NL2030910B1 - Bonding composition for a vegetarian or vegan foodstuff - Google Patents

Bonding composition for a vegetarian or vegan foodstuff Download PDF

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Publication number
NL2030910B1
NL2030910B1 NL2030910A NL2030910A NL2030910B1 NL 2030910 B1 NL2030910 B1 NL 2030910B1 NL 2030910 A NL2030910 A NL 2030910A NL 2030910 A NL2030910 A NL 2030910A NL 2030910 B1 NL2030910 B1 NL 2030910B1
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Netherlands
Prior art keywords
protein
alginate
food product
foodstuff
binder composition
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NL2030910A
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Dutch (nl)
Inventor
Alberts-Renssen Thomas
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Hanze Food B V
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Priority to NL2030910A priority Critical patent/NL2030910B1/en
Priority to PCT/NL2023/050062 priority patent/WO2023153929A1/en
Application granted granted Critical
Publication of NL2030910B1 publication Critical patent/NL2030910B1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P20/00Coating of foodstuffs; Coatings therefor; Making laminated, multi-layered, stuffed or hollow foodstuffs
    • A23P20/10Coating with edible coatings, e.g. with oils or fats
    • A23P20/105Coating with compositions containing vegetable or microbial fermentation gums, e.g. cellulose or derivatives; Coating with edible polymers, e.g. polyvinyalcohol
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23JPROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
    • A23J3/00Working-up of proteins for foodstuffs
    • A23J3/22Working-up of proteins for foodstuffs by texturising
    • A23J3/225Texturised simulated foods with high protein content
    • A23J3/227Meat-like textured foods
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23JPROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
    • A23J3/00Working-up of proteins for foodstuffs
    • A23J3/22Working-up of proteins for foodstuffs by texturising
    • A23J3/26Working-up of proteins for foodstuffs by texturising using extrusion or expansion
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/256Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin from seaweeds, e.g. alginates, agar or carrageenan

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Food Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Biochemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biotechnology (AREA)
  • Dispersion Chemistry (AREA)
  • Molecular Biology (AREA)
  • Jellies, Jams, And Syrups (AREA)
  • General Preparation And Processing Of Foods (AREA)

Abstract

The invention relates to a bonding composition for binding an alginate casing or coating to a vegetarian or vegan foodstuff. The composition comprises, on a dry matter basis; 0.50—45 wt.% of one or more hydrocolloid gelling agents, including at least alginate; 1.0—35 wt.% of one or more water binding agents; and one or more proteins selected from the group of plant protein, fungal protein, milk protein and egg protein. The bonding composition comprises 0.25—80 wt.% of alginate. It has the function of providing adherence between the coating and the foodstuff. In this capacity, it is present as an intermediate adhesive layer that is positioned in between the foodstuff and the coating. There is a first bond between the intermediate adhesive layer and the foodstuff, relying on coagulated protein; and there is a second bond between the intermediate adhesive layer and the coating, relying on the gelling of alginate. In this way, the coating is strongly connected to the foodstuff; no bursting or delamination takes place during heating. The foodstuff is in particular a vegan or vegetarian sausage.

Description

BONDING COMPOSITION FOR A VEGETARIAN OR VEGAN FOODSTUFF
FIELD OF THE INVENTION
The invention relates to a bonding composition for binding an alginate coating to a vegetarian or vegan foodstuff, to a method for coating a vegetarian or vegan foodstuff with a layer of gelled alginate and to a vegetarian or vegan foodstuff comprising a gelled alginate coating.
BACKGROUND
It is common practice in the food industry to provide foodstuffs with a casing or coating. For example, sausages are prepared by coating a meat dough or another sausage material. Conventional meat sausages have animal derived casings such as intestine or collagen. However, due to their animal origin, such casings cannot be used for vegan or vegetarian foodstuffs. As an alternative, anionic polysaccharides such as alginate are often used as a coating agent. The term "alginate" refers to a group of naturally occurring polysaccharides extracted from seaweed, and are therefore not animal-derived. They can form gels relatively easily in the presence of alkaline earth metals such as magnesium and calcium.
Such alginate gels can very well serve as a coating on a foodstuff.
Alginate casings and coatings have advantageous properties such as a high strength and the ability to provide sausages with a taste, texture and mouthfeel that is comparable to that of sausages enclosed in a conventional animal-derived casing. However, sausage material (vegetarian and animal) does not adhere very well to casings that are made from anionic polysaccharides such as alginate. In particular, when a sausage in an alginate casing is heated in water (an action commonly performed by the end-consumer), there is often accumulation of water between the sausage material and the coating, making the sausage prone to delamination.
For example, WO9955165A1 describes a sausage with an edible skin (i.e. coating) comprising alginate and protein. It is prepared by extruding a proteinaceous composition together with the alginate, which alginate is then gelled upon contact with an aqueous calcium dichloride solution. The document is however silent on any adhesion of the coating to the proteinaceous composition.
Indeed, it appears that the procedure does not lead to any substantial bonding between the two components.
Another approach is to use a separate composition that acts as an adhesive portion between a sausage material and a coating, but this has not yet provided a satisfactory solution to the lack of adherence that is observed for anionic polysaccharides such as alginate.
Other solutions in the art rely on modification of the foodstuff itself in order to improve its adherence to the coating an/or to an intermediate adhesive portion. This is however undesired, since this goes often at the expense of the taste, organoleptic properties, appearance, texture and/or mouthfeel of the entire foodstuff.
SUMMARY OF THE INVENTION
It is therefore an object of the present invention to provide an alginate-coated vegan or vegetarian foodstuff that does not suffer from one of the above disadvantages. It is also an object to provide an effective bonding composition for coating a vegan or vegetarian foodstuif with an alginate coating. It is in particular an object of the present invention to provide a method for coating wherein the bonding composition can be chosen independently from the alginate casing or coating. It is also an object that the vegan or vegetarian foodstuff does not need to be adapted to the bonding composition.
It has now been found that one or more of these objects can be reached by applying a particular bonding composition. Accordingly, in a first aspect the present invention relates to a bonding composition for binding an alginate coating, in particular an alginate casing, to a vegetarian or vegan foodstuff, the bonding composition comprising, on a dry matter basis, the following components a) 0.50-45 wt.% of one or more hydrocolloid gelling agents, including at least alginate; b) 1.0-35 wt.% of one or more water binding agents, optionally comprising one or more of the same hydrocolloid gelling agents as in component a);
c) 20-90 wi.% of one or more proteins selected from the group of plant protein, fungal protein, milk protein and egg protein; wherein the composition comprises, on a dry matter basis, 0.25-80 wt.% of alginate, in particular sodium alginate.
In a second aspect, the invention relates to a method for coating a vegetarian or vegan foodstuff with a layer of gelled alginate, comprising the use of a bonding composition of the invention.
In a third aspect, the invention relates to a vegetarian or vegan foodstuff comprising a gelled alginate coating, wherein - the foodstuff comprises one or more proteins selected from the group of proteins derived from plants, proteins derived from fungus, proteins derived from milk and proteins derived from egg; and - the coating adheres to the foodstuff.
BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 schematically displays a cross-section of a first foodstuff according to the invention.
Figure 2 schematically displays a cross-section of a second foodstuft according to the invention.
DETAILED DESCRIPTION OF THE INVENTION
Elements in the figures are illustrated for simplicity and clarity and have not necessarily been drawn to scale. For example, the dimensions of some of the elements in the figures may be exaggerated relative to other elements to help improve understanding of various exemplary embodiments of the present invention. In particular, the relative dimensions of a foodstuff, an intermediate adhesive layer and a coating or casing cannot be derived from the figures.
Furthermore, the terms “first”, “second”, and the like herein, if any, are generally used for distinguishing between similar elements and not necessarily for describing a sequential or chronological order.
In the context of the invention, by the term ‘alginate’ is meant an anionic form of alginic acid, wherein the positive counterion is chosen such that the alginate does or does not form a gel. For example, no gel is formed when the counter ion is sodium (alginic acid monosodium salt or, simply, sodium alginate).
When sodium alginate is contacted with a divalent metal ion, such as an alkaline earth metal (e.g. magnesium or calcium), the alginate converts into a gel (a ‘gelled alginate’ or an ‘alginate coating’). A skilled person knows which counter ions result inthe formation of a gel and which do not.
In the context of the invention, by the term ‘vegetarian foodstuff is meant a foodstuff that lacks any component that is derived from meat or any by-product of animal slaughter such as gelatin or organ tissue.
In the context of the invention, by the term ‘vegan foodstuff’ is meant a foodstuff that lacks any component that is derived from meat, egg, milk, and any other substance of animal origin.
In the context of the invention, by the terms ‘plant protein’, ‘fungal protein’, ‘milk protein’ and ‘egg protein’ is meant a protein obtained from or derived from a plant, a fungus, milk or egg, respectively. The plant, fungus, milk or egg protein may have undergone a modification before, during or after obtaining it from the plant, fungus, milk or egg, respectively. For example it may have been modified by cross-linking, (partial) hydrolysis or functional group modification.
Fungal protein is also known as ‘mycoprotein’.
In the context of the invention, by the term ‘hydrocolloid gelling agent’ is meant a polymeric hydrophilic material which is able to gel aqueous systems when present therein at or above a certain minimum concentration.
In this description, the contents of the different non-volatile components (e.g. salts and nutrients such as carbohydrates, fats and proteins) in a composition may be given on a so-called ‘dry matter basis’. This means that the content of each of these different components is expressed as a proportion of the total dry matter in the composition, typically a weight percentage (wt.%). In this respect, the ‘dry matter’ of a composition is meant to consist of all the constituents of the composition excluding water (and eventual other volatiles, for example ethanol); it is a measurement of the mass of a composition when completely dried.
The invention relates to a bonding composition for binding an alginate coating to a vegetarian or vegan foodstuff. When the bonding composition is applied as such, it is positioned between the foodstuff and an alginate coating precursor (typically an ungelled alginate composition such as sodium alginate).
After the formation of the alginate coating and its concurrent bonding with the foodstuff, the bonding composition is present as an intermediate adhesive layer between the foodstuff and the coating.
Accordingly, a bonding composition of the invention creates a first bond 5 with the foodstuff and a second bond with the alginate coating. Due to these two bonds, the coating and the foodstuff adhere to one another.
This is for example demonstrated in Figures 1 and 2, which are cross- sections of two different foodstuffs according to the invention; a sausage and a hamburger-type of foodstuff. In both figures, the foodstuff (1) is present as the substance that is to be coated. The foodstuff (1) is covered with two layers; an intermediate adhesive layer (2) and a coating (3). The intermediate adhesive layer (2) adheres to the foodstuff (1) by means of the first bond and it adheres to the coating (3) by means of the second bond.
The bonding composition of the invention is designed in such way that the first bond relies on a bonding principle that is different from that of the second bond.
The first bond involves the interaction of a protein of the foodstuff with the one or more proteins of the bonding composition. In this way, there is no need to include additives in the foodstuff that are essential to creating the first bond.
This is an advantage, since such additives are known to modify important properties of the foodstuff, such as taste, organoleptic properties, appearance, texture and/or mouthfeel. It is contemplated that the first bond is formed by the concurrent coagulation of protein(s) of the foodstuff and protein(s) of the bonding composition, which is typically induced by a heating step.
The second bond involves the interaction of alginate of the coating with alginate of the bonding composition. It is contemplated that both alginates together form a gel when contacted with a divalent metal ion solution, thereby forming a single structure that extends on both sides of the interface between the bonding composition and the coating. In this way, there is no need to include additives in the alginate coating that are essential to creating the second bond. This is an advantage, since such additives may impair the quality of the coating itself.
A bonding composition of the invention may or may not comprise water; it may comprise up to and including 90 wt.% of water. When the composition is actually applied in a method for the coating of a vegetarian or vegan foodstuff, the water content is preferably in the range of 60-90 wt.%. For example, it is in the range of 60-80 wt.%, in the range of 70-90 wi.®%, in the range of 65-85 wt.%, in the range of 75-90 wt.% or in the range of 75-85 wt.%.
In the event that a bonding composition of the invention comprises 60- 90 wt.% of water, then the bonding composition may comprise the following components: a) 0.10-11.25 wt.% of one or more hydrocolloid gelling agents, including at least alginate; b) 0.20-8.75 wt.% of one or more water binding agents, which may comprise one or more hydrocolloid gelling agents in addition to those of component a}; c) 4.0-22.5 wt.% of one or more proteins selected from the group of plant protein, fungal protein, milk protein and egg protein; d) 60-90 wt.% of water; wherein alginate constitutes 0.050-20 wt.% of the bonding composition.
The dry matter of such water-containing bonding composition comprises components a), b) and c) in principle in the same relative amounts as those as claimed in claim 1.
The water content of the bonding composition may be substantially lower prior to its actual application, for example during manufacture, transport and/or storage of the bonding composition. It then in fact acts as a precursor to the actually applied bonding composition. Preferably, the water content of the bonding composition is then as low as possible. For example, it is in the range of 0.0-2.0 wtl.%, in particular in the range of 0.0-0.20 wt.%. Water may also be substantially completely absent. In such case, the levels of the different components of the bonding composition are substantially the same as those of the composition on a dry matter basis as claimed in claim 1.
Alternatively, the water content of the bonding composition may also be upto 5.0 wt.%, in the range of 5-50 wt.%, in the range of 10-40 wt.% or in the range of 15-30 wt.%.
When any such bonding composition is to be applied in a process for the binding of an alginate coating to a vegetarian or vegan foodstuff, then it is typically diluted before its application, preferably to the extent that water constitutes 60-90 wt.% of the bonding composition, more preferably 75-85 wt.%.
A bonding composition of the invention comprises, on a dry matter basis, 0.50-45 wt.% of one or more hydrocolloid gelling agents. It may also comprise 1.0-10 wt.% of one or more hydrocolloid gelling agents, in particular 3.0-8.0 wt.%, on a dry matter basis. The function of these appears to be to stabilize the intermediate adhesive layer. Experiments have demonstrated that the intermediate adhesive layer becomes a slurry when no hydrocolloid gelling agent is present. In addition, it is contemplated that a hydrocolloid gelling agent may also be involved in the actual bonding with the foodstuff.
Usually, a hydrocolloid gelling agent is a cellulose or a cellulose derivative; in particular a cellulose derivative selected from the group of methyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, methyl ethyl cellulose, and sodium carboxymethyl cellulose. The hydrocolloid gelling agent may also be selected from the group of alginates, carrageenans, agar, gums, dextrans, pectins, glucans, xylans, modified starches, gelatinized starches and gelatin.
A bonding composition of the invention comprises, on a dry matter basis, 0.25-80 wt.% of alginate. It may also comprise 1.0-40 wt.% of alginate, in particular 2.0-20 wt.% of alginate, more in particular 3.0-10 wt.% of alginate, on a dry matter basis. The function of the alginate is to realize the second bond, i.e. the bond with the alginate coating. When the alginate coating is in contact with the bonding composition and when a divalent metal ion solution is applied to them, then the alginate of the bonding composition and the alginate of the coating will together form a gel. Extending on both sides of an interface between the bonding composition and the coating, the gel provides the second bond.
The alginate in a bonding composition of the invention is preferably sodium alginate. lt is in principle also possible to use other alginates, such as potassium alginate or lithium alginate.
The weight average molar mass, Mu, of the dissolved alginate, in particular of dissolved sodium alginate, is usually in the range of 10.000-600.000 kg/mol. It may also be in the range of 30.000-300.000 kg/mol.
A bonding composition of the invention comprises, on a dry matter basis, 1.0-35 wt.% of one or more water binding agents. lt may also comprise
4.0-30 wt.% of one or more water binding agents, in particular 8.0-25 wt.%, more in particular 10-20 wt.%, on a dry matter basis. The function of these is to bind water during and/or after the bonding of the alginate coating to the foodstuff, i.e. during and/or after the formation of the intermediate adhesive layer. Water that was initially dissolved in the binding composition often cannot dissolve anymore in its entirety in the adhesive layer when a water binding agent is lacking. It may then form a separate phase, which weakens the bonding of the intermediate adhesive layer with the foodstuff and/or with the coating, since it creates areas where there is no bonding. Ultimately, this may lead to bursting and delamination of the coating. This is remedied by including a sufficient amount of the one or more water binding agents in the bonding composition.
It is herewith understood that the one or more hydrocolloid gelling agents can be chosen such that some or all of them also fall in the category of water binding agent. This is however no problem as long as the quantitative requirements for each of the two types of agents are met. lt is emphasized that substances that fall in both categories (i.e. substances that are a hydrocolloid gelling agent as well as a water binding agent) may be present in the composition in an amount that exceeds 45 wt.%, which is the end value of the content range for the one or more hydrocolloid gelling agents. For example, alginate may be present in an amount of up to and including 80 wt.%.
Usually, the one or more water binding agents comprises a starch.
Preferably, such starch is selected from the group of potato starch, corn starch, rice starch, wheat starch and tapioca starch. The one or more water binding agents may also comprise plant fibers or a hydrocolloid gelling agent. In the event that it comprises a hydrocolloid gelling agent, then this is in addition to the hydrocolloid gelling agent in component a} of the bonding composition. Thus, the dry matter of a composition of the invention may comprise up to and including 80 wt.% of hydrocolloid gelling agent. In a particular case, it includes 80 wt.% of alginate, in particular 80 wt.% of sodium alginate.
A bonding composition of the invention comprises, on a dry matter basis, 20-90 wt.% of one or more proteins selected from the group of plant protein, fungal protein, milk protein and egg protein. It may also comprise 40-85 wt.% of the one or more proteins, in particular 50-80 wt.% of the one or more proteins, more in particular 60-75 wt.% of the one or more proteins, on a dry matter basis. The function of the one or more proteins is to realize the first bond, i.e. the bond with the foodstuff. The one or more proteins coagulate with one or more proteins in the vegetarian or vegan foodstuff, typically by a heat treatment.
Usually, the plant protein is derived from a species selected from the group of legumes, vegetables, cereals, nuts and seeds, in particular from a plant species selected from the group of fava bean, soy, pea, chickpea, guar, potato, sunflower, lentil, rice, lupine, wheat, hemp and pumpkin.
A bonding composition of the invention usually has a pH in the range of 6.0-9.0, preferably in the range of 6.5-8.5 or in the range of 7.0-8.0.
A bonding composition of the invention may comprise further additives, such as plant fibers, salts, preservative agents and/or coloring agents.
When present, plant fibers are preferably present in an amount in the range of 0.50-5.0 wt.%.
The invention further relates to a method for coating a vegetarian or vegan foodstuff with a layer of gelled alginate, comprising the use of a bonding composition as described hereabove. Such method may comprise providing a bonding composition having a water content of lower than 60 wt.%, in particular providing a bonding composition that is substantially void of water; followed by diluting the composition with water to a water content that is in the range of 60-90 wi. %, in particular in the range of 65-85 wt.®%.
The method of the invention preferably comprises - providing a vegetarian or vegan foodstuff comprising one or more proteins selected from the group of plant protein, fungal protein, milk protein and egg protein; - providing a bonding composition as described hereabove; - providing an alginate solution in water; - providing an aqueous solution of a divalent metal ion; - applying to the foodstuff a layer of the bonding composition and a layer of the alginate solution, so that the layer of the bonding composition is positioned in between the foodstuff and the layer of the alginate; thereafter - contacting the layer of the alginate solution with the aqueous solution of a divalent metal ion to yield the layer of gelled alginate; thereafter
- optionally heating the coated foodstuff to a temperature in the range of 40- 120 °C, in particular in the range of 60-100 °C, to generate an intermediate adhesive layer that binds the layer of gelled alginate to the foodstuff.
The heating step does not necessarily form part of the manufacturing process of the coated foodstuff. It may also be carried out by a consumer who prepares the foodstuff for consumption. To this end, a packaging of the foodstuff in which it is purchased and stored, typically instructs the consumer to heat the foodstuff, as a part of the general procedure that is to be carried out to prepare the foodstuff for consumption. A consumer may purchase the foodstuff at room temperature, in a cooled form (typically 0 — 10 °C) or in frozen form (typically -10 — -30 °C). Heating instructions to the consumer may entail keeping the foodstuff in a hot water bath or an oven for some time. In this way, the intermediate adhesive layer is generated in accordance with the invention, so that a foodstuff with a strongly bound coating is provided at the moment of its actual serving and consumption.
In an embodiment, the layer of the bonding composition and the layer of the alginate solution are provided sequentially.
In another embodiment, the foodstuff, the layer of the bonding composition and the layer of the alginate solution are coextruded by an extruder apparatus. This generally means that an elongated strand of food material leaves the die head of the extruder apparatus, and that such strand comprises a core of the foodstuff that is coated with an intermediate layer of the bonding composition and an outer layer of alginate solution. The strand is then contacted with the aqueous solution of a divalent metal ion, typically by pouring the solution over the strand or by dipping the strand into the solution, to provide the coating of gelled alginate. Thereafter, the extruded product may be heated to actually bind the coating to the foodstuff.
In a method of the invention, the protein in the bonding composition may be adapted to the protein in the foodstuff. For example, at least one type of protein that is present in the bonding composition corresponds to a type of protein that is also present in the foodstuff. This is typically performed by selecting a foodstuff and a bonding composition that both have at least one type of protein in common. For example, there is plant protein in the foodstuff and plant protein in the bonding composition; and/or there is fungal protein in the foodstuff and fungal protein in the bonding composition; and/or there is milk protein in the foodstuff and milk protein in the bonding composition; and/or there is egg protein in the foodstuff and egg protein in the bonding composition.
Preferably, the foodstuff and the bonding composition both comprise a protein that is derived from the same type of plant, for example from a plant selected from the group of legumes, vegetables, cereals, nuts and seeds. More preferably, the foodstuff and the bonding composition both comprise at least one and the same protein. This is typically performed by selecting a foodstuff and a bonding composition that both have at least one particular protein in common. For example, the protein that is present in the foodstuff as well in the bonding composition is a protein derived from a plant species selected from the group of fava bean, soy, pea, chickpea, guar, potato, sunflower, lentil, rice, lupine, wheat, hemp and pumpkin.
The presence of corresponding proteins may yield a stronger bond between the foodstuff and the bonding composition than when the proteins are different.
The alginate solution in water that is used in a method of the invention usually has an alginate content in the range of 0.050-10 wt.% or 0.10-6.0 wt.%.
Preferably, it is in the range of 0.20-4.0 wt.%, more preferably in the range of 0.50-3.0 wt. %.
The alginate used in a method of the invention is preferably sodium alginate. It is in principle also possible to use other alginates, such as potassium alginate or lithium alginate.
The weight average molar mass, Mw, of the dissolved alginate, in particular of dissolved sodium alginate, is usually in the range of 10.000-600.000 kg/mol. It may also be in the range of 30.000-300.000 kg/mol.
The aqueous solution of a divalent metal ion typically has a total divalent metal ion concentration in the range of 1.0-5.0 mol/L, in particular in the range of 1.3-4.0 mol/L. The divalent metal ion is preferably a calcium ion that is present as CaCl, i.e. the aqueous solution is a solution of CaClz in water. In such case, the concentration of CaCl: is typically in the range of 15-45 wt.%.
The invention further relates to a vegetarian or vegan foodstuff obtainable by a method as described above.
The invention further relates to a vegetarian or vegan foodstuff comprising a gelled alginate coating, wherein - the foodstuff comprises one or more proteins selected from the group of proteins derived from plants, proteins derived from fungus, proteins derived from milk and proteins derived from egg; and - the coating adheres to the foodstuff.
In an embodiment, the vegetarian or vegan foodstuff comprises an intermediate adhesive layer that is positioned in between the foodstuff and the coating or casing, wherein there is - a first bond between the intermediate adhesive layer and the foodstuff, the first bond relying on coagulated protein; and - a second bond between the intermediate adhesive layer and the coating or casing, the second bond relying on the gelling of alginate.
The intermediate adhesive layer usually comprises the following components a) a gel of one or more hydrocolloid gelling agents, including at least alginate; b) one or more water binding agents comprising bound water, optionally comprising one or more of the same hydrocolloid gelling agents as in component a); c) one or more coagulated proteins selected from the group of plant protein, fungal protein, milk protein and egg protein.
In a foodstuff of the invention, there may be at least one type of protein that is present in the intermediate adhesive layer as well as in the foodstuff. For example, there is plant protein in the foodstuff and plant protein in the bonding composition; and/or there is fungal protein in the foodstuff and fungal protein in the bonding composition; and/or there is milk protein in the foodstuff and milk protein in the bonding composition; and/or there is egg protein in the foodstuff and egg protein in the bonding composition.
Preferably, the foodstuff and the intermediate adhesive layer both comprise a protein that is derived from the same type of plant, for example from a plant selected from the group of legumes, vegetables, cereals, nuts and seeds.
More preferably, the foodstuff and the intermediate adhesive layer both comprise at least one and the same protein, i.e. there is at least one protein that is present in the foodstuff as well as in the intermediate adhesive layer. For example, the protein that is present in the foodstuff as well in the intermediate adhesive layer is a protein derived from a plant species selected from the group of fava bean, soy, pea, chickpea, guar, potato, sunflower, lentil, rice, lupine, wheat, hemp and pumpkin.
In an embodiment, the vegetarian or vegan foodstuff according to the invention is of an elongate shape having two opposite ends. lt may in particular have the shape of a sausage. More in particular, a vegetarian or vegan foodstuff according to the invention is a vegan or vegetarian sausage.
With a bonding composition of the invention, alginate coatings can be provided on foodstuff that are resistant to high temperatures and that are not prone to delamination, also during heating the foodstuff, for example in water. The invention therefore opens the way to vegan and vegetarian food products, in particular sausages, with a non-animal derived coating that has properties comparable to those of a conventional animal-derived coating, in particular the property of adhesion to the foodstuff itself. This fulfills a long-felt need in the field.
It is further beneficial that any bonding composition according to the invention can be selected independently from the alginate coating in order to arrive at a foodstuff according to the invention, i.e. at a coated foodstuff having a strong bonding between the foodstuff and the coating. There are, for example, no components — except for the alginate — that need to be present in both the alginate coating and the bonding composition. This is an advantage, since other components in the coating may impair the quality of the coating.
As regards the foodstuff, the invention offers the advantage that the vegan or vegetarian foodstuff itself does not need to be modified in order to arrive at a good bonding. A particularly improved bonding, however, is obtained when the protein in the bonding composition corresponds in some way to the protein in the foodstuff. This may entail a similarity in type of protein (plant, fungus, milk or egg) or a similarity in the plant from which the plant protein is obtained. The best bonding is achieved when the foodstuff and the bonding composition actually comprise the same protein.
EXAMPLES
Example 1: Vegan chicken filet with vegan chicken skin
A first coated vegan meat product was prepared according to the invention, wherein the foodstuff is a ‘vegan chicken dough’ and the alginate coating a ‘vegan chicken skin’.
The chicken dough is composed of water, rice texturate, wheat texturate, wheat gluten, soy isolate, methylcellulose, vegetable fibers, salt, aroma's, herbs and spices. lt is prepared by first blending the water and texturates, and then adding the other components. Mixing all components yields a firm and formable dough.
The chicken skin comprises water, sodium alginate, corn starch, vegetable fibers and aroma’s and is prepared by mixing these components.
The bonding composition according to the invention comprises alginate (2.8 wi.%), wheat fiber (4.7 wt.%), citrus fiber (1.9 wt.%), soy isolate (4.4 wt.%), methylcellulose (1.8 wt.%) and water (84.4 wt.%).
The preparation of the coated vegan chicken dough was performed by first forming the vegan chicken dough into ‘chicken filet shapes’. Then a layer of the bonding composition was applied to the filets, followed by a layer of the chicken skin (i.e. the alginate). Thereafter, the coated filets were shortly submerged in a CaClz solution. Finally, the filets were placed in a steam oven for a few minutes to cause the coagulation of the proteins that are present in the bonding composition and the chicken dough.
The coating of the resulting vegan chicken filets adhered strongly and in a continuous manner to the dough. No delamination and/or bursting of the coating was observed.
Example 2: Vegan Frankfurter with alginate casing
A coated vegan meat product was prepared according to the invention, wherein the foodstuff is a ‘Frankfurter dough’ that is composed of water, oil, soy isolate, methylcellulose, starches, vegetable fibers, salt, aroma's, herbs and spices. The dough is prepared in a bow! chopper. The oil and water are added and mixed into the dry components with high shear. The alginate comprises water,
sodium alginate, guar gum, food acid and preservative agent. The bonding composition is the bonding composition as described in Example 1.
The preparation of the coated foodstuff was performed by coextrusion of the Frankfurter dough, the bonding composition and the alginate. A special die head was used to get the vegan frankfurter dough on the inside, the bonding composition around it and the alginate on the outside. Each component was supplied by a separate pump. The extruded strand was passed through a CaCl solution and segmented to yield Frankfurter vegan sausages. Finally, the sausages were submerged in a 80 °C water bath for a few minutes to cause the coagulation of the proteins that are present in the bonding composition and the
Frankfurter dough. Figure 1 schematically displays a cross section of this product.
The coating of the resulting Frankfurter vegan sausages adhered strongly and in a continuous manner to the dough. No delamination and/or bursting of the coating was observed.

Claims (18)

CONCLUSIESCONCLUSIONS 1. Bindersamenstelling voor het binden van een alginaatcoating aan een vegetarisch of veganistisch voedselproduct, omvattende, op basis van droge stof, de volgende componenten a) 0,50-45 gew.% van een of meer gelvormende hydrocolloiden, omvattende ten minste alginaat; b) 1,0-35 gew.% van een of meer waterbinders; c) 20-90 gew.% van een of meer eiwitten gekozen uit de groep van plantaardig eiwit, schimmeleiwit, melkeiwit en ei-eiwit; waarbij alginaat 0,25-80 gew.% van de droge stof van de bindersamenstelling uitmaakt.Binder composition for binding an alginate coating to a vegetarian or vegan food product, comprising, on a dry matter basis, the following components a) 0.50-45% by weight of one or more gel-forming hydrocolloids, comprising at least alginate; b) 1.0-35% by weight of one or more water binders; c) 20-90% by weight of one or more proteins selected from the group of vegetable protein, fungal protein, milk protein and egg protein; wherein alginate constitutes 0.25-80% by weight of the dry matter of the binder composition. 2. Bindersamenstelling volgens conclusie 1, waarbij de samenstelling een pH heeft in het bereik van 6,5-8,5, in het bijzonder in het bereik van 7,0-8,0.Binder composition according to claim 1, wherein the composition has a pH in the range of 6.5-8.5, in particular in the range of 7.0-8.0. 3. Bindersamenstelling volgens conclusie 1 of 2, waarbij de een of meer waterbinders gekozen is uit de groep van aardappelzetmeel, maïszetmeel, rijstzetmeel, tarwezetmeel en cassavezetmeel.Binder composition according to claim 1 or 2, wherein the one or more water binders is selected from the group of potato starch, corn starch, rice starch, wheat starch and cassava starch. 4. Bindersamenstelling volgens een der conclusies 1-3, waarbij de een of meer gelvormende hydrocolloïden is gekozen uit de groep van cellulose, methylcellulose, hydroxypropylceliulose, hydroxypropylmethylicellulose, methylethylcellulose en natrium carboxymethyicellulose.Binder composition according to any one of claims 1-3, wherein the one or more gel-forming hydrocolloids is selected from the group of cellulose, methylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, methylethylcellulose and sodium carboxymethylcellulose. 5. Bindersamenstelling volgens een der conclusies 1-4, waarbij het plantaardig eiwit is afgeleid van een soort gekozen uit de groep van peulvruchten, groenten, granen, noten en zaden, in het bijzonder van een plantensoort gekozen uit de groep van veldboon, soja, erwt, kikkererwt, guar, aardappel, zonnebloem, linze, rijst, lupine, tarwe, hennep en pompoen.5. Binder composition according to any one of claims 1-4, wherein the vegetable protein is derived from a species selected from the group of legumes, vegetables, grains, nuts and seeds, in particular from a plant species selected from the group of field bean, soy, pea, chickpea, guar, potato, sunflower, lentil, rice, lupine, wheat, hemp and pumpkin. 6. Bindersamenstelling volgens een der conclusies 1-5, waarbij het alginaat 1.0- 40 gew.% van de droge stof van de bindersamenstelling uitmaakt, in het bijzonder 2.0-20 gew.%, meer in het bijzonder 3.0-10 gew.%.6. Binder composition according to any one of claims 1-5, wherein the alginate constitutes 1.0-40% by weight of the dry matter of the binder composition, in particular 2.0-20% by weight, more in particular 3.0-10% by weight. 7. Bindersamenstelling volgens een der conclusies 1-6, waarbij het watergehalte van de bindersamenstelling in het bereik ligt van 0.0-2.0 gew.%, in het bijzonder in het bereik van 0.0-0.20 gew.%.7. Binder composition according to any one of claims 1-6, wherein the water content of the binder composition is in the range of 0.0-2.0% by weight, in particular in the range of 0.0-0.20% by weight. 8. Bindersamenstelling volgens een der conclusies 1-7, waarbij het watergehalte van de bindersamenstelling in het bereik ligt van 60-90 gew.%, in het bijzonder in het bereik van 65-85 gew.%.Binder composition according to any one of claims 1-7, wherein the water content of the binder composition is in the range of 60-90% by weight, in particular in the range of 65-85% by weight. 9. Werkwijze voor het coaten van een vegetarisch of veganistisch voedselproduct met een laag van opgesteven alginaat, omvattende het gebruik van een bindersamenstelling volgens een der conclusies 1-8.A method of coating a vegetarian or vegan food product with a layer of set alginate, comprising the use of a binder composition according to any one of claims 1-8. 10. Werkwijze volgens conclusie 9, omvattende - het verschaffen van een vegetarisch of veganistisch voedselproduct omvattende een of meer eiwitten gekozen uit de groep van plantaardig eiwit, schimmeleiwit, melkeiwit en ei-eiwit; - het verschaffen van een bindersamenstelling volgens conclusie 8; - het verschaffen van een alginaatoplossing in water; - het verschaffen van een waterige oplossing van een tweewaardig metaalion; - het aanbrengen op het voedselproduct van een laag van de bindersamenstelling en een laag van de alginaatoplossing, zodat de laag van de bindersamenstelling gepositioneerd is tussen het voedselproduct en de laag van het alginaat; daarna - het in contact brengen van de laag van de alginaatoplossing met de waterige oplossing van een tweewaardig metaalion om de laag van opgesteven alginaat op te leveren; daarna - het optioneel verwarmen van het gecoate voedselproduct naar een temperatuur in het bereik van 40-120 °C, in het bijzonder in het bereik van 60-100 °C, om een hechtende tussenlaag te genereren die de laag van opgesteven alginaat bindt aan het voedselproduct.Method according to claim 9, comprising - providing a vegetarian or vegan food product comprising one or more proteins selected from the group of vegetable protein, fungal protein, milk protein and egg protein; - providing a binder composition according to claim 8; - providing an alginate solution in water; - providing an aqueous solution of a divalent metal ion; - applying to the food product a layer of the binder composition and a layer of the alginate solution, so that the layer of the binder composition is positioned between the food product and the layer of the alginate; then - contacting the alginate solution layer with the aqueous solution of a divalent metal ion to provide the set alginate layer; then - optionally heating the coated food product to a temperature in the range of 40-120°C, in particular in the range of 60-100°C, to generate an adhesive intermediate layer that bonds the set alginate layer to the food product. 11. Werkwijze volgens conclusie 10, waarbij het voedselproduct, de laag van de bindersamenstelling en de laag van de alginaatoplossing gecoëxtrudeerd worden door een extrusie-apparaat.A method according to claim 10, wherein the food product, the binder composition layer and the alginate solution layer are co-extruded through an extrusion device. 12.Werkwijze volgens een der conclusies 9-11, waarbij er ten minste één eiwit is dat aanwezig is in zowel het voedselproduct als de bindersamenstelling, welk eiwit in het bijzonder een eiwit is afgeleid van een plantensoort gekozen uit de groep van veldboon, soja, erwt, kikkererwt, guar, aardappel, zonnebloem, linze, rijst, lupine, tarwe, hennep en pompoen.12. Method according to any one of claims 9-11, wherein there is at least one protein that is present in both the food product and the binder composition, which protein is in particular a protein derived from a plant species selected from the group of field bean, soy, pea, chickpea, guar, potato, sunflower, lentil, rice, lupine, wheat, hemp and pumpkin. 13. Een vegetarisch of veganistisch voedselproduct omvattende een coating van opgesteven alginaat, waarbij - het voedselproduct een of meer eiwitten omvat gekozen uit de groep van plantaardig eiwit, schimmeleiwit, melkeiwit en ei-eiwit; en - de coating hecht aan het voedselproduct.13. A vegetarian or vegan food product comprising a coating of set alginate, wherein - the food product comprises one or more proteins selected from the group of vegetable protein, fungal protein, milk protein and egg protein; and - the coating adheres to the food product. 14. Een vegetarisch of veganistisch voedselproduct volgens conclusie 13, waarbij het voedselproduct een hechtende tussenlaag omvat die gepositioneerd is tussen het voedselproduct en de coating van opgesteven alginaat, waarbij er - een eerste binding is tussen de hechtende tussenlaag en het voedselproduct, waarbij de eerste binding gebaseerd is op gecoaguleerd eiwit; en - een tweede binding is tussen de hechtende tussenlaag en de coating, waarbij de tweede binding gebaseerd is op het opstijven van alginaat.A vegetarian or vegan food product according to claim 13, wherein the food product comprises an adhesive interlayer positioned between the food product and the set alginate coating, wherein - there is a first bond between the adhesive interlayer and the food product, wherein the first bond is based on coagulated protein; and - a second bond is between the adhesive intermediate layer and the coating, wherein the second bond is based on the setting of alginate. 15. Een vegetarisch of veganistisch voedselproduct volgens conclusie 14, waarbij de hechtende tussenlaag de volgende componenten omvat a) een gel van een of meer gelvormende hydrocolioiden, inclusief ten minste alginaat; b) een of meer waterbinders omvattende gebonden water; c) een of meer gecoaguleerde eiwitten gekozen uit de groep van plantaardig eiwit, schimmeleiwit, melkeiwit en ei-eiwit.A vegetarian or vegan food product according to claim 14, wherein the adhesive intermediate layer comprises the following components a) a gel of one or more gel-forming hydrocoloids, including at least alginate; b) one or more water binders comprising bound water; c) one or more coagulated proteins selected from the group of vegetable protein, fungal protein, milk protein and egg protein. 16. Een vegetarisch of veganistisch voedselproduct volgens een der conclusies 13-15, waarbij er ten minste één eiwit is dat aanwezig is in zowel het voedselproduct als de bindersamenstelling, welk eiwit in het bijzonder een eiwit is afgeleid van een plantensoort gekozen uit de groep van veldboon, soja, erwt, kikkererwt, guar, aardappel, zonnebloem, linze, rijst, lupine, tarwe, hennep en pompoen.A vegetarian or vegan food product according to any one of claims 13-15, wherein there is at least one protein present in both the food product and the binder composition, which protein is in particular a protein derived from a plant species selected from the group of field bean, soy, pea, chickpea, guar, potato, sunflower, lentil, rice, lupine, wheat, hemp and pumpkin. 17.Een vegetarisch of veganistisch voedselproduct volgens een der conclusies 13-16, waarbij het voedselproduct van een langwerpige vorm is met twee tegengestelde uiteinden, in het bijzonder waarbij het voedselproduct een vegetarische of veganistische worst is.A vegetarian or vegan food product according to any one of claims 13-16, wherein the food product is of an elongated shape with two opposite ends, in particular wherein the food product is a vegetarian or vegan sausage. 18. Een vegetarisch of veganistisch voedselproduct verkrijgbaar door een werkwijze volgens een der conclusies 9-12.18. A vegetarian or vegan food product obtainable by a method according to any one of claims 9-12.
NL2030910A 2022-02-11 2022-02-11 Bonding composition for a vegetarian or vegan foodstuff NL2030910B1 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999055165A1 (en) 1998-04-24 1999-11-04 Dsm N.V. Foodstuff with skin containing protein and hydrocolloid
EP1311165A1 (en) * 2000-08-25 2003-05-21 W. Ruitenberg CZN. N.V. Composition and method for coating foodstuffs
EP3732980A1 (en) * 2019-04-30 2020-11-04 Viscofan, S.A. Edible film and method for its manufacturing

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999055165A1 (en) 1998-04-24 1999-11-04 Dsm N.V. Foodstuff with skin containing protein and hydrocolloid
EP1311165A1 (en) * 2000-08-25 2003-05-21 W. Ruitenberg CZN. N.V. Composition and method for coating foodstuffs
EP3732980A1 (en) * 2019-04-30 2020-11-04 Viscofan, S.A. Edible film and method for its manufacturing

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