JPH09136821A - Water-in-oil type emulsified composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain the subject composition, comprising an aqueous phase and an oily phase containing a specific polymeric silicone and capable of manifesting temperature stability and protecting the skin from kitchen work, good in extensibility and having a refreshing feeling by using a specific organic modified clay mineral as an emulsifying agent. SOLUTION: This water-in-oil type emulsified composition is obtained by using an organic-modified clay mineral formed from a water-swellable clay mineral, a quaternary ammonium salt type cationic surfactant and a polyoxyalkylene-modified organopolysiloxane as an emulsifying agent and adding the organic-modified clay mineral to an aqueous phaseand an oily phase containing an amino-modified or an ammonium-modified polymeric silicone of formula I R<1> is methyl or partially phenyl; R<2> and R<3> are each methyl or OH; R<3> is R<4> Z [R<4> is an alkylene; Z is NR<5> 2 , etc., (R<5> is H or an alkyl)]; (m) and (n) are each a positive integer and [(m)+(n)] is 3000-20000; (n)/(m) is (1/500-(1/1000)}. A compound of formula II [R is an alkyl, etc.; R' is H or an alkyl; (p) is 1-5; (m) is 5-100; (n) and (x) are each 1-50; (y) is 0-50], etc., are preferred as the polyloxyalkylene-modified organopolysiloxane.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water-in-oil type emulsion composition which is useful as cosmetics and pharmaceuticals and protects the skin from rough skin (mainly rough skin) due to water work, and more specifically, it is an external phase. The present invention relates to a water-in-oil emulsion composition which can be widely used as an oil component from polar oils to non-polar oils, and in which the obtained emulsion composition has extremely excellent temperature stability and usability.

[0002]

2. Description of the Related Art Conventionally, the skin is effectively protected from water work (especially, the protective effect is not lost even after repeated washing with water).
As a skin cosmetic which spreads well, has a refreshing feeling of use, and has little adhesion to contact substances, there is known a skin cosmetic containing a specific amino-modified or ammonium-modified polymer silicone (Japanese Patent Laid-Open No. Hei 10 (1999) -242242). 5-32534).

[0003]

However, the conventional water-in-oil type emulsion composition containing a specific amino-modified or ammonium-modified polymer silicone is difficult to obtain a system excellent in temperature stability and usability. There was a flaw. For example, regarding temperature stability, separation of the oil phase, which is a continuous phase, easily occurs at low temperatures due to aggregation of water droplets, and at high temperatures, the particle size increases due to coalescence of water droplets, causing sedimentation to the lower layer, and the upper layer portion. There was a phenomenon such as oil phase separation in which only the oil phase was present. On the other hand, regarding the usability, since the external phase is an oil, it has advantages such as protection of skin and imparting of flexibility in the fields of cosmetics and pharmaceuticals, but on the other hand, there is a problem that stickiness during use and skin occluding ability are high. . One of the methods to improve the temperature stability is to add a large amount of wax to the oil phase to increase the viscosity. This improves the low temperature stability, but it is added at high temperature storage. Due to the softening and melting of the wax, the oil phase separation due to coalescence of water droplets cannot be sufficiently improved, and there is a drawback in that new problems concerning usability such as heavy spread occur. An oil-in-water type (O / W type) is a method for improving such usability problems.
It is preferable to mix polar oil components having an ester bond and the like, which are often used in emulsion systems, but the water-in-oil type (W / O type) emulsifiers that have been conventionally used have excellent stability in systems containing polar oil components. It was difficult to produce an / O emulsion.

[0004]

Means for Solving the Problems As a result of intensive studies to solve the above problems, the present inventors have found that a water-swellable clay mineral, a quaternary ammonium salt type cationic surfactant,
If an organically modified clay mineral produced from a polyoxyalkylene-modified organopolysiloxane is used as an emulsifier, the above-mentioned temperature stability is solved, and the specific amino-modified or ammonium-modified polymer silicone contained in the oil phase allows water to be added. It was found that a water-in-oil emulsion composition that effectively protects the skin from work, spreads well, and has a refreshing feeling of use is obtained, and based on this finding, the present invention has been completed.

That is, the present invention provides a water-swelling clay mineral, a quaternary ammonium salt type cationic surfactant, one or more polyoxyalkylene-modified organopolysiloxanes, an aqueous phase, and a general formula (1). :

[0006]

[Chemical 6]

[In the formula, R ¹ represents a methyl group or a part thereof represents a phenyl group, and R ² represents the same as R ³ or a methyl group or a hydroxyl group. R ³ is wherein R ⁴ Z {R ⁴ represents a divalent alkylene group having carbon atoms of 3 to 6, Z is -NR ⁵ _2, -
_{^{N + R 5 3 A -,}} -NR 5 (CH 2) a NR 5 2, -NR 5 (CH
_{^{2) a N + R 5 3}} A - and _{^{-NR 5 (CH 2) a N}} (R 5) C =
O (R ⁶ ) (R ⁵ represents hydrogen or an alkyl group having 1 to 4 carbon atoms, R ⁶ represents an alkyl group having 1 to 4 carbon atoms, and A represents a chlorine atom, a bromine atom or an iodine atom. And a is an integer of 2 to 6.) represents a monovalent group selected from the group consisting of: Represents a substituent having an amino group or an ammonium group represented by｝, m and n are each a positive integer, and m + n is 3,000 to 2
Represents an integer of 0000, and n / m is 1/500 to 1/1
It is 0000. ] A water-in-oil emulsion composition comprising an oil phase containing one or more amino-modified or ammonium-modified polymer silicones represented by

The structure of the present invention will be described below. The water-swelling clay mineral used in the present invention is a layered silicate mineral belonging to the genus Smectite, generally montmorillonite,
There are pyriderite, nontronite, saponite, hectorite, etc., which may be natural or synthetic. Examples of commercially available products include Kunipia, Smecton (all manufactured by Kunimine Industry Co., Ltd.), Veegum (manufactured by Vanderbilt Co., Ltd.), Laponite (manufactured by Raporte Co., Ltd.), tetrafluorosilicon mica (manufactured by Toby Industry Co., Ltd.) and the like. In carrying out the present invention, from these water-swellable clay minerals, one kind or two or more kinds are arbitrarily selected, and the blending amount thereof is 0.05 to 5% with respect to the total weight of the emulsion composition. It is preferably 3.0% by weight, more preferably 0.2 to 2.0% by weight.
If it is less than 0.05% by weight, the temperature stability may be insufficient depending on the product, and if it exceeds 3.0% by weight, the viscosity of the system may increase and the usability may be poor depending on the product. .

The quaternary ammonium salt type cationic surfactant used in the present invention is represented by the following general formula (2).

[0010]

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(In the formula, R ⁷ is an alkyl group having 10 to 22 carbon atoms or a benzyl group, and R ⁸ is a methyl group or 1 carbon atom.
An alkyl group of 0 to 22, R ⁹ and R ¹⁰ represent an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group, and X represents a halogen atom or a methyl sulfate residue. )

Specific examples of the quaternary ammonium salt type cationic surfactant include, for example, dodecyltrimethylammonium chloride, myristyltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride,
Aralkyltrimethylammonium chloride, behenyltrimethylammonium chloride, myristyldimethylethylammonium chloride, cetyldimethylethylammonium chloride, stearyldimethylethylammonium chloride, aralkyldimethylethylammonium chloride, behenyldimethylethylammonium chloride, myristyldiethylmethylammonium chloride,
Cetyldiethylmethylammonium chloride, stearyldiethylmethylammonium chloride, aralkyldiethylmethylammonium chloride, behenyldiethylmethylammonium chloride, benzyldimethylmyristylammonium chloride, benzyldimethylcetylammonium chloride, benzyldimethylcetylammonium chloride, benzyldimethylstearylammonium chloride, benzyl Dimethylbehenylammonium chloride, benzylmethylethylcetylammonium chloride, benzylmethylethylstearylammonium chloride, distearyldimethylammonium chloride, dibehenyldihydroxyethylammonium chloride, and the corresponding bromide, and further dipalmitylpropylethylammonium Chill sulfate and the like.
In carrying out the present invention, one or more of these are arbitrarily selected.

The content of the quaternary ammonium salt type cationic surfactant in the water-in-oil type emulsion composition of the present invention is preferably 40 to 140 milliequivalent with respect to 100 g of the water-swelling clay mineral, and further, It is preferably 60 to 120 meq. The quaternary ammonium salt-type cationic surfactant and the water-swelling clay mineral may be added separately to the oil phase and the water phase at the time of preparing the emulsion, or may be commercially available (for example, Benton: manufactured by National Red Co.) in advance. After reacting both in a suitable solvent, the reaction product may be added to the oil phase.

The polyoxyalkylene-modified organopolysiloxane used in the present invention has the following general formula [A]:
The polyoxyalkylene-modified organopolysiloxane represented by [B], [C] or [D] is preferable, and any one or two or more thereof are blended, and the blending amount is 75 to 100 g of the water-swelling clay mineral. It is preferably 2,000 g, more preferably 100 to 1,500 g.

[0015]

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[0016]

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[0017]

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[0018]

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(In the formula, R is an alkyl group having 1 to 3 carbon atoms,
Or a phenyl group, R'is hydrogen, or an alkyl group having 1 to 12 carbon atoms, p is an integer of 1 to 5, m is an integer of 5 to 100,
n and x are integers of 1 to 50, and t and y are integers of 0 to 50. )

In the present invention, an organically modified clay mineral is formed from a water-swellable clay mineral, a quaternary ammonium salt type cationic surfactant and a polyoxyalkylene-modified organopolysiloxane, and this organically modified clay mineral is used as an emulsifier. This emulsifier is described in, for example, Japanese Patent Publication No. 60695/1992.

The amino-modified or ammonium-modified polymeric silicone used in the present invention is represented by the above general formula (1), and m + n of this polymeric silicone is 3,000 to 20,000. m + n is 3,000
If the amount is less than 2, the liquid is insufficient in the effect of protecting the skin.
If it exceeds 50,000, it will not dissolve in other cosmetic raw materials such as silicone oil and cannot be incorporated into cosmetics. Also,
n / m is 1 / 500-1 / 10,000. 1/5
If it exceeds 00, the content of amino groups or ammonium groups in the silicone becomes high, a crosslinking reaction or the like may occur during production, and it is not preferable from the viewpoint of raw material odor. 1/1
If it is less than 10,000, the interaction with the skin becomes weak,
The skin protection effect deteriorates.

The amino-modified or ammonium-modified polymeric silicone of the present invention can be produced by the same manufacturing method as that for general amino-modified or ammonium-modified polymeric silicone. For example, it can be produced by polycondensation reaction of γ-aminopropylmethyldiethoxysilane, cyclic dimethylpolysiloxane and hexamethyldisiloxane under an alkali catalyst. The amount of the amino-modified or ammonium-modified polymer silicone in the present invention is 0.01 to 30.0% by weight, preferably 0.1 to 20.0% by weight, and more preferably the amount in the water-in-oil emulsion composition. 0.1
１10.0% by weight. If it is less than 0.01% by weight, sufficient effect cannot be obtained in terms of usability, and if it exceeds 30.0% by weight, stickiness occurs. The amino-modified or ammonium-modified polymer silicone used in the present invention has a soft rubbery state and does not have a sticky feeling even when used in a large amount, and an extremely excellent water-in-oil type emulsion composition can be obtained.

When the amino-modified or ammonium-modified polymeric silicone of the present invention is incorporated into an emulsion composition, a volatile low-boiling chain silicone oil (for example, dimethylpolysiloxane having a viscosity of 0.65 to 5 cs / 25 ° C.) is used. )
And low-boiling cyclic silicone oils (eg octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, etc.) or low-boiling isoparaffin hydrocarbons (carbon number 1-30) It is preferable to use.

In the water-in-oil type emulsion composition of the present invention, in addition to the above-mentioned oil components, all general oil components used in cosmetics, pharmaceuticals and the like can be used, and the range is from polar oil to non-polar oil. It can be used widely. Examples of oils include liquid paraffin, squalane, petrolatum, hydrocarbon oils such as microcrystalline wax, isopropyl myristate, cetyl isooctanoate, ester oils such as glyceryl trioctanoate, octamethyltetrasiloxane, decamethyl. Silicone oils such as pentasiloxane, dimethylpolysiloxane and methylphenylpolysiloxane, high molecular weight silicones such as soft rubbery dimethylpolysiloxane, methylphenylpolysiloxane, terminal hydroxyl group-containing dimethylpolysiloxane and terminal hydroxyl group-containing methylphenylpolysiloxane, Lanolin,
Beeswax, olive oil, palm oil, safflower oil,
Castor oil, cottonseed oil, jojoba oil, carnauba wax, macadamia nut oil, fatty acids, higher alcohols, anti-inflammatory agents, vitamins, hormones, etc., which can be compounded within the range that does not impair the effects of the present invention. Is. The blending amount of these oil components is 5.0 to 90.% in the water-in-oil emulsion composition.
It is about 0% by weight, and preferably 10.0 to 80.0% by weight.

If desired, the water-in-oil type emulsion composition of the present invention may contain an oil-soluble substance and a water-soluble substance as long as the effects of the present invention are not impaired. For example, NMF (Natural Moisturizing Factor) existing in the stratum corneum of the skin
Amino acids and their salts, lower alcohols, mucopolysaccharides, moisturizers, thickeners, preservatives, antioxidants, sequestering agents, UV absorbers, drugs, crude drugs, pigments, dispersants, fragrances, etc. it can.

[0026]

EXAMPLES In order to further understand the present invention, examples will be described in more detail. The present invention is not limited by these. In addition, the compounding amount is weight%.

Example 1 Hand Cream (1) Decamethylcyclopentasiloxane 30.0% (2) Liquid paraffin 10.0 (3) Amino-modified polymer silicone 15.0 (in the general formula (1), R ¹ and R ² is a methyl group, R ³ is — (CH ₂ ) ₃ N (CH ₃ ) ₂ , m = 10,000, n = 5) (4) Polyoxyalkylene-modified organopolysiloxane 4.0 (general formula [A ], The average molecular weight is 6,000, R is a methyl group, R'is hydrogen, p = 3, y = 0, x = 28) (5) Distearyldimethylammonium chloride 0.8 (6) Vitamin E acetate 0 1 (7) Ethylparaben proper amount (8) Perfume proper amount (9) Deionized water residual amount (10) Polyethylene glycol 4000 1.0 (11) Glycerin 10.0 (12) Smecton 1.2 (production method) (3) (1) is mixed by heating at 70 ℃ And, to this
(2), (4) to (8) are heated and added at 70 ° C. to prepare an oil phase in advance. (9) to (12) were dispersed and mixed at 70 ° C., then gradually added to the oil phase while stirring with a disper, and mixed and stirred sufficiently uniformly to cool to obtain a target hand cream.

Example 2 Emulsion (1) Squalane 13.0% (2) Vaseline 3.0 (3) Dimethylpolysiloxane (5cs) 30.0 (4) Amino-modified polymer silicone 2.0 (general formula (1 ), R ¹ and R ² are methyl groups, R ³ is — (CH ₂ ) ₃ N (CH ₃ ) (CH ₂ ) ₂ N (CH ₃ ) ₂ , m = 10,000, n = 2) (5 ) Polyoxyalkylene-modified organopolysiloxane 2.5 (in the general formula [B], the average molecular weight is 12,000, R is a methyl group, R'is hydrogen, p = 3, y = 0, x = 32) (6 ) Behenyltrimethylammonium chloride 0.2 (7) Ethylparaben Appropriate amount (8) Perfume Appropriate amount (9) Ion-exchanged water Remaining amount (10) 2-Hydroxy-4-methoxybenzophenone 0.2-5-Sodium sulfonate (11) Polyethylene glycol 6000 1.0 (12) Loofah extract 0.5 (13) Sodium hyaluronate 0.1 (14) 1,3-Butylene glycol 5.0 (15) Smecton 0.3 (Manufacturing method) Obtained.

Example 3 Makeup base emulsion (1) Squalane 23.0% (2) Jojoba oil 5.0 (3) Decamethylcyclopentasiloxane 20.0 (4) Dimethylpolysiloxane (5cs) 20.0 (5 ) 2-Ethylhexyl-p-dimethylaminobenzoate 2.0 (6) Ammonium-modified polymer silicone 0.5 (In the general formula (1), 10% of R ¹ is a phenyl group, the rest is a methyl group, and R ² is a methyl group. group, R ³ is ^{_{- (CH 2) 3 n +}} (CH 2) 3 Cl -, m = 5,000, n = 5) (7) polyoxyalkylene-modified organopolysiloxane 2.0 (general formula [C] In, the average molecular weight is 9,000, R is a methyl group, R'is hydrogen, p = 3, y = 0, x = 25) (8) Organically modified clay mineral 1.0 (previously smectone and distearyldimethylammonium chloride) 65:35 ratio (9) Fragrance suitable amount (10) Deionized water residual amount (11) Polyethylene glycol 20000 1.0 (12) Titanium oxide 1.0 (13) Color pigment 0.1 (14) Dipropylene glycol 7.0 (Manufacturing method) According to Example 1, a target makeup base emulsion was obtained.

Example 4 Sunscreen Cream (1) 2-Ethylhexyl-p-dimethylaminobenzoate 5.0% (2) 4-tert-butyl-4′-methoxydibenzoylmethane 2.0 (3) Di-P -Glyceryl monoethylhexanoate methoxycinnamate 2.0 (4) Vaseline 2.0 (5) Amino-modified polymer silicone 0.1 (in the general formula (1), R ¹ , R ² and R ³ are the same as those in Example 1). Same as: m = 5,000, n = 5) (6) Decamethylcyclopentasiloxane 5.0 (7) Dimethylpolysiloxane (molecular weight about 300,000) 1.0 (8) Polyoxyalkylene-modified organopolysiloxane 3.5 (in the general formula [D], the average molecular weight is 15,000, R is a methyl group, R'is hydrogen, p = 3, y = 0, x = 34) (9) 2-hydroxy-4-methoxy Benzophenone 1.0 (10) Diste Lyldimethylammonium chloride 1.2 (11) Perfume proper amount (12) Ion-exchanged water remaining amount (13) Fine-grained titanium oxide 7.0 (maximum particle size 0.1μ or less and average particle size 10-40mμ) (14) Colored pigment 0.5 (15) Glycerin 5.0 (16) 1,3-Butylene glycol 5.0 (17) Veegum 1.8 (Production method) According to Example 1, the intended sunscreen cream was obtained.

Comparative Example 1 Hand Cream In the formulation of Example 1, an organically modified clay mineral is formed,
Instead of (4) polyoxyalkylene-modified organopolysiloxane, (5) distearyldimethylammonium chloride and (12) smectone, a total amount of sorbitan sesquioleate was substituted to obtain a hand cream.

Comparative Example 2 Hand Cream A hand cream was prepared by substituting all of diglyceryl diisostearate in place of the polyoxyalkylene-modified organopolysiloxane (4) in the formulation of Example 1.

Comparative Example 3 Sunscreen Cream In Example 4, (5) dimethylpolysiloxane (polymerization degree: 3,000) was used instead of the amino-modified polymer silicone.
Was completely replaced to obtain a sunscreen cream.

Comparative Example 4 Sunscreen Cream In the formulation of Example 4, an organically modified clay mineral is formed,
Instead of (8) polyoxyalkylene-modified organopolysiloxane, (11) distearyldimethylammonium chloride, and (17) veegum, sorbitan sesquioleate was completely substituted to obtain a sunscreen cream.

The water repellency and usability of the water-in-oil type emulsion compositions obtained in Examples 1 and 4 and Comparative Examples 1 to 4 were evaluated according to the following criteria. Table 1 shows the results.

(1) Stability A sample left at 0 ° C., RT (25 ° C.) and 50 ° C. for 2 months was evaluated according to the following criteria. ◯: No separation is observed at all. Δ: Very little oil separates. X: Remarkable oil separation is observed.

(2) Water repellent The water-in-oil type emulsion compositions obtained in Examples 1 and 4 and Comparative Examples 1 to 4 were applied to the forearms of 25 female panels and washed with tap water for 1 minute. The water repellency of the coated part was evaluated organoleptically. The evaluation criteria are as follows. ◯: Out of 25 people, 20 or more people evaluated that the water repellency was good. Δ: Out of 25 persons, 10 or more and less than 20 persons evaluated that the water repellency was good. Poor: Less than 10 out of 25 people evaluated that the water repellency was good.

(3) Usability The water-in-oil emulsion compositions obtained in Examples 1 and 4 and Comparative Examples 1 to 4 were applied to the forearms of 25 female panels to evaluate the feel of use. The evaluation criteria are as follows. Criteria for evaluation of goodness ◯: Out of 25 people, 20 or more people evaluated it as good. Δ: Out of 25 people, 10 or more and less than 20 people evaluated that the spread was good. X: Out of 25 people, less than 10 people evaluated that it was easy to spread. Evaluation criteria for freshness ○: Out of 25 people, 20 or more people are evaluated as refreshing. Δ: Out of 25 people, 10 or more and less than 20 people were evaluated as refreshing. X: Out of 25 people, less than 10 people evaluated it as refreshing.

[0039]

[Table 1] ──────────────────────────────── Stability Usability ─────────── Water repellency ────────── 0 ℃ RT 50 ℃ spread light ────────────────────────────── Example 1 ○ ○ ○ ○ ○ ○ Comparative Example 1 ○ △ × ○ ○ △ Comparative Example 2 ○ ○ × ○ ○ △ Example 4 ○ ○ ○ △ △ ○ Comparative Example 3 ○ ○ ○ × × ○ Comparative Example 4 ○ ○ △ △ △ ○ ────────────────────────────────

Example 5 Foundation (1) Liquid paraffin 20.0% (2) Vaseline 2.0 (3) Microcrystalline wax 1.0 (4) Di-P-methoxycinnamate monoethylhexanoate glyceryl 2.0 (5) 4-tert-butyl-4′-methoxydibenzoylmethane 1.0 (6) Decamethylcyclopentasiloxane 20.0 (7) Amino-modified polymer silicone (the same as in Example 1) 8.0 ( 8) Polyoxyalkylene-modified organopolysiloxane 1.5 (1.0 of (4) of Example 1 and 0.5 of (7) of Example 3) (9) Diglyceryl diisostearate. 5 (10) Benton 2.0 (hydrophilic clay mineral and quaternary ammonium salt type cationic surfactant reacting at a ratio of 65:35) (11) Fragrance suitable amount (12) Deionized water remaining amount (13) Glycerin 3.0 (14) Dispersant Suitable Amount (15) Titanium oxide 15.0 (16) Kaolin 5.0 (17) Talc 3.0 (18) Color pigment 1.0 (19) Fine particle titanium oxide 2.0 (Average at maximum particle size 0.1μ or less Particle size 10 to 14 mμ) (Production method) According to Example 1, a desired foundation was obtained.

Example 6 Moisture Cream (1) Squalane 2.0% (2) Cetylisooctanoate 2.0 (3) Octamethyltetrasiloxane 24.0 (4) Amino-modified silicone (same as Example 1) ) 10.0 (5) Polyoxyalkylene-modified organopolysiloxane 3.5 (2.0 of Example 5 (5), 2.0 of Example 4 (8) 1.5) (6) Behenyldiethylmethyl Ammonium chloride 0.5 (7) Ion-exchanged water Remaining amount (8) Glycerin 15.0 (9) 1,3-Butylene glycol 5.0 (10) Sodium glutamate 0.5 (11) Kunipia 1.0 (Production method) According to the same manner as in Example 1, the desired moisture cream was obtained. The compositions of Examples 5 and 6 were excellent in temperature stability and usability.

[0042]

The water-in-oil emulsion composition of the present invention is an organically modified clay produced from a water-swellable clay mineral, a quaternary ammonium salt type cationic surfactant, and a polyoxyalkylene-modified organopolysiloxane. Since the mineral and amino-modified or ammonium-modified polymer silicone are used as the oil phase component, the emulsion obtained has excellent stability over a wide temperature range, spreads well, and has a refreshing feel. , Moreover, water resistance,
Good water repellency. The water-in-oil type emulsion composition of the present invention having such a great advantage can be utilized in a wide range of cosmetics and pharmaceuticals by utilizing its characteristics.

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁶ Identification code Internal reference number FI Technical display area A61K 7/42 A61K 7/42

Claims (6)

[Claims] 1. A water-swelling clay mineral, a quaternary ammonium salt type cationic surfactant, one or more polyoxyalkylene-modified organopolysiloxanes, an aqueous phase, and a general formula (1): 1] [In the formula, R ¹ represents a methyl group or a part thereof is a phenyl group, and R ² represents the same as R ³ or a methyl group or a hydroxyl group. R ³ is wherein R ⁴ Z {R ⁴ represents a divalent alkylene group having carbon atoms of 3 to 6, Z is _{^{-NR 5 2, -N + R 5}} 3
_{^{A -, -NR 5 (CH 2}} ) a NR 5 2, -NR 5 (CH 2) a N +
R ⁵ ₃ A ^- and _{^{-NR 5 (CH 2) a N}} (R 5) C = O
(R ⁶ ) (R ⁵ represents hydrogen or an alkyl group having 1 to 4 carbon atoms, R ⁶ represents an alkyl group having 1 to 4 carbon atoms, and A represents a chlorine atom, a bromine atom or an iodine atom. A represents an integer of 2 to 6.), and represents a monovalent group selected from the group consisting of: Represents a substituent having an amino group or an ammonium group represented by｝, m and n are each a positive integer, and m + n is 3,000 to 20,
000, and n / m is 1/500 to 1/10,
000. ] The water-in-oil type emulsion composition characterized by containing the oil phase containing 1 type, or 2 or more types of amino modified or ammonium modified polymeric silicone represented by these. 2. The water-in-oil emulsion composition according to claim 1, wherein the polyoxyalkylene-modified organopolysiloxane is a compound represented by the following general formula [A], [B], [C] or [D]. Stuff. Embedded image Embedded image Embedded image Embedded image (In the formula, R is an alkyl group having 1 to 3 carbon atoms, or a phenyl group, R'is hydrogen, or an alkyl group having 1 to 12 carbon atoms, p
Is an integer of 1 to 5, m is an integer of 5 to 100, n and x are integers of 1 to 50, and t and y are integers of 0 to 50. ) 3. The content of the quaternary ammonium salt type cationic surfactant is 40 per 100 g of the water-swelling clay mineral.
The water-in-oil emulsion composition according to claim 1, wherein the water-in-oil emulsion composition has an amount of ˜140 meq. 4. The water-in-oil emulsion composition according to claim 1, wherein the content of the polyoxyalkylene-modified organopolysiloxane is 75 to 2,000 g based on 100 g of the water-swelling clay mineral. 5. A compound obtained by dissolving an amino-modified or ammonium-modified polymer silicone in one or more selected from low-boiling cyclic silicone oil, low-boiling chain silicone oil and low-boiling isoparaffin hydrocarbon. Item 5. A water-in-oil emulsion composition according to any one of items 1 to 4. 6. The water-in-oil type emulsion composition according to claim 5, wherein the low-boiling cyclic silicone oil is octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane or dodecamethylcyclohexasiloxane.