CN1187763A - Cosmetic make-up compositions - Google Patents
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- CN1187763A CN1187763A CN96194829A CN96194829A CN1187763A CN 1187763 A CN1187763 A CN 1187763A CN 96194829 A CN96194829 A CN 96194829A CN 96194829 A CN96194829 A CN 96194829A CN 1187763 A CN1187763 A CN 1187763A
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Abstract
Cosmetic make-up compositions comprising water-insoluble polymeric materials in the form of an aqueous emulsion and a first surfactant or mixture of surfactants having an average HLB of from about 3 to about 6 and a second surfactant or mixture of surfactants having an average HLB of from about 8 to about 15. The compositions exhibit improved wear and water resistance and are removable with soap and water.
Description
The present invention relates to cosmetic composition, particularly contain the eye cosmetic and the mascara of the water-insoluble polymeric material that exists with aqueous emulsion or latex form.Compare with compositions known in the art, more than said compositions have improved durability, and can wash with soap and water at an easy rate.
Background technology
Eye cosmetic composition comprises mascara, is product important on the cosmetics market.Mascara is by on the eyelashes of eye, perhaps covers the aesthetic feeling that color increases user under the certain situation on eyebrow.
Although general eye cosmetic preparation has the characteristic that increases aesthetic feeling, because they can't produce satisfied effect in being coated with usefulness for a long time, so nonconforming always.For example pollute and dirty problem, be often referred to the generation stain and peel off from eyelashes, these problems are very common.Even even prolong its service life, this based composition is difficult to the problem disposed fully from meticulous eye position also very common.In concept, for a kind of eye cosmetic composition, what need especially is that it has very good service life, and washes with soap and water easily.
Contain polymer emulsion and know in this technical field with the eye cosmetic composition that eliminates blemishes, these compositionss typically comprise non-soluble polymer, are also referred to as latex.This based composition comprises the U.S.P3 that authorized Henrich on February 1st, 1972, disclosed eye shadow cream in 639,572; Nineteen eighty-three, December 27 days authorized people's such as Murui U.S.P4, disclosed mascara in 423,031; And disclosed european patent application on November 3 (EPA) 0568035 in 1993.These compositionss comprise plasticizer or solvent comes film forming with help with said latex.People know that these compositionss contain the viscosity that thickening agent is adjusted compositions.Here said thickening agent is included in water solublity and the water-swellable polymer that typically becomes known for this purposes in the cosmetics technical field.
A different embodiment of above-mentioned conception was disclosed among the disclosed PCT patent application WO94/17775 on August 18th, 1994.Disclosed content comprises mascara in this invention, and these composition comprises water based polysiloxane elasticity latex are with the relative emulsion of " water base " acrylic acid series polymeric compounds.Owing to used elasticity latex, to compare with acrylate copolymer, it and compositions substrate have the better compatibility, thereby make compositions have longer durability and service life.
On March 3rd, 1993 provided other at compositions embodiment known in the art among the disclosed EPO 0530084, and these compositionss all try hard to avoid plasticizer and insoluble polymer to be used in combination.In the disclosed compositions of this patent application, contain a decentralized photo and a dispersant mutually, decentralized photo contains at least a water-soluble polymer, and decentralized photo contains at least 50% wax.Wherein said compositions may also can contain material commonly used in other cosmetic composition, comprises non-soluble polymer.
Surprisingly, discover being used in combination of water-insoluble polymeric material and special surfactant in aqueous emulsion, can make mascara have good especially durability, and can wash with soap and water.These mascaras can be made in a variety of forms, as emulsifiable paste, and pastel and solid.Compositions of the present invention is water-in-oil type or emulsion oil-in-water preferably.
Summary of the invention
One aspect of the present invention provides a kind of cosmetic composition of making mascara and analog that is suitable for, and it comprises: (a) about 0.1wt% is to the insoluble polymer of about 60wt% in aqueous emulsion; (b) about 0.1wt% is about 3 to about 6 first surface activating agent or surfactant mixture to the average HLB of about 10wt%; (c) about 0.1wt% is about 8 to about 15 second surface activating agent or surfactant mixture to the average HLB of about 10wt%.
Second aspect present invention provides and is suitable for the cosmetic compounds of making mascara and analog, and it comprises: (a) about 0.1wt% is to the insoluble polymer of about 60wt% in aqueous emulsion; (b) about 0.1wt% is to the alkyl with following general formula of about 10wt%-or alkoxyl-dimethicone polyol: wherein X is hydrogen atom or C
1-C
16Alkyl, alkoxyl or acyl group, Y are C
8-C
22Alkoxyl or alkyl, n are about 0 to about 200, and m is about 1 to about 40, and q is about 1 to about 100, residual base (C
2H
4O-)
x (C
3H
6O-)
yThe molecular weight of X is about 250 to about 2000, and the selection of x and y should guarantee that the weight ratio of oxyethylene group/oxypropylene group is about 100: 0 to about 20: 80.
A third aspect of the present invention provides and is suitable for the cosmetic composition of making mascara and analog, and it comprises with emulsion form: (a) about 0.1wt% is to the insoluble polymer of about 60wt% in aqueous emulsion; (b) about 0.1wt% is to the oleophylic oil content of about 80wt%, and this lipophilic ingredient comprises the polyvinylpyrrolidone/hexadecene copolymer of about 0.1wt% to about 10wt%.
The durability of the present composition and resistance to water improve, and are easy to clean with soap and water.
All percentage ratio all is based on composition weight, except as otherwise noted.All solution all is to represent with w/w concentration, except as otherwise noted.
Detailed Description Of The Invention
Cosmetic composition first solvent of the present invention is the insoluble polymer in aqueous emulsion.Said polymer is disclosed as latex in this area, they are the aqueous emulsion or the dispersion of polymer, and said polymer comprises monomer, monomer mixture, derivant of described monomer mixture and composition thereof of addressing of polymerized form.Polymer described here also comprises the above-mentioned polymer through chemical modification (deriving).The polymerization for preparing polymer of the present invention is well known in the art.These class methods be disclosed in Kirk Othmer's " encyclopedia of chemical technology ", the volume 14, " latex technology ", the third edition, 1981; Be incorporated herein by reference.These insoluble polymers of the present invention account for about 0.1% to about 60% of composition weight; Preferred about 2% to about 40%, and most preferably from about 3% to about 30%.
Insoluble polymer of the present invention comprises the monomer that being selected from of polymerized form is following, monomer mixture, derivant of said monomer and said monomer mixture and composition thereof: aromatic ethylene base class, diene, acrylonitrile, vinyl halide, the ethenylidene dihalo-, vinyl esters, alkene and isomer thereof, vinyl pyrrolidone, unsaturated carboxylic acid, the Arrcostab of unsaturated carboxylic acid, the hydroxy derivatives of the Arrcostab of unsaturated carboxylic acid, the amide of unsaturated carboxylic acid, the amine derivative of unsaturated carboxylic acid, the (+)-2,3-Epoxy-1-propanol radical derivative of unsaturated carboxylic acid alkyl ester, olefinic diamidogen and isomer thereof, aromatic diamines, the halogenide of terephthalate, olefinic polyhydric alcohol and composition thereof.
Insoluble polymer preferably includes polymerized form, is selected from derivant of following monomer, monomeric mixture, said monomer and said monomer mixture and composition thereof: the hydroxy derivatives of the Arrcostab of aromatic ethylene base class, diene, vinyl esters, alkene and isomer thereof, unsaturated carboxylic acid, unsaturated carboxylic acid, the Arrcostab of unsaturated carboxylic acid, amide of unsaturated carboxylic acid and composition thereof.
In highly preferred embodiment, insoluble polymer comprises derivant of the following monomer of being selected from of polymerized form, monomeric mixture, said monomer and said monomer mixture and composition thereof: hydroxy derivatives of the Arrcostab of aromatic ethylene base class, diene, vinyl esters, unsaturated carboxylic acid, the Arrcostab of unsaturated carboxylic acid and composition thereof.
The concrete polymeric material of Shi Yonging comprises in the present invention, but be not limited in this, the Syntran series (latex) that has Interpolymer Corporation to produce, (use the copolymer of the acrylate of the ammonia allotment that adds as Syntran 5170 and Syntran 5130, propylene glycol, antiseptic and surfactant) and Syntran 5002 (using the copolymer of the phenylethylene ethylene/propenoic acid ester/methacrylate of the ammonia allotment that adds, propylene glycol, antiseptic and surfactant); Rohm﹠amp; The Primal series (acrylic latex) that Hass produces; The Appretan V (copolymer emulsion of phenylethylene ethylene/propenoic acid ester) that Hoechst produces; The Vinac (polyvinyl acetate latex) that Air Products produces; The UCAR latex resin 130 (polyvinyl acetate latex) that Union Carbide Corporation produces; The Rhodopas A series (polyvinyl acetate latex) that RhonePoulenc produces; The Appretan MB that Hoechst produces, EM, TV (copolymer emulsion of vinyl-acetic ester/ethylene); 200 series (copolymer emulsion of phenylethylene/butadiene) that Dow Chemical Company produces; The Rhodopas SB series (copolymer emulsion of phenylethylene/butadiene) that Rhone Poulenc produces; The Witcobond (polyurethane rubber latex) that Witco produces; The Hycar series (copolymer emulsion of butadiene/acrylonitrile) that Goodrich produces; The Chemigum series (copolymer emulsion of butadiene/acrylonitrile) that Goodyear produces; And the Neo Cryl (copolymer emulsion of phenylethylene ethylene/propenoic acid ester/acrylonitrile) of ICI Resins product.
Cosmetic composition of the present invention preferably also comprise about 0.1wt% to the average HLB of about 10wt% be about 3 to about 6 first surface activating agent and surfactant mixture and about 0.1wt% extremely the weight average HLB of about 10wt% be about 8 to about 15 second surface activating agent and surfactant mixture.
Preferred first surface activating agent comprises the alkyl of following general formula-or alkoxyl-dimethicone polyol:
Wherein X is hydrogen atom or C
1-C
16Alkyl, alkoxyl or acyl group, Y are C
8-C
22Alkoxyl or alkyl, n are about 0 to about 200, and m is about 1 to about 40, and q is about 1 to about 100, residual base (C
2H
4O-)
x(C
3H
6O-)
yThe molecular weight of X is about 250 to about 2000, and the selection of x and y should guarantee that the weight ratio of oxyethylene group/oxypropylene group is about 100: 0 to about 20: 80.Preferred Y is C
16-C
20Alkyl.From strengthening water-proof viewpoint, what especially preferably use with the emulsion of insoluble polymer here is cetyl dimethicone polyol.Therefore second aspect present invention provides the cosmetic composition that comprises following composition: (a) about 0.1wt% is to the insoluble polymer of about 60wt% in aqueous emulsion; (b) about 0.1wt% is to the alkyl with following general formula of about 10wt%-or alkoxyl-dimethicone polyol:
Wherein X is hydrogen atom or C
1-C
16Alkyl, alkoxyl or acyl group, Y are C
8-C
22Alkoxyl or alkyl, n are about 0 to about 200, and m is about 1 to about 40, and q is about 1 to about 100, residual base (C
2H
4O-)
x(C
3H
6O-)
yThe molecular weight of X is about 250 to about 2000, and the selection of x and y should guarantee that the weight ratio of oxyethylene group/oxypropylene group is about 100: 0 to about 20: 80.
Here preferred second surface activating agent comprises the neutral C of organic base
12-C
24Fatty acid.Here preferred organic base is a triethanolamine.Here preferred fatty acid is a stearic acid.
Said composition preferably also comprises polyvinylpyrrolidone/hexadecene copolymer of about 0.1% to about 10%.This copolymer can be used in combination with insoluble polymer in the aqueous emulsion and surfactant to improve the resistance to water and the durability of compositions.Therefore another aspect of the present invention provides and is suitable for the cosmetic composition with emulsion form of making mascara and analog, and it comprises: (a) about 0.1wt% is to the insoluble polymer of about 60wt% in aqueous emulsion; (b) about 0.1wt% is to the oleophylic oil content of about 80wt%, and this lipophilic ingredient comprises the polyvinylpyrrolidone/hexadecene copolymer of about 0.1wt% to about 10wt%.
Select useful in the present invention selectable components according to different shape or attribute that compositions has.The most preferred embodiment of the present invention is water-in-oil type or emulsion oil-in-water.Some the most frequently used selectable components have oil ﹠ fat, emulsifying agent, wax, colorant, and their mixture.
A. oil and fat
Compositions of the present invention comprises oil-in-water type or water-in-oil emulsion compositions.These compositionss are based on the combination of oleophilic substance with one or more solvents of choosing wantonly.Said oleophilic substance typically contains the oil known in the cosmetics technical field or fatty, and the general use amount here is about 0% to about 70%, preferred 20% to about 60% weight.
The grease separation that the typical case uses in the cosmetics is from polar oil, non-polar oil, ethereal oil, nonvolatile oil, and their mixture.These oil can be saturated or unsaturated, straight chain or side chain, aliphatic hydrocarbon or aromatic hydrocarbon.Preferred oil has nonpolar volatile hydrocarbon, comprises the isodecane (Permethyl-99A that produces of Presperse Inc. for example
) and C
7-C
8To C
12-C
15The isoparaffin (Isopar that produces as Exxon Chemicals
Series).
Fat used according to the invention is selected from the fat that is obtained by animal, plant, the synthetic fat that obtains, and their mixture, wherein the fusing point of said fat is about 55 ℃ to about 100 ℃, needle penetration according to Unite States Standard ASTM D5, is about 3 to about 40 in the time of 25 ℃.Fat preferred for the present invention is for solid-state and have a fatty acid ester of crystal structure under the room temperature.The embodiment of the fatty acid ester that uses among the present invention is just like the glyceride of high fatty acids such as stearic acid and Palmic acid, as glyceryl monostearate, and distearin, glyceryl tristearate, the cetylate of glycerol, C
18-36Triglyceride, San behenic acid glyceride, and their mixture.
B. wax
That wax is defined as is high-molecular weight, under the room temperature for solid and form and generally be similar to fat and oil just they do not contain the low-melting organic mixture or the chemical compound of glyceride.Some are hydrocarbon, and all the other are the ester of fatty acid and alcohol.The wax that is used for the present invention is selected from animal wax, vegetable wax, various native paraffin fraction, synthetic wax, pertroleum wax, vinyl polymer, hydro carbons such as Fischer-Tropsch wax, silicone wax and composition thereof, wherein said wax has 55 ℃-100 ℃ fusing point, and is 3-40 by the needle penetration at 25 ℃ that Unite States Standard ASTM D5 records.Measuring needle penetration according to standard A STM D5 mainly is the degree of depth of measuring with 1/10th expressions of millimeter, promptly on placing wax during 5 seconds, and the degree of depth that standard pin (heavy 2.5g and place the needle guard of a heavy 47.5g, promptly 50g) altogether thrusts.
The concrete wax that is used for the present invention is selected from Cera Flava, lanolin wax, shellac wax (animal wax), Carnauba wax, candelilla wax, Laurel resin (vegetable wax); Ozocerite, ceresin, (ceresine); Paraffin, microwax (pertroleum wax); Polyethylene (vinyl polymer); Natene (Fischer-Tropsch wax); C
24-25Alkyl first polysiloxanes (silicone wax); And composition thereof.Most preferably Cera Flava, lanolin wax, Carnauba wax, candelilla wax, ceresine, ceresin, paraffin, microwax, polyethylene, C
24-25Alkyl first polysiloxanes and composition thereof.
C. colorant
The solid constituent of make-up composition of the present invention contains acceptable colorant in the cosmetics, and described colorant is selected from inorganic color, organic toner and pearly-lustre colorant.During use, the degree of depth of the color that exists ratio to depend on colorant and estimate to produce of colorant.The amount of the colorant in the solid portion of compositions of the present invention is about 3% to about 30%, is preferably about 5%-about 20%.Colorant is selected from inorganic color, organic color lake colorant, pearly-lustre colorant and composition thereof.Described colorant can alternatively be surface treated, and this is within the scope of the present invention, but is not limited to the processing with polysiloxanes, perfluoro-compound, lecithin and aminoacid and so on.
The used inorganic color of the present invention comprises those that are selected from the group be made up of following material: rutile or anatase titanium dioxide, and reference number is CI77891 in color index (Color Index); Black, yellow, red and brown iron oxides, reference number are CI77499,77492 and 77491; Manganese violet (CI77742); Ultramarine blue (CI77007); Chromium oxide (CI77288); The hydrate of chromium (CI77289); With ashen (CI77510) and composition thereof.
Organic toner that the present invention is used and color lake are selected from those of the group be made up of following material: D﹠amp; The red No.19 of C (CI45170), D﹠amp; The red No.9 of C (CI15585), D﹠amp; The red No.21 of C (CI45380), D﹠amp; C orange No.4 (CI15510), D﹠amp; C orange No.5 (CI45370), D﹠amp; The red No.27 of C (CI45410), D﹠amp; The red No.13 of C (CI15630), D﹠amp; The red No.7 of C (CI15850), D﹠amp; The red No.6 of C (CI15850), D﹠amp; The yellow No.5 (CI19140) of C, D﹠amp; The red No.36 of C (CI12085), D﹠amp; C orange No.10 (CI45425), D﹠amp; The yellow No.6 (CI15985) of C, D﹠amp; The red No.30 of C (CI73360), D﹠amp; The red No.3 of C (CI45430) and based on alkermes (Cochineal Carmine) dyestuff or color lake and composition thereof (CI75570).
The used pearly-lustre colorant of the present invention comprises those that are selected from the group be made up of following material: the white pearlescent colorant as the Muscovitum that scribbles titanium dioxide, bismuth oxychloride, color pearl colorant as the odenite of the oxide that scribbles ferrum, scribble the odenite of ashen, chromium oxide and so on, scribble the organic toner of the above-mentioned type and based on odenite of the colorant of bismuth oxychloride and composition thereof.
D. other composition
Can add many selective compositions in the present invention so that additional advantage to be provided, described advantage is different from the advantage of the invention described above.For example, make-up composition preferably of the present invention contains preservative agent to suppress microbial growth and to keep the integrity of product.In the present invention, preservative agent does not have adverse effect to compositions.
Can also use among the present invention and well known to a person skilled in the art any selective composition.The example of selective composition is the cosmetics fillers, includes but not limited to Muscovitum, Talcum, nylon, polyethylene, silicon dioxide, polymethacrylates, Kaolin, polytetrafluoroethylene; The cosmetics preservative agent includes but not limited to methyl parahydroxybenzoate, propyl p-hydroxybenzoate, butyl p-hydroxybenzoate, ethylparaben, potassium sorbate, sodium versenate, phenyl phenol, ethanol, diazonium ureine (diazolidinylurea), imidazolidinyl urea, quaternary ammonium salt-15; In addition, resembling additives such as tall oil glyceride can be easy to add in the emulsion of mascara and go.
Also use among the present invention in water, can disperse and in oil dispersible clay make water or oil phase retrogradation.Dispersible clay contains bentonite and hectorite in water, as the BentoneEW that Rheox produces, LT; Magnesiumaluminumsilicate is as the Veegum of Vanderbilt Co. product; Attagel is as the Attasorb or the Pharamasorb of EngelhardInc. product; LAPONITE and Montmorillonitum are as the Gelwhite of ECC America product; And their mixture.Dispersible clay contains bentonite quaternary ammonium salt-18 in oil, as the Bentone34 and 38 of Rheox product; The Claytone series that ECC America produces; Hectorite quaternary ammonium salt-18 is as the Bentone gels of Rheox product; And their mixture.
The preparation process explanation present composition is prepared as follows: 1. emulsion oil-in-water
Wax and fat are put into a container that has heating and agitating device.Under stirring at low speed, wax and fat is heated to about 85 ℃ until liquefaction and reach even.Add colorant at 85-90 ℃, can in oil, disperse or oil-soluble component arbitrarily.The quickening mixing speed is high speed extremely, stirs to be dispersed in the mixture of lipids until colorant in about 30-35 minute.In the process of continuous stirring, in said lipids mixture, add emulsifying agent.
Another have stir and the container of heater in add entry and remaining in water dispersible component.This aqueous mixture is heated while stirring until about 85 ℃.Any moisture that from said aqueous mixture, loses of an amount of interpolation.
With two kinds of mixture slow fixation, stir with high speed dispersion type agitator.Remove thermal source and continue to stir said combination back mixture until about 65 ℃-70 ℃.Any moisture that loses from said combination back mixture of an amount of interpolation adds antiseptic and insoluble polymer component and also stirs.Be cooled to about 45 ℃-47 ℃ with said in conjunction with the back mixture, and add any remaining ingredient.Continue cooling and stir said in conjunction with extremely about 27 ℃ to about 30 ℃ in back mixture.Move in the suitable hold-up vessel in conjunction with the back mixture said, in the packing of retail specification, fill after being convenient to.2. water-in-oil emulsion (example I-V)
The phase of high shear premixing at room temperature A component 30 minutes.Then phase A pre-composition is heated to 85-90 ℃ under high shear.With low the shearing merging of phase B wax component premix is heated to 90 ℃, continues about 1 hour.At 90 ℃ wax phase is added in the phase A pre-composition, and high shear was stirred 20 minutes.Begin to cool down and add the water component.Continue high shear mixing.Chemical compound is cooled to 45 ℃, and adds all the other components.The paraffin of an amount of replenish lost.
Example I-V (water-in-oil emulsion)
I/％ II/％ III/％?IV/％?V/％
A petroleum distillate to 100 hectorite quaternary amine-18 4 3.5 4.2 4.0 3.8 iron oxide black 7.5 8.5 9.0 9.5 8.6
BPVP/ hexadecene copolymer 1 .7 2.5 2.2 1.9 2.0 polybutene 1.9 2.75 2.0 2.5 1.8
Cera Flava 2.8 3.5 4.4 4.0 3.0 Carnauba waxs 2.5 4.4 3.5 3.3 4.0
Paraffin 1.5 2.2 2.0 2.5 1.8C
18-C
36Carboxylic acid glyceryl ester 1.5 3.0 3.3 2.5 2.8 aethyl parabenums 0.15 0.15 0.15 0.15 0.15 nipagin 0.2 0.2 0.2 0.2 0.2 nipasols 0.2 0.2 0.2 0.2 0.2 zinc stearates 2.5 2.0 2.1 2.3 1.9 cetyl diformazans gather silicon 0.5 0.6 0.3 0.5 0.8 oxygen alkane polyols
Stearic acid 0.9 1.0 1.8 1.9 1.5
Propylene glycol 1.0 1.5 1.4 1.3 0.9 propylene carbonates 1.5 1.0 1.3 1.2 1.4
I/％ II/％ III/％?IV/％?V/％
C triethanolamine 0.4 0.5 0.25 0.3 0.5
Water 2.5 2.65 1.4 1.8 2.0
D ammonium acrylate copolymer
19.0 12.5 10.5 12.0 10.0
E
Panthenol 0.2 0.5 0.3 0.25 0.2
Water 1.0 1.0 1.5 0.8 1.2 quaternary ammonium salts-15 94% 0.05 0.06 0.07 0.08 0.07
EDTA trisodium 0.1 0.1 0.1 0.1 0.1
F
Phenyl phenol 0.8 1.0 0.75 1.1 0.851.Syntran5170 contain 41wt% insoluble polymer solid, available from InterpolymerCorp..
Claims (11)
1. one kind is suitable for the cosmetic composition of making mascara and analog, and it comprises: (a) about 0.1wt% is to the insoluble polymer of about 60wt% in aqueous emulsion; (b) about 0.1wt% is about 3 to about 6 first surface activating agent or surfactant mixture to the average HLB of about 10wt%; (c) about 0.1wt% is about 8 to about 15 second surface activating agent or surfactant mixture to the average HLB of about 10wt%.
2. according to the compositions of claim 1, wherein said insoluble polymer comprises the monomer that being selected from of polymerized form is following, monomer mixture, derivant of said monomer and said monomer mixture and composition thereof: aromatic ethylene base class, diene, acrylonitrile, vinyl halide, the ethenylidene dihalo-, vinyl esters, alkene and isomer thereof, vinyl pyrrolidone, unsaturated carboxylic acid, the Arrcostab of unsaturated carboxylic acid, the hydroxy derivatives of the Arrcostab of unsaturated carboxylic acid, the amide of unsaturated carboxylic acid, the amine derivative of unsaturated carboxylic acid, the (+)-2,3-Epoxy-1-propanol radical derivative of unsaturated carboxylic acid alkyl ester, olefinic diamidogen and isomer thereof, aromatic diamines, the halogenide of terephthalate, olefinic polyhydric alcohol and composition thereof.
3. according to the compositions of claim 1, comprise the insoluble polymer of about 2wt% to about 40wt%, this polymer comprises derivant of the following monomer of being selected from of polymerized form, monomeric mixture, said monomer and said monomer mixture and composition thereof: the hydroxy derivatives of the Arrcostab of aromatic ethylene base class, diene, vinyl esters, alkene and isomer thereof, unsaturated carboxylic acid, unsaturated carboxylic acid, the Arrcostab of unsaturated carboxylic acid, amide of unsaturated carboxylic acid and composition thereof.
4. according to the compositions of claim 1, comprise about 3wt% to about 30wt% insoluble polymer, this polymer comprises derivant of the following monomer of being selected from of polymerized form, monomeric mixture, said monomer and said monomer mixture and composition thereof: hydroxy derivatives of the Arrcostab of aromatic ethylene base class, diene, vinyl esters, unsaturated carboxylic acid, the Arrcostab of unsaturated carboxylic acid and composition thereof.
5. according to each compositions in the claim 1 to 4, wherein the first surface activating agent comprises the alkyl of following general formula-or alkoxyl-dimethicone polyol:
Wherein X is hydrogen atom or C
1-C
16Alkyl, alkoxyl or acyl group, Y are C
8-C
22Alkoxyl or alkyl, n are about 0 to about 200, and m is about 1 to about 40, and q is about 1 to about 100, residual base (C
2H
4O-)
x(C
3H
6O-)
yThe molecular weight of X is about 250 to about 2000, and the selection of x and y should guarantee that the weight ratio of oxyethylene group/oxypropylene group is about 100: 0 to about 20: 80.
6. according to the compositions of claim 5, wherein Y is C
16-C
20Alkyl.
7. according to each compositions in the claim 1 to 6, wherein the second surface activating agent comprises the neutral fatty acid of organic base.
8. according to each compositions in the claim 1 to 7, it comprises the oleophylic oil content of about 0.1wt% to about 70wt% with emulsion form.
9. according to each compositions in the claim 1 to 8, it contains polyvinyl pyrrolidone/hexadecene copolymer of about 0.1% to about 10% in addition.
10. according to each mascara in the claim 1 to 9, it comprises the insoluble polymer in aqueous emulsion of about 2wt% to about 40wt%.
11. according to each mascara in the claim 1 to 10, wherein compositions is with the water-in-oil emulsion form.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96194829A CN1187763A (en) | 1995-05-20 | 1996-04-23 | Cosmetic make-up compositions |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9510231.5 | 1995-05-20 | ||
| CN96194829A CN1187763A (en) | 1995-05-20 | 1996-04-23 | Cosmetic make-up compositions |
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| Publication Number | Publication Date |
|---|---|
| CN1187763A true CN1187763A (en) | 1998-07-15 |
Family
ID=5128849
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96194829A Pending CN1187763A (en) | 1995-05-20 | 1996-04-23 | Cosmetic make-up compositions |
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| Country | Link |
|---|---|
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105979929A (en) * | 2013-10-31 | 2016-09-28 | 莱雅公司 | Composition in form of an emulsion |
-
1996
- 1996-04-23 CN CN96194829A patent/CN1187763A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105979929A (en) * | 2013-10-31 | 2016-09-28 | 莱雅公司 | Composition in form of an emulsion |
| CN105979929B (en) * | 2013-10-31 | 2020-08-21 | 莱雅公司 | Composition in the form of an emulsion |
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