NO140223B - HAIR SHAMPOO. - Google Patents
HAIR SHAMPOO. Download PDFInfo
- Publication number
- NO140223B NO140223B NO4469/72A NO446972A NO140223B NO 140223 B NO140223 B NO 140223B NO 4469/72 A NO4469/72 A NO 4469/72A NO 446972 A NO446972 A NO 446972A NO 140223 B NO140223 B NO 140223B
- Authority
- NO
- Norway
- Prior art keywords
- shampoo
- resinous material
- hair
- weight
- organic solvent
- Prior art date
Links
- 239000002453 shampoo Substances 0.000 title claims description 65
- 239000012260 resinous material Substances 0.000 claims description 32
- 239000004094 surface-active agent Substances 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000003960 organic solvent Substances 0.000 claims description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 6
- 229920001470 polyketone Polymers 0.000 claims description 5
- 239000000344 soap Substances 0.000 claims description 5
- -1 alcohol ether salt Chemical class 0.000 claims description 4
- 238000007865 diluting Methods 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 239000001797 sucrose acetate isobutyrate Substances 0.000 claims description 4
- FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 claims description 3
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical class CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims description 3
- 239000003623 enhancer Substances 0.000 claims description 3
- UVGUPMLLGBCFEJ-SWTLDUCYSA-N sucrose acetate isobutyrate Chemical compound CC(C)C(=O)O[C@H]1[C@H](OC(=O)C(C)C)[C@@H](COC(=O)C(C)C)O[C@@]1(COC(C)=O)O[C@@H]1[C@H](OC(=O)C(C)C)[C@@H](OC(=O)C(C)C)[C@H](OC(=O)C(C)C)[C@@H](COC(C)=O)O1 UVGUPMLLGBCFEJ-SWTLDUCYSA-N 0.000 claims description 3
- 235000010983 sucrose acetate isobutyrate Nutrition 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 description 13
- 229920005989 resin Polymers 0.000 description 13
- 235000019441 ethanol Nutrition 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000002537 cosmetic Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 4
- 235000011613 Pinus brutia Nutrition 0.000 description 4
- 241000018646 Pinus brutia Species 0.000 description 4
- 229920002873 Polyethylenimine Polymers 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 2
- 230000002051 biphasic effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- FLPJVCMIKUWSDR-UHFFFAOYSA-N 2-(4-formylphenoxy)acetamide Chemical compound NC(=O)COC1=CC=C(C=O)C=C1 FLPJVCMIKUWSDR-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 206010015946 Eye irritation Diseases 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 206010039792 Seborrhoea Diseases 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229940074979 cetyl palmitate Drugs 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical class OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical class CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000004442 gravimetric analysis Methods 0.000 description 1
- 230000003741 hair volume Effects 0.000 description 1
- PXDJXZJSCPSGGI-UHFFFAOYSA-N hexadecanoic acid hexadecyl ester Natural products CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940099367 lanolin alcohols Drugs 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- QDIGBJJRWUZARS-UHFFFAOYSA-M potassium;decanoate Chemical compound [K+].CCCCCCCCCC([O-])=O QDIGBJJRWUZARS-UHFFFAOYSA-M 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8135—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers, e.g. vinyl esters (polyvinylacetate)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
Description
Denne oppfinnelse vedrører en hårsjampo inneholdende This invention relates to a hair shampoo containing
et harpiksaktig materiale. a resinous material.
Sjampoer som inneholder harpiksaktige materialer har Shampoos that contain resinous materials have
blitt foreslått for å gi forskjellige kosmetiske egenskaper til håret. Disse er generelt av to typer. have been proposed to provide various cosmetic properties to the hair. These are generally of two types.
I den første type er det harpiksaktige materialet vann-oppløselig, og også oppløselig i det vandige overflateaktive system som utgjør sjampoen. Det er forenelig med hår, og noe av det vil således under sjamponeringen bli adsorbert på håret. In the first type, the resinous material is water-soluble, and also soluble in the aqueous surfactant system that makes up the shampoo. It is compatible with hair, and some of it will thus be adsorbed on the hair during shampooing.
Men selv om det blir lett adsorbert, så blir det også, siden det But even if it is easily adsorbed, it will also be, since it
er vannoppløselig, lett fjernet under skylling. Generelt vil således sjampoer som inneholder vannoppløselige harpiksmaterialer, bare frembringe små kosmetiske virkninger på håret, siden det bare er små mengder av det harpiksaktige materialet som blir igjen på håret efter sjamponering/skylle-cyklusen. is water-soluble, easily removed during rinsing. Thus, in general, shampoos containing water-soluble resinous materials will produce only minor cosmetic effects on the hair, since only small amounts of the resinous material remain on the hair after the shampooing/rinsing cycle.
Det har blitt foreslått i US-patentskrifter nr. 3.313.734 og 3.400.198 at sjampoer bør inneholde harpiksaktige polyetylen-iminer som er oppløseliggjort i et spesielt overflateaktivt system. Polyetyleniminene er oppløselige i den konsentrerte sjampo, men utfelles ved fortynning. Når sjampoen således blir fortynnet under sjamponeringsprosessen, avsettes polyetyleniminet på håret, og det blir sagt at dette tilveiebringer effekter som gjør håret føyelig og bevarer frisyren. It has been suggested in US Patent Nos. 3,313,734 and 3,400,198 that shampoos should contain resinous polyethylene imines solubilized in a special surfactant system. The polyethyleneimines are soluble in the concentrated shampoo, but precipitate when diluted. Thus, when the shampoo is diluted during the shampooing process, the polyethyleneimine is deposited on the hair, and this is said to provide effects that make the hair manageable and preserve the style.
Men når vi undersøkte sjampoene som er beskrevet i ovennevnte patenter, fant vi at de vannoppløselige polymere materialer som avsatte seg på håret både hadde tilbøyelighet til å gjøre håret glansløst og til å påvirke i uheldig retning hvordan håret føles. However, when we examined the shampoos described in the above patents, we found that the water-soluble polymeric materials deposited on the hair tended both to dull the hair and to adversely affect the feel of the hair.
Vi har nå oppdaget at harpiksaktige materialer som gir håret fylde og bevarer hårets frisyre, kan avsettes fra en vandig sjampo ved hjelp av forandringen i oppløseligheten til det harpiksaktige materiale, hvilken foregår når en vandig overflateaktiv oppløsning som inneholder et vannblandbart organisk opp-løsningsmiddel, blir fortynnet under sjamponeringsprosessen. We have now discovered that resinous materials which add volume to the hair and preserve the style of the hair can be deposited from an aqueous shampoo by means of the change in the solubility of the resinous material which occurs when an aqueous surfactant solution containing a water-miscible organic solvent becomes diluted during the shampooing process.
Det er følgelig et formål for denne oppfinnelse å til-veiebringe en vandig sjampo som gir håret fylde og bevarer hårets frisyre. It is consequently an object of this invention to provide an aqueous shampoo which gives the hair volume and preserves the hairstyle of the hair.
Ifølge oppfinnelsen tilveiebringes en hårsjampo som omfatter en vandig oppløsning av et overflateaktivtstoff, fortrinnsvis et C12-C2^-fettalkohol- eller -alkoholeter-salt, According to the invention, a hair shampoo is provided which comprises an aqueous solution of a surfactant, preferably a C12-C2^ fatty alcohol or alcohol ether salt,
slik som et laurylsulfat-salt eller lauryletersulfat-salt, og om ønskes en såpeskum-forsterker i en mengde på fra 0,5 til 5 such as a lauryl sulfate salt or lauryl ether sulfate salt, and if desired a soap suds enhancer in an amount of from 0.5 to 5
vekt% av sjampoen, samt et harpiksaktig materiale og et vannblandbart, kosmetisk godtagbart, organisk oppløsningsmiddel, fortrinnsvis etanol, propanol eller isopropanol, slik at det harpiksaktige materiale blir avsatt på håret ved fortynning av sjampoen under sjamponeringen og gir håret fylde og bevarer frisyren. Sjampoen karakteriseres ved at det harpiksaktige materiale er et egnet, kosmetisk godtagbart harpiksaktig materiale som er uoppløselig i den vandige overflateaktive oppløsning og i vann, men er oppløselig i blandingen av overflateaktiv opp-løsning og det organiske oppløsningsmiddel, og er til stede i sjampoen i en.mengde fra 2 til 60 vekt%. % by weight of the shampoo, as well as a resinous material and a water-miscible, cosmetically acceptable, organic solvent, preferably ethanol, propanol or isopropanol, so that the resinous material is deposited on the hair by diluting the shampoo during shampooing and gives the hair fullness and preserves the hairstyle. The shampoo is characterized in that the resinous material is a suitable, cosmetically acceptable resinous material which is insoluble in the aqueous surfactant solution and in water, but is soluble in the mixture of surfactant solution and the organic solvent, and is present in the shampoo in a .amount from 2 to 60% by weight.
Med uttrykket "fylde" menes at håret ser tettere og tykkere ut, samt er lettere å frisere, lettere å sette opp og lettere holder på en frisyre enn hår som ikke har fylde. The expression "fullness" means that the hair looks denser and thicker, and is easier to style, easier to set up and more easily holds a hairstyle than hair that has no fullness.
I tysk offentliggjørelsesskrift 2.016.439 og dansk In German publication 2,016,439 and Danish
patent 128.184 er beskrevet en sjampo inneholdende en polyetylen-iminharpiks. Det fremgår imidlertid klart av beskrivelsen at denne harpiks er kationisk og avsettes på håret bare ved elektrostatisk tiltrekning til de anioniske partier av håret. patent 128,184 describes a shampoo containing a polyethylene imine resin. However, it is clear from the description that this resin is cationic and is deposited on the hair only by electrostatic attraction to the anionic parts of the hair.
De tyske offentliggjørelsesskrifter 1.492.262 og 1.617.947 angår oljeaktige hårbehandlingsmidler som er gelatinert med polyamidmateriale, og ikke-vandige sjampoer, og det beskrives således.ikke et preparat som ved fortynning med vann avsetter et harpiksaktig materiale på håret. The German publication documents 1,492,262 and 1,617,947 relate to oily hair treatment agents which are gelatinized with polyamide material, and non-aqueous shampoos, and thus describe a preparation which, when diluted with water, deposits a resinous material on the hair.
Tysk offentliggjørelsesskrift 1.912^646 angår behandlings-preparater så som kremskyllemidler inneholdende et polyalkylenoksyd. Dette materiale befinner seg i findelt suspensjon fordi det har vært utsatt for meget høy skjærspenning. Det beskrives ingen s j ampo. German Publication No. 1,912,646 relates to treatment preparations such as cream rinses containing a polyalkylene oxide. This material is in finely divided suspension because it has been exposed to very high shear stress. No shampoo is described.
Tysk offentliggjørelsesskrift 2.011.156 angår et aerosolpreparat som omfatter en vannuoppløselig polymer og et overflateaktivt stoff for avfetting og rengjøring av menneskehår. Dette preparat er vesentlig forskjellig fra en vandig sjampo. German publication 2,011,156 relates to an aerosol preparation comprising a water-insoluble polymer and a surfactant for degreasing and cleaning human hair. This preparation is significantly different from an aqueous shampoo.
Egnede harpiksaktige materialer i sjampoene ifølge foreliggende oppfinnelse, innbefatter polyvinyl-etyl-harpiks, alkyd-harpikser, polyketon-harpikser, vinylacetat-harpikser, akryl-harpikser, sukroseacetatisobutyrat og blandinger derav. Suitable resinous materials in the shampoos of the present invention include polyvinyl ethyl resin, alkyd resins, polyketone resins, vinyl acetate resins, acrylic resins, sucrose acetate isobutyrate and mixtures thereof.
De harpiksaktige materialer kan anvendes sammen med voksaktige materialer som gir fylde og virker kondisjonerende på håret. Egnede voksaktige materialer innbefatter kokosamid, etoksylert lanolin, stearylamid og etoksylerte høyere fettalkoholer. The resinous materials can be used together with waxy materials that give fullness and have a conditioning effect on the hair. Suitable waxy materials include cocoamide, ethoxylated lanolin, stearylamide and ethoxylated higher fatty alcohols.
Organiske oljer, slik som lanolin-alkoholer, cetylert ricinusolje og mineralolje-fraksjoner, som gir kondisjonerende effekt og en effekt som gjør kjemmingen av håret lettere, kan også anvendes sammen med det harpiksaktige materialet som hår-smøremidler. Organic oils, such as lanolin alcohols, cetylated castor oil and mineral oil fractions, which provide a conditioning effect and an effect that makes combing the hair easier, can also be used together with the resinous material as hair lubricants.
Foretrukne harpiksaktige materialer er polyketon-harpikser, sukroseacetatisobutyrat og polyvinyletyleterharpikser, anvendt enten alene eller i kombinasjon, eller sammen med furuharpiks som er beskrevet i vår henlagte søknad 4470/72 inngitt samtidig med foreliggende søknad. Preferred resinous materials are polyketone resins, sucrose acetate isobutyrate and polyvinyl ethyl ether resins, used either alone or in combination, or together with pine resin which is described in our abandoned application 4470/72 filed at the same time as the present application.
Kombinasjonen av for eksempel polyketon-sukroseacetat-isobutyrat og furuharpiks-polyketon kan anvendes i forhold på fra omkring 1:9 til 9:1, fortrinnsvis 1:5 til 5:1. Kombinasjoner av harpiksaktige materialer er ønskelig på grunn av den balanse av ønskelige kosmetiske egenskaper som de tilveiebringer. The combination of, for example, polyketone-sucrose acetate-isobutyrate and pine resin-polyketone can be used in a ratio of from about 1:9 to 9:1, preferably 1:5 to 5:1. Combinations of resinous materials are desirable because of the balance of desirable cosmetic properties they provide.
De harpiksaktige materialer er til stede i sjampo-preparatene i en mengde på fra 2 til 60 vekt%, fortrinnsvis 3 til 20 vekt%, av sjampoen. The resinous materials are present in the shampoo preparations in an amount of from 2 to 60% by weight, preferably 3 to 20% by weight, of the shampoo.
For å oppnå de beste resultater for sjampoen ifølge oppfinnelsen med hensyn til hårets fylde og frisyre, bør myknings-punktet til det harpiksaktige materiale være fra 30 til 50°C. Den metode til å bestemme mykriingspunkter som er egnet til formålet i foreliggende tilfelle, er beskrevet i brosjyren: "Wood Rosins, Modified Rosins and Related Resins", publisert av Hercules Powder Company. In order to achieve the best results for the shampoo according to the invention with regard to hair fullness and hairstyle, the softening point of the resinous material should be from 30 to 50°C. The method of determining softening points suitable for the purpose in the present case is described in the pamphlet: "Wood Rosins, Modified Rosins and Related Resins", published by the Hercules Powder Company.
Som nevnt ovenfor er det harpiksaktige polymere materiale uoppløselig i vann og i en vandig overflateaktiv oppløsning, og det er nødvendig å tilsette et vannblandbart organisk oppløsnings-middel til en slik oppløsning for å oppløse materialet. As mentioned above, the resinous polymeric material is insoluble in water and in an aqueous surfactant solution, and it is necessary to add a water-miscible organic solvent to such a solution to dissolve the material.
Eksempler på polare, vannblandbare oppløsningsmidler som er egnet til å anvendes i sjampoene i henhold til denne oppfinnelse, er monovalente alkoholer, slik som etylalkohol, n-propanol og isopropanol, divalente alkoholer slik som dipropylen-glykol og tripropylen-glykol, trioler slik som glycerol og polyetylen-glykoler (Mv. <400), og etere slik som monoetyleteren av etylenglykol og monoetyleteren av dietylen-glykoler. De mest foretrukne polare oppløsningsmidler er etylalkohol, n-propanol og isopropanol. Examples of polar, water-miscible solvents suitable for use in the shampoos according to this invention are monovalent alcohols, such as ethyl alcohol, n-propanol and isopropanol, divalent alcohols such as dipropylene glycol and tripropylene glycol, triols such as glycerol and polyethylene glycols (Mv. <400), and ethers such as the monoethyl ether of ethylene glycol and the monoethyl ether of diethylene glycols. The most preferred polar solvents are ethyl alcohol, n-propanol and isopropanol.
Oppløsningsmidlet kan også omfatte ikke-polare opp-løsningsmidler som ikke er blandbare med vann, slik som hydrokarboner, klorerte hydrokarboner slik som metylenklorid, og fluorerte hydrokarboner slik som triklortrifluoretan. The solvent may also include non-polar solvents which are not miscible with water, such as hydrocarbons, chlorinated hydrocarbons such as methylene chloride, and fluorinated hydrocarbons such as trichlorotrifluoroethane.
Oppløsningsmidlet er fortrinnsvis til stede i sjampoene The solvent is preferably present in the shampoos
i henhold til oppfinnelsen i en mengde på fra 8-10 til 60-70 vekt%, og mer foretrukket 12-45 vekt%, av sjampoen. according to the invention in an amount of from 8-10 to 60-70% by weight, and more preferably 12-45% by weight, of the shampoo.
Ved fortynning av sjampoen som inneholder vesentlige mengder med organisk oppløsningsmiddel, med vann, under sjamponeringsprosessen, avsettes det harpiksaktige materiale på håret, sidet det er uoppløselig i den fortynnede oppløsning av overflateaktivt stoff og oppløsningsmiddel. When diluting the shampoo containing significant amounts of organic solvent with water during the shampooing process, the resinous material is deposited on the hair, as it is insoluble in the dilute solution of surfactant and solvent.
Som allerede nevnt omfatter sjampoene i henhold til As already mentioned, the shampoos include
denne oppfinnelse et hår-smøremiddel for å gjøre det lettere å kjemme håret, og gi antistatiske egenskaper til håret efter anvendelsen. this invention a hair lubricant to make it easier to comb the hair, and to provide antistatic properties to the hair after application.
Når smøremidlet er oppløselig eller dispergert i sjampoen, bør det være til stede i en mengde på fra 1 til 15 vekt%, basert på den samlede vekt av sjampoen. Når det er uoppløselig, og danner en adskilt fase, foretrekkes det å øke den øvre grense til omkring 25 vekt%, med et ønsket område fra 4 til 20 vekt%. When the lubricant is soluble or dispersed in the shampoo, it should be present in an amount of from 1 to 15% by weight, based on the total weight of the shampoo. When it is insoluble, forming a separate phase, it is preferred to increase the upper limit to about 25% by weight, with a desired range of 4 to 20% by weight.
Eksempler på oppløselige eller dispergerbare smøremidler innbefatter organiske oljer, f.eks. estere slik som cetyl-palmitat, n-butyloleat, isopropylmyristat og adipater, glykol-polysiloksaner <p>g mineraloljer, og blandinger derav. Examples of soluble or dispersible lubricants include organic oils, e.g. esters such as cetyl palmitate, n-butyl oleate, isopropyl myristate and adipates, glycol polysiloxanes <p>g mineral oils, and mixtures thereof.
Som antydet ovenfor, kan også sjampoene inneholde et uoppløselig smøremiddel, og utgjøre et multifase system av den type som er åpenbart i US-patentskrift nr. 3.533.955. I disse preparater er det nødvendig å ytterligere innlemme i sjampo-komposisjonen fra 9 til 28 vekt%, basert på den samlede vekt av sjampoen, av en eller flere emulsjons-destabilisatorer. Eksempler på slike innbefatter C, til Cj monovalente alkoholer, monoalkyl-etere av C., til Cg alifatiske divalente alkoholer og C3~Cg di-alkylketoner. Disse substanser kan samtidig tjene som den organiske oppløsningsmiddel-komponent i sjampo i henhold til foreliggende oppfinnelse. As indicated above, the shampoos may also contain an insoluble lubricant, constituting a multiphase system of the type disclosed in US Patent No. 3,533,955. In these preparations, it is necessary to further incorporate into the shampoo composition from 9 to 28% by weight, based on the total weight of the shampoo, of one or more emulsion destabilizers. Examples of such include C, to Cj monovalent alcohols, monoalkyl ethers of C, to Cg aliphatic divalent alcohols and C3-Cg dialkyl ketones. These substances can simultaneously serve as the organic solvent component in shampoo according to the present invention.
Sjampoene i henhold til denne oppfinnelse omfatter ett eller flere overflateaktive stoffer. Salter av sulfonerte og sulfaterte anibniske overflateaktive stoffer er foretrukne, og spesielt natrium-, magnesium-, ammonium-, mono-, di- og tri-etanolamin-salter av sulfaterte C±2~'~ 21 f^t^^oholer og slike salter av de sulfonerte C2. 2~ <~ 21 alkylaryl-forbindelser. Typiske anioniske overflateaktive stoffer innbefatter laurylsulfater, lauryletersulfater og dodecylbenzensulfonater. The shampoos according to this invention comprise one or more surfactants. Salts of sulfonated and sulfated anibnic surfactants are preferred, and in particular sodium, magnesium, ammonium, mono-, di- and tri-ethanolamine salts of sulfated C±2~'~ 21 f^t^^ohols and the like salts of the sulfonated C2. 2~ <~ 21 alkylaryl compounds. Typical anionic surfactants include lauryl sulfates, lauryl ether sulfates, and dodecylbenzene sulfonates.
Egnede ikke-ioniske overflateaktive stoffer innbefatter fettsyre-alkanolamider slik som laurinsyre- dietanolamid, kokosnøtt mono- og dietanolamid og laurinsyre-isopropanolamid og etylen- og propylen-oksyd-kondensater av hydrofobe baser, slik som langkjedede fettalkoholer, alkylfenoler eller fettsyre-alkanolamider. Eksempler på kationiske overflateaktive stoffer som kan innlemmes i sjampoene i henhold til denne oppfinnelse, Suitable nonionic surfactants include fatty acid alkanolamides such as lauric acid diethanolamide, coconut mono- and diethanolamide and lauric acid isopropanolamide and ethylene and propylene oxide condensates of hydrophobic bases such as long chain fatty alcohols, alkylphenols or fatty acid alkanolamides. Examples of cationic surfactants that can be incorporated into the shampoos according to this invention,
i små mengder, er cetyltrimetyl-ammoniumklorid og alkyldimetyl-benzylammoniumklorid. Det overflateaktive stoff er fortrinnsvis til stede i en mengde på fra omkring 5 til omkring 60%, spesielt omkring 5 til omrking 25 vekt%, av komposisjonen. Sjampoer som inneholder mindre mengder av overflateaktivt stoff enn dette, renser ikke håret godt og gir også lave skum-volumer, mens slike som inneholder større mengder, fører til problemer med hensyn til irritasjon for øynene. in small amounts, are cetyltrimethylammonium chloride and alkyldimethylbenzylammonium chloride. The surfactant is preferably present in an amount of from about 5 to about 60%, especially about 5 to about 25% by weight, of the composition. Shampoos containing smaller amounts of surfactant than this do not clean the hair well and also produce low foam volumes, while those containing larger amounts lead to problems with regard to eye irritation.
Om ønskes kan sjampoen også inneholde fra 0,2 til 15 vekt%, eller vanligere 0,5 til 5 vekt%, av en eller flere såpeskum-forsterkere og/eller stabilisatorer, for å øke såpekraften og skum-stabiliteten. Eksempler på slike innbefatter kokosamid, laurinsyre-dietanolamid, laurinsyre-isopropanolamid, kokosnøtt-monoetanolamid, betainer og sulfobetainer. Såper av alkali-metaller, slik som natrium- og kalium-dekanoat og -laurat, kan også settes til sjampoen for å øke viskositeten til skummet som blir fremstilt ved anvendelse. If desired, the shampoo can also contain from 0.2 to 15% by weight, or more commonly 0.5 to 5% by weight, of one or more soap foam enhancers and/or stabilizers, in order to increase the soap power and foam stability. Examples of such include cocoamide, lauric acid diethanolamide, lauric acid isopropanolamide, coconut monoethanolamide, betaine and sulfobetaine. Alkali metal soaps, such as sodium and potassium decanoate and laurate, may also be added to the shampoo to increase the viscosity of the lather produced upon application.
Sjampoen kan selvsagt også om ønskes innbefatte slike ytterligere tilsetninger som parfymer, rensede oljer, farve-stoffer eller silikoner for å forhøye og forbedre den kommersielle antagelighet til produktet. The shampoo can of course also, if desired, include such additional additives as perfumes, purified oils, dyes or silicones in order to increase and improve the commercial acceptability of the product.
Resten av sjampoen omfatter vanligvis vann. The remainder of the shampoo usually comprises water.
Følgende eksempler belyser sjampoer i samsvar med foreliggende oppfinnelse. The following examples illustrate shampoos in accordance with the present invention.
Polyketon-harpikser kan fåes fra Union Carbide Chemical Corporation under varenavnet "ZKMA 0251". Polyketone resins are available from Union Carbide Chemical Corporation under the trade name "ZKMA 0251".
Vinyletyleter-harpikser kan fåes fra den samme kilde under varenavnet "EDBC", og det kan også polyvinylacetat-harpikser under varenavnet "AYAC 2517". Sukroseacetat- Vinyl ethyl ether resins can be obtained from the same source under the trade name "EDBC", and so can polyvinyl acetate resins under the trade name "AYAC 2517". Sucrose Acetate-
isobutyrat kan fåes fra Eastman Chemical International AG. isobutyrate can be obtained from Eastman Chemical International AG.
At en del av det harpiksaktige materiale i sjampoen That part of the resinous material in the shampoo
blir avsatt på håret, kan demonstreres ved å ekstrahere en prøve av håret med lettbensin og bestemme mengden av avsatt harpiksaktig materiale ved gravimetrisk analyse. is deposited on the hair, can be demonstrated by extracting a sample of the hair with light benzine and determining the amount of resinous material deposited by gravimetric analysis.
De kosmetiske egenskaper som ble gitt av sjampoene beskrevet ovenfor, ble vurdert subjektivt ved anvendelse av følgende generelle fremgangsmåte. The cosmetic properties provided by the shampoos described above were assessed subjectively using the following general procedure.
En samlet mengde av 20 hoder med hår ble vasket av fem dyktige frisører. Halvdelen av hodet ble vasket med undersøkelses-sjampoen og den andre halvdel med en sammenligningsprøve. Sammenligningsprøven var en kommersiell sjampo som ble solgt under varemerket "Sunsilk" i Storbritannia, eller når undersøkelses-sjampoen var et tofase-produkt, var sammenligningsprøven en tofase-sjampo som ble solgt i USA under varemerket "Twice-as-Nice". A total of 20 heads of hair were washed by five skilled hairdressers. Half of the head was washed with the study shampoo and the other half with a comparison sample. The comparator was a commercial shampoo sold under the trade name "Sunsilk" in the UK, or when the study shampoo was a biphasic product, the comparator was a biphasic shampoo sold in the US under the trade name "Twice-as-Nice".
"Sunsilk" har sammensetningen: "Sunsilk" has the composition:
Efter vaskeprosessen ble hver halvdel av hvert hode bedømt med hensyn til fylde-egenskaper, det vil si slike egenskaper som omfang, tetthet, oppsetning og elastisitet ved anvendelse av et punktpoeng-system. Resultatene ble behandlet statistisk for å bestemme om undersøkelsessjampoene ga fylde-effekter i noen betydelig utstrekning eller ikke. After the washing process, each half of each head was judged with regard to fullness characteristics, that is, such characteristics as volume, density, arrangement and elasticity using a point scoring system. The results were statistically processed to determine whether or not the study shampoos produced plumping effects to any significant extent.
Alle sjampoene i ovennevnte eksempler ble bedømt til at de ga fyldeeffekter. All of the shampoos in the above examples were judged to have plumping effects.
Vår henlagte søknad 4470/72 inngitt på samme dato som denne, beskriver en vandig sjampo for å gi kosmetiske egenskaper til håret, som omfatter et overflateaktivt stoff og en oppløselig-gjort eller dispergert vannuoppløselig furuharpiks som blir avsatt på håret ved fortynning av sjampoen under sjamponeringen. Sjampoer som inneholder furuharpiks som det eneste harpiksaktige materiale, omfattes ikke av foreliggende oppfinnelse. Our pending application 4470/72 filed on the same date as this describes an aqueous shampoo for imparting cosmetic properties to the hair, comprising a surfactant and a solubilized or dispersed water-insoluble pine resin which is deposited on the hair by diluting the shampoo during shampooing . Shampoos containing pine resin as the only resinous material are not covered by the present invention.
Claims (7)
Applications Claiming Priority (1)
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| DE3234365A1 (en) * | 1982-09-16 | 1984-03-22 | Henkel KGaA, 4000 Düsseldorf | OILY HAIR CONDITIONER |
| KR920700608A (en) * | 1990-01-19 | 1992-08-10 | 후쿠하라 요시하루 | Skin external preparations |
| EP1051151A1 (en) * | 1998-01-28 | 2000-11-15 | The Procter & Gamble Company | Liquid personal cleansing emulsion compositions which contain a weighting oil |
| US20050232876A1 (en) * | 2004-04-19 | 2005-10-20 | Robin Lynn Minga | Skin care compositions |
| EP2123329B1 (en) * | 2008-05-21 | 2014-07-02 | Unilever PLC | Use of hair care composition |
| MX2012008913A (en) * | 2010-02-01 | 2012-08-15 | Unilever Nv | Shampoo containing a gel network. |
| BR112013000227B1 (en) | 2010-07-08 | 2021-02-17 | Unilever N.V. | method for making a hair care composition |
| EP3708144A1 (en) * | 2019-03-11 | 2020-09-16 | Kevin Podolski | Haircare method for regeneration of hair follicles |
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| FR1256633A (en) * | 1960-02-11 | 1961-03-24 | Sulphurous shampoo and its preparation process | |
| DE1949606A1 (en) * | 1968-10-04 | 1970-06-25 | American Cyanamid Co | Hair treatment preparations |
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- 1972-12-04 ZA ZA728566A patent/ZA728566B/en unknown
- 1972-12-04 GB GB5583572A patent/GB1419117A/en not_active Expired
- 1972-12-04 LU LU66588A patent/LU66588A1/xx unknown
- 1972-12-04 AU AU49600/72A patent/AU4960072A/en not_active Expired
- 1972-12-05 JP JP47121240A patent/JPS5747236B2/ja not_active Expired
- 1972-12-05 BR BR8564/72A patent/BR7208564D0/en unknown
- 1972-12-05 DK DK606572A patent/DK132986C/en active
- 1972-12-05 NO NO4469/72A patent/NO140223C/en unknown
- 1972-12-05 BR BR8570/72A patent/BR7208570D0/en unknown
- 1972-12-05 CA CA158,271A patent/CA980254A/en not_active Expired
- 1972-12-05 IT IT70829/72A patent/IT988365B/en active
- 1972-12-05 SE SE7215862A patent/SE414703B/en unknown
- 1972-12-05 FR FR7243261A patent/FR2162464B1/fr not_active Expired
- 1972-12-06 CH CH1778972A patent/CH579910A5/xx not_active IP Right Cessation
- 1972-12-06 NL NL7216572A patent/NL7216572A/xx not_active Application Discontinuation
- 1972-12-14 ZA ZA728567A patent/ZA728567B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AT342781B (en) | 1978-04-25 |
| JPS5747236B2 (en) | 1982-10-07 |
| BR7208564D0 (en) | 1973-11-01 |
| SE414703B (en) | 1980-08-18 |
| AU471474B2 (en) | 1974-06-06 |
| CH579910A5 (en) | 1976-09-30 |
| CA980254A (en) | 1975-12-23 |
| JPS4862950A (en) | 1973-09-01 |
| FI55763C (en) | 1979-10-10 |
| IE36937L (en) | 1973-06-06 |
| FR2162464B1 (en) | 1977-01-14 |
| ATA1028972A (en) | 1977-08-15 |
| NL7216572A (en) | 1973-06-08 |
| ZA728566B (en) | 1974-07-31 |
| DK132986B (en) | 1976-03-08 |
| FI55763B (en) | 1979-06-29 |
| PH10039A (en) | 1976-07-26 |
| DE2258954A1 (en) | 1973-06-14 |
| ZA728567B (en) | 1974-07-31 |
| IE36937B1 (en) | 1977-03-30 |
| NO140223C (en) | 1979-07-25 |
| AU4959772A (en) | 1974-06-06 |
| GB1419117A (en) | 1975-12-24 |
| FR2162464A1 (en) | 1973-07-20 |
| DK132986C (en) | 1976-08-09 |
| BR7208570D0 (en) | 1973-09-25 |
| IT988365B (en) | 1975-04-10 |
| AU4960072A (en) | 1974-06-06 |
| BE792259A (en) | 1973-06-04 |
| LU66588A1 (en) | 1973-07-18 |
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