte morfolinderivater i jordbruket for bekjempelse av fytopatogene sopper. Et tyngdepunkt ved anvendelsen av disse virkestoffer, spesielt av N-tridecyl-2,6-dimetylmorfolin (tridemorf) ligger derunder i korn i bekjempelse av ekte meldugg-sopper som tilhører soppklassen Ascomyceter. Kornrust-sopper såsom rugdvergrust og hvetebrunrust som tilhører soppklassen Basidiomyceter bekjempes ikke med tridemorf.
Det er videre kjent å anvende N-tridecyl-2,6-trans-dimetyl-morfolin for bekjempelse av sopper som ødelegger trevirke såsom Coniophora og Polystictus (EP 129.211).
Det er nå overraskende funnet at N-tridecyl-2,6-dimetyl-morf olin i sammenligning med N-tridecyl-2,6-trans-dimetyl-morfolin viser en vesentlig bedre virksomhet mot slike sopper, som angriper og ødelegger trevirke, spesielt ikke lenger levende trevirke.
Foreliggende oppfinnelse ligger derfor i at man behandler soppene eller trevirket som er truet av soppangrep, unntatt trevirke fra gummitrær, med N-tridecyl-2,6-dimetylmorfolin.
Følgende sopper som ødeleggeer trevirke (Basidiomyceter) lar seg ifølge oppfinnelsen f.eks. bekjempe med trevirke-beskyttelsesmiddelet: Merulius lacrimans, Coniophora puteana, Lentinus lepideus, Lenzites trabea, Polystictus versicolor, Poria vaporaria.
Ikke lenger levende (dødt) trevirke er f.eks. skåret trevirke, bygningstrevirke, trevirkestoffer, f.eks. sponplater, trespon. Med N-tridecyl-2,6-dimetylmorfolin menes både virkestoffet selv og dets salter med uorganiske eller organiske syrer, f.eks. salter med hydrogenfluorid, saltsyre, hydrogen-bromid, svovelsyre, eddiksyre og propionsyre.
Virkestoffet kan anvendes i preparater eåsom løsninger, emulsjoner, pastaer, strykemidler (f.eks. maling, beis) og oljedispersjoner. Preparatene inneholder generelt mellom 0,1
og 90 vekt% virkestoff, fortrinnsvis 0,25 til 50%. Bruksmengden er avhengig av den virkning man ønsker å oppnå 0,5 til 8 g
virkestoff pr. m<2> trevirkeoverflate som skal beskyttes henholds-vis 50 til 4000 g virkestoff pr. m<3> trevirke. Strykemidler inneholder f.eks. 0,5 til 4 vekt% virkestoff. For beskyttelse av trevirkestoffer kan virkestoffene tilsettes bindemidlet i form av emulsjon, f.eks. i mengder på 2 til 6 vekt%.
Applikasjon av virkestoffet finner sted på vanlig måte, f.eks. ved strykning, sprøyting, spruting, dypping eller trykk-impregnerings- eller diffusjonsmetoder.
De følgende eksempler skal anskueliggjøre oppfinnelsen (prosenter i vekt%).
Eksempel 1
Trevirkebeskyttelsesgrunning farveløs
2,00% tridemorf
0,10% permetri.n
0,50% diklofluanid
6,00% linolje
91,40% prøvebensin (kp. 180-220°C)
Eksempel 2
Trevi rkebeskyttelsesglasur, farvet
1,00% tridemorf
0,10% permetri.n
0,50% diklofluanid
15,00% alkydharpiks
3,00% butylglykol
3,00% jernoksydpigment
0,20% tørkemiddel
77,20% prøvebensin (kp. 180-220°C)
Eksempel 3
Vakuumimpregneringsolje
2,00% tridemorf
0,50% diklofluanid
3,00% di.butylftalat
94,50% prøvebensin (kp. 180-220°C)
Eksempel 4
Trevi rkebeskyttelsesgrunni ng, vannfortynnbar 2,00% tridemorf
3,00% dimetylalkylberizylammoni umklori d
1,00% addisjonsprodukt av etylenoksyd (EO) til
nonylfenol (ca. 10 mol EO pr. mol fenol)
3,00% eddiksyre
5,00% propylenglykol
86,00% vann
For å utvide virkningsspektret eller for å oppnå spesielle virkninger kan virkestoffene kombineres med andre virkestoffer. Som spesielt heldig anses blandinger med følgende forbindelser: Organotinnforbindelser såsom tributyltinnoksyd og tributyl-ti nnbenzoat
metylenbi sti ocyanat
dimetylalkylaminsalter
dimetyldi alkylammoni um-klori der
dimetylalkylbenzylammonium-klorider
trimetylalkylammoni um-klorider
dimetylbi pyridi ni um-klori d
cetylpyri di ni um-klori d
klorerte fenoler, såsom tetra- og pentaklorfenol tetraklori softalsyre-di ni tri 1
2-halogenbenzosyreanilid
N-cykloheksyl-N-metoksy-2,5-dimetyl-furan-3-karboksylsyreamid N,N-dimetyl-N'-fenyl-(N-fluormetylti o)-sulfami d N,N-dimety1-N1-tolyl-(N-fluormetylti o)-sulfami d benzimi dazol-2-karbaminsyre-metylester
2-ti ocyanomety1-ti obenzoti azol
kobbernaftenat
kobber-8-oksyki noli n
alkali- og metallsalter av N'-hydroksy-N-cykloheksyl-di azeni umoksyder ^
1-(1',2',4'-tri azolyl-1')-[1-(4'-klorfenoksy)]-3,3-dimetyl-butan-2-on
1-(1<1>,2'-4'-triazolyl-1')-[1-(4'-klorfenoksy)]-3,3-dimetyl-butan-2-ol
N-[3,(p-tert.-butylfenyl)-2-mety1-propyl]-cis-2,6-dimetylmorfoli n heksaklorcykloheksan
0,0-di etyl-o-(a-cyanbenzyli den-ami no-ti ofosfat
0,0-di.etyl-o-3. 5.6. - tri klor-2-pyri di 1-ti ono-f os f at 0,0-diety1-ditio-fosforyl-metyl-6-klorbenzoksazolon 2- i-propoksyfenyl-N-metyl-karbamat
N-metyl-l-naftyl-karbamat
norbornen-di.metanolheksa-klorcyklosulf i tt
1-(4-klorfenyl)-3-(2.6-di-fluorbenzoyl)-urea
1-[2-(2,4-di klorfenyl)-1,3-dioksolan-2-yl-etyl]-1H-1,2,4-tri azol
1-[2-(2,4-diklorfenyl)-4-etyl-l,3-dioksolan-2-yl-etyl]-1H-1,2,4-tri azol
1- [ 2- (2 ,4-diklorf enyl) -4-n-propyl-l, 3-di.oksolan-2-yl-etyl] - 1H-1,2,4-triazol
Syntetiske pyretroider såsom
(±) -3- (2. 2-diklorvi.nyl-2 . 2-dimetyl) -cyklopropan-l-karboksylsyre-3- fenoksy-benzylester
3- (2 . 2-diklorvi.ny 1-2. 2-dimety1) -cyklopropan-l-karboksylsyre-ct-cyano-3-f enoksybenzylester
3- (2 . 2-dibromvinyl-2 . 2-di.metyl) -a-cyano-m-f enoksybenzyl (IR, 3R) - cyklopropan-karboksylat
a-cyano-3-f enoksybenzyl-i.sopropyl-2 . 4-klorf enylacetat Eksempel 5
For å fremstille et oljeaktig trevirke-beskyttelsesmiddel med 1% virkestoff oppløses først 1 del (vektdel) av virkestoffet under svak oppvarming i 55 deler av en aromatrik bensinfraksjon. Så tilsettes 10 deler av en alkydharpiks og kompletteres med prøvebensin ved romtemperatur til 100 deler.
For å fremstille vannavstøtende impregneringsmidler kan
de oljeaktige trevirke-beskyttelsesmidler tilsettes såkalte "water repellents". Egnede substanser er f.eks. sinkstearat, alumi.niumstearat og vokser.
Videre kan det for å oppnås farveeffekte* innarbeides finpartiklede uorganiske eller organiske pigmenter eller olje-løselige farvestoffer i formuleringene.
For å beskytte trevirke mot soppangrep påføres normalt
50 til 200 ml av de i eks. 5 oppførte oljeaktige trevirke-beskyttelsesmidler pr. m 2 trevirkeoverflate ved strykning, sprøyting eller dypping.
Anve ndelseseksempel 1
Tridemorf oppløses i aceton i mengder fra 100, trinnvis til 3 ppm og tilsettes en 5%ig maltekstraktagar. Agaren helles 1 petri-skåler og etter stivning inokkuleres de fungicid-holdige næringsagarplater adskilt med myzele av trevirke-angripende sopper Merculius lacrimans (ekte hussopp), Coniophora puteana (kjellersopp), Lenzites trabea, Polystictus versicolor og Poria vaporaria. Etter 5 dagers utvikling av skålene ved 2 5°C vurderes utviklingen av sopp-kolonier på næringsbunnen sammenlignet med N-tridecyl-2,6-trans-dimetylmorfolin (A)
og kontrollen (uten fungicid-tilsetning).
0 = ingen soppvekst (soppmyzel drept)
1 = litt soppvekst (opptil 1/3 av agaroverflaten bevokst)
2 = middels soppvekst (opptil 2/3 av agaroverflaten bevokst)
5 = uhemmet soppvekst (hele agaroverflaten bevokst)
Anvendelseseksempel 2
Følgende grenseverdier, d.v.s. den nødvendige mengde av virkestoffet tridemorf for beskyttelse av 1 m 3 trevirke ble
målt etter forutgående utvasking med vann.
4r
Claims (1)
- Fremgangsmåte ved bekjempelse av sopp som skader treverk, karakterisert ved at man behandler soppene eller trevirket som er truet av soppangrep, unntatt trevirke fra gummitrær, med N-tridecyl-2,6-dimetylmorfolin.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853507420 DE3507420A1 (de) | 1985-03-02 | 1985-03-02 | Holzschutzmittel |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO860755L NO860755L (no) | 1986-09-03 |
| NO167013B true NO167013B (no) | 1991-06-17 |
| NO167013C NO167013C (no) | 1991-09-25 |
Family
ID=6264020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO860755A NO167013C (no) | 1985-03-02 | 1986-02-28 | Fremgangsmaate ved bekjempelse av sopp som skader treverk |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0193890B1 (no) |
| JP (1) | JPH07115327B2 (no) |
| AT (1) | ATE37157T1 (no) |
| CA (1) | CA1272853A (no) |
| DE (2) | DE3507420A1 (no) |
| FI (1) | FI860750A (no) |
| NO (1) | NO167013C (no) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3539412A1 (de) * | 1985-11-07 | 1987-05-14 | Basf Ag | Holzschutzmittel |
| DE3641554C2 (de) * | 1986-12-05 | 1995-04-06 | Solvay Werke Gmbh | Holzschutzmittel |
| DE3736298A1 (de) * | 1987-10-27 | 1989-05-11 | Wolman Gmbh Dr | Holzschutzmittel |
| DE3839640A1 (de) * | 1988-11-24 | 1990-05-31 | Wolman Gmbh Dr | Holzschutzmittel |
| CH681436A5 (no) * | 1990-04-26 | 1993-03-31 | Warmoctro Bv | |
| CH681438A5 (no) * | 1990-04-26 | 1993-03-31 | Warmoctro Bv | |
| CH681437A5 (no) * | 1990-04-26 | 1993-03-31 | Warmoctro Bv | |
| CH681440A5 (no) * | 1990-04-26 | 1993-03-31 | Warmoctro Bv |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3121349A1 (de) * | 1981-05-29 | 1982-12-16 | Basf Ag, 6700 Ludwigshafen | Cyclohexenderivate, verfahren zu ihrer herstellung und diese enthaltende fungizide |
| DE3321712A1 (de) * | 1983-06-16 | 1984-12-20 | Basf Ag, 6700 Ludwigshafen | 2,6-trans-dimethylmorpholinderivate und diese enthaltende fungizide und verfahren zur bekaempfung von pilzen |
| DE3329694A1 (de) * | 1983-08-17 | 1985-03-07 | Dr. Wolman Gmbh, 7573 Sinzheim | Waessriges holzschutzmittel |
-
1985
- 1985-03-02 DE DE19853507420 patent/DE3507420A1/de not_active Withdrawn
-
1986
- 1986-02-20 FI FI860750A patent/FI860750A/fi not_active Application Discontinuation
- 1986-02-26 JP JP61039351A patent/JPH07115327B2/ja not_active Expired - Lifetime
- 1986-02-27 CA CA000502836A patent/CA1272853A/en not_active Expired - Lifetime
- 1986-02-28 EP EP86102615A patent/EP0193890B1/de not_active Expired
- 1986-02-28 AT AT86102615T patent/ATE37157T1/de not_active IP Right Cessation
- 1986-02-28 NO NO860755A patent/NO167013C/no unknown
- 1986-02-28 DE DE8686102615T patent/DE3660709D1/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FI860750A0 (fi) | 1986-02-20 |
| EP0193890B1 (de) | 1988-09-14 |
| CA1272853A (en) | 1990-08-21 |
| JPH07115327B2 (ja) | 1995-12-13 |
| EP0193890A1 (de) | 1986-09-10 |
| DE3660709D1 (en) | 1988-10-20 |
| ATE37157T1 (de) | 1988-09-15 |
| DE3507420A1 (de) | 1986-09-04 |
| JPS61202801A (ja) | 1986-09-08 |
| NO167013C (no) | 1991-09-25 |
| NO860755L (no) | 1986-09-03 |
| FI860750A (fi) | 1986-09-03 |
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