NO166225B - Fluorborsyresalt av n-tridecyl-2,6-dimetylmorfolin, fungicid og trebeskyttelsesmiddel inneholdende dette, samt anvendelse derav. - Google Patents
Fluorborsyresalt av n-tridecyl-2,6-dimetylmorfolin, fungicid og trebeskyttelsesmiddel inneholdende dette, samt anvendelse derav. Download PDFInfo
- Publication number
- NO166225B NO166225B NO870623A NO870623A NO166225B NO 166225 B NO166225 B NO 166225B NO 870623 A NO870623 A NO 870623A NO 870623 A NO870623 A NO 870623A NO 166225 B NO166225 B NO 166225B
- Authority
- NO
- Norway
- Prior art keywords
- acid
- water
- dimethylmorpholine
- tridecyl
- wood
- Prior art date
Links
- YTOPFCCWCSOHFV-UHFFFAOYSA-N 2,6-dimethyl-4-tridecylmorpholine Chemical compound CCCCCCCCCCCCCN1CC(C)OC(C)C1 YTOPFCCWCSOHFV-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 150000003839 salts Chemical class 0.000 title claims abstract description 15
- 239000002253 acid Substances 0.000 title abstract description 6
- 239000000126 substance Substances 0.000 title 1
- RILZRCJGXSFXNE-UHFFFAOYSA-N 2-[4-(trifluoromethoxy)phenyl]ethanol Chemical compound OCCC1=CC=C(OC(F)(F)F)C=C1 RILZRCJGXSFXNE-UHFFFAOYSA-N 0.000 claims description 15
- 230000000855 fungicidal effect Effects 0.000 claims description 8
- 239000000417 fungicide Substances 0.000 claims description 8
- 241000233866 Fungi Species 0.000 claims description 3
- 239000003171 wood protecting agent Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 239000000203 mixture Substances 0.000 description 21
- 239000002023 wood Substances 0.000 description 19
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 17
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 239000004310 lactic acid Substances 0.000 description 8
- 235000014655 lactic acid Nutrition 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 239000004530 micro-emulsion Substances 0.000 description 5
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 150000003973 alkyl amines Chemical class 0.000 description 4
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229910000147 aluminium phosphate Chemical class 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- -1 fluoride ions Chemical class 0.000 description 2
- 239000000174 gluconic acid Substances 0.000 description 2
- 235000012208 gluconic acid Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000847 nonoxynol Polymers 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011833 salt mixture Substances 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 description 1
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 description 1
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 description 1
- 241001600095 Coniophora puteana Species 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229940058303 antinematodal benzimidazole derivative Drugs 0.000 description 1
- 150000001556 benzimidazoles Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229910001610 cryolite Inorganic materials 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/027—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements containing only one hetero ring
- C07D295/03—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements containing only one hetero ring with the ring nitrogen atoms directly attached to acyclic carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/163—Compounds of boron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/30—Compounds of fluorine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/32—Mixtures of different inorganic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/343—Heterocyclic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Paints Or Removers (AREA)
- Saccharide Compounds (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Ink Jet (AREA)
Description
Den foreliggende oppfinnelse vedrører det nye salt av N-tridecyl-2,6-dimetylmorfolin med fluorborsyre med formelen
og fungicider eller trebeskyttelsesmidler inneholdende dette samt anvendelse ved behandling av materialer som er truet eller angrepet av sopp.
Det er kjent å anvende N-tridecyl-2,6-dimetylmorfolin (tridemorf) som fungicid (Tysk patent 1 164 152). Forbindelsen viser imidlertid ingen virkning mot insekter.
Det er også kjent å anvende saltet av 2-(metoksykarbonyl-amino)-benzimidazol med fluorborsyre som fungicid i trebeskyt-telse (tysk patent 3 138 575.3). Med fluorborsyre innføres et ytterligere fungicid virkestoff i benzimidazolderivater.
Videre er det kjent å bringe vannløselige salter av fluorborsyre til omsetning med alkalidikromat i tre, og derved be-skytte treet, disse salter er altså CFB-salter i handelen.
De vannløselige salter av fluorborsyre fastholdes ikke
i treet (fikseres ikke).
De kan bare fikseres ved tilsetning av kromater i treet gjennom krom-kryolittdannelse (f.eks. Na^CrFg). Denne fluorfik-sering er imidlertid ikke fulkommen, da de frie fluoridioner først dannes fra fluorboratene i treet ved pH-verdier over pH 7, og for dette er et betydelig kromatoverskudd nødvendig. Ved de vanlige saltblandinger (ca. 33% alkalidikromat) utvaskes over 50% av fluoret med vann. Saltblandingene krever for fikse-ring dessuten 2-6 uker avhengig av klimabetingelsene, herunder kan krom (VI) vaskes ut fra treet og derved belaste omgivelsene.
Det ble nå funnet at saltet av N-tridecyl-2,6-dimetylmor-folin med fluorborsyre (HBF^) har en meget god fungicid og insekticid virkning. Det er uløselig i vann, men ved hjelp av ioniske eller ikke-ioniske emulgatorer, eventuelt under tilsetning av organiske løsningsmidler, lar emulsjonskonsentrater seg frem-stille som danner klare mikroemulsjoner i vann. Disse mikroemulsjoner kan innføres i treet ved vanlige fremgangsmåter for hånd (f.eks. påstrykning, dypping, spraying) eller industrielle fremgangsmåter (f.eks. kjeletrykkprosesser, dobbeltvakuumprosesser) og bevirker en tilstrekkelig forebyggende beskyttelse mot øde-leggende animalske og vegetabilske angrep på treet, også i det utvendige område, da det ikke utvaskes ved værpåvirkninger.
Fremstillingseksempel
Man omsetter 20 g teknisk N-tridecyl-2,6-dimetylmorfolin med 8,8 g fluorborsyre i 26,4 g vann og får en vannuløselig pastaaktig felling som frafUtreres. Etter tørking får man 38,5 g salt av N-tridecyl-2,6-dimetylmorfolin med fluorborsyre med smeltepunkt ca. 30°C.
Man kan f.eks. blande tridemorf-fluorborat med organiske løsningsmidler og ikke-ioniske emulgatorer, og emulgere blandingen i vann. Det er også mulig å nøytralisere tridemorf i blanding med dimetyl (C-|q - C^^)alkylaminer med fluorborsyre (i ekvivalent mengde med tridemorf eller i overskudd), eventuelt under tilsetning av substituerte karboksylsyrer, f.eks. melkesyre, vinsyre, gluconsyre, adipinsyre) og/eller fosforsyre eller fosfonsyre, slik at saltene av dimetylalkylaminenen virker emul-gerende på tridemorffluorboratet og danner vandige mikroemulsjoner rned vann. Diinetylakylaminsaltene kan også tilsettes i blanding med løsningsmidler eller ikke-ioniske emulgatorer til tridemorf f luorborat . Ved dimetylalkylaminets egne fungicide virkning forbedres trebeskyttelsesvirkningen til blandingen ytterligere. Det er overraskende at det nye salt kan emulgeres i vann på enkel måte, hvorunder klare mikroemulsjoner oppstår.
For å bedre korrosjonsforholdene overfor jern eller stål kan eventuelt karboksylsyrer, f.eks. isononansyre, isooktansyre eller p-tert.-butylbenzosyre tilsettes.
De følgende eksempler illustrerer blandinger som i vann kan emulgeres til mikroemulsjoner.
E ksempel 1
20% tridemorf (vektprosent)
6% fluorborsyre
18% dipropylenglykol
50% etoksylert nonylfenol (9 mol etylenoksyd pr. mol substituert fenol)
6% vann
En 10% emulsjon av blandingen i vann kan f.eks. anvendes for fremgangsmåten for hånd.
Eksempel 2
20% tridemorf
31 % dimetyl-Cj q-Cj g-alkylaminblanding
9% melkesyre
10% fluorborsyre (overskudd)
20% butylglykolacetat 10% vann
En 10% emulsjon av blandingen i vann kan f.eks. anvendes i industrielle eller prosesser for hånd.
Eksempel 3
20% tridemorf
33% dimetyl-C^g-alkylamin 12% fosforsyre
6% fluorborsyre
20% propylenglykol
9% vann
En 1,5% emulsjon av blandingen i vann kan f.eks. anvendes for industrielle fremgangsmåter.
Eksempel 4
20% tridemorf
30% dimetyl-Cj 2~alkylamin 10% etoksylert nonylfenol (9 etylenoksy pr. fenol) 10% propylenglykol 10% fluorborsyre
7% fosforsyre
I, 3% isooktansyre
II, 7% vann
En 1 - 10% emulsjon av blandingen i vann kan anvendes for industrielle eller manuelle prosesser.
Eksempel 5
20% tridemorf
30% dimetyl-C14~alkylamin 20% propylenglykol 10% fluorborsyre
5% glukonsyre
15% vann
En 1 - 10% emulsjon av blandingen i vann kan anvendes
for industrielle eller manuelle fremgangsmåter.
Eksempel 6
20% tridemorf
35% dimetylalkylaminblanding (Cj2 - C^)
11,5% fluorborsyre
22,0% melkesyre
11,5% vann
Det kan også anvendes andre karboksylsyrer, f.eks. sitron-syre, vinsyre, adipinsyre. For den enkle fremstilling av blandinger anbefales det imidlertid å anvende syrer som foreligger i flytende form i handelen (f.eks. melkesyre 90%). Slike blandinger i form av løsninger oppnås straks ved blanding av de enkelte bestanddeler. Ved krystallinske syrer (som forut nevnt) er lange røretider nødvendig for fremstilling av løsninger. Fluorborsyrer kan også foreligge i overskudd, ved diffusjon besky-tes da store områder av treet som ikke er tilgjengelige for en impregnering (kjerneved).
Det anbefales avhengig av syretilsetning og anvendelses-konsentrasjon å innstille pH på 2,0 - 5,0, fortrinnsvis 3,0 -
4,0 i blandingen.
Blandingene kan også innfarges med vannløselige kontroll-fargestoffer. Med vannuløselige fargestoffer som lar seg løse i blandingen og emulgeres med disse kan også værbestandig farging av treet oppnås.
For å bestemme ved hvilken konsentrasjon forskjellige fungicider beskytter trevirket mot angrep av soppen Coniophora puteana, er følgende eksperimenter utført:
I hvert eksperiment ble stykker av splintved impregnert
med en løsning av de forskjellige fungicider, tørket og renset grundig med vann. Trestykkene ble så infisert med soppen og deretter undersøkt for å fastslå ved hvilken konsentrasjon av fungicidet i trevirket (a) ikke var noen skade på trevirket og (b) begynnende skade på trevirket forekom. Prosentdelen som er angitt i eksperimentene er vektprosent.
Sammenligningseksempel 1
Sammensetning: (av trebeskyttelsesmiddel)
100% tridemorph (oppløst i aceton da det er uløselig i vann) .
3 3 Konsentrasjon: 1,1-2,3 kg/m (kg trebeskyttelsesmiddel pr. m
trevirke som impregneres)
Sammenligningseksempel 2
Sammensetning:
45% tridemorph
45% melkesyre
10% vann
Konsentrasjon: 7,0-10,5 kg/m 3. (s.o.)
Sammenligningseksempel 3
Sammensetning:
50% N,N-dimetyl-N-C12-C14-alkylamin
15% melkesyre
10% fluorborsyre
25% vann
Konsentrasjon: mer enn 4,5 kg/m^ (s.o.)
Eksperiment ifølge oppfinnelsen
Sammensetning:
20% tridemorph
33% N,N-dimetyl-N-<C>12<-C>14<-a>lkylamin
20% melkesyre
11% fluorborsyre
16% vann
Konsentrasjon: mindre enn 1,2 kg/m 3 (s.o.)
Sammenligningen av de oppnådde resultater i disse eksperimenter viser at fungicidet som omfatter trimorp og fluorborsyre beskytter trevirket mot soppskade ved en konsentrasjon på mindre enn 1,2 kg/m 3 (eksperiment ifølge oppfinnelsen), mens tridemorph alene eller som salt av melkesyre, eller fluorborat/melkesyresalt av en N,N-dimetyl-N-alkylamin alene bare gir beskyttelse ved mye høyere konsentrasjner (2,3-10,5 kg/m^).
Claims (3)
1. Forbindelse, karakterisert ved at den er saltet av N-tridecyl-2,6-dimetylmorfolin med fluorborsyre,
2. Fungicid eller trebeskyttelselsmiddel, karakterisert ved at det inneholder et fast eller flytende bærerstoff og saltet av N-tridecyl-2,6-dimetylmorfolin med fluorborsyre.
3. Anvendelse av saltet av N-tridecyl-2,6-dimetylmorfolin med fluorborsyre ved behandling av materialer som er truet eller angrepet av sopp.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19863605007 DE3605007A1 (de) | 1986-02-18 | 1986-02-18 | Salz eines substituierten morpholins mit fluoroborsaeure und holzschutzmittel |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| NO870623D0 NO870623D0 (no) | 1987-02-17 |
| NO870623L NO870623L (no) | 1987-08-19 |
| NO166225B true NO166225B (no) | 1991-03-11 |
| NO166225C NO166225C (no) | 1991-06-26 |
Family
ID=6294295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO870623A NO166225C (no) | 1986-02-18 | 1987-02-17 | Fluorborsyresalt av n-tridecyl-2,6-dimetylmorfolin, fungicid og trebeskyttelsesmiddel inneholdende dette, samt anvendelse derav. |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US4908362A (no) |
| EP (1) | EP0234462B1 (no) |
| JP (1) | JP2512460B2 (no) |
| AT (1) | ATE53207T1 (no) |
| AU (1) | AU585129B2 (no) |
| BR (1) | BR8700698A (no) |
| CA (1) | CA1286295C (no) |
| CS (1) | CS264346B2 (no) |
| DE (2) | DE3605007A1 (no) |
| DK (1) | DK78687A (no) |
| ES (1) | ES2015896B3 (no) |
| FI (1) | FI86058C (no) |
| GR (1) | GR3000722T3 (no) |
| MY (1) | MY102423A (no) |
| NO (1) | NO166225C (no) |
| NZ (1) | NZ219284A (no) |
| PH (1) | PH23782A (no) |
| PL (1) | PL264165A2 (no) |
| ZA (1) | ZA871130B (no) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5179116A (en) * | 1987-10-27 | 1993-01-12 | Dr. Wolman Gmbh | Wood preservatives |
| DE3736298A1 (de) * | 1987-10-27 | 1989-05-11 | Wolman Gmbh Dr | Holzschutzmittel |
| DE3839640A1 (de) * | 1988-11-24 | 1990-05-31 | Wolman Gmbh Dr | Holzschutzmittel |
| ATE188341T1 (de) * | 1991-08-01 | 2000-01-15 | Hickson Int Plc | Konservierungsmittel und verfahren zur behandlung von holz |
| US5928672A (en) * | 1996-03-28 | 1999-07-27 | Hammons; Barry D. | Polyborate composition |
| US20080063723A1 (en) * | 2006-09-08 | 2008-03-13 | Sungmee Choi | Isothiazolin-3-one-containing antimicrobial composition |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL275086A (no) * | 1961-02-22 | |||
| US3686399A (en) * | 1970-01-05 | 1972-08-22 | Basf Ag | Method of controlling fungi |
| DE2461513A1 (de) * | 1974-12-27 | 1976-07-08 | Basf Ag | Morpholinderivate |
| DE2708977A1 (de) * | 1977-03-02 | 1978-09-07 | Basf Ag | Fungizid |
| DE3138575A1 (de) * | 1981-09-28 | 1983-04-07 | Basf Ag, 6700 Ludwigshafen | Fungizid |
| EP0222694A3 (de) * | 1985-09-13 | 1987-08-26 | Ciba-Geigy Ag | Mikrobizide |
-
1986
- 1986-02-18 DE DE19863605007 patent/DE3605007A1/de not_active Withdrawn
-
1987
- 1987-02-09 US US07/012,376 patent/US4908362A/en not_active Expired - Fee Related
- 1987-02-11 PH PH34847A patent/PH23782A/en unknown
- 1987-02-12 CA CA000529597A patent/CA1286295C/en not_active Expired - Fee Related
- 1987-02-13 FI FI870623A patent/FI86058C/fi not_active IP Right Cessation
- 1987-02-14 AT AT87102114T patent/ATE53207T1/de not_active IP Right Cessation
- 1987-02-14 ES ES87102114T patent/ES2015896B3/es not_active Expired - Lifetime
- 1987-02-14 DE DE8787102114T patent/DE3762968D1/de not_active Expired - Fee Related
- 1987-02-14 EP EP87102114A patent/EP0234462B1/de not_active Expired - Lifetime
- 1987-02-16 BR BR8700698A patent/BR8700698A/pt unknown
- 1987-02-16 NZ NZ219284A patent/NZ219284A/xx unknown
- 1987-02-16 JP JP62031665A patent/JP2512460B2/ja not_active Expired - Lifetime
- 1987-02-17 MY MYPI87000163A patent/MY102423A/en unknown
- 1987-02-17 ZA ZA871130A patent/ZA871130B/xx unknown
- 1987-02-17 NO NO870623A patent/NO166225C/no unknown
- 1987-02-17 AU AU68874/87A patent/AU585129B2/en not_active Ceased
- 1987-02-17 DK DK078687A patent/DK78687A/da unknown
- 1987-02-17 CS CS871035A patent/CS264346B2/cs unknown
- 1987-02-18 PL PL1987264165A patent/PL264165A2/xx unknown
-
1990
- 1990-08-16 GR GR90400579T patent/GR3000722T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO166225C (no) | 1991-06-26 |
| US4908362A (en) | 1990-03-13 |
| NZ219284A (en) | 1989-02-24 |
| EP0234462B1 (de) | 1990-05-30 |
| FI870623A (fi) | 1987-08-19 |
| DK78687D0 (da) | 1987-02-17 |
| ZA871130B (en) | 1987-08-11 |
| JP2512460B2 (ja) | 1996-07-03 |
| PH23782A (en) | 1989-11-03 |
| ATE53207T1 (de) | 1990-06-15 |
| PL264165A2 (en) | 1988-07-07 |
| PL151373B2 (no) | 1990-08-31 |
| MY102423A (en) | 1992-06-30 |
| CA1286295C (en) | 1991-07-16 |
| NO870623D0 (no) | 1987-02-17 |
| JPS62270568A (ja) | 1987-11-24 |
| GR3000722T3 (en) | 1991-10-10 |
| AU6887487A (en) | 1987-08-20 |
| AU585129B2 (en) | 1989-06-08 |
| CS264346B2 (en) | 1989-07-12 |
| EP0234462A1 (de) | 1987-09-02 |
| CS103587A2 (en) | 1988-11-15 |
| DE3605007A1 (de) | 1987-08-20 |
| DE3762968D1 (de) | 1990-07-05 |
| FI86058C (fi) | 1992-07-10 |
| ES2015896B3 (es) | 1990-09-16 |
| DK78687A (da) | 1987-08-19 |
| FI86058B (fi) | 1992-03-31 |
| NO870623L (no) | 1987-08-19 |
| BR8700698A (pt) | 1987-12-15 |
| FI870623A0 (fi) | 1987-02-13 |
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