NO135825B - - Google Patents
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- Publication number
- NO135825B NO135825B NO1383/72A NO138372A NO135825B NO 135825 B NO135825 B NO 135825B NO 1383/72 A NO1383/72 A NO 1383/72A NO 138372 A NO138372 A NO 138372A NO 135825 B NO135825 B NO 135825B
- Authority
- NO
- Norway
- Prior art keywords
- ethylene
- ethane
- reaction
- oxygen
- carbon dioxide
- Prior art date
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 62
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 51
- 238000000034 method Methods 0.000 claims description 51
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 43
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 41
- 239000005977 Ethylene Substances 0.000 claims description 41
- 230000008569 process Effects 0.000 claims description 38
- 239000001569 carbon dioxide Substances 0.000 claims description 31
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 31
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 26
- 238000007254 oxidation reaction Methods 0.000 claims description 21
- 230000003647 oxidation Effects 0.000 claims description 16
- 229910001882 dioxygen Inorganic materials 0.000 claims description 15
- 239000011541 reaction mixture Substances 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 description 40
- 239000007789 gas Substances 0.000 description 31
- 239000001301 oxygen Substances 0.000 description 26
- 229910052760 oxygen Inorganic materials 0.000 description 26
- 239000000203 mixture Substances 0.000 description 23
- 239000003054 catalyst Substances 0.000 description 20
- 239000003112 inhibitor Substances 0.000 description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 11
- 239000012495 reaction gas Substances 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 239000003085 diluting agent Substances 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000376 reactant Substances 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- -1 ethane Natural products 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 229920006389 polyphenyl polymer Chemical class 0.000 description 2
- 239000002683 reaction inhibitor Substances 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- NWLGCJLMUWJWRC-UHFFFAOYSA-N CC.O=C=O Chemical compound CC.O=C=O NWLGCJLMUWJWRC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 230000005526 G1 to G0 transition Effects 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 150000004074 biphenyls Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 238000006213 oxygenation reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13625671A | 1971-04-21 | 1971-04-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO135825B true NO135825B (cs) | 1977-02-28 |
| NO135825C NO135825C (cs) | 1977-06-08 |
Family
ID=22472045
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO1383/72A NO135825C (cs) | 1971-04-21 | 1972-04-20 |
Country Status (22)
| Country | Link |
|---|---|
| AU (1) | AU461502B2 (cs) |
| BE (1) | BE781107A (cs) |
| BG (1) | BG26670A3 (cs) |
| BR (1) | BR7202448D0 (cs) |
| CA (1) | CA991196A (cs) |
| CH (1) | CH538467A (cs) |
| CS (1) | CS174833B2 (cs) |
| DD (1) | DD97199A5 (cs) |
| DE (1) | DE2219748A1 (cs) |
| DK (1) | DK130462B (cs) |
| ES (1) | ES401973A1 (cs) |
| FR (1) | FR2133879B1 (cs) |
| GB (1) | GB1382099A (cs) |
| IE (1) | IE37214B1 (cs) |
| IL (1) | IL39252A (cs) |
| IT (1) | IT952732B (cs) |
| LU (1) | LU65037A1 (cs) |
| NL (1) | NL7205026A (cs) |
| NO (1) | NO135825C (cs) |
| RO (1) | RO62421A (cs) |
| SE (1) | SE383886B (cs) |
| ZA (1) | ZA722717B (cs) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1040402B (it) * | 1974-08-06 | 1979-12-20 | Inst Neftekhim Protsessov | Procedimento per ottenere ossido di etilene |
| EP0057066B1 (en) * | 1981-01-23 | 1985-03-13 | Imperial Chemical Industries Plc | Process for the production of ethylene oxide |
| CA2078480A1 (en) * | 1992-04-20 | 1993-10-21 | Bennie Albert Horrell Jr. | Improved process for ethylene epoxidation |
| US5362890A (en) * | 1993-10-04 | 1994-11-08 | Eastman Chemical Company | Gas phase process for the epoxidation of non-allylic olefins |
| US6040467A (en) * | 1997-07-24 | 2000-03-21 | Praxair Technology, Inc. | High purity oxygen for ethylene oxide production |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1423138A (fr) * | 1963-12-16 | 1966-01-03 | Halcon International Inc | Procédé de préparation de l'oxyde d'éthylène |
| BR6795345D0 (pt) * | 1966-12-09 | 1973-03-29 | Halcon International Inc | Processo aperfeicoado para producao de oxido de etileno pela oxidacao controlada do etileno com oxigenio molecular catalisada por prata |
-
1972
- 1972-03-23 BE BE781107A patent/BE781107A/xx unknown
- 1972-03-24 LU LU65037A patent/LU65037A1/xx unknown
- 1972-04-14 NL NL7205026A patent/NL7205026A/xx unknown
- 1972-04-17 RO RO7200070565A patent/RO62421A/ro unknown
- 1972-04-19 FR FR7213728A patent/FR2133879B1/fr not_active Expired
- 1972-04-20 CA CA140,116A patent/CA991196A/en not_active Expired
- 1972-04-20 IE IE528/72A patent/IE37214B1/xx unknown
- 1972-04-20 IT IT49771/72A patent/IT952732B/it active
- 1972-04-20 NO NO1383/72A patent/NO135825C/no unknown
- 1972-04-20 IL IL39252A patent/IL39252A/en unknown
- 1972-04-20 GB GB1832472A patent/GB1382099A/en not_active Expired
- 1972-04-20 BR BR2448/72A patent/BR7202448D0/pt unknown
- 1972-04-20 DD DD162454A patent/DD97199A5/xx unknown
- 1972-04-20 CH CH584372A patent/CH538467A/fr not_active IP Right Cessation
- 1972-04-20 AU AU41385/72A patent/AU461502B2/en not_active Expired
- 1972-04-20 DK DK194572AA patent/DK130462B/da unknown
- 1972-04-20 SE SE7205155A patent/SE383886B/xx unknown
- 1972-04-21 BG BG020284A patent/BG26670A3/xx unknown
- 1972-04-21 CS CS2707A patent/CS174833B2/cs unknown
- 1972-04-21 ES ES401973A patent/ES401973A1/es not_active Expired
- 1972-04-21 DE DE19722219748 patent/DE2219748A1/de active Pending
- 1972-04-21 ZA ZA722717A patent/ZA722717B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH538467A (fr) | 1973-06-30 |
| DD97199A5 (cs) | 1973-04-20 |
| ES401973A1 (es) | 1975-03-01 |
| FR2133879B1 (cs) | 1977-07-15 |
| IE37214L (en) | 1972-10-21 |
| AU4138572A (en) | 1973-10-25 |
| AU461502B2 (en) | 1975-05-29 |
| CA991196A (en) | 1976-06-15 |
| BG26670A3 (bg) | 1979-05-15 |
| NO135825C (cs) | 1977-06-08 |
| CS174833B2 (cs) | 1977-04-29 |
| GB1382099A (en) | 1975-01-29 |
| DK130462C (cs) | 1975-07-28 |
| IL39252A0 (en) | 1972-06-28 |
| BE781107A (fr) | 1972-09-25 |
| ZA722717B (en) | 1973-11-28 |
| DK130462B (da) | 1975-02-24 |
| LU65037A1 (cs) | 1973-09-26 |
| SE383886B (sv) | 1976-04-05 |
| RO62421A (fr) | 1978-02-15 |
| IE37214B1 (en) | 1977-06-08 |
| NL7205026A (cs) | 1972-10-24 |
| BR7202448D0 (pt) | 1973-05-31 |
| FR2133879A1 (cs) | 1972-12-01 |
| DE2219748A1 (de) | 1972-11-02 |
| IL39252A (en) | 1976-05-31 |
| IT952732B (it) | 1973-07-30 |
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