NO129207B - - Google Patents
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- Publication number
- NO129207B NO129207B NO04717/70A NO471770A NO129207B NO 129207 B NO129207 B NO 129207B NO 04717/70 A NO04717/70 A NO 04717/70A NO 471770 A NO471770 A NO 471770A NO 129207 B NO129207 B NO 129207B
- Authority
- NO
- Norway
- Prior art keywords
- oil
- acid
- percent
- lubricating oil
- test
- Prior art date
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- 239000000203 mixture Substances 0.000 claims description 48
- 239000003921 oil Substances 0.000 claims description 44
- 239000010687 lubricating oil Substances 0.000 claims description 25
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- -1 aliphatic ester Chemical class 0.000 claims description 8
- 229910019142 PO4 Inorganic materials 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 239000010452 phosphate Substances 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- 239000010689 synthetic lubricating oil Substances 0.000 claims description 5
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 4
- 230000001050 lubricating effect Effects 0.000 claims description 2
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims description 2
- 150000005002 naphthylamines Chemical class 0.000 claims 1
- 238000012360 testing method Methods 0.000 description 25
- 150000002148 esters Chemical class 0.000 description 16
- 239000002253 acid Substances 0.000 description 13
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 12
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 12
- 238000005260 corrosion Methods 0.000 description 11
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 9
- 230000007797 corrosion Effects 0.000 description 8
- 238000000151 deposition Methods 0.000 description 8
- 239000002199 base oil Substances 0.000 description 7
- 239000005643 Pelargonic acid Substances 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 230000008021 deposition Effects 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 239000010935 stainless steel Substances 0.000 description 6
- 229940005605 valeric acid Drugs 0.000 description 6
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- XYHKNCXZYYTLRG-UHFFFAOYSA-N 1h-imidazole-2-carbaldehyde Chemical compound O=CC1=NC=CN1 XYHKNCXZYYTLRG-UHFFFAOYSA-N 0.000 description 4
- OVBFMEVBMNZIBR-UHFFFAOYSA-N 2-methylvaleric acid Chemical compound CCCC(C)C(O)=O OVBFMEVBMNZIBR-UHFFFAOYSA-N 0.000 description 4
- GWYFCOCPABKNJV-UHFFFAOYSA-M 3-Methylbutanoic acid Natural products CC(C)CC([O-])=O GWYFCOCPABKNJV-UHFFFAOYSA-M 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- GWYFCOCPABKNJV-UHFFFAOYSA-N beta-methyl-butyric acid Natural products CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 238000005755 formation reaction Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 3
- 229960002446 octanoic acid Drugs 0.000 description 3
- GUEIZVNYDFNHJU-UHFFFAOYSA-N quinizarin Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC=C2O GUEIZVNYDFNHJU-UHFFFAOYSA-N 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 239000013049 sediment Substances 0.000 description 3
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- UUNBFTCKFYBASS-UHFFFAOYSA-N C(CCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCC Chemical compound C(CCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCC UUNBFTCKFYBASS-UHFFFAOYSA-N 0.000 description 2
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical class C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- QBPFLULOKWLNNW-UHFFFAOYSA-N chrysazin Chemical compound O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=CC=C2O QBPFLULOKWLNNW-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000010913 used oil Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 1
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 1
- UQJDVLPHTXQTRP-UHFFFAOYSA-N 2,2-bis(heptanoyloxymethyl)butyl heptanoate Chemical compound CCCCCCC(=O)OCC(CC)(COC(=O)CCCCCC)COC(=O)CCCCCC UQJDVLPHTXQTRP-UHFFFAOYSA-N 0.000 description 1
- RRWSDYNYJQHNKL-UHFFFAOYSA-N 2-[(2-hydroxyphenyl)methylideneamino]guanidine Chemical compound NC(=N)NN=CC1=CC=CC=C1O RRWSDYNYJQHNKL-UHFFFAOYSA-N 0.000 description 1
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 description 1
- WLPQHPARWSMVFW-UHFFFAOYSA-N 2-dodecylbenzoic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1C(O)=O WLPQHPARWSMVFW-UHFFFAOYSA-N 0.000 description 1
- XUDBVJCTLZTSDC-UHFFFAOYSA-N 2-ethenylbenzoic acid Chemical compound OC(=O)C1=CC=CC=C1C=C XUDBVJCTLZTSDC-UHFFFAOYSA-N 0.000 description 1
- SJOKOBRBIZPCSB-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;pentanoic acid Chemical compound CCCCC(O)=O.CCC(CO)(CO)CO SJOKOBRBIZPCSB-UHFFFAOYSA-N 0.000 description 1
- LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 description 1
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 1
- WLJVXDMOQOGPHL-PPJXEINESA-N 2-phenylacetic acid Chemical compound O[14C](=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-PPJXEINESA-N 0.000 description 1
- MLMQPDHYNJCQAO-UHFFFAOYSA-N 3,3-dimethylbutyric acid Chemical compound CC(C)(C)CC(O)=O MLMQPDHYNJCQAO-UHFFFAOYSA-N 0.000 description 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- RVKKRRXSXPNVLU-UHFFFAOYSA-N C(CCCCCCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCCCCCC Chemical compound C(CCCCCCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCCCCCC RVKKRRXSXPNVLU-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 101500021084 Locusta migratoria 5 kDa peptide Proteins 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 description 1
- AOZDHFFNBZAHJF-UHFFFAOYSA-N [3-hexanoyloxy-2,2-bis(hexanoyloxymethyl)propyl] hexanoate Chemical compound CCCCCC(=O)OCC(COC(=O)CCCCC)(COC(=O)CCCCC)COC(=O)CCCCC AOZDHFFNBZAHJF-UHFFFAOYSA-N 0.000 description 1
- 239000011825 aerospace material Substances 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- JPICKYUTICNNNJ-UHFFFAOYSA-N anthrarufin Chemical compound O=C1C2=C(O)C=CC=C2C(=O)C2=C1C=CC=C2O JPICKYUTICNNNJ-UHFFFAOYSA-N 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- GONOPSZTUGRENK-UHFFFAOYSA-N benzyl(trichloro)silane Chemical compound Cl[Si](Cl)(Cl)CC1=CC=CC=C1 GONOPSZTUGRENK-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- NZNMSOFKMUBTKW-UHFFFAOYSA-N cyclohexanecarboxylic acid Chemical compound OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 description 1
- 229960001577 dantron Drugs 0.000 description 1
- 150000004341 dihydroxyanthraquinones Chemical class 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- FRMDQIFINGQFGQ-UHFFFAOYSA-N n-[4-(2,4,4-trimethylpentan-2-yl)phenyl]naphthalen-2-amine Chemical compound C1=CC(C(C)(C)CC(C)(C)C)=CC=C1NC1=CC=C(C=CC=C2)C2=C1 FRMDQIFINGQFGQ-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- IELLVVGAXDLVSW-UHFFFAOYSA-N tricyclohexyl phosphate Chemical compound C1CCCCC1OP(OC1CCCCC1)(=O)OC1CCCCC1 IELLVVGAXDLVSW-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M3/00—Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/025—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with condensed rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/042—Metal salts thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/12—Gas-turbines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/12—Gas-turbines
- C10N2040/13—Aircraft turbines
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Syntetisk smøreoljesammensetning. Synthetic lubricating oil composition.
Foreliggende oppfinnelse angår syntetiske smøreoljesammen-setninger som brukes i gassturbin- eller jetmotorer. Gassturbinmotorer utsetter- smøremidlet for ekstreme forhold og det dannes indre motortemperaturer på 205-260°C eller høyere. Dette miljø angriper smøreoljen sterkt, slik at de mest avanserte smøreoljesammensetninger på mineraloljebasis ikke kan brukes til gassturbinmotorer. The present invention relates to synthetic lubricating oil compositions used in gas turbine or jet engines. Gas turbine engines expose the lubricant to extreme conditions and internal engine temperatures of 205-260°C or higher are formed. This environment strongly attacks the lubricating oil, so that the most advanced lubricating oil compositions on a mineral oil basis cannot be used for gas turbine engines.
I det siste har man med hell anvendt smøreoljeblandinger Recently, lubricating oil mixtures have been used with success
på basis av syntetiske estere, inneholdende en omhyggelig avpasset blanding av additiver, for smøring av gassturbinmotorer. Disse oljer på esterbasis er' virksomme innenfor et bredt temperaturområde og oppviser høy varmestabilitet, slitasjebestandighet, bæreevne og antioksydasjons-egenskaper samtidig som blandingen gir god smøring. on the basis of synthetic esters, containing a carefully adjusted mixture of additives, for the lubrication of gas turbine engines. These ester-based oils are effective within a wide temperature range and exhibit high thermal stability, wear resistance, load-bearing capacity and antioxidant properties, while the mixture provides good lubrication.
Med utviklingen av nyere og kraftigere gassturbinmotorer With the development of newer and more powerful gas turbine engines
som tas i bruk innen overlydsflyvning, stilles større krav med hensyn til temperaturbelastning og oksydasjonsbelastning av smøreoljen. which are used in supersonic flight, greater demands are made with regard to temperature stress and oxidation stress of the lubricating oil.
Ifølge foreliggende oppfinnelse er tilveiebragt en According to the present invention, a
syntetisk smøreoljesammensetning inneholdende en hoveddel olje på synthetic lubricating oil composition containing a major part of oil
basis av alifatisk ester med smørende egenskaper, fremstilt ved omsetning av pentaerytritol eller en polypentaerytritol eller trimetylolpropan og en organisk monokarboksylsyre med fra ca. 2 til 18 karbo-atomer pr. molekyl, samt et dialkyldifenylamin, en polyhydroksyantrachinon og et trihydrokarbylfosfat, kjennetegnet ved at den inneholder base of aliphatic ester with lubricating properties, produced by reacting pentaerythritol or a polypentaerythritol or trimethylolpropane and an organic monocarboxylic acid with from approx. 2 to 18 carbon atoms per molecule, as well as a dialkyldiphenylamine, a polyhydroxyanthraquinone and a trihydrocarbyl phosphate, characterized in that it contains
a) fra 0,3 til 5 vektprosent av sammensetningen av et a) from 0.3 to 5 percent by weight of the composition of a
alkyl- eller alkaryl-fenylnaftylamin, hvor alkyl- og alkarylradikalet alkyl- or alkaryl-phenylnaphthylamine, where the alkyl and alkaryl radical
har fra 4 til 12 karboatomer, has from 4 to 12 carbon atoms,
b) fra 0,3 til 5 prosent av nevnte dialkyldifenylamin, b) from 0.3 to 5 percent of said dialkyldiphenylamine,
c) fra 0,001 til 1 prosent av nevnte polyhydroksyantrachinon, og d) fra. 0,25 til 10 prosent av nevnte trihydrokarbylfosfat. c) from 0.001 to 1 percent of said polyhydroxyanthraquinone, and d) from. 0.25 to 10 percent of said trihydrocarbyl phosphate.
Smøreoljesammensetningen ifølge oppfinnelsen gir vesent- The lubricating oil composition according to the invention provides essentially
lige forbedringer i avleiringsmengden, korrosjonsbeskyttelse av rustfritt stål og har fremragende temperatur- og oksydasjonsstabilitet. Disse gode egenskaper blir oppnådd ved en kritisk avbalansert og sammensatt smøreoljeblanding på basis av syntetisk ester. Resultatene var overraskende og uventet fordi de er like gode eller bedre enn egenskapene til en fremragende kjent smøreoljesammensetning på syntetisk esterbasis og ble oppnådd med en oljesammensetning som var avgjørende og kritisk modifisert med hensyn til at blandingen ikke inneholdt et additiv som er betraktet som nødvendig for fremstilling av en kommersielt kjent syntetisk smøreolje, nemlig en smøre-olje som er beskrevet i britisk patent nr. 1.020.526. Det additiv det her menes er et ekvimolekylart salt av 1-salicylalaminoguanidin og en alifatisk karboksylsyre. En vesentlig forskjell ved sammensetningen i nevnte patent og den i foreliggende oppfinnelse, er at det anvendes forskjellige antioksydasjonsmidler hvilket resulterer i forskjellige egenskaper. Således benyttes det i det britiske patent usubstituert fenylnaftylamin, mens det i foreliggende sammensetning anvendes et alkyl- eller alkyl-substituert fenylnaftylamin. Forsøk viser at blant annet bruken av slike forskjellige antioksydasjonsmidler resulterer i at man ved anvendelse av foreliggende sammensetning får en vesentlig lavere grad av avleiring og en større viskositets- equal improvements in the amount of scale, corrosion protection of stainless steel and has excellent temperature and oxidation stability. These good properties are achieved by a critically balanced and complex lubricating oil mixture based on synthetic ester. The results were surprising and unexpected because they are as good as or better than the properties of an outstanding known synthetic ester base lubricating oil composition and were obtained with an oil composition that was crucially and critically modified in that the composition did not contain an additive considered necessary for manufacture of a commercially known synthetic lubricating oil, namely a lubricating oil described in British Patent No. 1,020,526. The additive referred to here is an equimolecular salt of 1-salicylalaminoguanidine and an aliphatic carboxylic acid. A significant difference in the composition in the said patent and that in the present invention is that different antioxidants are used, which results in different properties. Thus, unsubstituted phenylnaphthylamine is used in the British patent, while in the present composition an alkyl- or alkyl-substituted phenylnaphthylamine is used. Experiments show that, among other things, the use of such different antioxidants results in a substantially lower degree of deposition and a greater viscosity-
økning enn ved bruk av den kjente sammensetning (kfr. nedenstående tabell I og II hvor "olje E" og "olje F" henholdsvis representerer sammensetningen i det britiske patent og den ifølge foreliggende oppfinnelse). increase than when using the known composition (cf. Tables I and II below where "oil E" and "oil F" respectively represent the composition in the British patent and the one according to the present invention).
Hovedkomponenten i smøremidlet i henhold til oppfinnelsen er én væske på esterbasis fremstilt fra pentaerytritol eller trimetylolpropan og en blanding av hydrokarbyl-monokarboksylsyrer. Polypentaerytritoler som dipentaerytritol, tripentaerytritol og tetra-pentaerytritol kan også brukes til reaksjonen for fremstilling av basisoljen. The main component of the lubricant according to the invention is an ester-based liquid made from pentaerythritol or trimethylolpropane and a mixture of hydrocarbyl monocarboxylic acids. Polypentaerythritols such as dipentaerythritol, tripentaerythritol and tetra-pentaerythritol can also be used for the reaction to produce the base oil.
De hydrokarbonmonokarboksylsyrer som brukes for fremstilling av esterbasisoljen omfatter rettkjedede og forgrenede alifatiske syre, cykloalifatiske syrer og aromatiske syrer, samt blandinger av disse. De syrene som brukes har fra ca. 2 til 18 C-atomer i mole-kylet, fortrinnsvis fra ca. 5 til 10 C-atomer. Eksempler på slike spesielle syrer er eddiksyre, propionsyre, smøresyre, valeriansyre, isovaleriansyre, kaprionsyre, dekanoinsyre, heksadekanoinsyre, vinyl-benzosyre, dodecylbenzosyre, pelargonsyre, heksansyre, cykloheksan-syre, naftensyre, benzosyre, fenyleddiksyre, t-butyleddiksyre og 2-etylheksansyre. The hydrocarbon monocarboxylic acids used for the production of the ester base oil include straight-chain and branched aliphatic acids, cycloaliphatic acids and aromatic acids, as well as mixtures thereof. The acids used have from approx. 2 to 18 C atoms in the molecule, preferably from approx. 5 to 10 C atoms. Examples of such special acids are acetic acid, propionic acid, butyric acid, valeric acid, isovaleric acid, capric acid, decanoic acid, hexadecanoic acid, vinyl-benzoic acid, dodecylbenzoic acid, pelargonic acid, hexanoic acid, cyclohexanoic acid, naphthenic acid, benzoic acid, phenylacetic acid, t-butylacetic acid and 2-ethylhexanoic acid.
Generelt omsettes disse syrer i mengdeforhold som fører til en fullstendig forestret pentaerytritol eller trimetylolpropan, hvor foretrukne esterbaser er pentaerytritol-tetraestere. Eksempler på slike markedsførte"tetraestere er pentaerytritol-tetrakaproat som fremstilles fra renset pentaerytritol og rå kaprionsyre og inneholder andre C5_]_q monobasiske syrer. Andre egnede tetraestere fremstilles fra teknisk pentaerytritol og en blanding av syrer som omfatter 38 prosent valeriansyre, 13 prosent 2-metylpentansyre, 32 prosent oktansyre og 17 prosent pelargonsyre. Andre effektive estere er tri-esteren av trimetylolpropan hvor trimetylolpropanet er forestret med en blanding av monobasiske syrer bestående av 2 prosent valeriansyre, 9 prosent kaprionsyre, 13 prosent heptansyre, 7 prosent oktansyre, 3 prosent kaprylsyre, 65 prosent pelargonsyre og .1 prosent kaprinsyre. Trimetylolpropan-triheptanoat, trimetylolpropan pentanoat og tri-metylolpropanheksanoat er også egnede basisestere. In general, these acids are reacted in quantities that lead to a fully esterified pentaerythritol or trimethylolpropane, where preferred ester bases are pentaerythritol tetraesters. Examples of such marketed "tetraesters" are pentaerythritol tetracaproate which is prepared from purified pentaerythritol and crude capryonic acid and contains other C5_]_q monobasic acids. Other suitable tetraesters are prepared from technical pentaerythritol and a mixture of acids comprising 38 percent valeric acid, 13 percent 2-methylpentanoic acid . 65 percent pelargonic acid and .1 percent capric acid.Trimethylolpropane triheptanoate, trimethylolpropane pentanoate and trimethylolpropanehexanoate are also suitable base esters.
Basisesteren utgjør hoveddelen -av den ferdig sammensatte syntetiske oljesammensetning på esterbasis. Generelt utgjør basisesteren 90 til 98% av sammensetningen.. The base ester forms the main part of the ready-made ester-based synthetic oil composition. In general, the base ester makes up 90 to 98% of the composition.
Den essensielle alkyl- eller alkaryl-fenylnaftylaminkompo-nent i smøremidlet i henhold til oppfinnelsen har formelen The essential alkyl or alkaryl-phenylnaphthylamine component in the lubricant according to the invention has the formula
hvor R betegner et alkyl- eller alkarylradikal med fra 4 til 12 C-atomer. Denne gruppe kan være rettkjedet eller forgrenet, men hvor tertiært alkylstrukturen foretrekkes, eller kan være et alkarylradikal. Naftylaminet kan være enten a- eller 3-naftylamin. Spesielle effektive forbindelser innenfor denne klasse omfatter N-p-t-oktyl-fenyl-a-naftylamin, N-(p-a-kumylfenyl)-6-a-kumyl-B-naftylamin, N-p-t-oktylfenyl-3-naftylamin og tilsvarende p-t-dodecylfenyl-, p-t-butylfenyl-, og p-dodecylfenyl-a- og -g-naftylaminer. Foretrukne konsentrasjoner av denne komponent er fra ca. 0,5 til 2,5%. En annen essensiell bestanddel i smøreoljesammensetningen ifølge oppfinnelsen er et dialkyldifenylamin. Disse forbindelser where R denotes an alkyl or alkaryl radical with from 4 to 12 C atoms. This group can be straight-chain or branched, but where the tertiary alkyl structure is preferred, or can be an alkaryl radical. The naphthylamine can be either α- or 3-naphthylamine. Particular effective compounds within this class include N-p-t-octyl-phenyl-a-naphthylamine, N-(p-a-cumylphenyl)-6-a-cumyl-B-naphthylamine, N-p-t-octylphenyl-3-naphthylamine and corresponding p-t-dodecylphenyl-, p-t -butylphenyl-, and p-dodecylphenyl-a- and -g-naphthylamines. Preferred concentrations of this component are from approx. 0.5 to 2.5%. Another essential component in the lubricating oil composition according to the invention is a dialkyldiphenylamine. These connections
hvor R betegner et alkylradikal med fra ca. 4 til 12 C-atomer. Egnede alkylaminer er dioktyldifenylamin, didecyldifenylamin, didodecyldi-fenylamin, diheksyldifenylamin og lignende forbindelser. Dioktyldifenylamin er den foretrukne forbindelse dg den foretrukne konsentrasjon 0,5 til 2, 0%. where R denotes an alkyl radical with from approx. 4 to 12 C atoms. Suitable alkylamines are dioctyldiphenylamine, didecyldiphenylamine, didodecyldiphenylamine, dihexyldiphenylamine and similar compounds. Dioctyldiphenylamine is the preferred compound and the preferred concentration is 0.5 to 2.0%.
Den essensielle metalldeaktivator i'smøreoljesammenset-ningen er et polyhydroksyantrachinon. Egnede forbindelser innenfor denne klasse er dihydroksyåntrachinoner som 1,4-dihydroksyantrachinon, også kjent som chinizarin, 1,5-dihydroksyantrachinon og 1,8-dihydroksyantrachinon,' og høyere polyhydroksyantrachinoner. Den foretrukne konsentrasjon av denne komponent ligger mellom ca. 0,01 og 0,5 vektprosent . The essential metal deactivator in the lubricating oil composition is a polyhydroxyanthraquinone. Suitable compounds within this class are dihydroxyanthraquinones such as 1,4-dihydroxyanthraquinone, also known as chinizarin, 1,5-dihydroxyanthraquinone and 1,8-dihydroxyanthraquinone,' and higher polyhydroxyanthraquinones. The preferred concentration of this component is between approx. 0.01 and 0.5% by weight.
Den avsluttende kritiske komponent i smøreoljesammensetning-en i henhold til oppfinnelsen er en hydrokarbylfosfatester, mer spesielt et trihydrokarbylfosfat hvor hydrokarbylradikalet er alkyl, aryl, alkaryl, cykloalkyl eller aralkyl, eller blandinger av disse med fra 2 til 12 C-atomer, fortrinnsvis fra 4-8 C-atomer. Effektive spesielle forbindelser er trikresylfosfat, kresyldifenylfosfat, trifenylfosfat, tributylfosfat, tri(2-etylheksyl)-fosfat og tri-cykloheksylfosfat. Disse forbindelser foreligger fortrinnsvis i smøreoljesammensetningen i konsentrasjoner på mellom ca. 0,5 og 5%• The final critical component in the lubricating oil composition according to the invention is a hydrocarbyl phosphate ester, more particularly a trihydrocarbyl phosphate where the hydrocarbyl radical is alkyl, aryl, alkaryl, cycloalkyl or aralkyl, or mixtures thereof with from 2 to 12 C atoms, preferably from 4- 8 C atoms. Effective special compounds are tricresyl phosphate, cresyl diphenyl phosphate, triphenyl phosphate, tributyl phosphate, tri(2-ethylhexyl) phosphate and tri-cyclohexyl phosphate. These compounds are preferably present in the lubricating oil composition in concentrations of between approx. 0.5 and 5%•
Smbreoljesammensetningen i henhold til oppfinnelsen ble provet med henblikk på oksydasjons- og korrosjonsbestandighet ved oksydasjons-korrosjons-prbver og med henblikk på avleiringer og termostabilitet ved 1.5 Erdco lagerprove (1.5 Erdco Bearing Tests) og Erdco sorteringsprove (Erdco Screening Tes.t) beskrevet nedenfor. The lubricating oil composition according to the invention was tested for oxidation and corrosion resistance in oxidation-corrosion tests and for deposits and thermal stability in the 1.5 Erdco Bearing Tests and the Erdco Screening Test described below.
Oksydasjons-, og. korrosjonsprbven ved .204,5°C/72 timer Oxidation, and. the corrosion test at .204.5°C/72 hours
og 2l8,5°C/72 timer, gjennomføres i henhold til. metode .5308.4 i Federal Test Method and Standard No. 791a (av 31. desember 1961), bortsett ,fra modifikasjoner i henhold .til MIL-L-23699B. Badtém-peraturen holdes på respektivt 204,5 og 218,5°C. - 0,5°C (400 og 425°F - 1°F), i stedet"for ved 121°C og forsøkene gjennomføres over et tidsrom på 72 timer i stedet for 168. timer som spesifisert i originalprbven. and 2l8.5°C/72 hours, is carried out in accordance with. method .5308.4 in Federal Test Method and Standard No. 791a (of 31 December 1961), except for modifications in accordance with MIL-L-23699B. The bath temperature is maintained at 204.5 and 218.5°C, respectively. - 0.5°C (400 and 425°F - 1°F), instead of at 121°C and the tests are carried out over a period of 72 hours instead of 168 hours as specified in the original test.
Erdco sorteringsprove brukes- for testing av smbreolje-sammensetninger og består i å sirkulere en smbreolje under regu-lerte og kontrollerte betingelser i et bestemt tidsrom gjennom et gjennomluftet testkammer som inneholder et oppvarmet aluminiums-rbr. Ved avslutning av forsbket granskes tre bestemte områder.på aluminiumsrøret visuelt., og eventuelle avleiringer eller flekk-dannelser noteres og bedbmmes numerisk med karakterangivelse. The Erdco sorting sample is used for testing lubricant oil compositions and consists of circulating a lubricant oil under regulated and controlled conditions for a specific period of time through a ventilated test chamber containing a heated aluminum tube. At the end of the test, three specific areas on the aluminum tube are examined visually, and any deposits or spot formations are noted and graded numerically.
Apparaturen som brukes til denne prove er i det vesent-lige Wrigrfc Air Development Center Deposition Test Rig (avleirings-forsbksapparatur ifblge Wright Air Development, Center) som beskrevet i Federal Test Method Standard, metode 5003.med fblgende modifikasjoner: 1) Ledningsfilteret erstattes med et aluminiumsrør 89 cm langt og 4,76 mm i diameter. 2) Reservoirkolhen erstattes med en gradert 100 ml etter-fyl^ingsbeholder. 3) Oljekjbleren brukes bare for kjbling ay oljen på slutten av forsbket. The apparatus used for this test is essentially the Wright Air Development Center Deposition Test Rig (deposition test apparatus according to Wright Air Development, Center) as described in the Federal Test Method Standard, method 5003, with the following modifications: 1) The line filter is replaced with an aluminum tube 89 cm long and 4.76 mm in diameter. 2) The reservoir carbon is replaced with a graduated 100 ml refill container. 3) The oil cooler is only used for cooling the oil at the end of the test.
4) "På-av"-bryteren for oljetemperatur brukes ikke. 4) The oil temperature "on-off" switch is not used.
5) Filtertrykfcmåleren frakoples. 5) The filter pressure gauge is disconnected.
Patronvarmerenden på avleiringsrbret settes inn i en chuck som roterer med 17.00 til 1800 omdreininger pr. minutt. Alle avleiringer fjernes fra avleiringsrbret med silisiumkarbid nr. 400 papir fulgt av avstbving med en ren myk klut. Luftstrømmen reguleres, til innføring.av 300 ml pr. minutt mettet luft,med atmos-færetrykk og temperatur 49 - 2,7°C (120 <-> 5°F) og temperaturregu- The cartridge heater end of the depositing board is inserted into a chuck which rotates at 17.00 to 1800 revolutions per minute. minute. All deposits are removed from the deposit board with silicon carbide No. 400 paper followed by dusting with a clean soft cloth. The air flow is regulated, for the introduction of 300 ml per minute saturated air, with atmospheric pressure and temperature 49 - 2.7°C (120 <-> 5°F) and temperature regula-
lator på 274°C lator at 274°C
Apparaturen skylles med en oljeladning i 10 minutter og påfylles frisk olje ved oppfylling av det graderte reservoir til 100 ml merket. Oljenivået i avleiringskaret reguleres til det står omkring 1,25 cm over bunnen i glasset. The apparatus is rinsed with an oil charge for 10 minutes and topped up with fresh oil by filling the graduated reservoir to the 100 ml mark. The oil level in the deposit vessel is regulated until it is about 1.25 cm above the bottom of the glass.
Fremgangsmåten ved forsoket er som folger: The procedure for the trial is as follows:
Man slår på avleiringsvarmeroret og innstiller regula-toren på 149°C (300°F). Man holder temperaturen i 5 minutter og innstiller på 204°C (400°F). Man fortsetter til en temperatur på 316°C (600°F) er nådd. Etterhvert som forsoksoljen oppvarmes og utvides, tappes det av olje slik at man holder et nivå 63 mm over bunnen i avleiringsglasset. Man holder likevekts-temperaturforhold ved hjelp av ovnstemperaturen og riktig oljenivå, som dekker avleiringsrbret som omtalt ovenfor. Etterhvert som fordampning finner' sted tilsettes ny olje fra beholderen fo'r å holde riktig nivå. Etter 6 timers kjbring slås avleiringsvarmeren av, man slår på vannkjoler og lar utgående oljetemperatur synke til 122°C. Man slår av alle brytere og luft- og vanntilfbrsler. The deposition heater is switched on and the regulator is set to 149°C (300°F). The temperature is maintained for 5 minutes and set to 204°C (400°F). This is continued until a temperature of 316°C (600°F) is reached. As the pilot oil heats up and expands, the oil is drained so that a level of 63 mm above the bottom of the deposit glass is maintained. Equilibrium temperature conditions are maintained by means of the oven temperature and the correct oil level, which covers the deposit surface as discussed above. As evaporation takes place, new oil is added from the container to maintain the correct level. After 6 hours of heating, the deposit heater is switched off, water jets are switched on and the outgoing oil temperature is allowed to drop to 122°C. All switches and air and water supply valves are switched off.
Etter ca. 18 timers avbrutt prove, gjenopptas forsoket After approx. 18 hours of interrupted test, the attempt is resumed
på samme måten som for opprinnelig start og man fortsetter prbven under standardforhold som angitt i nye seks timer. (Man vil even-tuelt tilsette 5 til 10 ml ny olje til den brukte oljen for å bringe oljenivået opp til 1,25 cm over bunnen av avleiringsglasset). Etter avsluttet oppvarming slås varmeroret av, oljen kjoles og luftstrømmen stanses. Den brukte olje tappes av og avleiringsrbret tas ut fra beholderen. Avleiringsrbret senkes i n-pentan til alle synlige spor av olje er fjernet og blir deretter luft-tbrket. in the same way as for the original start and the test is continued under standard conditions as indicated for another six hours. (You may want to add 5 to 10 ml of new oil to the used oil to bring the oil level up to 1.25 cm above the bottom of the deposit glass). After the heating is finished, the heater is switched off, the oil is cooled and the air flow is stopped. The used oil is drained off and the sediment board is removed from the container. The sediment board is immersed in n-pentane until all visible traces of oil have been removed and is then air-dried.
Avleiringsrbret betraktes på forsiden som vendte inn The deposit rib is considered on the front as facing inwards
mot luftinnlbpet i avleiringsbeholderen. For å bedbmme avleiring-ene anbringes en sjablong med 1/2" graderinger over disse områder med 1 l/2" linjen anbragt på kontaktflaten damp/olje. Hvert halv^ toms segment bedbmmes numerisk med henblikk på type og tykkelse avleiring på dette område. Hvis avleiringenes bedbmmelseskarak-ter varierer innenfor et segment, brukes det hbyeste tall. Man knytter en vektfaktor til hvert av de tre, hovedområder for å få against the air inlet in the deposit container. To measure the deposits, a stencil with 1/2" graduations is placed over these areas with the 1 l/2" line placed on the steam/oil contact surface. Each half-inch segment is measured numerically with regard to the type and thickness of the deposit in this area. If the sediments' grading characteristics vary within a segment, the highest number is used. A weighting factor is attached to each of the three main areas to obtain
me(d forskjeller i deres relative betydning. Den samlede avleiringskarakter fåes ved å legge sammen karakterene for hovedområdene og multiplisere med vektfaktoren. Summen av tre områdekarakterer me(d differences in their relative importance. The overall deposit grade is obtained by adding up the grades for the main areas and multiplying by the weighting factor. The sum of three area grades
dividert med- '2 gir: total avleiringskarakter. divided by - '2 gives: total deposit grade.
Bedbmmelsesskalen for avleiringsrbret er oppfort i fblgende tabell: The assessment scale for the deposit body is listed in the following table:
Porsbksresultatene viser god reproduserbarhet og god overensstemmelse med data fra Erdco lagerprbve under betingelsene type 1.5 med hensyn på flekkdannelse og kulldannelse. The Porsbks results show good reproducibility and good agreement with data from Erdco storage tests under conditions type 1.5 with regard to spot formation and carbon formation.
Basisoljen A i smbreoljesammensetninger testet nedenfor var en teknisk kvalitet pentaerytritol inneholdende en mindre mengde dipentaerytritol forestret med en blanding av fettsyrer som i molprosent inneholdt ca. 38 $ valeriansyre, 13 i° 2-metylpentansyre, 32 $ n-oktansyre og 17 i° pelargonsyre, med en midlere The base oil A in the oil compositions tested below was a technical grade pentaerythritol containing a small amount of dipentaerythritol esterified with a mixture of fatty acids which in mole percentage contained approx. 38 $ valeric acid, 13 i° 2-methylpentanoic acid, 32 $ n-octanoic acid and 17 i° pelargonic acid, with a mean
■ syre-C-kjedelengde'"på ca. 6,5. Basisoljen hadde fblgende egenskaper ■ acid C chain length of about 6.5. The base oil had the following properties
Basisolje B var en teknisk kvalitet pentaerytritol forestret med en blanding av fettsyrer som i molprosent inneholdt ca. 12 % isovaleriansyre, 27 $ valeriansyre, 8 i° kaprionsyre, 14 i° heptylsyre, 19 $ kaprylsyre og 13 i° pelargonsyre.. Base oil B was a technical quality pentaerythritol esterified with a mixture of fatty acids which in mole percentage contained approx. 12% isovaleric acid, 27% valeric acid, 8% caprionic acid, 14% heptyl acid, 19% caprylic acid and 13% pelargonic acid.
Basisolje C var en teknisk pentaerytritol forestret med en blanding av fettsyrer som i molprosent inneholdt ca. 8 $ isovaleriansyre, 23 i° valeriansyre, 20 $ kapronsyre, 27 i° heptylsyre, 7 i° kaprylsyre og 16 % pelargonsyre. Base oil C was a technical pentaerythritol esterified with a mixture of fatty acids which in mole percentage contained approx. 8 $ isovaleric acid, 23 i° valeric acid, 20 $ caproic acid, 27 i° heptyl acid, 7 i° caprylic acid, and 16% pelargonic acid.
Sammensetningen av oppfinnelsens smbreoljer og sammen-ligningsoljer, samt resultater fra oksydasjons-korrosjons-prbvene er angitt i tabell I nedenfor. Smbreoljene E, G, H og I representerer foreliggende oppfinnelse. The composition of the lubricating oils of the invention and comparison oils, as well as the results of the oxidation-corrosion tests, are given in Table I below. The spreading oils E, G, H and I represent the present invention.
Basisoljen D var en .teknisk pentaerytritol forestret med en blanding av fettsyrer som i'molprosent inneholdt ca. 18 $ isovaleriansyre, 39 i° valeriansyre, 2 $ kaprylsyre og 40 <<>fo pelargonsyre. The base oil D was a technical pentaerythritol esterified with a mixture of fatty acids which contained approx. 18 $ isovaleric acid, 39 i° valeric acid, 2 $ caprylic acid, and 40 <<>fo pelargonic acid.
Smøreoljene A, B, C og D oppfyller ikke de militære spesifikasjoner-for oksydasjons-korrosjons-prover, særlig ved at de har meget dårlig viskositetskonstans og hby syredannelse. Oljen A oppfyller heller ikke korrosjonsspesifikasjonene med henblikk på kobber og magnesium. Disse olje sammensetninger viser de snevre krav som stilles til de fire additivkomponenter i henhold til oppfinnelsens oljesammensetning. Smøreoljene E, G, H og I er eksempler på sammensetninger i henhold til oppfinnelsen og de er like gode som eller bedre enn en fremragende markedsfbrt og kjent syntetisk esterbasert olje anfort i sammenligningen. The lubricating oils A, B, C and D do not meet the military specifications for oxidation-corrosion tests, particularly in that they have very poor viscosity constancy and high acid formation. Oil A also does not meet the corrosion specifications with regard to copper and magnesium. These oil compositions show the narrow requirements that are placed on the four additive components according to the oil composition of the invention. The lubricating oils E, G, H and I are examples of compositions according to the invention and they are as good as or better than an outstanding commercial and known synthetic ester-based oil cited in the comparison.
Avleiiringsegenskapene ■ f or oppfinnelsens esterbaserte smoreoljesammensetninger og markedsførte kjente syntetiske esterbaserte oljer ble sammenlignet ved Erdco avleiringsproven beskrevet oTanfor og Erdco lagerprbven, type: 1.5. Disse resultater- r?r oppfort i tabell II nedenfor: The deposition properties ■ for the invention's ester-based lubricating oil compositions and marketed known synthetic ester-based oils were compared by the Erdco deposition test described above and the Erdco stock test, type: 1.5. These results are listed in table II below:
Alle olje sammensetningene i henhold til oppfinnelsen oppfyller de gjeldende militære spesifikasjoner. Videre hadde de bedre karakterer enn en kjent smoreolje på esterbasis, smoreolje F. All the oil compositions according to the invention meet the applicable military specifications. Furthermore, they had better grades than a known ester-based lubricating oil, lubricating oil F.
Smoreoljesammensetningene C og E og en kjent esterbasert olje ble sammenlignet med hensyn på korrosivitet på rustfritt stål ved "410 Stainless Steel Corrosion Test" (korrosjonsprove for rustfritt stål, nr. 410). Ved dette forsok ble plater (2,5 x 15 x 0,32 cm) fremstilt av rustfrie stålplater nr. 410, som tilfredsstiller Aerospace Material Specification 5504 med Brinell-hårdhet på ca. B76 og overflatebehandling på 2D. To proveplater veies til nærmeste 0,1 mg og anbringes i en nikkelbombe sammen med 65 ml av den olje som skal proves. Oljen i bomben oppvarmes til 260°C og holdes ved denne temperatur i 72 timer. Deretter avkjbles oljen til romtemperatur, 5 ml olje tas ut for å bestemme total syretall og bomben inneholdende proveplater settes tilbake ved 260°C i nye 72 timer. Deretter avkjbles bomben og platene renses og veies til nærmeste 0,1 mg. Oljens viskositet ved 38°C og totalt syretall for oljen måles. Resultatene er oppfort i tabell III. The lubricating oil compositions C and E and a known ester-based oil were compared with regard to corrosivity on stainless steel by the "410 Stainless Steel Corrosion Test" (corrosion test for stainless steel, no. 410). In this experiment, plates (2.5 x 15 x 0.32 cm) were produced from No. 410 stainless steel plates, which satisfy Aerospace Material Specification 5504 with a Brinell hardness of approx. B76 and surface treatment on 2D. Two sample plates are weighed to the nearest 0.1 mg and placed in a nickel bomb together with 65 ml of the oil to be tested. The oil in the bomb is heated to 260°C and kept at this temperature for 72 hours. The oil is then cooled to room temperature, 5 ml of oil is taken out to determine the total acid number and the bomb containing the test plates is put back at 260°C for another 72 hours. The bomb is then disconnected and the plates are cleaned and weighed to the nearest 0.1 mg. The viscosity of the oil at 38°C and the total acid value of the oil are measured. The results are listed in Table III.
Ovenstående forsbk viser den vesentlig bedre evne hos smoreoljesammensetningen ifblge oppfinnelsen til å hindre korro-sjon av rustfritt stål nr. 410 sammenlignet med denne evne hos en kjent markedsfbrt olje og en lignende oljesammensetning som ikke inneholdt trikresylfosfat. The above test shows the significantly better ability of the lubricating oil composition according to the invention to prevent corrosion of stainless steel No. 410 compared to this ability of a known marketed oil and a similar oil composition which did not contain tricresyl phosphate.
Smoreoljesammensetningen i henhold til oppfinnelsen er særlig god med hensyn på oksydasjonsstabilitet, korrosjonsbeskyttelse og lav avleiringstendens som riet fremgår av de anfbrte forsbk. Smoreolje E er godkjent undtr,U.S. Navy's MIL-L-23699B-spesifikasjoner og spesifikasjoner tii Pratt og Whitney Aircraft 521B, og oljene G og H oppfyller også disse spesifikasjoner. The lubricating oil composition according to the invention is particularly good with regard to oxidation stability, corrosion protection and low depositing tendency, as can be seen from the tests cited. Lubricating oil E is approved except for the U.S. Navy's MIL-L-23699B specifications and Pratt and Whitney Aircraft 521B specifications, and the oils G and H also meet these specifications.
Claims (3)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US88532969A | 1969-12-15 | 1969-12-15 |
Publications (1)
Publication Number | Publication Date |
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NO129207B true NO129207B (en) | 1974-03-11 |
Family
ID=25386658
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO04717/70A NO129207B (en) | 1969-12-15 | 1970-12-08 |
Country Status (11)
Country | Link |
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JP (1) | JPS4943542B1 (en) |
BE (1) | BE759673A (en) |
CH (1) | CH558422A (en) |
DE (1) | DE2060750C3 (en) |
ES (1) | ES386259A1 (en) |
FR (1) | FR2068811B1 (en) |
GB (1) | GB1280247A (en) |
IE (1) | IE34785B1 (en) |
NL (1) | NL7018162A (en) |
NO (1) | NO129207B (en) |
ZA (1) | ZA707728B (en) |
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JP6928445B2 (en) * | 2016-12-21 | 2021-09-01 | 花王株式会社 | Lubricating oil base oil, lubricating oil composition containing the lubricating oil base oil, and a method for producing the same. |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
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FR1537943A (en) * | 1966-07-21 | 1968-08-30 | British Petroleum Co | Lubricant, especially for supersonic jet engines |
FR1534282A (en) * | 1966-07-21 | 1968-07-26 | British Petroleum Co | Lubricating composition |
FR1527892A (en) * | 1967-03-15 | 1968-06-07 | Rhone Poulenc Sa | New process for preparing the antibiotic 13057 r.p. |
-
0
- BE BE759673D patent/BE759673A/en unknown
-
1970
- 1970-11-16 ZA ZA707728A patent/ZA707728B/en unknown
- 1970-11-17 GB GB54597/70A patent/GB1280247A/en not_active Expired
- 1970-11-30 FR FR707042908A patent/FR2068811B1/fr not_active Expired
- 1970-12-03 IE IE1548/70A patent/IE34785B1/en unknown
- 1970-12-07 ES ES386259A patent/ES386259A1/en not_active Expired
- 1970-12-08 NO NO04717/70A patent/NO129207B/no unknown
- 1970-12-10 DE DE2060750A patent/DE2060750C3/en not_active Expired
- 1970-12-11 CH CH1833970A patent/CH558422A/en not_active IP Right Cessation
- 1970-12-14 NL NL7018162A patent/NL7018162A/xx unknown
- 1970-12-14 JP JP45110613A patent/JPS4943542B1/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
IE34785L (en) | 1971-06-15 |
DE2060750C3 (en) | 1975-11-27 |
IE34785B1 (en) | 1975-08-20 |
FR2068811A1 (en) | 1971-09-03 |
JPS4943542B1 (en) | 1974-11-21 |
ES386259A1 (en) | 1973-03-16 |
FR2068811B1 (en) | 1974-02-22 |
ZA707728B (en) | 1972-03-29 |
CH558422A (en) | 1975-01-31 |
BE759673A (en) | 1971-06-01 |
NL7018162A (en) | 1971-06-17 |
DE2060750A1 (en) | 1971-06-24 |
GB1280247A (en) | 1972-07-05 |
DE2060750B2 (en) | 1975-03-27 |
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