NL2031102B1 - Environment-friendly electric cleaning degreaser for shield tunneling machine cutter head and degreasing method thereof - Google Patents
Environment-friendly electric cleaning degreaser for shield tunneling machine cutter head and degreasing method thereof Download PDFInfo
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- NL2031102B1 NL2031102B1 NL2031102A NL2031102A NL2031102B1 NL 2031102 B1 NL2031102 B1 NL 2031102B1 NL 2031102 A NL2031102 A NL 2031102A NL 2031102 A NL2031102 A NL 2031102A NL 2031102 B1 NL2031102 B1 NL 2031102B1
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- tunneling machine
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- cutter head
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F1/00—Electrolytic cleaning, degreasing, pickling or descaling
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F7/00—Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects; Servicing or operating
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- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
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Abstract
The present disclosure provides an environment—friendly electric cleaning degreaser for a shield tunneling machine cutter head which is prepared by adding water into the following raw materials in. mass concentration: hydroxide, carbonate, sodium. disilicate, chloride and sodium dodecyl benzene sulfonate. The present disclosure also provides a degreasing method of the environment— friendly electric cleaning degreaser for the shield tunneling machine cutter head, comprising the steps of: an electrode is inserted into an inner hole of the shield tunneling machine cutter head, to be treated; the electrode is wrapped, with. a polyester cotton sheath dipped with the environment—friendly electric cleaning degreaser for the shield tunneling machine cutter head; the polyester cotton sheath and the inner hole of the shield tunneling machine cutter head to be treated are rotationally contacted for degreasing; the positive and negative polarity combined degreasing is adopted.
Description
ENVIRONMENT-FRIENDLY ELECTRIC CLEANING DEGREASER FOR SHIELD
TUNNELING MACHINE CUTTER HEAD AND DEGREASING METHOD THEREOF
The present disclosure belongs to the field of surface treat- ment, and particularly relates to an environment-friendly electric cleaning degreaser for a shield tunneling machine cutter head and a degreasing method thereof.
In the installation process of alloy nails of a large shield tunneling cutter, the tightening force between the alloy nails and a cutter head base body is greatly reduced due to the existence of lubricating oil film, alkali liquor is usually adopted for clean- ing and degreasing, but the traditional impregnation degreasing efficiency is low, the whole cutter head will be contaminated by degreasing through an impregnation method, and the working envi- ronment is poor.
In order to overcome the above defects in the prior art, the present disclosure provides an environment-friendly electric cleaning degreaser for a shield tunneling machine cutter head and a degreasing method thereof. The electric cleaning process of the electric cleaning degreaser is short in cleaning time and high in cleaning efficiency, the degreasing method realizes high-speed and high-precision fixed-point cleaning, and the tightening force of the alloy nails of the shield tunneling machine cutter head can be enhanced after cleaning.
In order to solve the technical problems, the present disclo- sure adopts the following technical solution: an environment- friendly electric cleaning degreaser for a shield tunneling ma- chine cutter head is prepared by adding water into the following raw materials in mass concentration: 20-50 g/L of hydroxide, 20-50 g/L of carbonate, 40-100 g/L of sodium disilicate, 2-5 g/L of chloride and 0.05-0.15 g/L of sodium dodecyl benzene sulfonate.
Preferably, the hydroxide is sodium hydroxide or potassium hydroxide.
Preferably, the carbonate is sodium carbonate or potassium carbonate.
Preferably, the chloride is sodium chloride or potassium chloride.
The present disclosure also provides a degreasing method of the environment-friendly electric cleaning degreaser for the shield tunneling machine cutter head. The method comprises the following steps:
An electrode is inserted into an inner hole of the shield tunneling machine cutter head to be treated; the electrode is wrapped with a polyester cotton sheath dipped with the environ- ment-friendly electric cleaning degreaser for the shield tunneling machine cutter head; the polyester cotton sheath and the inner hole of the shield tunneling machine cutter head to be treated are rotationally contacted for degreasing; and under the conditions that the electric cleaning voltage is 12-18 V and relative motion speed of the electrode and the surface of the shield tunneling ma- chine cutter head to be treated is 10-20 cm/s, the positive and negative polarity combined degreasing is adopted.
The positive and negative polarity combined degreasing method comprises the following steps: the positive electrode electric cleaning is performed; the shield tunneling machine cutter head to be treated is connected with a negative electrode of a DC power supply for 10-30 s, and is electrically cleaned by the negative electrode; the shield tunneling machine cutter head to be treated is connected with a positive electrode of the DC power supply for 5-10 s, and is electrically cleaned by the positive electrode; the shield tunneling machine cutter head to be treated is connected with the negative electrode of the DC power supply for 10-30 s, and is electrically cleaned by the negative electrode; and the shield tunneling machine cutter head to be treated is connected with the positive electrode of the DC power supply for 5-10 s to finish the degreasing of the shield tunneling machine cutter head to be treated.
In the present disclosure, firstly, positive electrode elec- tric cleaning is carried out, and the shield machine cutter head to be treated is connected with the negative electrode of the DC power supply; during electric cleaning, hydrogen ions in the envi- ronment-friendly electric cleaning degreaser on the surface of a part is reduced to form H, to be separated out; and an oil film breaks under the mechanical stripping action of H, bubbles to real- ize rapid and thorough removal of oil stains on the surface of the cutter head. The material of the cutter head is sensitive to hy- drogen so that negative electrode electric cleaning is carried out after positive electrode electric cleaning; and the shield machine cutter head to be treated is connected with the positive electrode of the DC power supply, and OH in the environment-friendly elec- tric cleaning degreaser is oxidized on the surface of a cutter to generate 0, to be separated out, thus mechanical stripping of oxy- gen bubbles is realized.
Compared with the prior art, the present disclosure has the following advantages:
The environment-friendly electric cleaning degreaser is free of phosphorization, sodium phosphate in traditional electric cleaning liquid is replaced by sodium disilicate, and thus phos- phorization-free treatment of the electric cleaning liquid is achieved; meanwhile, the particle surface of the electric cleaning liquid needs to adsorb equivalent positive ions, the combining ca- pacity of the positive ions to Ca®%’ and Mg” is very high, so water softening is achieved to a great extent; in addition, the electric cleaning liquid has a good adsorption effect on a surface active agent. The sodium disilicate carries negative charges, the polari- ty of the sodium disilicate is the same as that of an anionic sur- factant that is sodium dodecyl benzene sulfonate, opposite charges repel each other, so a good dispersion effect is formed among all components of the electric cleaning liquid due to this character- istic. Due to the addition of the anionic surfactant that is sodi- um dodecyl benzene sulfonate, the tension of the electric cleaning liquid surface is reduced, the interface wettability is improved, the emulsibility of the electric cleaning degreaser is enhanced, and the stability of effective components in the system is guaran-
teed; meanwhile, adhesion of calcium ions to the metal surface in the electric cleaning process is restrained, and it is particular- ly important in switching of positive and negative electrodes in the electric cleaning process because the alkalinity of a work- piece surface solution is enhanced when positive electrode elec- tric cleaning is adopted, a cutter head surface solution is acidic when negative electrode electric cleaning is adopted, and positive and negative polarity switching usually causes agglomeration fail- ure of the surface active agent, therefore, the sodium dodecyl benzene sulfonate is adopted as the amphoteric active agent, the chemical properties of alkali, dilute acid and hard water are sta- ble, and the surface activity of a brush plating solution can be maintained when the positive and negative electrodes are switched.
According to the electric cleaning technology, the cleaning time is only 30-80 s, the cleaning efficiency can reach 90-98%, and meanwhile the alloy nail tightening force of the shield tunneling machine cutter head can be enhanced after cleaning.
The present disclosure will be further described in detail below in conjunction with the embodiments.
Example 1
An environment-friendly electric cleaning degreaser for a shield tunneling machine cutter head provided in this example was prepared by adding water into the following raw materials in mass concentration: 30 g/L of sodium hydroxide, 40 g/L of sodium car- bonate, 50 g/L of sodium disilicate, 4 g/L of sodium chloride and 0.05 g/L of sodium dodecyl benzene sulfonate.
This example also provided a degreasing method of the envi- ronment-friendly electric cleaning degreaser for the shield tun- neling machine cutter head. The method comprised the following steps:
This example also provided a degreasing method of the envi- ronment-friendly electric cleaning degreaser for the shield tun- neling machine cutter head. The method comprised the following steps:
An electrode was inserted into an inner hole of the shield tunneling machine cutter head to be treated; the electrode was wrapped with a polyester cotton sheath dipped with the environ- ment-friendly electric cleaning degreaser for the shield tunneling machine cutter head; the polyester cotton sheath and the inner 5 hole of the shield tunneling machine cutter head to be treated were rotationally contacted for degreasing; and under the condi- tions that the electric cleaning voltage is 16 V and relative mo- tion speed of the electrode and the surface of the shield tunnel- ing machine cutter head to be treated was 10 cm/s, the positive and negative polarity combined degreasing was adopted;
The positive and negative polarity combined degreasing method comprised the following steps: the positive electrode electric cleaning was performed; the shield tunneling machine cutter head to be treated was connected with a negative electrode of a DC pow- er supply for 10 s, and was electrically cleaned by the negative electrode; the shield tunneling machine cutter head to be treated was connected with a positive electrode of the DC power supply for 5 s, and was electrically cleaned by the positive electrode; the shield tunneling machine cutter head to be treated was connected with the negative electrode of the DC power supply for 10 s, and was electrically cleaned by the negative electrode; and the shield tunneling machine cutter head to be treated was connected with the positive electrode of the DC power supply for 5 s to finish the degreasing of the shield tunneling machine cutter head to be treated.
The degrease rate of an environment-friendly electric clean- ing degreaser for a shield tunneling machine cutter head in this example was 98%, the surface friction factor was 0.19, and the cleaning time was 30 s in total. After degreasing was conducted through an electric cleaning method, the tightening force (74,544.7N) of an alloy nail of the cutter head (the hole diameter of 22 mm, and the interference of 0.07 mm) was increased by 54.9% compared with the tightening force (48,121.1N) in an uncleaned state.
A conventional cleaning agent (including components: 2.0 g/L of disodium dodecyl {sulphonatophenoxy) benzenesulphonate, 0.5 g/L of isomeric fatty alcohol alkoxylate (EH-6), 1.5 g/L of isomeric
C10 alcohol polyoxyethylene ether, 0.8 g/L of fatty alcohol- alkylene oxide copolymer, 5.0 g/L of sodium metasilicate pentahy- drate, 20.0 g/L of sodium carbonate and 10.0 g/L of sodium tripol- yphosphate) was used, the cutter head was soaked in the conven- tional cleaning agent for cleaning for 5 min, the cleaning rate was 80%, the surface friction factor was 0.145, and the tightening force (56,889.4N) of the alloy nail was increased by 18.2% com- pared with the tightening force (48,121.1N) in the uncleaned state.
Example 2
An environment-friendly electric cleaning degreaser for a shield tunneling machine cutter head provided in this example was prepared by adding water into the following raw materials in mass concentration: 50 g/L of sodium hydroxide, 20 g/L of potassium carbonate, 90 g/L of sodium disilicate, 2 g/L of potassium chlo- ride and 0.10 g/L of sodium dodecyl benzene sulfonate.
This example also provided a degreasing method of the envi- ronment-friendly electric cleaning degreaser for the shield tun- neling machine cutter head. The method comprised the following steps:
An electrode was inserted into an inner hole of the shield tunneling machine cutter head to be treated; the electrode was wrapped with a polyester cotton sheath dipped with the environ- ment-friendly electric cleaning degreaser for the shield tunneling machine cutter head; the polyester cotton sheath and the inner hole of the shield tunneling machine cutter head to be treated were rotationally contacted for degreasing; and under the condi- tions that the electric cleaning voltage is 16 V and relative mo- tion speed of the electrode and the surface of the shield tunnel- ing machine cutter head to be treated was 10 cm/s, the positive and negative polarity combined degreasing was adopted;
The positive and negative polarity combined degreasing method comprised the following steps: the positive electrode electric cleaning was performed; the shield tunneling machine cutter head to be treated was connected with a negative electrode of a DC pow- er supply for 30 s, and was electrically cleaned by the negative electrode; the shield tunneling machine cutter head to be treated was connected with a positive electrode of the DC power supply for 10 s, and was electrically cleaned by the positive electrode; the shield tunneling machine cutter head to be treated was connected with the negative electrode of the DC power supply for 30 s, and was electrically cleaned by the negative electrode; and the shield tunneling machine cutter head to be treated was connected with the positive electrode of the DC power supply for 10 s to finish the degreasing of the shield tunneling machine cutter head to be treated.
The degrease rate of an environment-friendly electric clean- ing degreaser for a shield tunneling machine cutter head in this example was 97.5%, the surface friction factor was 0.17, and the cleaning time was 80 s in total. After degreasing was conducted through an electric cleaning method, the tightening force (70,621.3 N) of an alloy nail of the cutter head (the hole diame- ter of 22 mm, and the interference of 0.7 mm) was increased by 46.7% compared with the tightening force (48,121.1N) in an un- cleaned state.
Example 3
An environment-friendly electric cleaning degreaser for a shield tunneling machine cutter head provided in this example was prepared by adding water into the following raw materials in mass concentration: 50 g/L of potassium hydroxide, 40 g/L of potassium carbonate, 100 g/L of sodium disilicate, 5 g/L of potassium chlo- ride and 0.15 g/L of sodium dodecyl benzene sulfonate.
This example also provided a degreasing method of the envi- ronment-friendly electric cleaning degreaser for the shield tun- neling machine cutter head. The method comprised the following steps:
An electrode was inserted into an inner hole of the shield tunneling machine cutter head to be treated; the electrode was wrapped with a polyester cotton sheath dipped with the environ- ment-friendly electric cleaning degreaser for the shield tunneling machine cutter head; the polyester cotton sheath and the inner hole of the shield tunneling machine cutter head to be treated were rotationally contacted for degreasing; and under the condi- tions that the electric cleaning voltage is 12 V and relative mo-
tion speed of the electrode and the surface of the shield tunnel- ing machine cutter head to be treated was 10 cm/s, the positive and negative polarity combined degreasing was adopted;
The positive and negative polarity combined degreasing method comprised the following steps: the positive electrode electric cleaning was performed; the shield tunneling machine cutter head to be treated was connected with a negative electrode of a DC pow- er supply for 15 s, and was electrically cleaned by the negative electrode; the shield tunneling machine cutter head to be treated was connected with a positive electrode of the DC power supply for 5 s, and was electrically cleaned by the positive electrode; the shield tunneling machine cutter head to be treated was connected with the negative electrode of the DC power supply for 15 s, and was electrically cleaned by the negative electrode; and the shield tunneling machine cutter head to be treated was connected with the positive electrode of the DC power supply for 5 s to finish the degreasing of the shield tunneling machine cutter head to be treated.
The degrease rate of an environment-friendly electric clean- ing degreaser for a shield tunneling machine cutter head in this example was 96.5%, the surface friction factor was 0.17, and the cleaning time was 40 s in total. After degreasing was conducted through an electric cleaning method, the tightening force (66,697.9 N) of an alloy nail of the cutter head was increased by 38.6% compared with the tightening force (48,121.1N) in an un- cleaned state.
Example 4
An environment-friendly electric cleaning degreaser for a shield tunneling machine cutter head provided in this example was prepared by adding water into the following raw materials in mass concentration: 20 g/L of sodium hydroxide, 20 g/L of sodium car- bonate, 40 g/L of sodium disilicate, 2 g/L of sodium chloride and 0.05 g/L of sodium dodecyl benzene sulfonate.
This example also provided a degreasing method of the envi- ronment-friendly electric cleaning degreaser for the shield tun- neling machine cutter head. The method comprised the following steps:
An electrode was inserted into an inner hole of the shield tunneling machine cutter head to be treated; the electrode was wrapped with a polyester cotton sheath dipped with the environ- ment-friendly electric cleaning degreaser for the shield tunneling machine cutter head; the polyester cotton sheath and the inner hole of the shield tunneling machine cutter head to be treated were rotationally contacted for degreasing; and under the condi- tions that the electric cleaning voltage is 18 V and relative mo- tion speed of the electrode and the surface of the shield tunnel- ing machine cutter head to be treated was 20 cm/s, the positive and negative polarity combined degreasing was adopted;
The positive and negative polarity combined degreasing method comprised the following steps: the positive electrode electric cleaning was performed; the shield tunneling machine cutter head to be treated was connected with a negative electrode of a DC pow- er supply for 15 s, and was electrically cleaned by the negative electrode; the shield tunneling machine cutter head to be treated was connected with a positive electrode of the DC power supply for 5 g, and was electrically cleaned by the positive electrode; the shield tunneling machine cutter head to be treated was connected with the negative electrode of the DC power supply for 15 s, and was electrically cleaned by the negative electrode; and the shield tunneling machine cutter head to be treated was connected with the positive electrode of the DC power supply for 5 s to finish the degreasing of the shield tunneling machine cutter head to be treated.
The degrease rate of an environment-friendly electric clean- ing degreaser for a shield tunneling machine cutter head in this example was 90.8%, the surface friction factor was 0.15, and the cleaning time was 40 s in total. After degreasing was conducted through an electric cleaning method, the tightening force (58,851.1 N) of an alloy nail of the cutter head (the hole diame- ter of 22 mm, and the interference of 0.7 mm) was increased by 22.3% compared with the tightening force (48,121.1N) in an un- cleaned state.
Example 5
An environment-friendly electric cleaning degreaser for a shield tunneling machine cutter head provided in this example was prepared by adding water into the following raw materials in mass concentration: 20 g/L of potassium hydroxide, 40 g/L of sodium carbonate, 80 g/L of sodium disilicate, 4 g/L of potassium chlo- ride and 0.10 g/L of sodium dodecyl benzene sulfonate.
This example also provided a degreasing method of the envi- ronment-friendly electric cleaning degreaser for the shield tun- neling machine cutter head. The method comprised the following steps:
An electrode was inserted into an inner hole of the shield tunneling machine cutter head to be treated; the electrode was wrapped with a polyester cotton sheath dipped with the environ- ment-friendly electric cleaning degreaser for the shield tunneling machine cutter head; the polyester cotton sheath and the inner hole of the shield tunneling machine cutter head to be treated were rotationally contacted for degreasing; and under the condi- tions that the electric cleaning voltage is 12 V and relative mo- tion speed of the electrode and the surface of the shield tunnel- ing machine cutter head to be treated was 15 cm/s, the positive and negative polarity combined degreasing was adopted;
The positive and negative polarity combined degreasing method comprised the following steps: the positive electrode electric cleaning was performed; the shield tunneling machine cutter head to be treated was connected with a negative electrode of a DC pow- er supply for 20 s, and was electrically cleaned by the negative electrode; the shield tunneling machine cutter head to be treated was connected with a positive electrode of the DC power supply for 10 s, and was electrically cleaned by the positive electrode; the shield tunneling machine cutter head to be treated was connected with the negative electrode of the DC power supply for 20 s, and was electrically cleaned by the negative electrode; and the shield tunneling machine cutter head to be treated was connected with the positive electrode of the DC power supply for 10 s to finish the degreasing of the shield tunneling machine cutter head to be treated.
The degrease rate of an environment-friendly electric clean- ing degreaser for a shield tunneling machine cutter head in this example was 90%, the surface friction factor was 0.19, and the cleaning time was 60 s in total. After degreasing was conducted through an electric cleaning method, the tightening force (78,469.4N) of an alloy nail of the cutter head (the hole diameter of 22 mm, and the interference of 0.7 mm) was increased by 63% compared with the tightening force (48,121.1IN) in an uncleaned state.
The above description only describes the preferred embodi- ments of the present disclosure, and is not intended to limit the present disclosure in any way. Any simple modifications, altera- tions, and equivalent changes made to the above embodiments based on the technical essence of the present disclosure shall still fall within the protection scope of the technical solutions of the present disclosure.
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JPS5039636A (en) * | 1973-08-14 | 1975-04-11 | ||
US5104501A (en) * | 1989-06-13 | 1992-04-14 | Daicel Chemical Industries, Ltd. | Electrolytic cleaning method and electrolytic cleaning solution for stamper |
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JPH0790700A (en) * | 1993-09-17 | 1995-04-04 | Sumitomo Metal Ind Ltd | Electrolytic washing device for cold rolled steel strip |
JP2005298919A (en) * | 2004-04-13 | 2005-10-27 | Sawada Kinji | Cleaning method |
CN101514468B (en) * | 2009-02-19 | 2010-11-10 | 中国人民解放军装甲兵工程学院 | Device and method for inner bore type component brush plating |
CN103521080A (en) * | 2013-10-10 | 2014-01-22 | 云南城投碧水源水务科技有限责任公司 | Alkaline cleaning agent for depth cleaning of separating membrane and application thereof |
CN107794561A (en) * | 2017-10-19 | 2018-03-13 | 江门市濠成化工科技有限公司 | A kind of steel electrolytic degreasing powder and its preparation and application |
CN108588730A (en) * | 2018-04-20 | 2018-09-28 | 广东红日星实业有限公司 | A kind of degreaser and preparation method thereof for galvanized sheet |
KR20200047184A (en) * | 2018-10-26 | 2020-05-07 | (주)일신종합환경 | A normal temperature defat agent applicable in normal temperature and a defat method using the same |
CN111850578A (en) * | 2020-07-17 | 2020-10-30 | 广东致卓环保科技有限公司 | Medium-low temperature phosphorus-free oil removing powder for surfaces of steel parts and preparation and use methods thereof |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US2830942A (en) * | 1957-05-24 | 1958-04-15 | Jr Robert H Elliott | Electrocleaner for brass |
JPS5039636A (en) * | 1973-08-14 | 1975-04-11 | ||
US5104501A (en) * | 1989-06-13 | 1992-04-14 | Daicel Chemical Industries, Ltd. | Electrolytic cleaning method and electrolytic cleaning solution for stamper |
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CN113684525B (en) | 2024-05-24 |
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