NO145985B - COLLOIDAL MIXTURE USED AS A SHARP-REDUCED ADDITIVE FOR MALEIN AND / OR FUMAR ACID POLYESTERS - Google Patents
COLLOIDAL MIXTURE USED AS A SHARP-REDUCED ADDITIVE FOR MALEIN AND / OR FUMAR ACID POLYESTERS Download PDFInfo
- Publication number
- NO145985B NO145985B NO329271A NO329271A NO145985B NO 145985 B NO145985 B NO 145985B NO 329271 A NO329271 A NO 329271A NO 329271 A NO329271 A NO 329271A NO 145985 B NO145985 B NO 145985B
- Authority
- NO
- Norway
- Prior art keywords
- weight
- parts
- mixture
- acid polyesters
- styrene
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 50
- 229920000728 polyester Polymers 0.000 title claims description 15
- 239000000654 additive Substances 0.000 title description 4
- 239000002253 acid Substances 0.000 title description 3
- 230000000996 additive effect Effects 0.000 title description 3
- PMVSDNDAUGGCCE-TYYBGVCCSA-L Ferrous fumarate Chemical compound [Fe+2].[O-]C(=O)\C=C\C([O-])=O PMVSDNDAUGGCCE-TYYBGVCCSA-L 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 30
- 239000004698 Polyethylene Substances 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 11
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 10
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 5
- 239000001530 fumaric acid Substances 0.000 claims description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
- 239000011976 maleic acid Substances 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 3
- 229920013716 polyethylene resin Polymers 0.000 claims description 3
- -1 polyethylene Polymers 0.000 description 8
- 229920000573 polyethylene Polymers 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 238000003825 pressing Methods 0.000 description 5
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- 201000004624 Dermatitis Diseases 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 208000010668 atopic eczema Diseases 0.000 description 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 3
- 230000032050 esterification Effects 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 229920006305 unsaturated polyester Polymers 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- BIIBYWQGRFWQKM-JVVROLKMSA-N (2S)-N-[4-(cyclopropylamino)-3,4-dioxo-1-[(3S)-2-oxopyrrolidin-3-yl]butan-2-yl]-2-[[(E)-3-(2,4-dichlorophenyl)prop-2-enoyl]amino]-4,4-dimethylpentanamide Chemical compound CC(C)(C)C[C@@H](C(NC(C[C@H](CCN1)C1=O)C(C(NC1CC1)=O)=O)=O)NC(/C=C/C(C=CC(Cl)=C1)=C1Cl)=O BIIBYWQGRFWQKM-JVVROLKMSA-N 0.000 description 1
- UXHQLGLGLZKHTC-CUNXSJBXSA-N 4-[(3s,3ar)-3-cyclopentyl-7-(4-hydroxypiperidine-1-carbonyl)-3,3a,4,5-tetrahydropyrazolo[3,4-f]quinolin-2-yl]-2-chlorobenzonitrile Chemical compound C1CC(O)CCN1C(=O)C1=CC=C(C=2[C@@H]([C@H](C3CCCC3)N(N=2)C=2C=C(Cl)C(C#N)=CC=2)CC2)C2=N1 UXHQLGLGLZKHTC-CUNXSJBXSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- MCRWZBYTLVCCJJ-DKALBXGISA-N [(1s,3r)-3-[[(3s,4s)-3-methoxyoxan-4-yl]amino]-1-propan-2-ylcyclopentyl]-[(1s,4s)-5-[6-(trifluoromethyl)pyrimidin-4-yl]-2,5-diazabicyclo[2.2.1]heptan-2-yl]methanone Chemical compound C([C@]1(N(C[C@]2([H])C1)C(=O)[C@@]1(C[C@@H](CC1)N[C@@H]1[C@@H](COCC1)OC)C(C)C)[H])N2C1=CC(C(F)(F)F)=NC=N1 MCRWZBYTLVCCJJ-DKALBXGISA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 101150038956 cup-4 gene Proteins 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- VOVZXURTCKPRDQ-CQSZACIVSA-N n-[4-[chloro(difluoro)methoxy]phenyl]-6-[(3r)-3-hydroxypyrrolidin-1-yl]-5-(1h-pyrazol-5-yl)pyridine-3-carboxamide Chemical compound C1[C@H](O)CCN1C1=NC=C(C(=O)NC=2C=CC(OC(F)(F)Cl)=CC=2)C=C1C1=CC=NN1 VOVZXURTCKPRDQ-CQSZACIVSA-N 0.000 description 1
- XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 1
- KMIOJWCYOHBUJS-HAKPAVFJSA-N vorolanib Chemical compound C1N(C(=O)N(C)C)CC[C@@H]1NC(=O)C1=C(C)NC(\C=C/2C3=CC(F)=CC=C3NC\2=O)=C1C KMIOJWCYOHBUJS-HAKPAVFJSA-N 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
- C08J3/11—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids from solid polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
Oppfinnelsen vedrører en kolloidal blanding til anvendelse som krympningsnedsettende tilsetning til malein- og/ eller fumarsyrepolyestere. The invention relates to a colloidal mixture for use as a shrinkage reducing additive to maleic and/or fumaric acid polyesters.
Det er funnet at polyetylen og ABS-harpikser opp-løser seg eller sveller i varmen til malein- og/eller fumarsyrepolyestere på-polymeriserbare monomere som sbyren, a-metylstyren og vinyltoluen, således at disse blandinger etter avkjøling, eventuelt under omrøring, danner mer eller mindre viskøse kolloidale blandinger. Fra disse blandinger kan eventuelt overskudd av monomere avsuges, idet det dannes konsentrerte, lett smuldrende blandinger som eventuelt kan knuses. It has been found that polyethylene and ABS resins dissolve or swell in the heat to maleic and/or fumaric acid polyesters onto polymerizable monomers such as sbyrene, α-methylstyrene and vinyltoluene, so that after cooling, possibly during stirring, these mixtures form more or less viscous colloidal mixtures. Any surplus of monomers can be extracted from these mixtures, as concentrated, easily crumbly mixtures are formed which can possibly be crushed.
Før avkjølingen kan blandingene eventuelt tilsettes pigmentdispersjoner. Ved omrøring kan pigmentet lett fordeles meget jevnt, således at det også i de avkjølte vis-køse eller eventuelt smuldrebare kolloidale blandinger kan foreligge i fin og jevn fordeling. Before cooling, pigment dispersions can optionally be added to the mixtures. By stirring, the pigment can easily be distributed very evenly, so that it can also be present in a fine and even distribution in the cooled viscous or possibly crumbly colloidal mixtures.
De kolloidale blandinger ifølge oppfinnelsen er spesielt verdifulle som tilsetninger til blandinger av malein-og/eller fumarsyrepolyestere og på-polymeriserbare monomere, The colloidal mixtures according to the invention are particularly valuable as additives to mixtures of maleic and/or fumaric acid polyesters and on-polymerizable monomers,
da derved ved herdningen av polyesterblandinger krympningen nedsettes meget sterkt, og man kan få formlegemer med spesielt glatte og glinsende overflater. as thereby, during the curing of polyester mixtures, the shrinkage is greatly reduced, and molded bodies with particularly smooth and shiny surfaces can be obtained.
Oppfinnelsen vedrører altså en kolloidal blanding til anvendelse som krympningsnedsettende tilsetning til malein- og/eller fumarsyrepolyestere, bestående av The invention thus relates to a colloidal mixture for use as a shrinkage-reducing additive to maleic and/or fumaric acid polyesters, consisting of
a) 10-80 vekt-% polyetylen eller ABS-harpiks, og a) 10-80% by weight polyethylene or ABS resin, and
b) 90-20 vekt-% styren, a-metylstyren eller vinyltoluen, idet blandingen er karakterisert ved at den er fremstilt ved at polymeren a) er blitt oppløst eller svellet under oppvarming i monomeren b) eventuelt med etterfølgende tilsetning av pigmentdispersjoner, hvoretter blandingen, eventuelt under omrøring, er blitt avkjølt, eventuelt overskudd av den monomere frasugd og blandingen eventuelt pulverisert . b) 90-20% by weight styrene, α-methylstyrene or vinyltoluene, the mixture being characterized by the fact that it is produced by the polymer a) having been dissolved or swollen during heating in the monomer b) possibly with the subsequent addition of pigment dispersions, after which the mixture , optionally while stirring, has been cooled, any excess of the monomer sucked off and the mixture optionally pulverized.
Denne anvendelse av de kolloidale blandinger ifølge oppfinnelsen medfører med hensyn til de nevnte virk-ninger et fremskritt i forhold til den kjente tilsetning av finpulverisert polyetylen (sml. f.eks. DAS 1.192.820) og poly-metylmetacrylatoppløsninger ifølge belgisk patent nr. 700.910. This use of the colloidal mixtures according to the invention entails, with regard to the aforementioned effects, an advance compared to the known addition of finely powdered polyethylene (cf. e.g. DAS 1,192,820) and polymethyl methacrylate solutions according to Belgian patent no. 700,910 .
I følgende eksempler omtales fremstillingen ifølge oppfinnelsen av forskjellige kolloide blandinger. In the following examples, the preparation according to the invention of various colloidal mixtures is discussed.
Eksemgel_l Eczema gel_l
20 vektdeler høytrykkspolyetylenpulver (smelteindeks ifølge ASTM-D 1238-62 T 2 g/10 minutter, tetthet 0,919 g/cm<3>) oppløses ved 70-90°C under kraftig omrøring i 80 vektdeler styren. Etter blandingens avkjøling får man en middelviskos, opak masse. 20 parts by weight of high-pressure polyethylene powder (melting index according to ASTM-D 1238-62 T 2 g/10 minutes, density 0.919 g/cm<3>) are dissolved at 70-90°C with vigorous stirring in 80 parts by weight of styrene. After the mixture has cooled, a medium-viscous, opaque mass is obtained.
Eksempel_2 Example_2
Fra 100 vektdeler av den ifølge eksempel 1 dann-ede middelviskose masse, som inneholder 20 vektdeler polyetylen og 80 vektdeler styren, fjernes ved kraftig frasugning 33 vektdeler styren, således at det oppstår 67 vektdeler av en smulderbar blanding av 20 vektdeler polyetylen og 4 7 vektdeler styren (ca. 30% faststoff). From 100 parts by weight of the medium-viscous mass formed according to example 1, which contains 20 parts by weight of polyethylene and 80 parts by weight of styrene, 33 parts by weight of styrene are removed by strong suction, so that 67 parts by weight of a crumbly mixture of 20 parts by weight of polyethylene and 47 parts by weight are produced styrene (approx. 30% solids).
Eksemgel_3 Eczema gel_3
Tilsvarende eksempel 1 oppløses 15 vektdeler ABS-harpiks i 85 vektdeler styren varmt. Etter avkjøling Corresponding to example 1, 15 parts by weight of ABS resin are dissolved in 85 parts by weight of styrene hot. After cooling
får man likeledes en middelviskos, opak masse. you also get a medium-viscous, opaque mass.
Eksemp_el_4 Example_el_4
Man oppløser 30 vektdeler høytrykkspolyetylen-granulat (smelteindeks 5,9-7,1 g/10 min., tetthet 0,917 g/cm 3) i 7 0 vektdeler a-metylstyren ved oppvarming av blandingen ved 70,80°C under stadig omrøring. Etter avkjøling under omrøring får man en middels til høyviskos, opak masse. 30 parts by weight of high-pressure polyethylene granules (melting index 5.9-7.1 g/10 min., density 0.917 g/cm 3 ) are dissolved in 70 parts by weight of α-methylstyrene by heating the mixture at 70.80°C with constant stirring. After cooling with stirring, a medium to highly viscous, opaque mass is obtained.
Eksempel_5 Example_5
Man oppløser 20 vektdeler av et blandingspolymerisat av 60 vektdeler styren og 40 vektdeler a-metylstyren (spesifikk viskositet, målt på en oppløsning av 5 g produkt i 1000 cm<3> dimetylformamid ved 20°C = 19) i 80 vektdeler styren ved oppvarming ved ca. 7 0°C. Etter blandingens avkjøling under omrøring får man en lavviskos, opak masse. 20 parts by weight of a mixed polymer of 60 parts by weight styrene and 40 parts by weight a-methylstyrene (specific viscosity, measured on a solution of 5 g of product in 1000 cm<3> dimethylformamide at 20°C = 19) are dissolved in 80 parts by weight styrene by heating at about. 70°C. After cooling the mixture while stirring, a low-viscosity, opaque mass is obtained.
Eksemgel_6 Eczema gel_6
Man oppløser 30 vektdeler av det i eksempel 5 anvendte blandingspolymerisat i 70 vektdeler vinyltoluen ved oppvarming ved 70°C under omrøring. Etter blandingens avkjøl-ing får man en middelviskos, opak masse. 30 parts by weight of the mixed polymer used in example 5 are dissolved in 70 parts by weight of vinyltoluene by heating at 70°C with stirring. After the mixture has cooled, a medium-viscous, opaque mass is obtained.
Eksemp_el_7 Example_el_7
Man oppløser 80 vektdeler av det i eksempel 5 anvendte blandingspolymerisat i 20 vektdeler styren ved oppvarming ved ca. 100°C under omrøring. Etter avkjøling får man en pastøs, opak masse. 80 parts by weight of the mixed polymer used in example 5 are dissolved in 20 parts by weight of styrene by heating at approx. 100°C with stirring. After cooling, a pasty, opaque mass is obtained.
Eksempel_8 Example_8
120 vektdeler av det i eksempel 4 anvendte poly-etylengranulat oppløses i 480 vektdeler styren ved ca. 100°C under omrøring. Før avkjøling tilsettes en i et valseverk fremstilt fargeutrivning av følgende bestanddeler: 500 vektdeler titandioksyd, 20 vektdeler av en 65 vektprosentig opp-løsning av en umettet polyester av 60 mol-% maleinsyreanhydrid, 40 mol-% ftalsyreanhydrid og 103 mol-% propylenglykol-1,2 med en viskositet på 600 cP og 1,5 vektdeler av en 1 vekt-prosentig oppløsning av toluhydrokinon i den 65 vektprosentige' polyesterstyrenoppløsning. Etterat denne blanding er avkjølt til ca. 30°C, tilsetter man dessuten 2 vekt-% av en høydispers kiselsyre. Man får en lett pastøs, uklar masse. 120 parts by weight of the polyethylene granules used in example 4 are dissolved in 480 parts by weight of styrene at approx. 100°C with stirring. Before cooling, a color stripping produced in a rolling mill of the following components is added: 500 parts by weight of titanium dioxide, 20 parts by weight of a 65% by weight solution of an unsaturated polyester of 60 mol% maleic anhydride, 40 mol% phthalic anhydride and 103 mol% propylene glycol-1 .2 with a viscosity of 600 cP and 1.5 parts by weight of a 1% by weight solution of toluhydroquinone in the 65% by weight polyester styrene solution. After this mixture has cooled to approx. 30°C, 2% by weight of a highly dispersed silicic acid is also added. You get a slightly pasty, cloudy mass.
I følgende eksempler omtales anvendelsen ifølge oppfinnelsen av noen kolloide blandinger ifølge oppfinnelsen som tilsetning til blandinger av umettede polyestere og på-polymeriserbare monomere. Herved ble det anvendt to forskjellige polyesterblandinger A og B. In the following examples, the use according to the invention of some colloidal mixtures according to the invention is referred to as addition to mixtures of unsaturated polyesters and polymerizable monomers. Hereby, two different polyester mixtures A and B were used.
51,2 6 vektdeler propylenglykol-1,2 polykonden-seres med 56,18 vektdeler maleinsyreanhydrid og 3,80 vektdeler ftalsyreanhydrid til en umettet polyester. Forestringstempe-raturen utgjør, gående ut fra ca. 100°C, ca. 210°C, forestringstiden ca. 13 timer. Polyesterens syretall utgjør 29, 51.26 parts by weight of propylene glycol-1.2 polycondensate with 56.18 parts by weight of maleic anhydride and 3.80 parts by weight of phthalic anhydride to an unsaturated polyester. The esterification temperature is, based on approx. 100°C, approx. 210°C, esterification time approx. 13 hours. The polyester's acid number is 29,
og viskositeten av en 55 vekt-prosentig oppløsning i styren med DIN-beger 4 utgjør ca. 70 sek. 65 vektdeler av denne polyester oppløses i 35 vektdeler styren. Oppløsningen stabiliseres ved tilsetning av 0,011 vekt-% hydrokinon og har en viskositet på 2500 cp. and the viscosity of a 55% by weight solution in styrene with DIN cup 4 is approx. 70 sec. 65 parts by weight of this polyester are dissolved in 35 parts by weight of styrene. The solution is stabilized by the addition of 0.011% by weight of hydroquinone and has a viscosity of 2500 cp.
Som omtalt under blanding A fremstilles av like mengder propylenglykol, maleinsyreanhydrid og ftalsyreanhydrid en polyester. Forestringstiden utgjør 12 timer, polyesterens syretall 31 og dens viskositet 65 sek., målt som omtalt ved A. 80 vektdeler av denne polyester blandes med 20 vektdeler styren og denne blanding stabiliseres ved tilsetning av 0,014 vekt-% hydrokinon. Dens viskositet utgjør ca. 109.000 cp. As discussed under mixture A, a polyester is produced from equal amounts of propylene glycol, maleic anhydride and phthalic anhydride. The esterification time is 12 hours, the polyester's acid number 31 and its viscosity 65 sec., measured as discussed at A. 80 parts by weight of this polyester are mixed with 20 parts by weight of styrene and this mixture is stabilized by adding 0.014% by weight of hydroquinone. Its viscosity is approx. 109,000 cp.
Eksempel_9 Example_9
I dette eksempel sammenlignes fremstillingen av et presstykke fra en blanding ifølge oppfinnelsen a) med et slikt av en blanding ifølge, det belgiske patent nr. 700.910 In this example, the production of a press piece from a mixture according to the invention a) is compared with that of a mixture according to Belgian patent no. 700,910
b). Følgende bestanddeler blandes godt med hverandre: b). The following ingredients mix well with each other:
Hver gang 26 vektdeler av en gass-silkematte Each time 26 parts by weight of a gas-silk mat
impregneres med hver gang 74 vektdeler av blanding a) resp. b). impregnated with each time 74 parts by weight of mixture a) or b).
Etter 3 dagers lagring presses de impregnerte matter i et oppvarmet stålverktøy ved 140°C og med et press-trykk på 100 kp/cm 2 til normstaver (6 med hverandre forbundne flatstaver av dimensjoner 120 mm x 15 mm x 10 mm). Herved utgjør den lineære skrumpning av blanding a) 0,107%, av blanding b) 0,148% . After 3 days of storage, the impregnated mats are pressed in a heated steel tool at 140°C and with a pressing pressure of 100 kp/cm 2 into standard bars (6 interconnected flat bars of dimensions 120 mm x 15 mm x 10 mm). Hereby, the linear shrinkage of mixture a) amounts to 0.107%, of mixture b) 0.148%.
Eksempel_10 Example_10
I dette eksempel sammenlignes med hverandre glan-sen av blandinger ifølge oppfinnelsen b) og b) på den ene side og en blanding ifølge belgisk patent nr. 700.910 c) på den annen side pressede tabletter. Følgende bestanddeler blandes godt med hverandre: In this example, the gloss of mixtures according to the invention b) and b) on the one hand and a mixture according to Belgian patent no. 700,910 c) on the other hand pressed tablets are compared with each other. The following ingredients mix well with each other:
Hver gang 26 vektdeler av en glass-silkematte gjennomimpregneres med hver gang 74 vektdeler av blanding a), b) og c). Etter 3 dagers lagring presses herav tabletter 28 cm x 37 cm. Presstemperaturen utgjør 140°C og presstrykket Each time 26 parts by weight of a glass-silk mat are impregnated with each time 74 parts by weight of mixture a), b) and c). After 3 days of storage, tablets 28 cm x 37 cm are pressed from this. The pressing temperature amounts to 140°C and the pressing pressure
2 2
100 kp/cm . 100 kp/cm.
Tablettene av blanding a) og b) viser i forhold til tablettene av blanding c) foruten en høyere glans også en mindre fargeseparering og derfor en jevnere fargning. The tablets of mixture a) and b) show, in comparison to the tablets of mixture c), in addition to a higher gloss, also a smaller color separation and therefore a more uniform coloring.
Eksemgel_ll Exemgel_ll
I dette eksempel vises at viskositeten av polyester-styrenblandinger øker betraktelig mindre ved tilsetning av en kolloid blanding-ifølge oppfinnelsen enn ved tilsetning av en tilsvarende mengde av pulverformet polyetylen, se følgende tabell: In this example, it is shown that the viscosity of polyester-styrene mixtures increases considerably less when adding a colloidal mixture - according to the invention - than when adding a corresponding amount of powdered polyethylene, see the following table:
Eksempel_12 Example_12
Dessuten viser polyesterpressmasser med en tilsetning av en blanding ifølge oppfinnelsen ved pressing likeledes en mindre skrumpning enn slike med en tilsetning av en tilsvarende mengde polyetylenpulver som følgende eksempel viser. Følgende bestanddeler blandes godt'med hverandre: In addition, polyester pressings with an addition of a mixture according to the invention during pressing likewise show less shrinkage than those with an addition of a corresponding amount of polyethylene powder, as the following example shows. The following components mix well with each other:
Eksempel_13 Example_13
Til 6Q vektdeler blanding A tilblandes 4 0 vektdeler av blandingen ifølge eksempel 3, videre 0,75 vektdeler tert.-butylperbenzoat (95%-ig), 4 vektdeler zinkstearat, 70 vektdeler kaolin, 1,5 vektdeler magnesiumoksyd og 70 vektdeler glassfibre (lengde ca. 26 mm) i den angitte rekkefølge i løpet av 2 min. To 60 parts by weight of mixture A are mixed 40 parts by weight of the mixture according to example 3, further 0.75 parts by weight of tert-butyl perbenzoate (95% strength), 4 parts by weight of zinc stearate, 70 parts by weight of kaolin, 1.5 parts by weight of magnesium oxide and 70 parts by weight of glass fibers (length approx. 26 mm) in the specified order within 2 min.
i en knaer. Den samlede blanding gjennomknas deretter ytter-ligere 5 minutter. Etter 3 dagers lagring presses normalstaver, som omtalt ovenfor. Skrumpningen^utgjør 0,107%. in one knee. The combined mixture is then kneaded for a further 5 minutes. After 3 days of storage, normal rods are pressed, as discussed above. The shrinkage^is 0.107%.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702044168 DE2044168C3 (en) | 1970-09-05 | 1970-09-05 | Colloid mixtures |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO145985B true NO145985B (en) | 1982-03-29 |
| NO145985C NO145985C (en) | 1982-07-07 |
Family
ID=5781738
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO329271A NO145985C (en) | 1970-09-05 | 1971-09-03 | COLLOIDAL MIXTURE USED AS A SHARP-REDUCED ADDITIVE FOR MALEIN AND / OR FUMAR ACID POLYESTERS |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS5522490B1 (en) |
| AT (1) | AT316144B (en) |
| BE (1) | BE772187A (en) |
| CH (1) | CH563421A5 (en) |
| DE (1) | DE2044168C3 (en) |
| FI (1) | FI58148C (en) |
| FR (1) | FR2107271A5 (en) |
| GB (1) | GB1343511A (en) |
| LU (1) | LU63803A1 (en) |
| NL (1) | NL174731C (en) |
| NO (1) | NO145985C (en) |
| SE (1) | SE391943B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2621107C3 (en) * | 1975-11-10 | 1985-08-08 | Owens-Corning Fiberglas Corp., Toledo, Ohio | Pigmented, thermosetting polyester resin molding compounds with low shrinkage |
| JPS5220513B2 (en) * | 1975-03-05 | 1977-06-03 | ||
| NL175188C (en) * | 1975-10-31 | 1984-10-01 | Synres Internationaal Nv | METHOD FOR PREPARING THERMO-HARDBAR COMPOSITIONS AND ARTICLES THEREOF |
| JPS58188500U (en) * | 1982-06-10 | 1983-12-14 | 羽田ヒューム管株式会社 | Step fittings for manholes, etc. |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1008487B (en) * | 1954-10-21 | 1957-05-16 | Steuler Industriewerke Gmbh | Process for the production of molded articles |
| CH342331A (en) * | 1955-02-21 | 1959-11-15 | Dentaire Ivoclar Ets | Process for the production of hardened dental plastics |
| NL248971A (en) * | 1959-03-05 | |||
| AT220369B (en) * | 1959-03-05 | 1962-03-26 | Degussa | Shrinkage-free hardenable filling, casting and modeling compounds |
| DE1166467B (en) * | 1959-04-15 | 1964-03-26 | Beck & Co G M B H Dr | Polyester molding compounds |
| NL264053A (en) * | 1960-04-26 | |||
| FR1530817A (en) * | 1966-07-20 | 1968-06-28 | Rohm & Haas | Polymerizable resinous compositions based on unsaturated polyesters |
| US3701748A (en) * | 1966-07-20 | 1972-10-31 | Rohm & Haas | Unsaturated polyester resinous compositions |
| JPS6022507B2 (en) * | 1973-06-27 | 1985-06-03 | 株式会社日立製作所 | charge transfer device |
| JPS5022580A (en) * | 1973-06-26 | 1975-03-11 |
-
1970
- 1970-09-05 DE DE19702044168 patent/DE2044168C3/en not_active Expired
-
1971
- 1971-08-31 LU LU63803D patent/LU63803A1/xx unknown
- 1971-09-03 NO NO329271A patent/NO145985C/en unknown
- 1971-09-03 FI FI246871A patent/FI58148C/en active
- 1971-09-03 FR FR7132005A patent/FR2107271A5/fr not_active Expired
- 1971-09-03 NL NL7112180A patent/NL174731C/en not_active IP Right Cessation
- 1971-09-03 BE BE772187A patent/BE772187A/en not_active IP Right Cessation
- 1971-09-03 GB GB4122171A patent/GB1343511A/en not_active Expired
- 1971-09-03 AT AT770171A patent/AT316144B/en not_active IP Right Cessation
- 1971-09-06 JP JP6881871A patent/JPS5522490B1/ja active Pending
- 1971-09-06 CH CH1304771A patent/CH563421A5/xx not_active IP Right Cessation
- 1971-09-06 SE SE1126671A patent/SE391943B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FI58148B (en) | 1980-08-29 |
| DE2044168B2 (en) | 1980-08-07 |
| LU63803A1 (en) | 1972-01-06 |
| NL174731B (en) | 1984-03-01 |
| SE391943B (en) | 1977-03-07 |
| DE2044168A1 (en) | 1972-03-09 |
| GB1343511A (en) | 1974-01-10 |
| NL174731C (en) | 1984-08-01 |
| FR2107271A5 (en) | 1972-05-05 |
| CH563421A5 (en) | 1975-06-30 |
| NL7112180A (en) | 1972-03-07 |
| BE772187A (en) | 1972-03-03 |
| AT316144B (en) | 1974-06-25 |
| DE2044168C3 (en) | 1981-03-12 |
| FI58148C (en) | 1980-12-10 |
| JPS5522490B1 (en) | 1980-06-17 |
| NO145985C (en) | 1982-07-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69126740T2 (en) | Unsaturated polyester resin compositions and new anti-shrink agent | |
| US4188316A (en) | Process for producing shaped articles with patterns | |
| CN104371237A (en) | Unsaturated polyester resin composition thickened by non-alkali metal systems and bulk molding compound with unsaturated polyester resin composition | |
| NO145985B (en) | COLLOIDAL MIXTURE USED AS A SHARP-REDUCED ADDITIVE FOR MALEIN AND / OR FUMAR ACID POLYESTERS | |
| DE1803345A1 (en) | Polyester molding compounds | |
| US3578728A (en) | Liquid unsaturated polyesters and polyester urethanes containing cross-linked particles of the same resins | |
| TW575531B (en) | Acrylyl SMC or BMC and preparation the same, preparation of synthetic acrylyl marble and thickener | |
| US3692736A (en) | Polyester resin granulates and process for preparation of same | |
| US3211676A (en) | Composition comprising polyvinyl chloride and hexamethoxymethyl melamine | |
| US3969311A (en) | Fiber reinforced polyester resin having a low surface profile | |
| JP2000063613A (en) | Acrylic premix, acrylic smc or bmc, and preparation of acrylic artificial marble | |
| JPH0274549A (en) | Production of translucent artificial stone | |
| JP3527638B2 (en) | Method for producing (meth) acrylic premix, (meth) acrylic SMC or BMC, and (meth) acrylic artificial marble | |
| JPH1192533A (en) | Acrylic resin composition, premix, smc or bmc and preparation of artificial marble | |
| JPH0513899B2 (en) | ||
| JP3561410B2 (en) | Method for producing (meth) acrylic premix, (meth) acrylic SMC or BMC, and (meth) acrylic artificial marble | |
| JP3428357B2 (en) | Acrylic resin composition, acrylic premix, method for producing acrylic artificial marble, and thickener | |
| JP3285656B2 (en) | Thickened acrylic premix and acrylic artificial marble using it | |
| JPH0468325B2 (en) | ||
| JP3433890B2 (en) | Method for producing acrylic resin composition, acrylic premix, acrylic SMC or BMC, and acrylic artificial marble | |
| JPH09111085A (en) | Resin composition, acrylic premix and production of acrylic artificial marble | |
| JP3361034B2 (en) | Method for producing acrylic resin composition, acrylic premix, acrylic SMC or BMC, and acrylic artificial marble | |
| JPS6157644A (en) | Unsaturated polyester resin composition | |
| US2808379A (en) | Process for foaming resins using furan adduct foaming agents and foamable compositions containing same | |
| JPH0481448A (en) | Methacrylate resin premix and production of artificial marble |