NL2028205B1 - Controllable paste filling method for underground waste space based on coal-based solid waste - Google Patents

Controllable paste filling method for underground waste space based on coal-based solid waste Download PDF

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Publication number
NL2028205B1
NL2028205B1 NL2028205A NL2028205A NL2028205B1 NL 2028205 B1 NL2028205 B1 NL 2028205B1 NL 2028205 A NL2028205 A NL 2028205A NL 2028205 A NL2028205 A NL 2028205A NL 2028205 B1 NL2028205 B1 NL 2028205B1
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Netherlands
Prior art keywords
paste
coal
filling
solid waste
concentration
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NL2028205A
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Dutch (nl)
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NL2028205A (en
Inventor
Li Zhihua
Lv Xin
Yang Ke
Feng Feisheng
Fu Qiang
Chen Denghong
Liu Qinjie
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Univ Anhui Sci & Technology
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Publication of NL2028205A publication Critical patent/NL2028205A/en
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Publication of NL2028205B1 publication Critical patent/NL2028205B1/en

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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21FSAFETY DEVICES, TRANSPORT, FILLING-UP, RESCUE, VENTILATION, OR DRAINING IN OR OF MINES OR TUNNELS
    • E21F15/00Methods or devices for placing filling-up materials in underground workings
    • E21F15/005Methods or devices for placing filling-up materials in underground workings characterised by the kind or composition of the backfilling material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/142Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
    • C04B28/144Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being a flue gas desulfurization product
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034Physico-chemical characteristics of the mixtures
    • C04B2111/00146Sprayable or pumpable mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00724Uses not provided for elsewhere in C04B2111/00 in mining operations, e.g. for backfilling; in making tunnels or galleries
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/70Grouts, e.g. injection mixtures for cables for prestressed concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Mining & Mineral Resources (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The present invention discloses a controllable paste filling method for an underground waste space based on coal-based solid waste, and belongs to the field of paste filling for underground waste spaces. The controllable paste filling method for an underground waste 5 space based on coal-based solid waste includes preparing a coal-based paste, reserving a moving space for a filling device, constructing a filling and grouting space, adjusting the concentration and performing paste filling. A traditional paste filling device is upgraded, and secondary processing on a working surface is performed so that the concentration of the filling paste can be manually controlled, and the paste filling operation efficiency is improved, and a 10 coal-based solid waste material is reasonably used, so that not only is the environment protected, but also the performance of the filling material is effectively improved, and strategic support is provided for sustainable development of paste filling in the future.

Description

P100662NL00
CONTROLLABLE PASTE FILLING METHOD FOR UNDERGROUND WASTE SPACE BASED ON COAL-BASED SOLID WASTE
BACKGROUND S Technical Field The present invention belongs to the field of paste filling for underground waste spaces, and specifically relates to a controllable paste filling method for an underground waste space based on coal-based solid waste. Related Art Underground waste spaces in mines and coal-based solid waste materials brought about by coal mining are two major disaster sources of mines, and a paste filling technology is an advanced technology which includes compounding of surface waste materials, cementing materials, water and the like to prepare a toothpaste-like slurry for backfilling and sealing of underground waste spaces in mines; the mining and filing costs are greatly reduced by paste filling, and the roof contact performance and integrity of filling bodies are great so that the ground pressure can be effectively controlled, and the safety level of mining activities can be improved. At present, paste filling and mining provide a safe and efficient way for recovery of mineral resources having features such as deep burying and broken roofs, and have unique advantages in terms of technology, economy, environmental protection and safety. However, since the concentration of a paste is uncontrollable in a traditional paste filling process, the paste filling efficiency is affected.
SUMMARY In view of the shortcomings of the prior art, the objective of the present invention is to provide a controllable paste filling method for an underground waste space based on coal- based solid waste, and the problem that the concentration of a filling paste in the prior art 1s uncontrollable is solved. The objective of the present disclosure can be achieved by the following technical solution: a controllable paste filling method for an underground waste space based on coal-based solid waste, comprising the following steps: step one: preparing a coal-based solid waste paste; step two: reserving a moving space for a filling device; step three: constructing a filling and grouting space; step four: adjusting the concentration: transporting the coal-based solid waste paste in a storage chamber to a working surface, and injecting the paste into the filling device for adjusting the concentration; and adding a water-absorbing material into the coal-based solid waste paste to increase the concentration of the paste; and step five: performing paste filling: operating the filling device to perform paste filling on the working surface. Further, the preparation concentration of the paste on the ground in step one should be 5%-15%, and the filling concentration in step five should be 75%-85%. Further, the water-absorbing material in step four is glass water. Further, the coal-based solid waste paste in step one includes, based on solid materials, 15%-30% of fly ash, 30%-40% of gasification slag, 20%-40% of furnace bottom slag, 10%- 25% of desulfurized gypsum and 10%-25% of cement and other additives. Beneficial effects of the present disclosure: the concentration of the filling paste can be controlled, and the paste filling operation efficiency is improved.
BRIEF DESCRIPTION OF THE DRAWINGS To describe the technical solutions in embodiments of the present disclosure or in the related art more clearly, the following briefly describes accompanying drawings required for describing the embodiments or the related art. Apparently, a person of ordinary skill in the art may still derive other drawings from these accompanying drawings without creative efforts. FIG. 1 is a schematic diagram for implementing a controllable paste filling method for an underground waste space based on coal-based solid waste according to the present invention; FIG. 2 is a side view for implementing a controllable paste filling method for an underground waste space based on coal-based solid waste according to the present invention; FIG. 3 is a schematic diagram of an internal structure of a filling device.
DETAILED DESCRIPTION The following clearly and completely describes the technical solutions in the embodiments of the present disclosure with reference to the accompanying drawings in the embodiments of the present disclosure. Apparently, the described embodiments are merely some of the embodiments of the present disclosure rather than all of the embodiments. All other embodiments obtained by a person of ordinary skill in the art based on the embodiments of the present disclosure without creative efforts shall fall within the protection scope of the present disclosure. A controllable paste filling method for an underground waste space based on coal-based solid waste includes the following steps:
Step one: a coal-based solid waste paste is prepared.
An appropriate coal-based solid waste filling material is selected for preparation on the ground according to properties of rock strata above a mine recovery working surface: the material, Portland cement and coal gangue are mixed and stirred, water is added to prepare a low-concentration paste, and then the paste is transported to a storage chamber in a mine.
The preparation concentration of the paste on the ground needs to be low, so as to facilitate long-distance transportation of the paste.
The following experiments are made for determining the preparation concentration value of the paste on the ground: 1) different concentrations of pastes are prepared on the ground: 5% concentration, 10% concentration, 15% concentration, 20% concentration and 25% concentration; and 2) horizontal conveying distances of different concentrations of pastes under pressurized conveying of a filling pump are measured and counted; and the experimental data are as follows: 3) it can be seen through analysis of the data that when the preparation concentration of the paste on the ground is 10%-15%, the horizontal conveying distance is the highest, and the transportation effect is better.
In the present embodiment, the coal-based solid waste paste includes, based on solid materials, 15%-30% of tly ash, 30%-40% of gasification slag, 20%-40% of furnace bottom slag, 10%-25% of desulfurized gypsum and 10%-25% of cement and other additives.
Step two: a moving space for a filling device is reserved.
In the present embodiment, as shown in FIG. 2, a controllable paste filling apparatus for an underground waste space based on coal-based solid waste includes a hydraulic support 3 and a filling device 6; and an enough moving space in an underground waste space 1 in a rear part is reserved for the filling device 6 by controlling the hydraulic support 3 to advance forward.
Step three: a filling and grouting space is constructed.
As shown in FIG. 1, a flexible film 2 is fixedly connected to the rear surface of the hydraulic support 3 and the flexible film 2 is used to cover the rear surface of the hydraulic support 3. When paste filling is performed on the underground waste space behind the hydraulic support 3, the flexible film 2 can effectively prevent the situation that the paste splashed on the surface of the hydraulic support 3 is difficult to remove.
Step four, the concentration is adjusted.
The coal-based solid waste paste in the storage chamber is transported to the working surface and injected into the filling device for adjusting the concentration; As shown in FIG. 3, the filling device 6 includes an inlet end 9, an outlet end 5, a water absorption storage tank 6-1 and a spiral drill rod 6-2; the water absorption storage tank 6-1 is located in the filling device 6, and a water-absorbing material is stored in the water absorption storage tank 6-1; the coal-based solid waste paste in the storage chamber enters the filling device 6 from the inlet end 9, and the water-absorbing material in the water absorption storage tank 6-1 and the paste are mixed and stirred with the spiral drill rods 6-2 to obtain a certain concentration of paste.
A loading top plate 7 is arranged at the upper end of the water absorption storage box 6- 1 and the loading top plate 7 is used to seal the upper end part of the water absorption storage box 6-1 to avoid the situation that air the water absorption storage box 6-1 and thus the water- absorbing material in the water absorption storage box loses effect. In addition, the water- absorbing material can be injected into the water absorption storage box 6-1 by opening the loading top plate 7.
In the present embodiment, water glass is used as the water-absorbing material to increase the concentration of the paste and improve the filling effect. Of course, the water absorbing material includes but is not limited to water glass, as long as a water absorption effect can be achieved, and the concentration of the paste can be increased.
Step five, paste filling is performed.
The coal-based solid waste paste in the storage chamber is connected to the inlet end 9 of the filling device 6, mixed with the water-absorbing material in the device in accordance with design requirements, and discharged from the outlet end 5 after the concentration of the paste is adjusted.
The lower end of the filling device 6 is provided with walking wheels 8 rolling on the working surface, the filling device 6 is pushed to one end of the working surface and slowly pulled when filling is performed until paste grouting and filling are completed in the entire space, and the device is recycled and used again after the working surface is advanced.
Before paste filling, the concentration of the paste is controlled so as to increase the concentration of the paste, and improve the strength of a paste filling material. The following experiments are made for determining the concentration value of the paste during filling: 1) different amounts of glass water are added into the paste to produce different concentrations of pastes: 75% concentration, 80% concentration, 85% concentration and 90% concentration; 5 2) uniaxial compressive strengths of different concentrations of paste filling test pieces are measured and counted; as shown in FIG. 4, obviously, the uniaxial compressive strengths of the paste filling test pieces are improved with ages; at 28 days of age, the strength of the paste filling material basically reaches a stable state; and when the concentration of the paste is 80%-85%, the uniaxial compressive strength of the paste filling test piece is the highest after 28 days, which can fully meet the paste filling and mining requirements of mines.
The foregoing displays and describes basic principles, main features of the present disclosure and advantages of the present disclosure. A person skilled in the art can understand that the present disclosure is not limited in the foregoing embodiments. Descriptions in the embodiments and this specification only illustrate the principles of the present disclosure. Various modifications and improvements are made in the present disclosure without departing from the spirit and scope of the present disclosure, and these modifications and improvements shall fall within the protection scope of the present disclosure.

Claims (4)

P100662NL00 CONCLUSIESP100662NL00 CONCLUSIONS 1. Vulmethode met controleerbare pasta voor ondergrondse afvalruimte op basis van vast afval op steenkoolbasis, met het kenmerk, dat de vulmethode de volgende stappen omvat: stap 1: bereid de pasta van vast afval op steenkoolbasis; stap 2: reserveer verplaatsbare ruimte voor vulapparatuur; stap 3: bouw vul- en voegruimte voor drijfmest; stap 4: pas de concentratie aan, omvattende transporteer de pasta van vast afval op steenkoolbasis in de opslagkamer naar het werkoppervlak en injecteer deze in de vulapparatuur voor aanpassing van de concentratie, en verhoog de pastaconcentratie door waterabsorberende materialen toe te voegen aan de pasta van vast afval op steenkoolbasis; stap 5: vul de pasta: bedien de vulapparatuur om de pasta op het werkoppervlak te vullen.1. The controllable paste filling method for underground waste space based on coal-based solid waste, characterized in that the filling method comprises the following steps: step 1: prepare the paste of coal-based solid waste; step 2: reserve movable space for filling equipment; step 3: build filling and joint space for slurry; step 4: adjust the concentration, including transport the paste of coal-based solid waste in the storage chamber to the working surface and inject it into the concentration adjustment filling equipment, and increase the paste concentration by adding water-absorbent materials to the paste of solid coal-based waste; step 5: fill the paste: operate the filling equipment to fill the paste on the work surface. 2. De vulmethode met controleerbare pasta voor ondergrondse afvalruimte op basis van vast afval op steenkoolbasis volgens conclusie 1, met het kenmerk dat de bereidingsconcentratie van de pasta op de grond in stap 1 5% tot 15% moet zijn en de vulconcentratie in stap 5 85% is.The controllable paste filling method for underground waste space based on coal-based solid waste according to claim 1, characterized in that the preparation concentration of the paste on the ground in step 1 should be 5% to 15% and the filling concentration in step 5 is 85 % is. 3. De vulmethode met controleerbare pasta voor ondergrondse afvalruimte op basis van vast afval op steenkoolbasis volgens conclusie 1, met het kenmerk dat het waterabsorberende materiaal 1n stap 4 leidingwater is.The controllable paste filling method for underground waste space based on coal-based solid waste according to claim 1, characterized in that the water-absorbent material 1n step 4 is tap water. 4. De vulmethode met controleerbare pasta voor ondergrondse afvalruimte op basis van vast afval op steenkoolbasis volgens conclusie 1, met het kenmerk dat de pasta van vast afval op steenkoolbasis in stap | vliegas, vergassingsslakken, ovenbodemslakken en ontzwaveld gips omvat, waarbij vliegas verantwoordelijk is voor 15% tot 30% van het vast material, vergassingsslakken 30% tot 40%, ovenbodemslakken 20% tot 40%, ontzwaveld gips 10% tot 25%, cement en andere toevoegingen in totaal 10% tot 25%.The controllable paste filling method for underground waste space based on coal-based solid waste according to claim 1, characterized in that the paste of coal-based solid waste in step | fly ash, gasification slag, kiln floor slag and desulphurised gypsum, fly ash accounting for 15% to 30% of the solid material, gasification slag 30% to 40%, kiln floor slag 20% to 40%, desulphurised gypsum 10% to 25%, cement and others additions in total 10% to 25%. -0-0-0-0-0--0-0-0-0-0-
NL2028205A 2020-12-03 2021-05-12 Controllable paste filling method for underground waste space based on coal-based solid waste NL2028205B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011414141.XA CN112431631A (en) 2020-12-03 2020-12-03 Coal-based solid waste-based goaf controllable paste filling method

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NL2028205A NL2028205A (en) 2022-07-06
NL2028205B1 true NL2028205B1 (en) 2022-09-20

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FR (1) FR3117107B3 (en)
NL (1) NL2028205B1 (en)

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Publication number Priority date Publication date Assignee Title
CN112901261B (en) * 2021-01-28 2022-06-03 山西大学 Coal gangue and fly ash mixed ecological filling method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102211916B (en) * 2011-03-25 2012-11-14 长安大学 Paste filling material composition prepared from drift-sand and industrial solid waste
CN102230396A (en) * 2011-05-31 2011-11-02 大连大学 Filling method capable of exploring while filling coal mine goaf
CN103319123B (en) * 2013-07-08 2015-01-07 李凤义 Fly ash-based cemented filling material and preparation method thereof
CN106348713A (en) * 2016-08-30 2017-01-25 北京玉锦资源与环境技术研究院(有限合伙) Cementing filling material for co-processing copper-containing dangerous waste of mine and preparation method of cementing filling material
CA2958381A1 (en) * 2017-02-17 2018-08-17 Yen-Jui Ting Paste for use in mining processes
CN107857547A (en) * 2017-12-05 2018-03-30 山西工程技术学院 A kind of red mud sill for goaf filling
CN108222938B (en) * 2018-02-07 2020-01-03 西安科技大学 Combined grouting filling mining method for large-inclination-angle coal seam goaf
CN110668739A (en) * 2018-07-03 2020-01-10 厦门紫金矿冶技术有限公司 Tailing cemented filling material and preparation method thereof
CN111268992A (en) * 2020-03-13 2020-06-12 河北建设勘察研究院有限公司 Waste desulfurized gypsum-waste fly ash foundation backfill material and preparation method and application thereof

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CN112431631A (en) 2021-03-02
FR3117107B3 (en) 2022-11-18
NL2028205A (en) 2022-07-06
FR3117107A3 (en) 2022-06-10

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