NO163882B - Produkt for absorpsjon av kroppsvaesker. - Google Patents
Produkt for absorpsjon av kroppsvaesker. Download PDFInfo
- Publication number
- NO163882B NO163882B NO863001A NO863001A NO163882B NO 163882 B NO163882 B NO 163882B NO 863001 A NO863001 A NO 863001A NO 863001 A NO863001 A NO 863001A NO 163882 B NO163882 B NO 163882B
- Authority
- NO
- Norway
- Prior art keywords
- compounds
- product
- liquid
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- preparation
- Prior art date
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- 239000007788 liquid Substances 0.000 title abstract 4
- 238000010521 absorption reaction Methods 0.000 title 1
- 238000002360 preparation method Methods 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 230000000749 insecticidal effect Effects 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 claims description 3
- 239000004480 active ingredient Substances 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 125000003785 benzimidazolyl group Chemical class N1=C(NC2=C1C=CC=C2)* 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 230000002745 absorbent Effects 0.000 abstract 3
- 239000002250 absorbent Substances 0.000 abstract 3
- 230000000979 retarding effect Effects 0.000 abstract 2
- 210000001124 body fluid Anatomy 0.000 abstract 1
- 239000010839 body fluid Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 230000000630 rising effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 18
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- -1 nitro, cyan, amino Chemical group 0.000 description 8
- 150000001556 benzimidazoles Chemical class 0.000 description 7
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000009736 wetting Methods 0.000 description 5
- 239000002917 insecticide Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 241001124076 Aphididae Species 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 241000255969 Pieris brassicae Species 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000003701 inert diluent Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 2
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 241000255925 Diptera Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 241000171293 Megoura viciae Species 0.000 description 2
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 2
- 241001606077 Tatochila autodice Species 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- CBQDTCDOVVBGMN-UHFFFAOYSA-N 2-methyl-3-octylphenol Chemical compound CCCCCCCCC1=CC=CC(O)=C1C CBQDTCDOVVBGMN-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- BXCSXZJKEJQDKS-UHFFFAOYSA-N 4,5,6-trichloro-2-(trifluoromethyl)-1h-benzimidazole Chemical compound ClC1=C(Cl)C=C2NC(C(F)(F)F)=NC2=C1Cl BXCSXZJKEJQDKS-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 244000178937 Brassica oleracea var. capitata Species 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- 239000005574 MCPA Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 108010009736 Protein Hydrolysates Proteins 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 description 1
- 241000219873 Vicia Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- JIJAYWGYIDJVJI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 JIJAYWGYIDJVJI-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 150000002194 fatty esters Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000002418 insect attractant Substances 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 125000006682 monohaloalkyl group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- CBFCDTFDPHXCNY-UHFFFAOYSA-N octyldodecane Natural products CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000006684 polyhaloalkyl group Chemical group 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
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- A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
- A61F13/534—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
- A61F2013/53445—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad from several sheets
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
- A61F13/534—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
- A61F13/537—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer
- A61F13/53708—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer the layer having a promotional function on liquid propagation in at least one direction
- A61F2013/53721—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer the layer having a promotional function on liquid propagation in at least one direction with capillary means
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/56—Supporting or fastening means
- A61F13/58—Adhesive tab fastener elements
- A61F2013/583—Adhesive tab fastener elements with strips on several places
Landscapes
- Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Biomedical Technology (AREA)
- Heart & Thoracic Surgery (AREA)
- Vascular Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Hematology (AREA)
- Materials Engineering (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Socks And Pantyhose (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Compounds Of Unknown Constitution (AREA)
- Undergarments, Swaddling Clothes, Handkerchiefs Or Underwear Materials (AREA)
- Gas Separation By Absorption (AREA)
- Paper (AREA)
- Pens And Brushes (AREA)
- External Artificial Organs (AREA)
- Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
- Fuses (AREA)
Abstract
Produkt for absorpsjon av kroppsvæsker som skal bæres i skrittdelen av undertøyet er tilveiebrakt. Produktet innbefatter et første absorberende lag ved den siden som vender mot kroppen og et andre absorberende lag på den siden som vender mot bekledningen. Mellom lagene er det anbrakt strømningsretar-derende innretninger for å retardere væsken som passerer fra et absorberende lag til det andre. Den væskeretarderende innretningen innbefatter ett eller flere lag av et nettverk av hydrofobe fibrer, hvor nettverket har en gjennomslagsverdi ved stigende kolonne på minst 25,4 cm vann og en luftpermeabilitet på minst 6,1 m^ pr. m^ pr. minutt.
Description
Insekticid preparat.
Foreliggende oppfinnelse angår et insekticid preparat.. Hollandsk patent nr. 64IO 413 beskriver substituerte benz-iraidazoler med den generelle formel:
hvor. X er klor, brom, nitro, cyan, amino, monoalkylamino og dialkyl-aminogrupper, R1er hydrogen, alkyl, aryl eller aralkyl, substituert eller, usubstituert, og R er en mono- eller polyhalogenalkylgruppe, og det er angitt at slike forbindelser har herbicide og biocide egen-Kfr. kl. 12p-9 og ;45 1-9/12
skaper. De definerte forbindelser er imidlertid ikke egnet for insekticid bruk.. Ifolge foreliggende oppfinnelse er det funnet at de neden-for definerte forbindelser, som har gruppen -CO(Z) R^ i 1-stillingen, er meget aktive insekticider og er egnet for kommersiell bruk som insekticider.
Foreliggende oppfinnelse angår et insekticid preparat, kjennetegnet ved at det består av eller som aktiv bestanddel inneholder et substituert benzimidazol med folgende formel:
hvor R 1 , R 2, ' R-? > og Ir å. er like eller forskjellige og er klor, brom, Ky/roj*», eller nitro, hvor minst en av disse substituenter er forskjellige fra hydrogen, og hoyst en av dem er nitro, Z er oksygen eller svovel, n er 0 eller 1, R^ er lavere alkyl, lavere alkenyl, fenyl eller fenyl-lavere alkyl, idet R-* ikke er lavere alkyl når Z er oksygen og n=l, samt salter derav.
Det insekticide preparat kan også inneholde bærestoffer, fuktende forbindelser, inerte og faste fortynningsmidler, opplSsnings-midler, spiselige forbindelser for å tiltrekke insekter, farger og fernisser. De materialtyper som kan behandles ved hjelp av preparat ets omfatter enhver type som kan forventes å bli angrepet av skadelige or-ganismer, og som eksempel kan nevnes vevede stoffer, papir og trevirke.
Dé substituerte benzimidazoler kan fremstilles ved hjelp av den generelle fremgangsmåte hvor benzimidazolet med formel I, men hvor lj-stillingen er usubstituert, omsettes med et halogenid med den generelle formel:
hvor Hal representerer et halogen som f.eks. klor, | ; i nærvær av en syreakseptor. Vanligvis utfåres reaksjonen med benzimidazol-utgangs-materialet i form av et alkalimetallsalt eller i nærvær av en organisk base.
I det tilfellet hvor Z er oksygen og n er 1, så kan reaksjonen f.eks. fremstilles slik:
hvor R 1 , R 2 , R T , å. og r *S har samme betydning som angitt ovenfor, og hvor reaksjonen egnet utfores i nærvær av en base som kaliumkarbonat og et opplosningsmiddel som f.eks. aceton.
I de tilfeller hvor n er 1 og Z er svovel, så kan reaksjonen på lignende måte fremstilles slik:
og egnet, utfores i nærvær av en base som f.eks. trietylamin.
I de tilfeller hvor n er null, så kan reaksjonen på lignende måte fremstilles slik:
og egnet uforés i nærvær av en base som f.eks. trietylamin, samt et opplOsningsmiddel som f.eks. aceton.
Det substituerte benzimidazol kan inkorporeres i insekti-cidaktive preparater på vanlig måte med eller uten fuktende forbindelser og inerte fortynningsmidler.
Hvis det er onskelig, kan de substituerte benzimidazoler
loses i et opplosningsmiddel som ikke er blandbart méd vann, .som f.eks. et hoyerekokende hydrokarbon hvor det egnet er opplost en emulgerende forbindelse, slik at hydrokarbonet virker som en selvemulgerende olje ved tilsetning til vann.
De substituerte benzimidazoler kan videre blandes med en fuktende forbindelse med eller uten et inert fortynnihgsmiddel, slik at det formes et fuktbart pulver som er opploselig eller dispergerbart i vann, eller de kan blandes med et inert opplosningsmiddel slik at det dannes et fast eller pulveraktig produkt.
De substituerte benzimidazoler og salter av disse kan inkorporeres i faste inerte fortynningsmidler i pulverisert eller oppdelt form, som f.eks. leire, sand, talkum, glimmer*, gjodningsstoffer o.l., uten hensyn til hvorvidt slike produkter er i pulverform eller består av storre partikler.
De fuktende forbindelser som kan brukes, innbefatter anion-iske.forbindelser som seper, fettsulfatestere som dpdecyl-natriumsulfat, aromatiske fettsulfonater som alkylbenzensulfonåter eller butyl-naftalensulfonat, mer komplekse fettsulfonater som amidkondensasjons-produktet av olje»isyre og N-metyltaurin eller natriumsulfat av dioktyl-succinat.
De fuktende forbindelser kan videre.; innbefatte ikke-ioniske forbindelser som f.eks. kondensasjonsproduktene av fettsyrer, fett-alkoholer eller fettsubstituerte fenoler med etylenoksyd,•eller fett-estere av sukkere eller polyalkoholer, eller de produkter som oppnås ved å kondensere de sistnevnte forbindelser med etylenoksyd, eller de" produkter som benevnes blokk kopolymere av etylenoksyd og propylen-oksyd. De fuktende forbindelser kan videre innbefatte kationiske forbindelser som f.eks. cetyl trimetylammoniumbromid og lignende.
Det insekticid aktive preparat ifolge foreliggende oppfinnelse kan videre i tillegg til de substituerte benzimidazoler eller salter av disse, inneholde andre fysiologisk aktive forbindelser som herbicider (f.eks.MCPA), insekticider (f.eks. DDT), fungicider (f.eks. kobberderivater) og snegledrepende midler. Preparatet kan videre inneholde spiselige stoffer som tiltrekker insekter, som f.eks. sukker, melasse og proteinhydrolysater, fortrinnsvis sammen med spesifike in-sekttiltrekkende midler.
De folgende eksempler er gitt for å illustrere oppfinnelsen.
Eksempel 1
Skiver (7 cm diameter) av kålblad ble penslet med 1 ml vandig acetonopplosning av etyl-4,5,6(5,6,7)triklor-2-trifluormetylbenzimida-zol-l-tiolokarboksylat med konsentrasjoner som-tilsvarte _en anvendelse av 5,6, 1.12, O.56, 0.28, 0.14, og 0.07 kg aktiv bestanddel.per hektar. Etter torking ble hver bladskive plasert i en petriskål med 9 cm diameter, infesert med ti larver av den hvite kålsdmmerfuglerf Pieris brassicae, hvoretter skålene ble dekket med et glasslokk. Det ble ut-fort tre parallelle forsok på hvert konsentrasjonsnivå. Etter 48 timer ble bladene undersokt, og man fant at alle larvene •alle konsentra-sjonsnivåer var dode. Tilsvarende larver på ubehandlede blader var helt uberorte.
Eksempel 2
En vandig suspensjon som inneholdt 1 del l-acetyl-4,5,6-tri-klor-2-trifluormetylbenzimidazol i 1000 deler vann ble fremstilt ved å fortynne en 20$ opplosning i aceton med en 0.05$ opplosning av oktyl-kresol polyetylenoksydkondensat i vann. Denne opplosning ble i en
mengde som tilsvarte 5^5 1-per hektar sproytet på unge bonneplanter
(Vicia fabae) som var angrepet av utvokste bladlus (Megoura viciae). Etter behandling bl*e plantene i 24 timer satt inn i glassbur med gass på toppen for ventilasjon, og en undersSkelse viste at alle bladlus var drept
Forbindelsene som anvendes i foreliggende preparat, er meget mer aktive enn. tilsvarende forbindelser hvor nitrogenatomet er usubstituert. LD^q for 4,5i6-.triklor-2-trifluormetylbenzimidazol anvendt på bladlus (Megoura viciae) er således f.eks. 900 deler av forbindel-. sen per 1 million del preparat, mens derimot for l-etyltiokarl?onyl-
~4>5>6-triklor-2-trifluormetylbenzimidazol er 50 deler av forbindel-
sen per 1 million del preparat. Dette betyr at den insekticide aktivitet for l-etyltiokarbonyl-4,5,6-triklor-2-trifluormetylbenzimidazol er mer enn 10 ganger storre enn den til tilsvarende forbindelse som er usubstituert i 1-stillingen.
Folgende ytterligere sammenligningsforsok viser også en slik overlegen aktivitet for forbindelsene som anvendes i foreliggende preparat:
Forsok 1 - Aktivitet mot mygg (Åedes aegyptii)
Forsok 2 - Aktivitet mot larver av hvit kålsommerfugl(Pieris brassicae) Forsok 3 - aktivitet mot larver av hvit kålsommerfugl(Pieris brassicae) Forsok 4 - Aktivitet mot mygg (Åedes aegyptii)
Claims (1)
- Insekticid preparat, karakterisert ved at det består av eller som aktiv bestanddel inneholder et substituert benzimidazol med folgende formel:12 A hvor R , R , RJ og R4" er like eller forskjellige og er hydrogen, klor, brom eller nitro, hvor minst en av disse substituenter er forskjellig fra hydrogen, og hSyst en av dem er nitro, Z er oksygen eller svovel, n er 0 eller 1, R^ er lavere alkyl, lavere alkenyl, fenyl eller fenyl-lavere alkyl, idet R^ ikke er lavere alkyl når Z er oksygen og n = 1, samt salter derav.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/760,004 US4657538A (en) | 1985-07-29 | 1985-07-29 | Panty liner with flow retarding layer |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| NO863001D0 NO863001D0 (no) | 1986-07-25 |
| NO863001L NO863001L (no) | 1987-01-30 |
| NO163882B true NO163882B (no) | 1990-04-30 |
| NO163882C NO163882C (no) | 1990-08-08 |
Family
ID=25057751
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO863001A NO163882C (no) | 1985-07-29 | 1986-07-25 | Produkt for absorpsjon av kroppsvaesker. |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US4657538A (no) |
| EP (1) | EP0211376B1 (no) |
| JP (1) | JPH0710271B2 (no) |
| CN (1) | CN1009989B (no) |
| AT (1) | ATE70714T1 (no) |
| AU (1) | AU596983B2 (no) |
| BR (1) | BR8603555A (no) |
| CA (1) | CA1277804C (no) |
| DE (1) | DE3683102D1 (no) |
| ES (1) | ES2001036A6 (no) |
| GR (1) | GR861952B (no) |
| HK (1) | HK25792A (no) |
| IE (1) | IE59554B1 (no) |
| IN (1) | IN165004B (no) |
| MX (1) | MX163459B (no) |
| MY (1) | MY101014A (no) |
| NO (1) | NO163882C (no) |
| NZ (1) | NZ216842A (no) |
| PH (1) | PH24351A (no) |
| PT (1) | PT83082B (no) |
| SG (1) | SG16292G (no) |
| ZA (1) | ZA865622B (no) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4795455A (en) * | 1987-08-31 | 1989-01-03 | Personal Products Company | Sanitary napkin pad liner |
| US4963139A (en) * | 1988-09-22 | 1990-10-16 | Mcneil-Ppc, Inc. | Absorbent body having hydrophobic insert |
| US5817079A (en) * | 1989-04-04 | 1998-10-06 | Mcneil-Ppc, Inc. | Selective placement of absorbent product materials in sanitary napkins and the like |
| US5013309A (en) * | 1989-04-24 | 1991-05-07 | Kem-Wove Incorporated | Incontinent pad with high absorbent packet |
| US5141794A (en) * | 1989-11-03 | 1992-08-25 | At&T Bell Laboratories | Superabsorbent article having relatively thin liquid absorbent portion |
| EP0548188B1 (en) * | 1990-09-12 | 1995-08-09 | The Procter & Gamble Company | Shape and adhesive fastening means for an absorbent article |
| US5429631A (en) * | 1991-10-11 | 1995-07-04 | Grenier; Dyandra | Sanitary article |
| TW354889U (en) * | 1992-05-29 | 1999-03-21 | Kimberly Clark Co | An absorbent article having a non-absorbent resilient layer |
| DE4418319C3 (de) * | 1994-05-26 | 2001-08-09 | Stockhausen Chem Fab Gmbh | Schichtförmig aufgebauter Körper zur Absorption von Flüssigkeiten sowie seine Herstellung und seine Verwendung |
| US5624423A (en) * | 1994-11-30 | 1997-04-29 | Kimberly-Clark Corporation | Absorbent article having barrier means and medial bulge |
| US5545156A (en) * | 1994-12-22 | 1996-08-13 | Kimberly-Clark Corporation | Absorbent article having a preformed member |
| US5613961A (en) * | 1994-12-30 | 1997-03-25 | Kimberly-Clark Corporation | Thin, curved absorbent article having elasticized edges |
| CA2209133C (en) * | 1995-01-10 | 2001-04-24 | The Procter & Gamble Company | Absorbent articles for fluid management |
| USH1788H (en) * | 1995-09-12 | 1999-02-02 | Christon; Patricia Lee | Multi-layer absorbent product with peel away components |
| US5599339A (en) * | 1995-10-31 | 1997-02-04 | The Procter & Gamble Company | Absorbent article |
| AU728570B2 (en) * | 1995-11-27 | 2001-01-11 | Procter & Gamble Company, The | Stacked layered absorbent products |
| USH1724H (en) * | 1995-12-01 | 1998-04-07 | Ahr; Nicholas Albert | Absorbent article having multiple backsheet members |
| US6027611A (en) * | 1996-04-26 | 2000-02-22 | Kimberly-Clark Worldwide, Inc. | Facial tissue with reduced moisture penetration |
| US6503233B1 (en) | 1998-10-02 | 2003-01-07 | Kimberly-Clark Worldwide, Inc. | Absorbent article having good body fit under dynamic conditions |
| US6562192B1 (en) | 1998-10-02 | 2003-05-13 | Kimberly-Clark Worldwide, Inc. | Absorbent articles with absorbent free-flowing particles and methods for producing the same |
| US6673982B1 (en) | 1998-10-02 | 2004-01-06 | Kimberly-Clark Worldwide, Inc. | Absorbent article with center fill performance |
| US6667424B1 (en) * | 1998-10-02 | 2003-12-23 | Kimberly-Clark Worldwide, Inc. | Absorbent articles with nits and free-flowing particles |
| CA2287699A1 (en) * | 1998-11-18 | 2000-05-18 | Nancy S. Clungeon | Soft highly absorbent paper product containing ketene dimer sizing agents |
| US6238519B1 (en) | 1998-11-18 | 2001-05-29 | Kimberly Clark Worldwide, Inc. | Soft absorbent paper product containing deactivated ketene dimer agents |
| USD426303S (en) * | 1998-12-03 | 2000-06-06 | Kimberly-Clark Worldwide, Inc. | Absorbent article |
| US6613028B1 (en) * | 1998-12-22 | 2003-09-02 | Kimberly-Clark Worldwide, Inc. | Transfer delay for increased access fluff capacity |
| USD433820S (en) * | 1999-07-19 | 2000-11-21 | Mcneil-Ppc, Inc. | Surface pattern for an absorbent article |
| USD434568S (en) * | 1999-07-19 | 2000-12-05 | Mcneil-Ppc, Inc. | Surface pattern for an absorbent article |
| USD433572S (en) * | 1999-07-19 | 2000-11-14 | Mcneil-Ppc, Inc. | Surface pattern for an absorbent article |
| US6440111B1 (en) * | 1999-09-27 | 2002-08-27 | Mcneil-Ppc, Inc. | Ultrathin fluid management article |
| JP2001190597A (ja) * | 2000-01-06 | 2001-07-17 | Uni Charm Corp | 水解性の吸収性物品 |
| US7179951B2 (en) * | 2000-06-21 | 2007-02-20 | The Procter & Gamble Company | Absorbent barrier structures having a high convective air flow rate and articles made therefrom |
| WO2001097734A2 (en) * | 2000-06-21 | 2001-12-27 | The Procter & Gamble Company | Absorbent articles with an improved ventilation |
| US7264615B2 (en) * | 2001-04-03 | 2007-09-04 | Kimberly-Clark Worldwide, Inc. | Absorbent insert for use with an outer absorbent garment |
| US20050222546A1 (en) * | 2004-04-01 | 2005-10-06 | The Procter & Gamble Company | Disposable absorbent article having refastenable side seams and a wetness sensation member |
| US6642427B2 (en) * | 2001-05-14 | 2003-11-04 | The Procter & Gamble Company | Wearable article having a temperature change element |
| US8445743B2 (en) * | 2001-11-26 | 2013-05-21 | The Procter & Gamble Company | Wearable article enhancing awareness of urination |
| US6627786B2 (en) * | 2001-11-26 | 2003-09-30 | The Procter & Gamble Company | Wearable article having a wetness sensation member |
| US6958432B2 (en) * | 2001-12-14 | 2005-10-25 | Kimberly-Clark Worldwide, Inc. | Disposable absorbent article |
| US7767876B2 (en) * | 2003-10-30 | 2010-08-03 | The Procter & Gamble Company | Disposable absorbent article having a visibly highlighted wetness sensation member |
| US7947864B2 (en) * | 2004-01-07 | 2011-05-24 | Kimberly-Clark Worldwide, Inc. | Low profile absorbent pantiliner |
| US7799169B2 (en) * | 2004-09-01 | 2010-09-21 | Georgia-Pacific Consumer Products Lp | Multi-ply paper product with moisture strike through resistance and method of making the same |
| BRPI0520734A2 (pt) * | 2005-12-09 | 2009-05-26 | Sca Hygiene Prod Ab | produto absorvente |
| FR2928383B1 (fr) * | 2008-03-06 | 2010-12-31 | Georgia Pacific France | Feuille gaufree comportant un pli en materiau hydrosoluble et procede de realisation d'une telle feuille. |
| US20100280476A1 (en) * | 2009-05-01 | 2010-11-04 | Mateo Queency D | Undergarment liners |
| US20110172627A1 (en) * | 2009-05-01 | 2011-07-14 | Mateo Queency D | Undergarment liner |
| US10646380B2 (en) * | 2016-04-01 | 2020-05-12 | Asalia Vargas | Feminine night pad |
| CN110613556A (zh) * | 2019-09-17 | 2019-12-27 | 福建恒安集团有限公司 | 一种吸收性物品的制备方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4518451A (en) * | 1982-09-02 | 1985-05-21 | Personal Products Company | Embossed panty liner |
| US4648876A (en) * | 1982-09-24 | 1987-03-10 | Personal Products Company | Breathable panty liner |
-
1985
- 1985-07-29 US US06/760,004 patent/US4657538A/en not_active Expired - Lifetime
-
1986
- 1986-07-02 IN IN494/CAL/86A patent/IN165004B/en unknown
- 1986-07-14 NZ NZ216842A patent/NZ216842A/xx unknown
- 1986-07-24 GR GR861952A patent/GR861952B/el unknown
- 1986-07-25 NO NO863001A patent/NO163882C/no unknown
- 1986-07-25 CA CA000514712A patent/CA1277804C/en not_active Expired - Fee Related
- 1986-07-28 BR BR8603555A patent/BR8603555A/pt not_active IP Right Cessation
- 1986-07-28 ES ES8600632A patent/ES2001036A6/es not_active Expired
- 1986-07-28 JP JP61175820A patent/JPH0710271B2/ja not_active Expired - Lifetime
- 1986-07-28 DE DE8686110400T patent/DE3683102D1/de not_active Expired - Lifetime
- 1986-07-28 EP EP86110400A patent/EP0211376B1/en not_active Expired - Lifetime
- 1986-07-28 IE IE200686A patent/IE59554B1/en not_active IP Right Cessation
- 1986-07-28 AT AT86110400T patent/ATE70714T1/de not_active IP Right Cessation
- 1986-07-28 PT PT83082A patent/PT83082B/pt active IP Right Grant
- 1986-07-28 AU AU60629/86A patent/AU596983B2/en not_active Ceased
- 1986-07-28 ZA ZA865622A patent/ZA865622B/xx unknown
- 1986-07-29 MX MX3288A patent/MX163459B/es unknown
- 1986-07-29 CN CN86105559A patent/CN1009989B/zh not_active Expired
- 1986-07-29 PH PH34080A patent/PH24351A/en unknown
-
1987
- 1987-09-04 MY MYPI87001551A patent/MY101014A/en unknown
-
1992
- 1992-02-19 SG SG162/92A patent/SG16292G/en unknown
- 1992-04-09 HK HK257/92A patent/HK25792A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MX163459B (es) | 1992-05-18 |
| JPS6227950A (ja) | 1987-02-05 |
| ZA865622B (en) | 1988-03-30 |
| CA1277804C (en) | 1990-12-18 |
| ES2001036A6 (es) | 1988-04-16 |
| AU596983B2 (en) | 1990-05-24 |
| CN86105559A (zh) | 1987-01-28 |
| NO863001L (no) | 1987-01-30 |
| MY101014A (en) | 1991-06-29 |
| EP0211376A3 (en) | 1988-07-27 |
| PT83082A (pt) | 1987-01-26 |
| BR8603555A (pt) | 1987-03-04 |
| IN165004B (no) | 1989-07-29 |
| IE862006L (en) | 1987-01-29 |
| GR861952B (en) | 1986-11-25 |
| PH24351A (en) | 1990-06-13 |
| HK25792A (en) | 1992-04-16 |
| NO863001D0 (no) | 1986-07-25 |
| NO163882C (no) | 1990-08-08 |
| IE59554B1 (en) | 1994-03-09 |
| SG16292G (en) | 1992-04-16 |
| US4657538A (en) | 1987-04-14 |
| EP0211376A2 (en) | 1987-02-25 |
| ATE70714T1 (de) | 1992-01-15 |
| CN1009989B (zh) | 1990-10-17 |
| NZ216842A (en) | 1989-08-29 |
| EP0211376B1 (en) | 1991-12-27 |
| DE3683102D1 (de) | 1992-02-06 |
| PT83082B (pt) | 1994-07-29 |
| JPH0710271B2 (ja) | 1995-02-08 |
| AU6062986A (en) | 1987-02-05 |
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