NO151706B - N-PHOSPHONOMETHYLGYLINE COMPOUNDS WITH HERBICIDE EFFECT AND USE thereof IN HERBICIDE PREPARATIONS - Google Patents
N-PHOSPHONOMETHYLGYLINE COMPOUNDS WITH HERBICIDE EFFECT AND USE thereof IN HERBICIDE PREPARATIONS Download PDFInfo
- Publication number
- NO151706B NO151706B NO773960A NO773960A NO151706B NO 151706 B NO151706 B NO 151706B NO 773960 A NO773960 A NO 773960A NO 773960 A NO773960 A NO 773960A NO 151706 B NO151706 B NO 151706B
- Authority
- NO
- Norway
- Prior art keywords
- ozone
- air
- cooling battery
- cooling
- chamber
- Prior art date
Links
- 230000000694 effects Effects 0.000 title description 2
- 230000002363 herbicidal effect Effects 0.000 title 2
- 239000004009 herbicide Substances 0.000 title 2
- 150000001875 compounds Chemical class 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 32
- 238000001816 cooling Methods 0.000 claims description 25
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000007789 gas Substances 0.000 description 5
- 230000008878 coupling Effects 0.000 description 4
- 238000010168 coupling process Methods 0.000 description 4
- 238000005859 coupling reaction Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4084—Esters with hydroxyaryl compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing aromatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Description
Anordning for fremstilling av ozon. Device for producing ozone.
Foreliggende oppfinnelse angår en anordning for fremstilling av ozon under an-vendelse av en ozongenerator som inneholder to elektroder som er koblet til en strømkilde og mellom hvilke det er ut-formet en forholdsvis trang gjennomstrøm-ningskanal som tjener som utladningsrom. Mellom elektrodene påtrykkes en forholds- The present invention relates to a device for the production of ozone using an ozone generator which contains two electrodes which are connected to a current source and between which a relatively narrow through-flow channel is formed which serves as a discharge space. Between the electrodes, a relative
vis høy spenning, eksempelvis 10—20 kV og når luft eller annen gass som inneholder surstoff ledes gjennom kanalen mellom elektrodene bevirker denne høyspenning en glim-utladning hvorved en del av sur-stoffet omdannes til ozon. Den ozongenerator som forekommer oftest, er av såkalt rørtype og består av to sylindriske elektro- show high voltage, for example 10-20 kV and when air or other gas containing oxygen is passed through the channel between the electrodes, this high voltage causes a flash discharge whereby part of the oxygen is converted into ozone. The ozone generator that occurs most often is of the so-called tube type and consists of two cylindrical electro-
der hvorav den ene med et mellomrom omgir den annen konsentrisk. Et sylindrisk dielektrikum som i alminnelighet funge- where one of them with a space surrounds the other concentrically. A cylindrical dielectric that generally functions
rer som bærer for den ene elektrode opp- rer as a carrier for one electrode up-
tar herunder en del av det ringformete mellomrom mens den gjenværende del dan- takes up part of the annular space, while the remaining part forms
ner glim-utladningsrommet. down the glimmer discharge room.
For å utvinne ozon med tilfredsstillen- To extract ozone satisfactorily
de utbytte er det nødvendig å anvende tørr luft. Tørkingen foregår nå i alminnelig- those yielded, it is necessary to use dry air. The drying now takes place in general
het ved kjøling av luften slik at den fuk-tighet som forekommer fjernes ved ut-frysing. Da ozon er temmelig ustabil alle- hot by cooling the air so that the moisture that occurs is removed by freezing. Since ozone is rather unstable all-
rede ved ubetydelig forhøyede temperatu- ready at slightly elevated temperatures
rer er ozonutbyttet dessuten i høy grad av-hengig av at temperaturen holdes så lav som mulig i generatoren. Elektrodene ut-settes selvsagt for en sterk oppvarming under utladningen og de oppvarmer der- rer, the ozone yield is also highly dependent on the temperature being kept as low as possible in the generator. The electrodes are of course exposed to a strong heating during the discharge and they heat up
ved igjen den luft som passerer. For å ned-sette ulempene er det tidligere kjent å la kold luft passere gjennom utladningsrom- by again the air that passes. In order to reduce the disadvantages, it is previously known to allow cold air to pass through the discharge chamber
met, samtidig som ozongeneratoren kjøles utvendig med kjølevann eller kjølet luft. Hittil har det dog ikke i praktisk drift vært mulig med rimelige omkostninger å senke temperaturen så lavt at det er opp-nådd noen særlig betydelig økning av ozon-konsentrasjonen i den gassblanding som forlater generatoren. met, while the ozone generator is cooled externally with cooling water or chilled air. Until now, however, it has not been possible in practical operation at reasonable costs to lower the temperature so low that a particularly significant increase in the ozone concentration in the gas mixture leaving the generator has been achieved.
Foreliggende oppfinnelse som bygger Present invention that builds
på de prinsipper som er angitt ovenfor, on the principles set out above,
går ut på å gjøre det mulig å foreta en effektiv og økonomisk kjøling av ozongeneratoren, samtidig som det utvinnes en gass-blanding med høy ozon-konsen-trasjon. involves making it possible to carry out efficient and economical cooling of the ozone generator, while at the same time extracting a gas mixture with a high ozone concentration.
Ved at den kjøleluftmengde som ikke suges inn i ozongeneratoren, hele tiden sirkulerer går det ikke tapt noen særlig kjøleeffekt, og kjøleluften kan derfor gis så stort volum at den varme som avgis av elektrodene, bevirker en ganske rimelig temperaturforhøyelse. Generatoren hol- As the amount of cooling air that is not sucked into the ozone generator constantly circulates, no particular cooling effect is lost, and the cooling air can therefore be given such a large volume that the heat given off by the electrodes causes a fairly reasonable increase in temperature. The generator hol-
des på denne måten effektivt nedkjølet slik at den luft som passerer gjennom utladningsrommet, får en høy ozonkonsentra- is effectively cooled in this way so that the air that passes through the discharge room has a high ozone concentration
sjon. Som eksempel kan nevnes at den luft som kommer fra kjøleanlegget, kan ha en temperatur mellom 4-10 og -4-15°C, og av denne luft kan eksempelvis 2—5 pst. tas ut gjennom generatoren mens resten av kjøle-luftmengden får sirkulere. Temperaturen i generatorens reaksjonsrom kan under tion. As an example, it can be mentioned that the air coming from the cooling system can have a temperature between 4-10 and -4-15°C, and of this air, for example, 2-5 per cent can be taken out through the generator, while the rest of the cooling air quantity gets circulate. The temperature in the generator's reaction room can drop below
slike forhold ligge på ca. 0°C, i hvertfall under +10°C. Ved tidligere fremstilling av ozon har det som regel ikke vært mulig å unngå en temperatur på 20—30°C i reak-sjonsrommet, slik at ozonutbyttet ble til-svarende dårligere. such conditions lie at approx. 0°C, in any case below +10°C. In previous production of ozone, it has usually not been possible to avoid a temperature of 20-30°C in the reaction room, so that the ozone yield was correspondingly worse.
Oppfinnelsen omfatter således en anordning for fremstilling av ozon og anordningen består av en eller flere ozongenera-torer som hver for seg inneholder to elektroder som er koblet til en strømkilde og mellom hvilke det finnes en forholdsvis trang gjennomstrømningskanal som tjener som utladningsrom og hvis ene ende er åpen mens den annen ende kan forbindes med et forbrukssted gjennom en ledning. Det særegne ved oppfinnelsen består i at ozongeneratorene og et kjølebatteri er byg-get inn i to adskilte, fortrinnsvis varmeisolerte kammere som står i forbindelse med hverandre gjennom to kanaler som er anordnet ved hver sin ende av kjølebatte-riet, at en vifte er innrettet til å bringe en luftstrøm til å sirkulere gjennom de to kammere, og at kjølebatterikammeret dessuten står i forbindelse med den ytre luft gjennom en åpning som befinner seg i avstand fra de nevnte kanaler. The invention thus includes a device for the production of ozone and the device consists of one or more ozone generators that each contain two electrodes that are connected to a current source and between which there is a relatively narrow flow channel that serves as a discharge chamber and one end of which is open while the other end can be connected to a point of consumption through a wire. The peculiarity of the invention is that the ozone generators and a cooling battery are built into two separate, preferably heat-insulated chambers that are connected to each other through two channels arranged at each end of the cooling battery, that a fan is arranged to to cause a current of air to circulate through the two chambers, and that the cooling battery chamber is also in communication with the external air through an opening located at a distance from the said channels.
På vedføyete tegning viser fig. 1 skje-matisk en utførelsesform for anordningen i henhold til oppfinnelsen i loddrett snitt, mens fig. 2 og 3 viser loddrette snitt gjennom øvre henhv. nedre ende av en ozongenerator av rørtypen. The attached drawing shows fig. 1 schematically shows an embodiment of the device according to the invention in a vertical section, while fig. 2 and 3 show vertical sections through the upper or lower end of a tube-type ozone generator.
I fig. 1 betegner 4 et hus som ved hjelp av en loddrett og en vannrett skillevegg 5 henhv. 6 er delt i tre kammere 7, 8, 9 hvorav det ene 7 omslutter et antall ozon-generatorer 10, i den viste utførelse 2 styk-ker, samt en høyspenningstransformator 11. Kammeret 8 inneholder en kjølekom-pressor 12 som gjennom rørledninger 13, 14 er koblet til et kjølebatteri 15 som er innbygget i kammeret 9. Kamrene 7 og 9 er fortrinnsvis varmeisolerte, og kammeret 9 har øverst en åpning 16 hvorigjen-nom det står i forbindelse med den ytre luft. In fig. 1 denotes 4 a house which by means of a vertical and a horizontal dividing wall 5 respectively. 6 is divided into three chambers 7, 8, 9, one of which 7 encloses a number of ozone generators 10, in the shown embodiment 2 pieces, as well as a high-voltage transformer 11. The chamber 8 contains a cooling compressor 12 which through pipelines 13, 14 is connected to a cooling battery 15 which is built into the chamber 9. The chambers 7 and 9 are preferably thermally insulated, and the chamber 9 has an opening 16 at the top through which it is in contact with the outside air.
Kjølebatteriet 15 har en loddrett gjen-nomstrømningskanal 17 hvis nedre ende er åpen. Fra den øvre ende av kanalen 17 går det ut en kanal 18 som munner ut i den øvre del av generatorkammeret 7. En vifte 19 som er anbragt i kanalen 18, suger luft oppover gjennom kjølekanalen og fører den kjølte luft inn i kammeret 7. Fra den nedre del av generatorkammeret 7 går det ut en loddrett kanal 20 som munner ut i kjølebatterikammeret 9 like ved innløps-enden for kanalen 17. The cooling battery 15 has a vertical through-flow channel 17 whose lower end is open. From the upper end of the channel 17, a channel 18 exits which opens into the upper part of the generator chamber 7. A fan 19, which is placed in the channel 18, sucks air upwards through the cooling channel and leads the cooled air into the chamber 7. From in the lower part of the generator chamber 7, a vertical channel 20 exits which opens into the cooling battery chamber 9 close to the inlet end of the channel 17.
Ozongeneratorene 10, som fortrinnsvis er av rørtypen, har sine ytre og indre elektroder koblet til høyspenningstrans-formatoren 11 gjennom ledninger 21 henhv. 22. Den ytre elektrode kan bestå av et metallbelegg 23 på et glassrør 24 som tjener som dielektrikum, mens den indre elektrode kan utgjøres av et aluminiumrør 25, fig. 2 og 3. De to ender av det indre rør er lukket ved hjelp av lokk 26 som holdes fast ved hjelp av muttere 27 som er skrudd inn på endene av en forbindelsesstang 28 som går aksialt gjennom røret og er ført ut gjennom sentrumhull i lokkene. En utvendig gjenget hylse 29 er tredd på hver av endene av ytterrøret 24 og en innven-dig gjenget koblingshylse 30 er under inn-legg av en tetningsring 31 som griper inn mot glassrøret 24 skrudd på hylsen 29. Det indre rør 25 er fastholdt koaksialt i det ytre rør ved at de to endelokk 26 har utvendig gjengete kantflenser 32 som er skrudd inn i koblingshylsene 30. På denne måten holdes hele ozongeneratoren sam-men ved hjelp av enkle midler, slik at den ved behov lett kan demonteres for eventuelt utskifting av deler. For at luften skal kunne strømme gjennom det ringformete mellomrom 33 mellom det ytre rør 24 og det indre rør 25 er kantflensene 32 på lokkene forsynt med et stort antall perforeringer eller utsparinger 34. Eventuelt kan flen-sene være utført som en tanning rundt lokkene. Koblingshylsene må naturligvis være av isolasjonsmaterial, hensiktsmessig plast. The ozone generators 10, which are preferably of the tube type, have their outer and inner electrodes connected to the high-voltage transformer 11 through lines 21 or 22. The outer electrode can consist of a metal coating 23 on a glass tube 24 which serves as a dielectric, while the inner electrode can consist of an aluminum tube 25, fig. 2 and 3. The two ends of the inner tube are closed by means of lids 26 which are held in place by means of nuts 27 which are screwed onto the ends of a connecting rod 28 which passes axially through the tube and is led out through central holes in the lids. An externally threaded sleeve 29 is threaded onto each of the ends of the outer tube 24 and an internally threaded coupling sleeve 30 is fitted with a sealing ring 31 which engages against the glass tube 24 screwed onto the sleeve 29. The inner tube 25 is held coaxially in the outer tube in that the two end caps 26 have externally threaded edge flanges 32 which are screwed into the coupling sleeves 30. In this way, the entire ozone generator is held together by means of simple means, so that it can be easily dismantled if necessary for possible replacement of parts . In order for the air to be able to flow through the annular space 33 between the outer tube 24 and the inner tube 25, the edge flanges 32 on the lids are provided with a large number of perforations or recesses 34. Optionally, the flanges can be designed as a tan around the lids. The connection sleeves must of course be made of insulating material, suitable plastic.
Koblingshylsene 30 ved de nedre ender av generatorene er festet til knekter 35, fig. 3, som rager ut fra den ene vegg i kammeret 7. De øvre koblingshylser 30 er tettende forbundet med en felles samle-kasse 36 hvorfra en rørledning 37 går til sugesiden på en pumpe som ikke er vist og som er innrettet til å føre ozongass-blandingen videre til et forbrukssted. The coupling sleeves 30 at the lower ends of the generators are attached to jacks 35, fig. 3, which protrudes from one wall of the chamber 7. The upper coupling sleeves 30 are sealingly connected to a common collection box 36 from which a pipeline 37 goes to the suction side of a pump which is not shown and which is designed to carry ozone gas the mixture further to a point of consumption.
Som det i det vesentlige allerede frem-går av det som er sagt ovenfor, virker denne anordning slik at viften 19 bringer luft til å passere gjennom kjølebatteriet inn i den øvre del av kammeret 7 hvor luften som eksempelvis er nedkjølet til -=-10 eller + 15°C, synker nedover under spyling rundt elektroderørene 23, 24. En mindre brøkdel av luften suges inn i utladningsrommene 33 mellom elektrodene 23, 25 for, etter ozondannelse å strømme ut gjennom ledningen 37, mens den største del av luften føres tilbake til kjølebatterikammeret 9 gjennom kanalen 20. Gjennom åpningen 16 suges frisk luft inn i en mengde som As is essentially already clear from what has been said above, this device works so that the fan 19 brings air to pass through the cooling coil into the upper part of the chamber 7 where the air, which has been cooled to -=-10 or + 15°C, sinks downwards during flushing around the electrode tubes 23, 24. A smaller fraction of the air is sucked into the discharge spaces 33 between the electrodes 23, 25 in order, after ozone formation, to flow out through the line 37, while the largest part of the air is led back to the cooling battery chamber 9 through the channel 20. Through the opening 16, fresh air is sucked in in an amount that
tilsvarer den ozongassblanding som føres corresponds to the ozone gas mixture that is carried
bort gjennom ledningen 37. away through the wire 37.
Som nevnt er anlegget hensiktsmessig As mentioned, the facility is appropriate
dimensjonert slik at høyst ca. 5 pst. av den dimensioned so that at most approx. 5 percent of it
kolde luft som tilføres ved hjelp av viften cold air supplied by the fan
19 tas ut gjennom ozongeneratorene. Kold-luften som sirkulerer i stort overskudd bevirker herunder en effektiv kjøling av elektrodene med derav følgende stor ozondannelse. Samtidig blir energiforbruket lavt 19 is taken out through the ozone generators. The cold air that circulates in large excess also causes an effective cooling of the electrodes with the resulting large ozone formation. At the same time, energy consumption is low
da det ikke går tapt noen kjøleluft som as no cooling air is lost which
ikke benyttes. not used.
Den anordning som er beskrevet kan The device described can
selvsagt varieres når det gjelder detaljer. obviously varies when it comes to details.
Således kan eksempelvis viften være anbragt på et annet sted, og det turde også Thus, for example, the fan can be placed in another place, and it was also possible
være mulig å la luftstrømmen sirkulere i be possible to allow the air flow to circulate in
motsatt retning, d.v.s. nedenfra og oppover opposite direction, i.e. from the bottom up
i generatorkamrene. in the generator chambers.
Claims (2)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/750,327 US4067719A (en) | 1976-12-13 | 1976-12-13 | O-Aryl N-phosphonomethylglycinonitriles and the herbicidal use thereof |
| US05/807,954 US4089671A (en) | 1976-12-13 | 1977-06-20 | N,N'-methylenebis-[O,O-diaryl N-phosphonomethylglycinonitriles] |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO773960L NO773960L (en) | 1978-06-14 |
| NO151706B true NO151706B (en) | 1985-02-11 |
| NO151706C NO151706C (en) | 1985-05-22 |
Family
ID=27115260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO773960A NO151706C (en) | 1976-12-13 | 1977-11-18 | N-PHOSPHONOMETHYLGYLINE COMPOUNDS WITH HERBICIDE EFFECT AND USE thereof IN HERBICIDE PREPARATIONS |
Country Status (30)
| Country | Link |
|---|---|
| JP (1) | JPS601319B2 (en) |
| AR (1) | AR227502A1 (en) |
| AT (1) | AT358318B (en) |
| AU (1) | AU509848B2 (en) |
| BG (1) | BG28424A3 (en) |
| BR (1) | BR7707672A (en) |
| CA (1) | CA1085415A (en) |
| CH (1) | CH638533A5 (en) |
| CS (1) | CS199209B2 (en) |
| DD (1) | DD136095A5 (en) |
| DE (1) | DE2751630A1 (en) |
| DK (1) | DK144334C (en) |
| EG (1) | EG12897A (en) |
| ES (1) | ES464221A1 (en) |
| FI (1) | FI66621C (en) |
| FR (1) | FR2373555A1 (en) |
| GB (1) | GB1561317A (en) |
| HU (1) | HU177354B (en) |
| IE (1) | IE46094B1 (en) |
| IN (1) | IN146348B (en) |
| IT (1) | IT1114670B (en) |
| MX (1) | MX4713E (en) |
| MY (1) | MY8100165A (en) |
| NL (1) | NL7712654A (en) |
| NO (1) | NO151706C (en) |
| NZ (1) | NZ185721A (en) |
| PH (1) | PH13235A (en) |
| PL (1) | PL107838B1 (en) |
| PT (1) | PT67296B (en) |
| SE (2) | SE440359B (en) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PH16509A (en) * | 1971-03-10 | 1983-11-08 | Monsanto Co | N-phosphonomethylglycine phytotoxicant composition |
-
1977
- 1977-11-16 EG EG645/77A patent/EG12897A/en active
- 1977-11-17 ES ES464221A patent/ES464221A1/en not_active Expired
- 1977-11-17 NL NL7712654A patent/NL7712654A/en not_active Application Discontinuation
- 1977-11-18 FR FR7734835A patent/FR2373555A1/en active Granted
- 1977-11-18 AU AU30753/77A patent/AU509848B2/en not_active Expired
- 1977-11-18 CH CH1410377A patent/CH638533A5/en not_active IP Right Cessation
- 1977-11-18 IT IT29815/77A patent/IT1114670B/en active
- 1977-11-18 NZ NZ185721A patent/NZ185721A/en unknown
- 1977-11-18 NO NO773960A patent/NO151706C/en unknown
- 1977-11-18 DD DD77202147A patent/DD136095A5/en unknown
- 1977-11-18 CA CA291,238A patent/CA1085415A/en not_active Expired
- 1977-11-18 SE SE7713048A patent/SE440359B/en not_active IP Right Cessation
- 1977-11-18 HU HU77MO995A patent/HU177354B/en unknown
- 1977-11-18 JP JP52138010A patent/JPS601319B2/en not_active Expired
- 1977-11-18 CS CS777616A patent/CS199209B2/en unknown
- 1977-11-18 DK DK511877A patent/DK144334C/en not_active IP Right Cessation
- 1977-11-18 BG BG037830A patent/BG28424A3/en unknown
- 1977-11-18 PT PT67296A patent/PT67296B/en unknown
- 1977-11-18 BR BR7707672A patent/BR7707672A/en unknown
- 1977-11-18 PL PL1977202251A patent/PL107838B1/en unknown
- 1977-11-18 MX MX776566U patent/MX4713E/en unknown
- 1977-11-18 PH PH20449A patent/PH13235A/en unknown
- 1977-11-18 DE DE19772751630 patent/DE2751630A1/en not_active Ceased
- 1977-11-18 GB GB48083/77A patent/GB1561317A/en not_active Expired
- 1977-11-18 FI FI773496A patent/FI66621C/en not_active IP Right Cessation
- 1977-11-18 IN IN1628/CAL/77A patent/IN146348B/en unknown
- 1977-11-18 AT AT825077A patent/AT358318B/en not_active IP Right Cessation
- 1977-11-18 IE IE2353/77A patent/IE46094B1/en unknown
- 1977-12-12 AR AR270320A patent/AR227502A1/en active
-
1981
- 1981-12-30 MY MY165/81A patent/MY8100165A/en unknown
-
1983
- 1983-03-25 SE SE8301673A patent/SE8301673L/en not_active Application Discontinuation
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