NO157362B - BACTERICIDE AND FUNGICIDE EFFECT AND USE OF ITS. - Google Patents
BACTERICIDE AND FUNGICIDE EFFECT AND USE OF ITS. Download PDFInfo
- Publication number
- NO157362B NO157362B NO821845A NO821845A NO157362B NO 157362 B NO157362 B NO 157362B NO 821845 A NO821845 A NO 821845A NO 821845 A NO821845 A NO 821845A NO 157362 B NO157362 B NO 157362B
- Authority
- NO
- Norway
- Prior art keywords
- weight
- compounds
- cyclohexyl
- dimethyl
- acid amide
- Prior art date
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 7
- 230000000855 fungicidal effect Effects 0.000 title claims description 5
- 239000003899 bactericide agent Substances 0.000 title abstract description 4
- 239000000417 fungicide Substances 0.000 title abstract 3
- 230000000694 effects Effects 0.000 title description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- QTDRLOKFLJJHTG-UHFFFAOYSA-N Furmecyclox Chemical compound C1=C(C)OC(C)=C1C(=O)N(OC)C1CCCCC1 QTDRLOKFLJJHTG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 4
- SBXWFLISHPUINY-UHFFFAOYSA-N triphenyltin Chemical class C1=CC=CC=C1[Sn](C=1C=CC=CC=1)C1=CC=CC=C1 SBXWFLISHPUINY-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000002023 wood Substances 0.000 claims description 8
- 241000894006 Bacteria Species 0.000 claims description 6
- 241000233866 Fungi Species 0.000 claims description 4
- 239000013543 active substance Substances 0.000 abstract description 2
- 230000003115 biocidal effect Effects 0.000 description 4
- 230000002538 fungal effect Effects 0.000 description 4
- 244000005700 microbiome Species 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- LHHPEAQVCCPLBC-UHFFFAOYSA-N tributyltin;hydrate Chemical compound O.CCCC[Sn](CCCC)CCCC LHHPEAQVCCPLBC-UHFFFAOYSA-N 0.000 description 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-M 9-cis,12-cis-Octadecadienoate Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O OYHQOLUKZRVURQ-HZJYTTRNSA-M 0.000 description 1
- 241000228212 Aspergillus Species 0.000 description 1
- 241000223261 Trichoderma viride Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229940049918 linoleate Drugs 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000001967 plate count agar Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- DBGVGMSCBYYSLD-UHFFFAOYSA-N tributylstannane Chemical compound CCCC[SnH](CCCC)CCCC DBGVGMSCBYYSLD-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003171 wood protecting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
- A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
- A01N55/04—Tin
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/343—Heterocyclic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/38—Aromatic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
Abstract
Description
Denne, oppfinnelse angår et middel som har baktericide This invention relates to an agent that has a bactericide
og fungicide egenskaper, og som egner seg som desinfeksjons-middel, som trebeskyttelsesmiddel, som middel til å gi tekstiler, kunststoffer og bygningsmaterialer baktericide og fungicide egenskaper, som konserveringsmiddel og for å. and fungicidal properties, and which is suitable as a disinfectant, as a wood preservative, as a means of giving textiles, plastics and building materials bactericidal and fungicidal properties, as a preservative and for
gjøre belegningssystemer biocide. Oppfinnelsen angår også anvendelse av midlet for beskyttelse av trevirke mot bakterier og fungi. make coating systems biocidal. The invention also relates to the use of the agent for the protection of wood against bacteria and fungi.
Den store virkning av triorganotinnforbindelser mot mikroorganismer, f.eks. skadelige sopper og bakterier, er velkjent. Den optimale virkning av forbindelsene i denne klasse oppnåes når det totale antall C-atomer i de til tinn bundne alkylgrupper er fra 9 til 12. Kortere eller lengre grupper forringer den biocide virkning. Riktignok oppviser triorganotinnforbindelser et relativt bredt virknings-spektrum, men overfor forskjellige mikroorganismer såsom f.eks. gramnegative bakterier og bestemte blåsopper, er imidlertid virkningen forholdsvis svak. The great effect of triorganotin compounds against microorganisms, e.g. harmful fungi and bacteria, is well known. The optimal effect of the compounds in this class is achieved when the total number of C atoms in the alkyl groups bound to tin is from 9 to 12. Shorter or longer groups impair the biocidal effect. Admittedly, triorganotin compounds exhibit a relatively broad spectrum of action, but against various microorganisms such as e.g. Gram-negative bacteria and certain blue fungi, however, the effect is relatively weak.
Forbindelsen 2,5-dimethyl-N-cyclohexyl-N-methoxy-3-furan-carboxylsyreamid, som likeledes er kjent for å hå biocid virkning, oppviser god virkning mot en rekke sopparter som ødelegger trevirke. Mot bakterier og bestemte sopparter, f.eks. Cladosporum herbarum, Trichoderma viride og enkelte Asper-gillus-arter oppviser imidlertid denne forbindelse knapt noen virkning eller bare en svak virkning. The compound 2,5-dimethyl-N-cyclohexyl-N-methoxy-3-furan-carboxylic acid amide, which is also known to have a biocidal effect, shows a good effect against a number of fungal species that destroy wood. Against bacteria and specific fungal species, e.g. Cladosporum herbarum, Trichoderma viride and certain Aspergillus species, however, show this compound hardly any effect or only a weak effect.
Det har nu overraskende vist seg at kombinasjoner av visse triorganotinnforbindelser og 2,5-dimethyl-N-cyclohexyl-N-meth-oxy-3-furancarboxylsyreamid oppviser en synergistisk virkning overfor mikroorganismer. It has now surprisingly been shown that combinations of certain triorganotin compounds and 2,5-dimethyl-N-cyclohexyl-N-meth-oxy-3-furancarboxylic acid amide exhibit a synergistic effect against microorganisms.
Med basis i denne erkjennelse tilveiebringes det nu Based on this recognition, it is now provided
i henhold til oppfinnelsen et nytt middel med baktericid og fungicid virkning, som er særpreget ved at det består av eller inneholder en blanding av: according to the invention, a new agent with bactericidal and fungicidal action, which is characterized by the fact that it consists of or contains a mixture of:
(a) trialkyltinnforbindelser med et totalt antall C-atomer (a) trialkyltin compounds with a total number of C atoms
i de til tinn bundne alkylgrupper på 9-12, eller trifenyl-tinnforbindelser og (b) 2,5-dimethyl-N-cyclohexyl-N-methoxy-3-furancarboxylsyre-amid . in the tin-bonded alkyl groups of 9-12, or triphenyltin compounds and (b) 2,5-dimethyl-N-cyclohexyl-N-methoxy-3-furancarboxylic acid amide.
Fortrinnsvis inneholder midlet de to komponenter i Preferably, the agent contains the two components i
et vektforhold på fra 4:1 til 1:4, aller helst fra 2:1 til 1:2. a weight ratio of from 4:1 to 1:4, most preferably from 2:1 to 1:2.
Det nye middel ifølge oppfinnelsen utvider i betydelig grad virkningsspektret for de enkelte forbindelser og for-sterker den hemmende virkning overfor mikroorganismer, mot hvilke forbindelser også enkeltvis oppviser en god virkning (se tabeller 1-4). The new agent according to the invention significantly expands the spectrum of action for the individual compounds and strengthens the inhibitory effect against microorganisms, against which compounds also individually show a good effect (see tables 1-4).
Midlet ifølge oppfinnelsen er spesielt anvendelig for beskyttelse av trevirke, idet man her også oppnår en beskyttelse mot bakterieangrep i tillegg til at nedbygning av trevirket gjennom soppangrep forhindres. Bakterier bevirker ingen nedbygning av treet, men de kan skape gunstige forhold for soppangrep. The agent according to the invention is particularly useful for the protection of wood, as protection against bacterial attack is also achieved here, in addition to preventing degradation of the wood through fungal attack. Bacteria do not cause any degradation of the wood, but they can create favorable conditions for fungal attack.
Midlet blir i form av oppløsninger, eventuelt inneholdende farve- og hjelpestoffer, innført i trevirket ved påstrykning eller påsprutning. The agent is introduced into the wood in the form of solutions, possibly containing dyes and additives, by brushing or spraying.
Dessuten kan midlet ifølge oppfinnelsen anvendes for å gi tekstiler, kunststoffer og bygningsmaterialer biocide egenskaper, i hvilket tilfelle det er hensiktsmessig å anvende midlet i form av en oppløsning, emulsjon eller dispersjon, med eller uten bindemiddel eller med faste bærerstoffer eller fortynningsmidler og eventuelt med tilsetning av tverr-bindingsmidler, heftemidler, emulgeringsmidler og disper-geringshjelpemidler. In addition, the agent according to the invention can be used to give textiles, plastics and building materials biocidal properties, in which case it is appropriate to use the agent in the form of a solution, emulsion or dispersion, with or without a binder or with solid carriers or diluents and possibly with addition of cross-linking agents, adhesives, emulsifiers and dispersing aids.
Konsentrasjonen av aktivt stoff ligger vanligvis i om-rådet fra 0,1 til 5% og bestemmes av de krav som anvendelsen stiller. The concentration of active substance is usually in the range from 0.1 to 5% and is determined by the requirements of the application.
Eksempel 1 Example 1
Et farveløst, ikke bindemiddelholdig preparat, bestående av: A colourless, binder-free preparation, consisting of:
2 vektdeler tri-n-butyltinnlinoleat 2 parts by weight of tri-n-butyltin linoleate
2 vektdeler 2,5-dimethyl-N-cyclohexyl-N-methoxy-3-furan-carboxy1syreamid 2 parts by weight 2,5-dimethyl-N-cyclohexyl-N-methoxy-3-furan-carboxyl-acid amide
6 vektdeler diethylenglycolmonobutylether 6 parts by weight of diethylene glycol monobutyl ether
90 vektdeler høytkokende testbensin (Krystallolje 60) 90 parts by weight of high-boiling test petrol (Crystal oil 60)
oppviser god gjennomtrengningsevne og kan anvendes f.eks. exhibits good penetration and can be used e.g.
som en grunning for trevirke for byggeformål. as a primer for wood for construction purposes.
Eksempel 2 Example 2
Et preparat (farvet lasur) bestående av A preparation (colored glaze) consisting of
1,3 vektdeler tri-n-butyltinnoxyd 1.3 parts by weight of tri-n-butyltin oxide
2,2 vektdeler 2,5-dimethyl-N-cyclohexyl-N-methoxy-3-furancarboxy1syreamid 2.2 parts by weight of 2,5-dimethyl-N-cyclohexyl-N-methoxy-3-furancarboxylic acid amide
30 vektdeler alkydharpiks ("Synthalat MF 620", 60%-ig] 30 parts by weight alkyd resin ("Synthalat MF 620", 60%]
0,5 vektdel sikkativ 0.5 part by weight siccative
0,5 vektdel antiavsetningsmiddel 0.5 part by weight anti-deposition agent
8,5 vektdeler jernoxydrødt-pasta 8.5 parts by weight iron oxide red paste
1,5 vektdeler jernoxydsvart-pasta 1.5 parts by weight of iron oxide black paste
5 vektdeler diethylenglycolmonobutylether 5 parts by weight diethylene glycol monobutyl ether
50,5 vektdeler høytkokende testbensin (Krystallolje 60) egner seg til bestrykning av vindusrammer, dører, trefor-skalinger, osv. 50.5 parts by weight of high-boiling test petrol (Krystal oil 60) is suitable for coating window frames, doors, wooden linings, etc.
Eksempel 3 Example 3
15 vektdeler tri^n-butyltinnoxyd- 15 parts by weight of tri-n-butyltin oxide
15 vektdeler 2,5-dimethyl-N-cyclohexyl-N-methoxy-3-furancarboxylsyreamid 70 vektdeler ikke-ionogen emulgator ("Marlomet ISM") Den klare blanding gir fortynnet med vann i mengdeforhold fra 1:5 til 1:30 stabile emulsjoner som kan påføres for beskyttelse av nyfelt trevirke ved påstrykning, påsprøytning eller neddykning. 15 parts by weight 2,5-dimethyl-N-cyclohexyl-N-methoxy-3-furancarboxylic acid amide 70 parts by weight non-ionic emulsifier ("Marlomet ISM") The clear mixture, diluted with water in a ratio of 1:5 to 1:30, gives stable emulsions which can be applied to protect newly felled timber by brushing, spraying or immersion.
TABELL 1 TABLE 1
For sammenligning av virkningen ble papirrundfiltere (0 For comparison of the effect, paper round filters (0
5,5 cm) gjennomtrukket med de i det følgende nærmere angitte ethanoliske oppløsninger, tørret i luft og deretter anbragt i petriskåler, på Plate-count-Agar" som var blitt podet med bakteriesuspensjoner, og inkubert i 2 dager ved +37°C. Deretter ble størrelsen av hemningssonene rundt filteret bestemt: 5.5 cm) permeated with the following ethanolic solutions, dried in air and then placed in Petri dishes, on Plate-count-Agar" which had been inoculated with bacterial suspensions, and incubated for 2 days at +37°C. Then the size of the inhibition zones around the filter was determined:
Claims (3)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19813122270 DE3122270A1 (en) | 1981-06-04 | 1981-06-04 | BACTERICIDAL AND FUNGICIDAL AGENT |
Publications (3)
Publication Number | Publication Date |
---|---|
NO821845L NO821845L (en) | 1982-12-06 |
NO157362B true NO157362B (en) | 1987-11-30 |
NO157362C NO157362C (en) | 1988-03-09 |
Family
ID=6133943
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO821845A NO157362C (en) | 1981-06-04 | 1982-06-03 | BACTERICIDE AND FUNGICIDE EFFECT AND USE OF ITS. |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0066764B1 (en) |
AT (1) | ATE12160T1 (en) |
DE (2) | DE3122270A1 (en) |
DK (1) | DK158537C (en) |
NO (1) | NO157362C (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3139252A1 (en) * | 1981-10-02 | 1983-04-21 | Basf Ag, 6700 Ludwigshafen | WOOD PRESERVATIVES |
DE3522788A1 (en) * | 1985-06-26 | 1987-01-08 | Schering Ag | BIOCIDAL COMBINATION OF ACTIVE SUBSTANCES |
DE202008000452U1 (en) * | 2008-01-11 | 2009-05-28 | Parkett Leuthe Gmbh | Hallway made of old wood |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1593305A (en) * | 1967-11-22 | 1970-05-25 | ||
DE2830503A1 (en) * | 1978-07-12 | 1980-01-24 | Solvay Werke Gmbh | AGENTS FOR THE PRESERVATION OF WOOD AND WOOD MATERIALS |
DE2927349A1 (en) * | 1979-07-06 | 1981-01-29 | Solvay Werke Gmbh | AGENT FOR THE PRESERVATION OF WOOD AND WOOD MATERIALS AND METHOD FOR THE PRODUCTION OF THE PRESERVATIVE AGENT |
DE3004249A1 (en) * | 1980-02-06 | 1981-08-13 | Desowag-Bayer Holzschutz GmbH, 4000 Düsseldorf | WOOD PROTECTIVE CONCENTRATE AND PRODUCT MADE THEREOF FOR THE PRESERVATION OF WOOD AND WOOD MATERIALS |
DE3014194A1 (en) * | 1980-04-14 | 1981-10-22 | Dr. Wolman Gmbh, 7573 Sinzheim | AQUEOUS WOOD PRESERVATIVE |
-
1981
- 1981-06-04 DE DE19813122270 patent/DE3122270A1/en not_active Withdrawn
-
1982
- 1982-05-22 AT AT82104499T patent/ATE12160T1/en not_active IP Right Cessation
- 1982-05-22 DE DE8282104499T patent/DE3262623D1/en not_active Expired
- 1982-05-22 EP EP82104499A patent/EP0066764B1/en not_active Expired
- 1982-06-03 NO NO821845A patent/NO157362C/en unknown
- 1982-06-03 DK DK249882A patent/DK158537C/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DK158537C (en) | 1990-11-12 |
DK249882A (en) | 1982-12-05 |
NO157362C (en) | 1988-03-09 |
ATE12160T1 (en) | 1985-04-15 |
DE3122270A1 (en) | 1982-12-23 |
NO821845L (en) | 1982-12-06 |
EP0066764B1 (en) | 1985-03-20 |
DE3262623D1 (en) | 1985-04-25 |
EP0066764A1 (en) | 1982-12-15 |
DK158537B (en) | 1990-06-05 |
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