NL7107505A - Ruthenium complexes prepn catalysts - Google Patents

Ruthenium complexes prepn catalysts

Info

Publication number
NL7107505A
NL7107505A NL7107505A NL7107505A NL7107505A NL 7107505 A NL7107505 A NL 7107505A NL 7107505 A NL7107505 A NL 7107505A NL 7107505 A NL7107505 A NL 7107505A NL 7107505 A NL7107505 A NL 7107505A
Authority
NL
Netherlands
Prior art keywords
diket
ruthenium complexes
prepn
catalysts
formula
Prior art date
Application number
NL7107505A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR100058A external-priority patent/FR1540346A/en
Priority claimed from FR102292A external-priority patent/FR1526197A/en
Priority claimed from FR112456A external-priority patent/FR1537041A/en
Priority claimed from FR131735A external-priority patent/FR93712E/en
Priority claimed from NL6803738A external-priority patent/NL6803738A/xx
Application filed filed Critical
Publication of NL7107505A publication Critical patent/NL7107505A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0208—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Ruthenium complexes of formula I are prepared by reacting CO with a compound of formula II - V: (Diket)2Ru(CO)2 (Diket)3Ru (Diket)2Ru(CO)2 I II III (Diket)2Ru(CO)L (Diket)2RuL2 IV V (where Diket is a group of formula VI; and L is a mono- or polyfunctional ligand which is not a beta-diketone). (where R1 and R3 are each alkyl, haloalkyl, aryl, or haloaryl; R2 is the same as R1 or is H; two of groups R1, R2 and R3 can be alkylene, or all three groups can be alkanetriyl). Used as catalyst for organic reactions such as dimerisation of acrylonitrile.
NL7107505A 1967-03-23 1971-06-01 Ruthenium complexes prepn catalysts NL7107505A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
FR100058A FR1540346A (en) 1967-03-23 1967-03-23 New ruthenium complexes and their preparation
FR102292A FR1526197A (en) 1967-04-11 1967-04-11 New ruthenium complexes and their preparation
FR112456A FR1537041A (en) 1967-06-29 1967-06-29 New ruthenium complexes and processes for their production
FR131735A FR93712E (en) 1967-06-29 1967-12-11 New ruthenium complexes and methods of obtaining them.
NL6803738A NL6803738A (en) 1967-03-23 1968-03-15

Publications (1)

Publication Number Publication Date
NL7107505A true NL7107505A (en) 1971-09-27

Family

ID=27514860

Family Applications (2)

Application Number Title Priority Date Filing Date
NL7107505A NL7107505A (en) 1967-03-23 1971-06-01 Ruthenium complexes prepn catalysts
NL7107506A NL7107506A (en) 1967-03-23 1971-06-01

Family Applications After (1)

Application Number Title Priority Date Filing Date
NL7107506A NL7107506A (en) 1967-03-23 1971-06-01

Country Status (1)

Country Link
NL (2) NL7107505A (en)

Also Published As

Publication number Publication date
NL7107506A (en) 1971-09-27

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