MXPA97008968A - Cosmetic compositions for makeup - Google Patents

Abstract

Cosmetic compositions for make-up comprising water-insoluble polymeric materials in the form of an aqueous emulsion and a first surfactant or mixture of surfactants having an average HLB of from about 3 to about 6 and a second surfactant or mixture of surfactants which it has an average HLB of from about 8 to about 15, the compositions exhibit improved durability and water resistance and are removable with soap and water.

Description

COSMETIC COMPOSITIONS PñRfl MAKEUP TECHNICAL FIELD The present invention relates to cosmetic compositions for make-up, particularly for make-up and masks for eyes, comprising a poly-epco-material insoluble in water in the form of an aqueous emulsion or latex. Such compositions have improved durability benefits compared to compositions known in the art, and are easily removed with soap and water.

BACKGROUND OF THE INVENTION Make-up compositions for children, including masks, are significant products in the cosmetics market. The mask enhances the beauty of the user by covering with color the pes + arias or in some cases the eyebrows. Despite their beauty enhancement characteristics, conventional eye makeup preparations have been criticized for their inability to produce the desired effects during long periods of use. Problems such as staining and streaking, commonly known as sooty, and scaly mascara, are well known. Even when longevity has been improved, it is also known that such compositions are difficult to remove completely from the delicate area of the eyes. It would be very desirable to have a make-up composition for o os that conceptually had a significantly higher life, as well as an ability to remove soap and water. Make-up compositions for eyes comprising polypeptide emulsions to eliminate etching are well known in the art and typically include water-insoluble polymers also known as latexes. Said compositions including eye shadows are disclosed in the U.S. patent. No. 3,639,572, Henpch, issued February 1, 1972; and masks described in the US patent. No. 4,423,031, Rlurui et al., Issued December 27, 1983 and European Patent Application (EPA) 0568035, published November 3, 1993. These compositions include plasticizers or solvents to help form films using such latexes. . It is known that these compositions contain thickeners to adjust the viscosity of the composition. Such thickeners include water-soluble and water-swellable polymers, typically known for such use in the cosmetics industry. A different embodiment of the foregoing concept is described in the application of the Patent Cooperation Treaty WO 94/17775, published on August 18, 1994. The invention described therein includes mask compositions which comprise the silicone-based elastomeric tex water, emulsions opposed to acp-based "water-based" polymers. Longer durability is attributed to the use of elastomepco tex, since it is more compatible with the r es of the cornpositional matrix than acrylic polymers. Other compositions known in the art which seek to avoid the combination of softeners and polymers are exemplified in EPO 0530084, published on March 3, 1993. This application describes compositions comprising a dispersed phase and a dispersing phase, the phase dispersant has at least one water-soluble polymer and the dispersed phase contains at least 50% wax. Said composition may contain other materials routinely used in cosmetic compositions that include water-insoluble polymers. Surprisingly, it has been discovered that the combination of water-soluble materials in water in an aqueous emulsion and of particular surfactants, provides masks and other cosmetic compositions for makeup that have a superior durability and that are renewable with soap and water. These make-up compositions can be manufactured in a multitude of forms, such as creams, pastes and solids. Preferably, the compositions of the present invention are water-in-oil and oil-in-water emulsions.

BRIEF DESCRIPTION OF THE INVENTION According to one aspect of the present invention, there is provided a cosmetic makeup composition suitable for use as a mask or the like, and comprising: (a) from about 0.1% to about 60% by weight of a polirnecopic material insoluble in an aqueous emulsion; (b) from about 0.1% to about 10% by weight of a first surfactant or mixture of surfactants having an HLB averaged by weight of from about 3 to about 6; and (c) from about 0.1% to about 10% by weight of a second surfactant or mixture of surfactants having an HLB averaged by weight of from about 8 to about 15. According to a second aspect of the present invention, A cosmetic makeup composition suitable for use as a mascara or the like is provided, and which comprises: (a) from about 0.1% to about 60% by weight of a more polymeric polymeric material in an aqueous emulsion; and (b) from about 0.1% to about 10% by weight of an alkyl- or alkoxy-dirnet copolyol having the general formula: CH3 -CH3 wherein X is a hydrogen atom or an alkyl, alkoxy or acyl radical of Ci to Cie, Y is an alkoxy or alkyl radical of Ce -22, n - from about 0 to about 200, in = from about 1 to about 40 , q = from about 1 to about 100, the molecular weight of the residue (C2H4O-)? (C3H6O-) vX being from about 250 to about 2000, x and y being selected so that the weight ratio of the oxyethylene / oxypropylene groups is from about 100: 0 to about 20:80. According to a third aspect of the present invention, a cosmetic makeup composition suitable for use as a mask or the like is provided, and which is in the form of an emulsion comprising: (a) from about 0.1% to about 60% by weight of more soluble polymepore material in an aqueous emulsion; Y (b) from about 0.1% to about 80% by weight of lipophilic oil components which include from about 0.1% to about 10% by weight of polyvinylpyrrolidone / hexadecene copolymer. The compositions of the present invention exhibit improved durability, increased aggression resistance and are easily removed with soap and water.All percentages are by weight of the composition unless otherwise indicated. in a weight / weight ratio, unless otherwise indicated.

DETAILED DESCRIPTION OF THE INVENTION A first essential component of the makeup composition of the present invention is a polyener co-soluble in an aqueous emulsion. Said materials, described in the art as latexes, are aqueous emulsions or dispersions of poly- eric materials comprising polyne- poned monomers, mixtures of monomers, derivatives of said monoline and mixtures of said monomers and mixtures thereof. These polyrneric materials described herein also include chemically modified derivatives of said polymer material described above. The polymerization process for manufacturing said polyarne material of the present invention is well known in the art. Such procedures are described in Encyclopedia of Chemical Technology, Volume 14, "Latex Technology" 3rd Ed. 1981; incorporated in the present for s? reference. The insoluble polyrneric materials of the present invention comprise from about 0.1% to about 60%; preferably about 2% of about 40% and most preferably about 3% of about 30% by weight of the composition. These insoluble polyester materials comprise polyrnened goods, mixtures of monomers, derivatives of said goods and mixtures thereof. monorneros and mixtures of the misinos selected from the group consisting of aromatic vmilos, dienes, vmilo cyanides, vinyl halides, vinylidene halides, vinyl esters, olefins and their isomers, vmylprolidone, more saturated carboxylic acids, alkyl esters of unsaturated carboxylic acids, hydroxy derivatives of alkyl esters of unsaturated carboxylic acids, carboxylic acid amides msat? ades, amine derivatives of unsaturated carboxylic acids, glycidyl derivatives of alkyl esters of unsaturated carboxylic acids, diarynins and olefinic isomers, aromatic diaryms , terephthaloyl halides, olef polyols iicos and mixtures of the same. The more soluble polirnecop material preferably comprises polimerized monomers, mixtures of monomers, derivatives of said monomers and mixtures of said monomers and mixtures thereof preferably selected from the group consisting of aromatic vinyls, dienes, vimic esters, olefms and their isomers. , msaturated carboxylic acids, alkyd esters of unsaturated carboxylic acids, hydroxy derivatives of alkylic esters of more saturated carboxylic acids, amides of carboxylic and unsaturated acids and mixtures of the same. In modal L ades to the aforementioned the insoluble polynomial material includes polynomials.mixtures of inonorneros, derivatives of said rnonorneros and mixtures of said rnonorneros and mixtures of the selected rnrnos and preferably from the group consisting of aromatic vinyls, dienes, vines, esters, alkyl esters of more saturated carboxylic acids, hydroxy derivatives of alchemical esters of carboxylated acids and saturated mixtures of minerals. The specific polumeric material useful in the present invention includes, but is not necessarily limited to, the Syntran series (of latexes) from Interpolyrner Corporation, for example Syntran 5170 and Syntran 5130 (copolymers of acnlatos formulated with ammonia, propylene glycol, preservative and surfactant added. ) and Syntran 5002 (ester copolymer / acrylates / methacrylate formulated with ammonia, propylene glycol, preservative and surfactant added); the Primal series (acrylic latexes) of Rohn 8 Hass; Pppretan V (styrene copolymer latexes / acrylic ester) from Hoechst; Vinac (polyvinyl acetate latex) from Air Products; latex resin UCAR 130 (polyvinyl acetate latex) from Union Caribe; Rhodopas A series (polyvinyl acetate latexes) from Rhone Poulenc; ñppretan MB, EM, TV (latexes of vmilo / ethylene acetate copolymer) from Hoechst; 200 series (styrene / butadiene copolymer latexes) from Dow Chemical; Rhodopas SB series (latexes of esthene / butadiene copolymer) by Rhone Pouienc; Uitcobond (latexes of poli uretano) of Uitco; Hycar Series (latexes of butadiene / acrylonitrile copolymer) from Goodrich: Chenigurn Series (latexes of butadiene / acrylonitrile buffing copolymer) from Goodyear; and Neo Cpl (latex copolymer latex / acp lat-os / acrilonitplo) from 1CT Resins. The makeup compositions of the present invention also comprise, for example, from about 0.1% to about 10% by weight of a first surfactant or mixture of surfactants having an average HLB of from about 3 to about 6 and about 20% by weight. 0.1% to about 10% by weight of a second surfactant or mixture of surfactants having a weight average HLB of from about 8 to about 15. Preferably, the first surfactant comprises an alkyl- or alkoxy-dimethicone copolyol which has the following general formula: CH3 CH3 CH3 CH3 CH3 CH3 iiO- -SiO iiO- -Si --CH3 CH3 CH3 (CH2) 3 and CH3 n 0 - (C2H4? -) x (C3H60-) and X rn wherein X is a hydrogen atom or an alkyl, alkoxy or acyl radical of Ci to Cie, Y is an alkoxy radical or Alkyl of Ce -, n * of about 0 to about 200, m - from about 1 to about 40, q - approximately 1 to about 100, the molecular weight of the residue (C2H «0-)« (C3H6? ~) and X being from about 250 to about 2000, x and y being selected so that the weight ratio of the oxyethylene / oxypropylene groups is from about 100: 0 to about 20:80. Preferably Y is C 16 -C 20 alkyl. Especially preferred herein in combination with the emulsified polymer emulsion from the viewpoint of water-increasing resistance is the copolyol of cetyl dimethicone. Accordingly, according to a second aspect of the present invention, there is provided a make-up composition comprising: (a) from about 0.1% to about 60% by weight of polyrneric material insoluble in an aqueous emulsion; Y (b) from about 0.1% to about 10% by weight of an alkyl- or alkoxy-direthylene copolyol having the following general formula: CH3 CH3 CH3 CH3 CH3 CH3 - S1O- SiO- -SiO -SlO- -Si --CH3 CH3 OH3 (CH2) 3 AND CH3 m wherein X is a hydrogen atom or an alkyl, alkoxy or acyl radical of Ci to Cie, Y is an alkoxy or alkyl radical of Cß-22, n - from about 0 to about 200, rn - • * of about 1 to about AO, q = approximately about 100, the molecular weight of the residue (C2H O -)? (C3H6? -) X being from about 250 to about 2Q00, xy being selected so that the weight ratio of the oxyethylene / oxypropylene groups is from about 100: 0 to about 20:80. The second surfactant of the present invention preferably comprises a organic base of C 2 -C 2 2 fatty acid; neutralized A preferred organic base in the present is triethanolarnine. A preferred fatty acid herein is stearic acid. Preferably, the compositions herein further comprise from about 0.1% to about 10% polyvinylpyrrolidone hexadecene copolymer. This copolymer is useful in combination with the polirnepco material insoluble in an aqueous emulsion and surfactants to improve the water resistance and the durability of the compositions. Accordingly, in accordance with a further aspect of the present invention, a cosmetic makeup composition suitable for use as a mascara or the like is provided, and which is in the form of an emulsion comprising: (a) from about 0.1% a about 60% by weight of a more polymeric polymeric material in an aqueous emulsion; and (b) from about 0.1% to about 80% by weight of Lipofi oil components which include from about 0.1% to about 10% by weight polyvinylpyrrolidone / hexadecene copolymer. The optional ingr-edient.es useful in the present invention are selected based either on the different forms or attributes that the composition should have. The most preferred embodiments of the present invention are water-in-oil or oil-in-water emulsions. Some of the other common optional ingredients include oils and fats, ernulsifiers, waxes, pigments and mixtures thereof.

A. Oils and fats The makeup compositions of the present invention may take the form of oil-in-water and water-in-oil emulsion compositions. These compositions are based on a combination of lipophilic materials optionally with one or more solvents. Said lipophilic materials typically comprise oils and fats generally known for use in the cosmetic industry and are generally used herein at a level of from about 0% to about 70%, preferably from about 20% to about 60% in pe. Oils typically used in cosmetics include those selected from the group consisting of Po-es oils, non-polar oils, volatile oils, non-volatile oils and mixtures thereof. These oils may be aliphatic or aromatic hydrocarbons, straight or branched chain, saturated or more saturated. Preferred oils include non-polar volatile hydrocarbons including isodecane (such as Perrnethyl-99AR, available from Presperse Tnc.) And the paraphases of C7-Ce to C? 2-Ci5 (such as the Isopar * series available from Exxon Chemicals). The fats employed according to the invention are selected from the group consisting of fats derived from animals, vegetables, synthetically derived fats and mixtures thereof, wherein said fats have a melting point of about 55 ° C to about 100. ° C and a needle penetration, measured in accordance with the American standard ASTM D5, approximately 3 to approximately 40 to 25 ° C. Preferably, the fats selected for use in the present invention are fatty acid esters which are solid at room temperature and which exhibit a crystalline structure. Examples of fatty acid esters useful in the present invention include the glyceryl esters of higher fatty acids such as stearic and palmitic stearates such as glycemic monostearate, glycemic distearate, glyceptal stearate, glycerol palnitol esters, C? B triglycerides. -36, glycemic tnbehenate and mixtures thereof.

L B. Waxes Waxes are defined as organic mixtures of low melting or high molecular weight compounds, solid at room temperature and similarly generated in composition to fats and oils, except that they do not contain glycends. Some are hydrocarbons, others are ester-es of fatty acids and Lcoholes. The waxes useful in the present invention are selected from the group consisting of ceriaceous animals, vegetable waxes, mineral waxes, various fractions of natural waxes, synthetic waxes, petroleum waxes, ethylene polymers, hydrocarbon types such as waxes of Fi cher-Tropsch, silicone waxes and mixtures thereof, where the waxes have a melting point between 55 ° and 100 ° C and a needle penetration, measured in accordance with the American standard ASTM D5, from 3 to 40 to 25 ° C. The principle of needle penetration measurement according to ASTM D5 standards is to measure the depth, expressed in tenths of a millimeter, at which a normal needle (weighing 2.5 g and placed in a needle holder weighing 47.5 g) , ie a total of 50 g) penetrates when it is placed on the wax for 5 seconds. The specific waxes useful in the present invention are selected from the group consisting of beeswax, lanolin wax, lacquer wax (animal waxes); carnauba, candelila, arrayan (vegetable waxes); ozokerite, ceresin (mineral waxes); parafma, rnicrocpstalinas waxes (petroleum waxes); ethylene poly (ethylene polymers); furnace Polyethylene lime (F? scher- ~ Tropsch waxes); alkyl rnetics of O-2.-.-- C45 (nlicon waxes) and mixtures thereof. Most preferred are beeswax, lanolin wax, carnauba, candelila, ozokerite, ceresin, for fines, rnicrocnstalmas waxes, polyethylene, alkyl rnet cones of C2¿-C45 and mixtures thereof.

C. Pigments The solid component of the makeup compositions of the present invention contains cosmetically acceptable pigments selected from the group consisting of inorganic pigments, organic pigments and pearlescent pigments. When used, pigments are present in proportions that depend on the color and intensity of the color you want to produce *. The level of pigments in the solid portion of the composition of the present invention is from about 3% to about 30%, preferably from about 5% to about 20%. The pigments are selected from the group consisting of inorganic pigments, organic lacquer pigments, pearlescent pigments and mixtures thereof. Such pigments may be surface treated optionally within the scope of the present invention, but are not limited to treatments such as silicones, perfluorinated compounds, lecithin and amino acids. Inorganic pigments useful in the present invention include those selected from the group consisting of rutile or anatase titanium dioxide, encoded in the color index - reference 01 77,891; oxides of black, yellow, red and brown iron, coded under references C 77,499, 77,492 and 77,491; manganese violet (Cl 77, 71 * 2); ultramarine blue (Cl 77,007); chromium oxide (Cl 77,288); chromium hydrate (01 77,289); and ferric blue (Cl 77, 510) and mixtures of the same. Organic pigments and lacquers useful in the present invention include those selected from the group consisting of D &C red No. 19 (01 45,170), D &C red No. 9 (Cl 15,585), D &C red No 21 (Cl 45,380), D &C orange No. 4 (01 15,510), D &C orange No. 5 (Cl 45,370), D &C red No. 27 (Cl 45,410), D &C No. 13 red (Ci 15,630), D &C red No. 7 (Cl 15,850), D &C red No.6 (Cl 15,850), D &C yellow No. 5 (Cl 19,140), Red DSC No. 36 (Cl 12,085) , D &C orange No. 10 (Cl 45,425), D &C yellow No. 6 (Cl 15,985), D &C red No. 30 (01 73,360), D &C red No. 3 (Cl 45,430) and the dye or lacquers based on carmine carmine (Cl 75, 570) and mixtures thereof. The pearlescent pigments useful in the present invention include those selected from the group consisting of white pearlescent pigments such as mica coated with titanium oxide, bismuth oxychloride, color pearlescent pigments such as titanium mica with iron oxides, titanium mica with ferric blue, chromium oxide and the like, titanium mica with an organic pigment of the aforementioned Lpo, as well as those based on oxychloride and bismuth and mixtures thereof.

D. Miscellaneous In the present invention numerous optional ingredients may be added to provide additional benefits other than those ascribed to the invention defined above. For example, it is preferred that the composition of the present invention contain a preservative system to inhibit the growth and maintain the integrity of the product. In the present invention the preservative system does not have a harmful effect on the composition. Any optional ingredients known to those in the art may also be used in the invention. Examples of optional ingredients are cosmetic fillers that include, but are not limited to, mica, talc, nylon, polyethylene, silica, polyurethane, kaolin, teflon; cosmetic preservatives including, but not limited to n est, rnetiiparabeno, propylparaben, butylparaben, ethylparaben, potassium sorbate, EDTA tpsodico, phenoxyethanol, ethyl alcohol, diazolidinyl urea, urea ímidazolidimlo, Quaternary? o-15. Similarly, additives such as tallow oil glycols are easily incorporated into the emulsion forms of the composition. Dispersible in oil and dispersible in water for L8 clays may also be useful in the invention. thicken- the water or the oil phase. Water-dispersible arils comprise bentonite and hectorite, such as Bentone EU, Rheox LT; magnesium aluminum silicate such as Veegurn by Vanderbilt Co.; attapulgite such as Attasorb or Pharamasorb from Engelhard, Inc .; lapo ita and rnontrnorplonita such as Gelwhite from ECC America; and mixtures thereof. The oil dispersible clays comprise bentonite of c? Atern? 18, such as Bentone 34 and 38 of Rheox: the Claytone series of ECC America; hectorita of cuatermo-18, such as Bentone gels of Rheox and mixtures thereof.

Manufacturing methods The compositions of the invention can be prepared as follows: 1. Oil in water emulsion Waxes and greases are placed in a container equipped with heating and mixing. The waxes and greases are heated to approximately 85 ° C with a low speed mixing until they are liquidized and made homogeneous. At 85-90 ° C, pigments and any dispersible or oil soluble component are added. The mixing speed is increased to high and mixed until the pigments are uniformly dispersed through the lipid mixture; approximately 30-35 minutes. The ernulsifiers are added to said lipid mixture continuing mixing.

In a second vessel equipped with mixing and heating, water and the rest of the water-dispersible components are added. The aqueous mixture is mixed with heating until this aqueous mixture is at about 85 °. U.S. for any loss of water of said aqueous mixture. The two mixtures are slowly combined and mixed with a high speed dispersing type mixer. The heat source is removed and the mixing is continued until the temperature of said combined mixture is approximately 65 ° C-70 ° C. 0-S. said combined mixture for any water loss. The preservatives and the more soluble polymer component are added and mixed until homogeneous. Said combined mixture is cooled to about 45 ° C-47 ° C and any remaining component is added. The cooling and mixing is continued until said mixture combined this about 27"C to about 30 ° O. This combined mixture to suitable storage containers for subsequent transfers packet filling retail size. 2. Water-in-oil emulsions (Examples I-V) The components of phase A are pre-mixed during minutes at room temperature with high shear stress. The pre-mix of phase A is then heated to 85-90 ° C with high shear stress. The phase B wax ingredients are pre-blended and heated to 9 ° C with slow stirring for one hour. the cer-a phase is added to the premix of phase A at 90 ° C and mixed for 20 minutes with high shear stress. The cooling starts and the ingredients of the water phase are added. It continues mixing with high cutting force. The mixture is cooled to 45 ° C and the remaining ingredients are added. OS for loss of paraffin.

Examples I-V (water-in-oil emulsions) I /% U /% IIT /% IV /% v /% A. Petroleum distillates up to 100 Hectopta of quaternum-18 4 3.5 4.2 4.0 3.8 Oxide of black iron 7.5 8.5 9.0 9.5 8.6 Copolymer of PVP / Hexadecene 1.7 2.5 2.2 1.9 2.0 Polybutene 1.9 2.75 2.0 2.5 1.8 Beeswax 2.8 3.5 4.4 4.0 3.0 Carnauba wax 2.5 4.4 3.5 3.3 4.0 Paraffin wax 1.5 2.2 2.0 2.5 1.8 Triglicepdos acids of C18-C36 1.5 3.0 3.3 2.5 2.8 Et i parabeno 0.15 0.15 0.15 0.15 0.15 Methyl paraben 0.2 0.2 0.2 0.2 0.2 Propyl paraben 0.2 0.2 0.2 0.2 0.2 Zinc stearate 2.5 2.0 2.1 2.3 1.9 Oop Liol of cetil dirnet icona 0.5 0.6 0.3 0.5 0.8 Acid this rich 0.9 1.0 1.8 1.'1 1.5 Prop ien glieol 1.0 1.5 1.4 1.3 0.9 Propylene carbonate 1.5 1.0 1.3 1.2 1.4 I /% EI /% III /% IV /% V /% 0. Trietanolarnin 0.4 0.5 0.25 0.3 0.5 Water 2.5 2.65 1.4 1.8 2.0 D. Copol irnero1 de amomo-ac p lato 9.0 12.5 10.5 1 .0 10.0 Pantenol 0.2 0.5 0.3 0.25 0.2 Water 1.0 1.0 1.5 0.8 1.2 C? Atern-15 to 94% 0.05 0.06 0.07 0.08 0.07 EDTA trisodium 0.1 0.1 0.1 0.1 0.1 Phenoxyethanol 0.8 1.0 0.75 1.1 0.85 1. Syntran 5170, which contains 41% by weight of insoluble polymer solids, available from Interpolyrner Corp.

Claims (11)

'.' or NOVELTY OF THE INVENTION CLAIMS

1. - A cosmetic makeup composition suitable for use as a mask or the like, and which comprises: (a) from about 0.1% to about 60% by weight of a more soluble polyrneric material in an aqueous emulsion; (b) from about 0.1% to about 10% by weight of a first surfactant or mixture of surfactants having an HLB averaged by weight from about 3 to about 6; and (c) from about 0.1% to about 10% by weight of a second surfactant or mixture of surfactants having an HLB averaged by weight of from about 8 to about 15.

2. A composition according to claim 1 , wherein said insoluble polyrneric material comprises impregnated polymers, mixtures of monomers, derivatives of said monomers and mixtures of said monomers and mixtures of the others, selected from the group consisting of aromatic vinyls, dienes, vinyl cyanides. , vimlo halides, vimlidene halides, vmyl ester, defines and their isomers, vinylpyrrole idona, unsaturated carboxylic acids, alkyl esters of more saturated carboxylic acids, hydroxy derivatives of esters to the carboxylic acids unsaturated carboxylic acids, carboxylic acid amides unsaturated icos, amine derivatives of unsaturated earboxi acids, glycidyl derivatives of ester-es alq? hairs of unsaturated earboxyl acids, diarrins and olefinic isomers, aromatic diamines, terephthaloyl halide halides, olefin polyols and mixtures of the same.

3. A composition according to claim 1, comprising from about 2% to about 40% by weight of a polymersible water-soluble material comprising polimerized monomers, mixtures of monomers, derivatives thereof, and mixtures of said monomers. and mixtures thereof, selected from the group consisting of aromatic oils, dienes, olefins and their isomers, more saturated carboxylic acids, alkyl esters of more saturated carboxylic acids, hydroxy derivatives of alkyl esters of carboxylic acids neat ions, amides of carboxylated acids and more mixtures of the same.

4. A composition according to claim 1, comprising from about 3% to about 30% by weight of an agueous insoluble polyrneric material comprising polimerized polymers, mixtures of monomers, derivatives of said nanores and mixtures of said compounds, and mixtures of the same, selected from the group consisting of aromatic vinyls, dienes, villic esters, alkyls of more saturated carboxylic acids, hydroxy derivatives of alkyl esters of carboxy acids, msat You guys and mixtures of the myos.

5. A composition according to claim 1, wherein the first surfactant comprises an alkyl- or alkoxy-dinethicone copolyol having the following general formula: CH3 wherein X is a hydrogen atom or an alkyl, alkoxy or acyl radical of Ci to Cie, Y is an alkoxy or C2-22 alkyl radical, n - from about 0 to about 200, m = from about 1 to about 40 , q = from about 1 to about 100, the molecular weight of the residue (C2H4O-)? (C3H6O-) and X being from about 250 to about 2000, x and y being selected so that the weight ratio of the oxyethylene / oxypropylene groups is from about L00: 0 to about 20:80.

6. A composition according to claim 5, wherein Y is Ci6-C2o alkyl.

7. A composition according to claim 1, wherein the second surfactant comprises a neutralized organic base fatty acid. . * "-;

8. - A composition of conformity with the indication r-e iv 1, in the form of an emulsion comprising from about 0.1% to about 70% by weight of 1-phylophilic oils.

9. A composition according to claim 1, which additionally comprises from about 0.1% to about 10% copolymer of polyvinylpyrrithione-hexadecene.

10. A mask composition according to claim 4, comprising from about 2 to about 40% by weight of the polirnecopic material insoluble in an aqueous emulsion.

11. A mask composition according to claim 8, wherein the composition is in the form of a water-in-oil emulsion.