NO118977B - - Google Patents
Download PDFInfo
- Publication number
- NO118977B NO118977B NO168760A NO16876067A NO118977B NO 118977 B NO118977 B NO 118977B NO 168760 A NO168760 A NO 168760A NO 16876067 A NO16876067 A NO 16876067A NO 118977 B NO118977 B NO 118977B
- Authority
- NO
- Norway
- Prior art keywords
- magnesium
- reaction
- aryl
- chloride
- grignard
- Prior art date
Links
- 229910052749 magnesium Inorganic materials 0.000 claims description 23
- 239000011777 magnesium Substances 0.000 claims description 23
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 22
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 150000001500 aryl chlorides Chemical class 0.000 claims description 9
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 9
- 150000001499 aryl bromides Chemical class 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 9
- -1 aryl magnesium chlorides Chemical class 0.000 description 6
- QARVLSVVCXYDNA-UHFFFAOYSA-N bromobenzene Chemical compound BrC1=CC=CC=C1 QARVLSVVCXYDNA-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 3
- 229910052740 iodine Inorganic materials 0.000 description 3
- 239000011630 iodine Substances 0.000 description 3
- 235000011147 magnesium chloride Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000001502 aryl halides Chemical class 0.000 description 2
- 235000019416 cholic acid Nutrition 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- HSINOMROUCMIEA-FGVHQWLLSA-N (2s,4r)-4-[(3r,5s,6r,7r,8s,9s,10s,13r,14s,17r)-6-ethyl-3,7-dihydroxy-10,13-dimethyl-2,3,4,5,6,7,8,9,11,12,14,15,16,17-tetradecahydro-1h-cyclopenta[a]phenanthren-17-yl]-2-methylpentanoic acid Chemical compound C([C@@]12C)C[C@@H](O)C[C@H]1[C@@H](CC)[C@@H](O)[C@@H]1[C@@H]2CC[C@]2(C)[C@@H]([C@H](C)C[C@H](C)C(O)=O)CC[C@H]21 HSINOMROUCMIEA-FGVHQWLLSA-N 0.000 description 1
- BHQCQFFYRZLCQQ-UHFFFAOYSA-N (3alpha,5alpha,7alpha,12alpha)-3,7,12-trihydroxy-cholan-24-oic acid Natural products OC1CC2CC(O)CCC2(C)C2C1C1CCC(C(CCC(O)=O)C)C1(C)C(O)C2 BHQCQFFYRZLCQQ-UHFFFAOYSA-N 0.000 description 1
- SODQFLRLAOALCF-UHFFFAOYSA-N 1lambda3-bromacyclohexa-1,3,5-triene Chemical compound Br1=CC=CC=C1 SODQFLRLAOALCF-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004380 Cholic acid Substances 0.000 description 1
- 238000003747 Grignard reaction Methods 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 239000003613 bile acid Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- BHQCQFFYRZLCQQ-OELDTZBJSA-N cholic acid Chemical compound C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(O)=O)C)[C@@]2(C)[C@@H](O)C1 BHQCQFFYRZLCQQ-OELDTZBJSA-N 0.000 description 1
- 229960002471 cholic acid Drugs 0.000 description 1
- 239000002812 cholic acid derivative Substances 0.000 description 1
- 150000001842 cholic acids Chemical class 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- KXGVEGMKQFWNSR-UHFFFAOYSA-N deoxycholic acid Natural products C1CC2CC(O)CCC2(C)C2C1C1CCC(C(CCC(O)=O)C)C1(C)C(O)C2 KXGVEGMKQFWNSR-UHFFFAOYSA-N 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003163 gonadal steroid hormone Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L magnesium chloride Substances [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
- IWCVDCOJSPWGRW-UHFFFAOYSA-M magnesium;benzene;chloride Chemical compound [Mg+2].[Cl-].C1=CC=[C-]C=C1 IWCVDCOJSPWGRW-UHFFFAOYSA-M 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ANRQGKOBLBYXFM-UHFFFAOYSA-M phenylmagnesium bromide Chemical group Br[Mg]C1=CC=CC=C1 ANRQGKOBLBYXFM-UHFFFAOYSA-M 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000003718 tetrahydrofuranyl group Chemical group 0.000 description 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21H—OBTAINING ENERGY FROM RADIOACTIVE SOURCES; APPLICATIONS OF RADIATION FROM RADIOACTIVE SOURCES, NOT OTHERWISE PROVIDED FOR; UTILISING COSMIC RADIATION
- G21H1/00—Arrangements for obtaining electrical energy from radioactive sources, e.g. from radioactive isotopes, nuclear or atomic batteries
- G21H1/10—Cells in which radiation heats a thermoelectric junction or a thermionic converter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63C—LAUNCHING, HAULING-OUT, OR DRY-DOCKING OF VESSELS; LIFE-SAVING IN WATER; EQUIPMENT FOR DWELLING OR WORKING UNDER WATER; MEANS FOR SALVAGING OR SEARCHING FOR UNDERWATER OBJECTS
- B63C11/00—Equipment for dwelling or working underwater; Means for searching for underwater objects
- B63C11/02—Divers' equipment
- B63C11/28—Heating, e.g. of divers' suits, of breathing air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24V—COLLECTION, PRODUCTION OR USE OF HEAT NOT OTHERWISE PROVIDED FOR
- F24V30/00—Apparatus or devices using heat produced by exothermal chemical reactions other than combustion
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- High Energy & Nuclear Physics (AREA)
- Ocean & Marine Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- Thermotherapy And Cooling Therapy Devices (AREA)
- Apparatus For Radiation Diagnosis (AREA)
- Radiation-Therapy Devices (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US56051166A | 1966-06-27 | 1966-06-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO118977B true NO118977B (xx) | 1970-03-09 |
Family
ID=24238102
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO168760A NO118977B (xx) | 1966-06-27 | 1967-06-26 |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3513824A (xx) |
| GB (2) | GB1198861A (xx) |
| NO (1) | NO118977B (xx) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3737620A (en) * | 1969-07-01 | 1973-06-05 | Sanders Nuclear Corp | Body heating system |
| US3892225A (en) * | 1973-09-28 | 1975-07-01 | Mike Twose | Cold weather clothing suit |
| JPS5280972A (en) * | 1975-12-25 | 1977-07-07 | Katsumi Suzuki | Underwater pocket warmer |
| US4167932A (en) * | 1977-08-03 | 1979-09-18 | Energy Systems Corporation | Diver heater system |
| US4294225A (en) * | 1979-05-22 | 1981-10-13 | Energy Systems Corporation | Diver heater system |
| US5082617A (en) * | 1990-09-06 | 1992-01-21 | The United States Of America As Represented By The United States Department Of Energy | Thulium-170 heat source |
| JP3088127B2 (ja) * | 1991-05-22 | 2000-09-18 | 謙治 岡安 | 携帯式熱伝達装置 |
| US6698510B2 (en) * | 2001-04-24 | 2004-03-02 | Mide Technology Corporation | Article and method for temperature regulation using a thermosensitive reactive hydrogel material |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2541328A (en) * | 1949-05-19 | 1951-02-13 | Henry O Boklep | Ice-fishing heater |
| US3112792A (en) * | 1952-09-13 | 1963-12-03 | Jet Heet Inc | Personal thermal device |
| DE1048363B (xx) * | 1957-07-17 | |||
| US3265125A (en) * | 1964-02-05 | 1966-08-09 | United Aircraft Corp | Radiator sealing scheme |
| US3295594A (en) * | 1964-09-03 | 1967-01-03 | United Aircraft Corp | Thermal garment |
-
1966
- 1966-06-27 US US560511A patent/US3513824A/en not_active Expired - Lifetime
-
1967
- 1967-06-26 NO NO168760A patent/NO118977B/no unknown
- 1967-06-27 GB GB29686/67A patent/GB1198861A/en not_active Expired
- 1967-06-27 GB GB63130/69A patent/GB1198862A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1198861A (en) | 1970-07-15 |
| US3513824A (en) | 1970-05-26 |
| GB1198862A (en) | 1970-07-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2462433A (en) | Preparation of organic thiocyanates and isothiocyanates | |
| NO118977B (xx) | ||
| US3060216A (en) | Complex metal aluminum hydrides and their production | |
| US2380057A (en) | Dialkylated silicon esters and method of making them | |
| US2431038A (en) | Tin hydrocarbon compounds and process for making same | |
| JPS5879935A (ja) | １，１−ジハロ−１，２，２，２−テトラフルオロエタンの製造方法 | |
| US5211887A (en) | High purity alkyllithium compounds and process of preparation | |
| US2795628A (en) | Preparation of phenyl magnesium chloride | |
| US2247821A (en) | Manufacture of trialkyl borons | |
| US2214117A (en) | Preparation of aromatic 1, 3-diketones | |
| US4165332A (en) | Preparation of aliphatic perchlorates and of trifluoromethane sulfonates | |
| JPS63238086A (ja) | エーテルを含まない有機金属アミド組成物 | |
| US5171467A (en) | Synthesis of organometallic/organobimetallic compositions | |
| US1705723A (en) | Process of producing tetra-ethyl lead | |
| US2881225A (en) | Preparation of grignard reagents | |
| US2082568A (en) | Vinylethinyl derivatives and processes for producing same | |
| US2959598A (en) | Allyl chloride-cyclic ether grignard reagents | |
| US2563797A (en) | Chlorination of acetic acid | |
| US1967864A (en) | Halogen-vinyl acetylene and process of preparing same | |
| US3424793A (en) | Preparation of trimethyl chloro-substituted lower alkyl quaternary ammonium salts | |
| Spencer et al. | CLXXXI.—The interaction of metals of the aluminium group and organic halogen derivatives | |
| US5430208A (en) | Method for preparing 1-chloro-1-iodoethane | |
| US2909565A (en) | Production of organometallic compounds | |
| US3786083A (en) | Process for the preparation of acyl succinic acid dialkyl esters | |
| US2925369A (en) | Abnormal addition of hydrogen bromide to vinylaromatic compounds |