MXPA06006209A

MXPA06006209A - Combinations of active compounds that have insecticides and acaricity

Info

Publication number: MXPA06006209A
Authority: MX
Priority date: 2003-12-04
Filing date: 2006-06-01
Publication date: 2006-08-09
Also published as: PL1691608T5; CN1889835A; DE102004021566A1; CN100393208C; ATE497697T1; ES2359923T3; PL1691608T3; ES2359923T5; DE502004012183D1; PT1691608E; JP2007513103A; CN101253861B; CN101253861A; JP4705585B2; IL176058A0

Abstract

Composition (A) contains synergistic amounts of a phenylpyrazolone compound (I) or at least one insecticide (IA) comprising amitraz, buprofezin, triazamate, pymetrozin, pyriproxifen, flonicamide or pirimicarb and at least one anthranilic acid amide compound (II). Composition (A) contains synergistic amounts of a phenylpyrazolone compound of formula (I), its N oxides or salts or at least one insecticide (IA) comprising amitraz, buprofezin, triazamate, pymetrozin, pyriproxifen, flonicamide or pirimicarb and at least one anthranilic acid amide compound of formula (II). [Image] X : halo, alkyl, haloalkyl, alkoxy, haloalkoxy or cyano; W 1>, Y, Z : H or X; A 3> : H, alkyl, alkoxyalkyl or optionally substituted cycloalkyl in which at least one ring atom is optionally replaced by a heteroatom (all optionally substituted by halo); A 4> : H or alkyl, or A 3> + A 4> : a saturated or unsaturated ring optionally containing at least one heteroatom and optionally substituted; D : alkyl, alkenyl, alkoxyalkyl or cycloalkyl in at least 1 ring member is optionally replaced by heteroatoms (all optionally substituted) or H, or D + A 3> : a saturated or unsaturated ring optionally containing at least one heteroatom and optionally substituted; G 1> : e.g. H or COR 20>; R 20> : alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl or polyalkoxyalkyl (all optionally substituted by halo), cycloalkyl optionally including at least one heteroatom (optionally substituted by halo, alkyl or alkoxy), or phenyl, phenalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl (all optionally substituted); A 1>, A 2> : O or S; X 1> : N or CR 10>; R 1> : 1-6C alkyl, 2-6C alkenyl, 2-6C alkynyl or 3-6C cycloalkyl (all optionally substituted) or H; R 2> : H, 1-6C alkyl, 2-6C alkenyl, 2-6C alkynyl, 3-6C cycloalkyl, 1-4C alkoxy, 1-4C alkylamino, 2-8C dialkylamino, 3-6C cycloalkylamino, 2-6C alkoxycarbonyl or 2-6C alkylcarbonyl; R 3> : H, R 11> or 1-6C alkyl, 2-6C alkenyl, 2-6C alkynyl or 3-6C cycloalkyl (all optionally substituted), or R 2> + R 3> : a ring; R 4> : e.g. 1-6C alkyl, 2-6C alkenyl, 2-6C alkynyl or 3-6C cycloalkyl (all optionally substituted), or H; R 5>, R 8> : 1-4C alkyl or 1-4C haloalkyl (both optionally substituted), H or halo; R 7> : H, halo or 1-4C alkyl, alkoxy or alkylS(O) x (all optionally substituted), with specified provisos. Full definitions are given in the Definitions Field (Full Definitions). ACTIVITY : Insecticide; Nematocide; Arachnicide; Acaricide; Antifouling. In a test against Aphis gossypii on cotton, results showed that N-(2-methyl-4-chloro-6-(dimethylaminocarbonyl)phenyl-1-(3-chloropyrid-2-yl)-3-trifluoromethyl-pyrrole-5-carboxamide, at 20 ppm, gave 55% kill after 6 days, while flonicamide at 20 ppm gave 40% kill. The specified amounts of both compounds, when applied together, gave a 99% kill, with 73% expected from an additive effect. MECHANISM OF ACTION : None given.

Description

COMBINATIONS OF ACTIVE COMPOUNDS THAT HAVE INSECTICIDES AND ACARICIDES PROPERTIES Description of the Invention The present invention relates to novel combinations of active compounds comprising, first, known cyclic ketoenols and, secondly, known, additional insecticide-active compounds, combinations that are highly suitable to control animal pests, such as insects and unwanted acarids. It is already known that certain cyclic ketoenols have herbicidal, insecticidal and acaricidal properties. The activity of these compounds is good; however, at low application rates it is sometimes unsatisfactory. It is known that the unsubstituted bicyclic 3-arylpyrrolidin-2, 4-dione derivatives (EP-A 0 355 599 and EP-A 0 415 211) and the monocyclic 3-arylpyrrolidin-2,4-dione derivatives, substituted (EP-A 0 377 893 and EP-A 0 442 077) have a herbicidal, insecticidal or acaricidal action. Also known are the polycyclic 3-arylpyrrolidin-2,4-dione derivatives (EP-A 0 442 073) and the lH-arylpyrrolidinedione derivatives (EP-A 0 456 063, EP-A 0 521 334, EP-A 0 596 298, EP-A 0 613 884, EP-A 0 613 885, WO 94/01 997, WO 95/26 954, WO 95/20 572, EP-A 0 668 267, WO REF: 173123 96/25395, WO 96/35664, WO 97/01535, WO 97/02243, WO 97/36868, WO 97/43275, WO 98/05638, WO 98/06721, WO 98/25928, WO 99 / 16748, WO 99/24437, WO 99/43649, WO 99/48869 and WO 99/55673, WO 01/23354, WO 01/74770). The activity of these compounds is good; however, at low application rates it is sometimes unsatisfactory. It is also known that mixtures of phthalamides and additional bioactive compounds have an insecticidal and / or acaricidal action (WO 02/087334). However, the activity of this mixture is not always optimal. Furthermore, it is already known that numerous heterocycles, organotin compounds, benzoylureas and pyrethroids have insecticidal and acaricidal properties (see WO 93/22297, WO 93/10083, DE-A 26 41 343, EP-A 0 347 488, EP-A 210 487, EU 3,364,177 and EP-A 234 045). However, in the same way, the activity of these compounds is not always satisfactory. It has now been found that mixtures of the compounds of the formula (I) (group 1) wherein X represents halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano, W1, Y and Z independently represent hydrogen, halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano, A3 represents hydrogen, in each case optionally substituted alkyl by halogen, alkoxyalkyl, optionally substituted cycloalkyl, saturated in which optionally at least one ring atom is replaced by a heteroatom, A4 represents hydrogen or alkyl A3 and A4 together with the carbon atom to which they are attached further represent a substituted or unsubstituted, saturated or unsaturated which optionally contains at least one heteroatom, D represents hydrogen or a radical optionally substituted from the group consisting of alkyl, alkenyl, alkoxyalkyl, saturated cycloalkyl in which optionally one or more ring members are replaced by heteroatoms , A3 and D together with the atoms to which they are attached represent a satur cycle or unsaturated which is unsubstituted or substituted in the portion A3, D and optionally contains at least one heteroatom, G1 represents hydrogen (a) or represents one of the groups E represents a metal ion or an ammonium ion, L1 represents oxygen or sulfur, M1 represents oxygen or sulfur, R20 represents in each case alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl optionally substituted by halogen or cycloalkyl optionally substituted by halogen, alkyl or alkoxy which can be interrupted by at least one heteroatom, in each case phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl optionally substituted, R21 represents in each case alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl optionally substituted by halogen or represents in each case cycloalkyl, phenyl or benzyl optionally substituted, R22 represents alkyl optionally substituted by halogen or phenyl optionally substituted, R23 and R24 represent in each case independently of each other alkyl, alkoxy, alkylamino, dialkylamino, alkylthio alkenylthio, cycloalkylthio optionally substituted by halogen or in each case represent optionally substituted phenyl, benzyl, phenoxy or phenylthio and R25 and R25 independently represent hydrogen, in each case alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl optionally substituted by halogen, represent phenyl optionally substituted, represent benzyl optionally substituted or together with the nitrogen atom to which they are attached represent an optionally substituted ring which is optionally interrupted by oxygen or sulfur, or an active compound from the viewpoint of Secticide (group 2), preferably (2-1) amitraz (known from DE-A 20 61 132) and / or (2-2) buprofezin (known from DE-A 28 24 126) and / or (2-3) triazamate (known from EP-A 0 213 718) and / or (2-4) pymetrozine (known from EP-A 0 314 615) and / or (2-5) pyriproxyfen (known from EP-A 0 128 648) and / or (2-6) flonicamid (known from EP-A 0 580 374) and / or (2-7) pirimicarb (known from GB 1 181 657) and at least one active compound from the group of the anthranilamides of the formula (II) are synergistically effective and have very good insecticidal and acaricidal properties. Surprisingly, the insecticidal and / or acaricidal activity of the combinations of active compounds according to the invention is higher than the sum of the activities of the individual active compounds. In this way, a synergistic, true, unpredictable effect is present and not just an addition of activities. In addition to at least one active compound of the formula (I) or an active compound of the group 2 (compounds (2-1) to (2-7)), the combinations of active compounds according to the invention comprise at least one compound active of the formula (II). Preference is given to combinations of active compounds comprising the compounds of the formula (I) in which W1 represents hydrogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, chlorine, bromine or fluorine, X represents alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, haloalkyl of 1 to 4 carbon atoms, fluorine, chlorine or bromine, Y and Z independently represent hydrogen, alkyl of 1 to 4 carbon atoms, halogen, alkoxy 1 to 4 carbon atoms or haloalkyl of 1 to 4 carbon atoms, A3 represents hydrogen or in each case alkyl of 1 to 6 carbon atoms or cycloalkyl of 3 to 8 carbon atoms optionally substituted by halogen, A4 represents hydrogen, - methyl or ethyl, A3 and A4 together with the carbon atom to which they are attached further represent saturated cycloalkyl of 3 to 6 carbon atoms in which optionally a ring member is replaced by oxygen or sulfur and which is mono- or disubstituted optionally by alkyl of 1 to 4 carbon atoms, trifluoromethyl or alkoxy of 1 to 4 carbon atoms, D represents hydrogen, in each case alkyl of 1 to 6 carbon atoms, alkenyl of 3 to 4 carbon atoms or cycloalkyl of 3 at 6 carbon atoms optionally substituted by fluorine or chlorine, A3 and D together represent alkanediyl of 3 to 4 carbon atoms optionally substituted by methyl in which optionally a methylene group is replaced by sulfur re, G1 represents hydrogen (a) or represents one of the groups E (f) 0 (g), in particular (a), (b), (c) or (g) E represents a metal ion or an ammonium ion, L1 represents oxygen or sulfur, M1 represents oxygen or sulfur, R20 represents in each case alkyl of 1 to 10 carbon atoms, alkenyl of 2 to 10 carbon atoms, alkoxy- ( C1-C4) -alkyl of 1 to 4 carbon atoms, alkylthio- (C 1 -C 4) -alkyl of 1 to 4 carbon atoms optionally substituted by halogen or cycloalkyl of 3 to 6 carbon atoms optionally substituted by fluorine, chlorine, alkyl of 1 to 4 carbon atoms or alkoxy of 1 to 2 carbon atoms, represents phenyl optionally substituted by fluorine, chlorine, bromine, cyano, nitro, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms , trifluoromethyl or trifluoromethoxy, represents in each case pyridyl or thienyl optionally substituted by chlorine or methyl, R21 represents in each case alkyl of 1 to 10 carbon atoms, alkenyl of 2 to 10 carbon atoms, alkoxy- (C1-C4) - alkyl of 2 to 4 carbon atoms optionally substituted by fluorine or chlorine, represents cycloalkyl of 5 to 6 carbon atoms optionally substituted by methyl or methoxy or represents in each case phenyl or benzyl optionally substituted by fluorine, chlorine, bromine, cyano, nitro, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, trifluoromethyl or trifluoromethoxy, R22 represents alkyl of 1 to 4 carbon atoms optionally substituted by fluorine or represents phenyl optionally substituted by fluorine, chlorine, bromine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, trifluoromethyl , trifluoromethoxy, cyano or nitro, R23 represents in each case alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms optionally substituted by fluorine or chlorine or represents in each case phenyl, phenoxy or phenylthio optionally substituted by fluorine, chlorine, bromine, nitro, cyano, alkoxy of 1 to 4 carbon atoms, trifluoromethoxy, alkylthio of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, alkyl of 1 to 4 carbon atoms or trifluoromethyl, R24 represents alkoxy of 1 to 4 carbon atoms or alkylthio of 1 to 4 carbon atoms, R25 represents alkyl of 1 to 6 carbon atoms, cycloa alkyl of 3 to 6 carbon atoms, alkoxy of 1 to 6 carbon atoms, alkenyl of 3 to 6 carbon atoms ", alkoxy- (C1-C4) -alkyl of 1 to 4 carbon atoms, R26 represents alkyl of 1 to 6 carbon atoms, alkenyl of 3 to 6 carbon atoms or alkoxy- (C 1 -C 4) -alkyl of 1 to 4 carbon atoms, R 25 and R 26 together represent an alkylene radical of 3 to 6 carbon atoms optionally substituted by methyl or ethyl in which a carbon atom is optionally replaced by oxygen or sulfur, and at least one active compound of the formula (II). In the halogen radicals in the preferred ranges, halogen preferably represents chlorine and fluorine. Particular preference is given to combinations of active compounds comprising the compounds of formula (I), in which W1 represents hydrogen, methyl, ethyl, chloro, bromo or methoxy, X represents chloro, bromo, methyl, ethyl, propyl, isopropyl , methoxy, ethoxy or trifluoromethyl, Y and Z independently represent hydrogen, fluorine, chlorine, bromine, methyl, ethyl, propyl, isopropyl, trifluoromethyl or methoxy, A3 represents methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec- butyl, tere-butyl, cyclopropyl, cyclopentyl or cyclohexyl, A4 represents hydrogen, ethyl or methyl, A3 and A4 further represent, together with the carbon atom to which they are attached, cycloalkyl of 6 saturated carbon atoms in which a ring member is optionally replaced by oxygen and which is optionally monosubstituted by methyl, ethyl, methoxy, ethoxy, propoxy or butoxy, D represents hydrogen, represents methyl, ethyl, propyl, isopropyl, butyl, isobutyl, allyl, cyclopropyl, cyclopentyl or cyclohexyl, A3 and D together represent alkanediyl of 3 to 4 carbon atoms optionally substituted by methyl, G1 represents hydrogen (a) or represents one of the groups L1 represents oxygen or sulfur, M1 represents oxygen or sulfur, R20 represents alkyl of 1 to 8 carbon atoms, alkenyl of 2 to 4 carbon atoms, methoxymethyl, ethoxymethyl, ethylthiomethyl, cyclopropyl, cyclopentyl or cyclohexyl, represents phenyl which is mono optionally disubstituted by fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, methoxy, trifluoromethyl or trifluoromethoxy, represents pyridyl or thienyl, each of which is optionally mono- or disubstituted by chlorine or methyl, R21 represents alkyl 1 to 8 carbon atoms, alkenyl of 2 to 4 carbon atoms, methoxyethyl, ethoxyethyl or represents phenyl or benzyl, R25 and R26 independently represent methyl, ethyl or together with the nitrogen atom to which they are attached represent morpholino, and at least one active compound of the formula (II). Particular preference is given to the combinations of active compounds comprising the compounds of the formula (I) in which W1 represents hydrogen or methyl, X represents chlorine, bromine or methyl, Y and Z independently represent hydrogen, chlorine, bromine or methyl, A3 and A4 further represent together with the carbon atom to which are attached 6-carbon-saturated cycloalkyl in which optionally a ring member is replaced by oxygen and is optionally monosubstituted by methyl, methoxy, ethoxy, propoxy or butoxy, D represents hydrogen, G1 represents hydrogen (a) or represents one of the groups L1 represents oxygen or sulfur, M1 represents oxygen or sulfur, R20 represents alkyl of 1 to 8 carbon atoms, alkenyl of 2 to 4 carbon atoms, methoxymethyl, ethoxymethyl, ethylmethylthio, cyclopropyl, cyclopentyl, cyclohexyl, represents phenyl which is monosubstituted optionally by fluorine, chlorine, bromine, methyl, methoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro, represents pyridyl or thienyl, each of which is optionally monosubstituted by chlorine or methyl, R21 represents alkyl of 1 to 8 carbon atoms, alkenyl of 2 to 4 carbon atoms, methoxyethyl, ethoxyethyl, phenyl or benzyl, R 25 and R 26 independently of one another methyl, ethyl or together with the nitrogen atom to which they are attached represent morpholino, and at least one active compound of the formula ( II). Especially preferred are combinations of active compounds comprising at least one of the following compounds of the formula (I-a) Example No. W1 X Y z R27 G1 p.f. (SC) l-a-1 H Br 5-CH 3 H OCH 3 CO-i-C 3 H 7 122 l-a-2 H Br 5 -CH 3 H OCH 3 CO2-C 2 H 5 140-142 l-a-3 H CH 3 5 -CH 3 H OCH 3 H > 220 l-a-4 H CH 3 5-CH 3 H OCH 3 CO2-C 2 H 5 128 l-a-5 CH 3 CH 3 3-Br H OCH 3 H > 220 l-a-6 HH3 CH3 3-CI H OCH3 H 219 l-a-7 H Br 4-CH 3 5-CH 3 OCH 3 CO-i-C 3 H 7 217 l-a-8 H CH 3 4-CI 5-CH 3 OCH 3 CO2C 2 H 5 162 l-a-9 H CHa 4-CH 3 5-CH 3 OCH 3 Co -? / "or oil l-a-10 CH3 CH3 3-CH3 4-CH3 OCH3 H > 220 / ~? l-a-11 H CH3 5-CH3 H OC2H5 CO- N O oil la-12 CH3 CH3 3-Br H OC2H5 CO-i-C3H7 212-214 la-13 H CH3 4-CH3 5-CH3 OC2H5 CO-n-Pr 134 la-14 H CH3 4-CH3 5-CH3 OC2H5 CO- i-Pr 108 la-15 H CH3 4-CH3 5-CH3 OC2H5 CO-c-Pr 163 at least one active compound of the formula (II) The combinations of active compounds comprising the compound of the formula are especially preferred. and at least one active compound of the formula (II). Depending inter alia on the nature of the substituents, the compounds of the formula (I) may be present as geometric and / or optical isomers or mixtures of isomers of variant composition which, if desired, may be prepared in the usual manner. The present invention provides both pure isomers and mixtures of isomers, their preparation and use and also compositions comprising them. However, later in this document, for reasons of simplicity, only the compounds of the formula (I) are referred, although what is meant are both pure compounds and, if appropriate, also mixtures having varying proportions of the isomeric compounds. . Especially preferred are combinations of active compounds comprising a compound selected from the compounds (2-1) to (2-7) of group 2 and at least one active compound of the formula (II).

The anthranilamides of the formula (II) are likewise known compounds which are known from the following publications or are included therein: WO 01/70671, WO 03/015518, WO 03/015519, WO 03/016284, WO 03/016282, WO 03/016283, WO 03/024222, WO 03/062226. The generic formulas and definitions described in these publications and the individual compounds described therein are expressly incorporated herein by way of reference. The anthranilamides can be summarized by the formula (II): wherein A1 and A2 independently represent oxygen or sulfur, X1 represents N or CR10, R1 represents hydrogen or represents alkyl of 1 to 6 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkynyl of 2 to 6 carbon atoms carbon or cycloalkyl of 3 to 6 carbon atoms, each of which is optionally mono- or poly-substituted, wherein the substituents can be independently selected from the group consisting of R6, halogen, cyano, nitro, hydroxyl, alkoxy from 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, alkoxycarbonyl of 2 to 4 carbon atoms, alkylamino of 1 to 4 atoms carbon, dialkylamino 2 to 8 carbon atoms, cycloalkylamino of 3 to 6 carbon atoms, (C1-C4 alkyl) -cycloalkylamino of 3 to 6 carbon atoms and R 11, R 2 represents hydrogen, alkyl of 1 to 6 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkynyl of 2 to 6 carbon atoms, cycloalkyl of 3 to 6 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, cycloalkylamino of 3 to 6 carbon atoms, alkoxycarbonyl of 2 to 6 carbon atoms or alkylcarbonyl of 2 to 6 carbon atoms , R3 represents hydrogen, R11 or represents alkyl of 1 to 6 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkynyl of 2 to 6 carbon atoms, cycloalkyl of 3 to 6 carbon atoms, each of which is mono- or polysubstituted optionally, wherein the substituents can be independently selected from the group consisting of R6, halogen, cyano, nitro, hydroxyl, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, alkoxycarbonyl of 2 to 6 carbon atoms, alkylcarbonyl of 2 to 6 carbon atoms, trialkylsilyl of 3 to 6 carbon atoms carbon, R11, phenyl, phenoxy and a 5- or 6-membered heteroaromatic ring, wherein each phenyl, phenoxy and 5- or 6-membered heteroaromatic ring can be optionally substituted and where the substituents can be independently selected from each other. one to three radicals W or one or more radicals R12, or R2 and R3 can be linked together and form the ring M, R4 represents hydrogen, alkyl of 1 to 6 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkynyl from 2 to 6 carbon atoms, cycloalkyl of 3 to 6 carbon atoms, haloalkyl of 1 to 6 carbon atoms, haloalkenyl of 2 to 6 carbon atoms, haloalkynyl of 2 to 6 carbon atoms, halocycloalkyl of 3 to 6 carbon atoms, halogen, cyano, nitro, hydroxyl, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkynylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 carbon atoms, haloalkylsulfonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms carbon, cycloalkylamino of 3 to 6 carbon atoms, trialkylsilyl of 3 to 6 carbon atoms or represents phenyl, benzyl or phenoxy, each of which is optionally mono- or poly-substituted, wherein the substituents can be independently selected from the group consisting of alkyl of 1 to 4 carbon atoms. carbon, alkenyl of 2 to 4 carbon atoms, alkynyl of 2 to 4 carbon atoms, cycloalkyl of 3 to 6 carbon atoms, haloalkyl of 1 to 4 carbon atoms, haloalkenyl of 2 to 4 carbon atoms, haloalkynyl of 2 to 4 carbon atoms, halocycloalkyl of 3 to 6 carbon atoms, halogen, cyano, nitro, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, cycloalkylamino of 3 to 6 carbon atoms, (C3-C6 alkyl) -cycloalkylamino , alkylcarbonyl of 2 to 4 carbon atoms, alkoxycarbonyl of 2 to 6 carbon atoms, alkylaminocarbonyl of 2 to 6 carbon atoms, dialkylaminocarbonyl of 3 to 8 carbon atoms and trialkylsilyl of 3 to 6 carbon atoms, R8 represent in each case independently of each other hydrogen, hal or in each case represent alkyl of 1 to 4 carbon atoms optionally substituted, haloalkyl of 1 to 4 carbon atoms, R12, G, J, -OJ, -OG, -S (0) pJ, -S (0) pG, -S (O) p-phenyl, wherein the substituents can be independently selected from one to three W radicals or from the group consisting of R12, alkyl of 1 to 10 carbon atoms, alkenyl of 2 to 6 carbon atoms, carbon, alkynyl of 2 to 6 carbon atoms, alkoxy of 1 to 4 carbon atoms and alkylthio of 1 to 4 carbon atoms, wherein each substituent may be substituted by one or more substituents independently selected from the group consisting of G , J, R6, halogen, cyano, nitro, amino, hydroxyl, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms , alkylsulfonyl of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 atoms of carbon, haloalkylsulfonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, trialkylsilyl of 3 to 6 carbon atoms, phenyl and phenoxy, where each ring of phenyl or phenoxy can optionally be substituted and where the substituents can be independently selected from one to three W radicals or from one to more R12 radicals, each independently representing a carbocyclic or heterocyclic, nonaromatic 5 or 6 membered ring which may optionally contain one or two ring members of the group consisting of C (= 0), SO and S (= 0) 2 and which may be optionally substituted by one to four substituents independently selected from the group consisting of alkyl of 1 to 2 carbon atoms, halogen, cyano, nitro and alkoxy of 1 to 2 carbon atoms or independently represents alkenyl of 2 to 6 carbon atoms, alkynyl of 2 to 6 atom s of carbon, cycloalkyl of 3 to 7 carbon atoms, (cyano) -cycloalkyl of 3 to 7 carbon atoms, (C1-C4 alkyl) -cycloalkyl of 3 to 6 carbon atoms, (C3-Ce cycloalkyl) -alkyl from 1 to 4 carbon atoms, wherein each cycloalkyl, (alkyl) cycloalkyl and (cycloalkyl) -alkyl can be optionally substituted by one or more halogen atoms, J represents in each case independently a 5- or 6-membered heteroaromatic ring optionally substituted, wherein the substituents can be independently selected from one to three radicals W or one or more radicals R12, R6 independently of one another -C (= E1) R19, -LC (= E1) R19, -C (= E1) LR19, -LC (= EX) LR19, -0P (= Q) (OR19) 2, -S02LR18 or -LS02LR19, where each E1 independently represents O, S, N-R15, N-OR15, N- N (R15) 2, NS = 0, N-CN or N-N02, R7 represents hydrogen, alkyl of 1 to 4 carbon atoms, haloalkyl of 1 to 4 carbon atoms carbon, halogen, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, haloalkylthio - from 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 carbon atoms, haloalkylsulfonyl of 1 to 4 carbon atoms, R9 represents haloalkyl of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 carbon atoms or halogen, R10 represents hydrogen, alkyl of 1 to 4 carbon atoms, haloalkyl of 1 to 4 carbon atoms, halogen, cyano or haloalkoxy of 1 to 4 carbon atoms, R11 represents in each case or independently of one another alkylthio of 1 to 6 carbon atoms, alkylsulfenyl of 1 to 6 carbon atoms, haloalkylthio of 1 to 6 carbon atoms, haloalkylsulfenyl of 6 carbon atoms, phenylthio or phenylsulphenyl mono- to tri-substituted optionally, where substituents can be independently selected from the list consisting of W, -S (O) nN (R16) 2, -C (= 0) R13, -L (C = 0) R14, -S (C = 0) LR14, -C (= 0) LR13, -S (OJp R ^ C (= 0 =) R13, -S (0) nNR13C (= 0) LR14 or -S (0) nNR13S (0) 2LR14, L represents in each case independently of one another OR, NR18 or S, R12 in each case independently represents B (OR17) 2 / amino, SH, thiocyanate, trialkylsilyloxy of 3 to 8 carbon atoms, alkyl disulfide of 1 to 4 carbon atoms , -SF5, -C (= E1) R19, -LC (= E1) R19, -C ^ E ^ LR19, -LC (= E1) LR19, -OP (= Q) (OR19) 2, -S02LR19 or - LS02LR19, Q represents O or S, R13 represents in each case independently hydrogen or represents in each case alkyl of 1 to 6 atom carbon, alkenyl of 2 to 6 carbon atoms, alkynyl of 2 to 6 carbon atoms or cycloalkyl of 3 to 6 carbon atoms mono- or polysubstituted optionally, wherein the substituents can be independently selected from the group consisting of R6, halogen, cyano, nitro, hydroxyl, alkoxy of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, cycloalkylamino of 3 to 6 carbon atoms or (C 1 -C 4 alkyl) -cycloalkylamino of 3 to 6 carbon atoms, each independently represents alkyl of 1 to 20 carbon atoms, alkenyl of 2 to 20 carbon atoms, alkynyl of 2 to 20 carbon atoms or cycloalkyl of 3 to 6 carbon atoms mono- or polysubstituted optionally, wherein the substituents can be independently selected from each other from the group consisting of R6, halogen, cyano, nitro, hydroxyl, alkoxy of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms , cycloalkylamino of 3 to 6 carbon atoms and (C 1 -C 4 alkyl) -cycloalkylamino of 3 to 6 carbon atoms or represents optionally substituted phenyl, wherein the substituents can be independently selected from one to three W radicals or one or more radicals R12, R15 in each case independently represents hydrogen or represents in each case haloalkyl of 1 to 6 carbon atoms or alkyl of 1 to 6 carbon atoms mono- or polysubstituted optionally, where the substituents can be independently selected from each other group consisting of cyano, nitro, hydroxyl, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 atom of carbon, alkylsulfonyl of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 carbon atoms, haloalkylsulfonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, alkoxycarbonyl of 2 to 6 carbon atoms, alkylcarbonyl of 2 to 6 carbon atoms, trialkylsilyl having 3 to 6 carbon atoms and optionally substituted phenyl, wherein the substituents can be independently selected from one to three radicals W or one or more radicals R12 or N (R15) 2 represents a cycle which the ring M forms, R16 represents alkyl of 1 to 12 carbon atoms or haloalkyl of 1 to 12 carbon atoms or N (R16) 2 represents the ring in which the ring M, R17 represents in each case independently of each other hydrogen or alkyl of 1 to 4 carbon atoms or B (OR17) 2 represents a ring in which the two oxygen atoms are linked via a chain having two to three carbon atoms which are optionally substituted by one or twosubstituents independently selected from the group consisting of methyl and alkoxycarbonyl of 2 to 6 carbon atoms, R 18 each independently represents hydrogen, alkyl of 1 to 6 carbon atoms or haloalkyl of 1 to 6 carbon atoms or N (R13) (R18) represents a ring which forms the ring M, R19 represents in each case independently hydrogen or represents in each case alkyl of 1 to 6 carbon atoms mono- or polysubstituted optionally, where the substituents can be selected independently from each other of the group consisting of cyano, nitro, hydroxyl, alkoxy of 1 to 4 carbon atom, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 carbon atoms, haloalkylsufonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, C02H, alkoxycarbonyl of 2 to 6 carbon atoms, alkylcarbonyl of 2 to 6 carbon atoms, trialkylsilyl of 3 to 6 carbon atoms and optionally substituted phenyl, where the substituents can be independently selected from one to three radicals W, haloalkyl of 1 to 6 carbon atoms, cycloalkyl of 3 to 6 carbon atoms or phenyl or pyridyl, each of which is mono- to trisubstituted optionally by W , M represents in each case an optionally mono-a-substituted ring which, in addition to the nitrogen atom attached to the pair of substituents R13 and R18, (R15) 2 or (R16), contains from two to six carbon atoms and optionally additionally an additional nitrogen, sulfur or oxygen atom, where the substituents can be independently selected from the group consisting of alkyl of 1 to 2 atoms of carbon, halogen, cyano, nitro and alkoxy having 1 to 2 carbon atoms, each independently represents alkyl of 1 to 4 carbon atoms, alkenyl of 2 to 4 carbon atoms, alkynyl of 2 to 4 carbon atoms, carbon, cycloalkyl of 3 to 6 carbon atoms, haloalkyl of 1 to 4 carbon atoms, haloalkenyl of 2 to 4 carbon atoms, haloalkynyl of 2 to 4 carbon atoms, halocycloalkyl 3 to 6 carbon atoms, halogen. cyano, nitro, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, cycloalkylamino of 3 to 6 carbon atoms, (C1-C4 alkyl) -cycloalkylamino of 3 to 6 carbon atoms, alkylcarbonyl of 2 to 4 carbon atoms, alkoxycarbonyl of 2 to 6 carbon atoms, C02H, alkylaminocarbonyl of 2 to 6 carbon atoms, dialkylaminocarbonyl of 3 to 8 carbon atoms or trialkylsilyl of 3 to 6 carbon atoms carbon, n represents in each case independently of each other 0 or 1, p represents in each case independently of each other 0, 1 or 2, where, if (a) R5 represents hydrogen, alkyl of 1 to 6 carbon atoms, haloalkyl of 1 to 6 carbon atoms, haloalkenyl of 2 to 6 carbon atoms, haloalkynyl of 2 to 6 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms or halogen and (b) R8 represents hydrogen , alkyl of 1 to 6 carbon atoms, haloalkyl of 1 to 6 carbon atoms, haloalkenyl of 2 to 6 carbon atoms, haloalkynyl of 2 to 6 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, halogen, alkylcarbonyl 2 to 4 carbon atoms, alkoxycarbonyl of 2 to 6 carbon atoms, alkylaminocarbonyl of 2 to 6 carbon atoms or dialkylaminocarbonyl of 3 to 8 carbon atoms, (c) at least one substituent selected from the group consisting of R6 is present , R11 and R12 and (d) if R12 is not present, at least one of the radicals Rd and R11 is different from alkylcarbonyl of 2 to 6 carbon atoms, alkoxycarbonyl 2 to 6 carbon atoms, alkylaminocarbonyl of 2 to 6 carbon atoms. carbon and dialkylaminocarbonyl of 3 to 8 carbon atoms. The compounds of the general formula (II) comprise N-oxides and salts. Depending inter alia on the nature of the substituents, the compounds of the formula (II) may be present as geometric and / or optical isomers or mixtures of isomers of variant composition. which, if desired, can be separated in the usual way. The present invention provides both pure isomers and mixtures of isomers, their preparation and use and also compositions comprising them. However, later in this document, for reasons of simplicity, only compounds of the formula (II) are referred, although what is proposed are both pure compounds and, if appropriate, also mixtures having varying proportions of isomeric compounds. Preference is given to combinations of active compounds comprising the compounds of the formula (II-1) in which R 2 represents hydrogen or alkyl of 1 to 6 carbon atoms, R 3 represents alkyl of 1 to 6 carbon atoms which is optionally substituted by an R6, R4 represents alkyl of 1 to 4 carbon atoms, haloalkyl of 1 to 2 carbon atoms, haloalkoxy of 1 to 2 carbon atoms or halogen, R5 represents hydrogen, alkyl of 1 to 4 carbon atoms, haloalkyl of 1 to 2 carbon atoms, haloalkoxy of 1 to 2 carbon atoms or halogen, R6 represents -C (= E2) R19, -LC (= E2) R19, -C (= E2) LR19 or -LC (= E2) LR19, wherein each E2 independently represents 0, S, N-R15, N-OR15, NN (R15) 2, and each L independently of each other 0 or NR18, R7 represents haloalkyl of 1 to 4 carbon atoms or halogen, R9 represents haloalkyl of 1 to 2 carbon atoms, haloalkoxy of 1 to 2 carbon atoms, S (O) p-haloalkyl of 1 to 2 carbon atoms or halogen, R15 represents in each case independently of each other hydrogen or represents in each haloalkyl group of 1 to 6 carbon atoms optionally substituted or alkyl of 1 to 6 carbon atoms, wherein the substituents can be independently selected from the group consisting of cyano, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 carbon atoms and haloalkylsulfonyl of 1 to 4 carbon atoms, R18 represents in each case hydrogen or alkyl of 1 to 4 carbon atoms, R19 represents in each case independently of each other hydrogen or alkyl of 1 to 6 carbon atoms, p independently of each other 0, 1, 2. In the definitions of radicals mentioned as preferred, halogen represents fluorine, chlorine, bromine and iodine, in particular fluorine, chlorine and bromine. Particular preference is given to combinations of active compounds comprising the compounds of the formula (II-1) in which R 2 represents hydrogen or methyl, R 3 represents alkyl of 1 to 4 carbon atoms (in particular methyl, ethyl, n- , isopropyl, n-, iso-, sec-, tere-butyl), R4 represents methyl, trifluoromethyl, trifluoromethoxy, fluorine, chlorine, bromine or iodine, R5 represents hydrogen, fluorine, chlorine, bromine, iodine, trifluoromethyl or trifluoroethoxy, R7 represents chlorine or bromine, R9 represents trifluoromethyl, chlorine, bromine, difluoromethoxy or trifluoroethoxy. Particular preference is given to combinations of active compounds comprising the following compounds of the formula (II-1): Example R2 R3 R4 R5 R7 R9 pf- (° C) No. 11-1-1 H Me Me Cl Cl CF3 185-186 11-1-2 H Me Me Cl Cl OCH2CF3 207-208 11-1-3 H Me Cl Cl Cl 225-226 11-1-4 H Me Cl Cl Cl 162-164 11-1-5 H Cl Cl Cl CF 155-157 11-1-6 H Cl Cl Cl OCH2CF3 192-195 11 -1-7 H Cl Cl CL Cl 205-206 Example R2 R3 R4 R5 R7 R9 pf (° C) No. 11-1-8 H Cl Cl Cl Cl 245-246 11-1-9 H i-Pr Me Cl Cl CF3 195-196 11-1-10 H i-Pr Me Cl Cl OCH2CF3 217-218 - 11-1-11 H i-Pr Me Cl Cl Cl 173-175 11-1-12 H i-Pr Me Cl Cl Br 159-161 11-1-13 H i-Pr Cl Cl Cl CF3 200-201 11-1-14 H i-Cl Cl Cl Cl OCH2CF3 232-235 11-1-15 H - -Pr Cl Cl Cl Cl 197-199 11-1-16 H i-Cl Cl Cl Cl 188-190 11-1-17 H Et Me Cl Cl CF3 163-164 11-1-18 H Et Me Cl Cl OCH2CF3 205-207 11-1-19 H Et Cl Cl Cl 199-200 11-1-20 H Et Me Cl Cl Br 194-195 11-1-21 H Et Cl Cl Cl CF3 201-202 11-1-22 H Et Cl Cl Cl Cl 206-208 11-1-23 H Et Cl Cl Cl Br 214-215 11-1-24 H t-Bu Cl Cl Cl CF3 223-225 11-1-25 H t-Bu Me Cl Cl Cl 163-165 11-1-26 H t-Bu Me Cl Cl Br 159-161 11-1-27 H t-Bu Cl Cl Cl CF3 170-172 11-1-28 H t-Bu CI Cl Cl Cl 172-173 11-1-29 H t-Bu Cl Cl Cl Br 179-180 11-1-30 H Me Me Br Cl CF3 222-223 Example R2 R3 R4 R5 R7 R9 p.f. (° C) No. 11-1-31 H Et Me Br Cl CF3 192-193 11-1-32 H i-Pr Me Br Cl CF3 197-198 11-1-33 H t-Bu Me Br Cl CF3 247-248 11-1-34 H Me Me Br Cl Cl 140-141 11-1-35 H Et Me Br Cl Cl 192-194 11-1-36 H i-Pr Me Br Cl Cl 152-153 11-1-37 H t-Bu Me Br Cl Cl 224-225 11-1-38 H Me Me Br Cl Br 147-149 11-1-39 H Et Me Br Cl Br 194-196 11-1-40 H i-Pr Me Br Cl Br 185-187 11-1-41 H t-Bu Me Br Cl Br 215-221 11-1-42 H Me Me Cl CF3 199-200 11-1-43 H Et Me Cl CF3 199-200 11-1-44 H i-Pr Me Cl CF3 188-189 11-1-45 H t-Bu Me Cl CF3 242-243 11-1 -46 H Me Me Cl Cl 233-234 11-1-47 H Et Me Cl Cl 196-197 11-1-48 H i-Pr Me Cl Cl 189-190 11-1-49 H t-Bu Cl Cl Cl 228-229 11-1-50 H Me Me Cl Br 229-230 11-1-51 H i-Pr Me Cl Br 191-192 11-1-52 H Me Br Br Cl CF3 162-163 11-1-53 H Et Br Br Cl CF3 188-189 Example R7 pf (° C) No. -1 -54 H i-Pr Br Br Cl CF3 192-193 -1-55 H t-Bu Br Br Cl Cl3 246-247 -1-56 H Me Br Br Cl Cl 188-190 -1-57 H Et Br Br Cl Cl 192-194 -1-58 H - -Pr Br Br Cl Cl 197-199 -1-59 H t -Bu Br Br Cl Cl 210-212 -1-60 H Br Br Cl Cl 166-168 -1-61 H Et Br Br Cl Br 196-197 -1-62 H i-Pr Br Br Cl Cl 162-163 -1-63 H t-Bu Br Br Cl Br 194-196 -1-64 H t-Bu Cl Br Cl CF3 143-145 • 1-65 Me Me Br Br Cl Cl 153-155 • 1-66 Me Me Me Br Cl CF3 207-208 -1-67 Me Me Cl Cl Cl Cl 231-232 -1-68 Me Me Br Br Cl Br 189-190 -1-69 Me Me Cl Cl Cl Br 216-218 -1-70 Me Cl Cl Cl CF 225-227 1-71 Me Me Br Br Cl CF 228-229 • 1-72 H i-Pr Me H Cl CF 3 237-239 and also an active compound of the formula (I) (group 1) or of group 2 selected from the compounds (2-1) to (2-7). Especially preferred are combinations of active compounds comprising a compound of the (6-l-T (2-l-TJ) (l-l-JÚ (e-t-p) fe-i-p) (I-I-?) sexnuij j s? ^ u? tnßts (n -? - 7i) (H-l-72) and also an active compound of the formula (I) (group 1) or of the group 2 selected from the compounds (2-l) to (2-7). Emphasis is given to the combinations of active compounds comprising the compound of the formula (II-1-9) and the established active compound of the formula (I) (group 1) or of the group 2: a) Combinations of active compounds which comprise (II- 1-9) and (Ia-4). b) Combinations of active compounds comprising (II- 1-9) and (2-2) buprofezin. c) Combinations of active compounds comprising (II- 1-9) and (2-6) flonicamid. d) Combinations of active compounds comprising (II- 1-9) and (2-7) pyrimicarb. Emphasis is given to the following combinations of specifically established active compounds (mixtures of 2 components) comprising a compound of the formula (I) and a compound of the formula (II-1) or of the group 2: Compound combination Compound combination No. assets that comprises active No. that includes 16c) (2-6) flonicamid and (11-1-21) 43c) (2-6) flonicamid y (11-1-61) 16d) (2-7) pirimicarb and (11-1 -21) 43d) (2-7) pirimicarb and (11-1-61) 17a) (l-a-4) and (11-1-22) 44a) (l-a-4) and (11-1-62) 17b) (2-2) buprofezin and (11-1-22) 44b) (2-2) buprofezin and (11-1-62) 17c) (2-6) flonicamid and (11-1-22) 44c) (2-6) flonicamid y (11-1-62) 17d) (2-7) pirimicarb and (11-1-22) 44d) (2-7) pirimicarb y (11-1-62) 18a) (l-a-4) and (11-1-23) 45a) (l-a-4) and (11-1-64) 18b) (2-2) buprofezin and (11-1-23) 45b) (2-2) buprofezin and (11-1-64) 18c) (2-6) flonicamid and (11-1-23) 45c) (2-6) flonicamid y (11-1-64) 18d) (2-7) pirimicarb and (11-1-23) 45d) (2-7) pirimicarb y (11-1-64) 19a) (l-a-4) and (I-24) 46a) (l-a-4) and (11-1-65) 19b) (2-2) buprofezin and (11-1-24) 46b) (2-2) buprofezin and (11-1-65) 19c (2-6) flonicamid and (11-1-24) 46c) (2-6) flonicamid y (11-1 -65) 19d) (2-7) pirimicarb and (11-1-24) 46d) (2-7) pirimicarb y (11-1-65) 20a) (l-a-4) and (11-1-26) 47a) (l-a-4) and (11-1-66) 20b) (2-2) buprofezin and (11-1-26) 47b) (2-2) buprofezin and (11-1-66) 20c) (2-6) flonicamid and (11-1 -26) 47c) (2-6) flonicamid y (11-1 -66) 20d) (2-7) pirimicarb and (11-1-26) 47d) (2-7) pirimicarb y (11-1-66) 21a) (l-a-4) and (11-1-27) 48a) (l-a-4) and (11-1 -67) 21b) (2-2) buprofezin and (11-1-27) 48b) (2-2) buprofezin and (11-1-67) 21c) (2-6) flonicamid and (11-1-27) 48c) (2-6) flonicamid y (11-1-67) 21 d) (2-7) pirimicarb and (11-1-27) 48d) (2-7) pirimicarb y (11-1-67) 22a) (l-a-4) and (11-1-29) 49a) (l-a-4) and (11-1-68) Compound combination Compound combination No. assets that comprises active No. that includes 22b) I (2-2) buprofezin and (11-1-29) 49b) (2-2) buprofezin and (11-1-68) 22c) (2-6) flonicamid and (11-1 -29) 49c) (2-6) flonicamid and (11-1-68) 22d) (2-7) pirimicarb and (11-1-29) 49d) (2-7) pirimicarb and (11-1-68) 23a) (l-a-4) and (11-1-30) 50a) (l-a-4) and (11-1 -69) 23b) (2-2) buprofezin and (11-1 -30) 50b) (2-2) buprofezin and (11-1-69) 23c) (2-6) flonicamid and (11-1 -30) 50c) (2-6) flonlcamid and (11-1-69) 23d) (2-7) pirimicarb and (11-1 -30) 50d) (2-7) pirimicarb and (11-1-69) 24a) (la-4) and (11-1-31) 51a) ( la-4) and (11-1-70) 24b) (2-2) buprofezin and (11-1 -31) 51b) (2-2) buprofezin and (li-1 -70) 24c) (2-6) flonicamid and (11-1 -31) 51c) (2-6) flonicamid y (11-1-70) 24d) (2-7) pirimicarb and (11-1-31) 51 d) (2-7) pirimicarb y (11-1-70) 25a) (la-4) and (11-1 -32) 52a) (la-4) and (11-1 -71) 25b) (2-2) buprofezin and (11-1-32) 52b) (2 -2) buprofezin and (11-1-71) 25c) (2-6) flonicamid and (11-1 -32) 52c) (2-6) flonicamid y (11-1-71) 25d) (2-7) pirimicarb and (11-1-32) 52d) (2-7) pirimicarb and (11-1-71) 26a) (l-a-4) and (11-1-33) 53a) (l-a-4) and (11-1-72) 26b) (2-2) buprofezin and (11-1 -33) 53b) (2-2) buprofezin and (11-1 -72) 26c) (2-6) flonicamid and (11-1 -33) 53c) (2-6) flonicamid and (11-1-72) 26d) (2-7) pirimicarb and (11-1-33) 53d) (2-7) pirimicarb y (11-1 -72) 27a) (la-4) and (11-1-38) 27b) (2-2) buprofezin and (11-1 -38) 27c) (2-6) flonicamid and (11-1 -38) 27d) ( 2-7) pirimicarb and (11-1 -38) However, the general or preferred definitions or illustrations of the radicals given above can also be combined with each other as desired, i.e. including combinations between the respective ranges and the preferred ranges. These apply both to the final products and, correspondingly, to the precursors and intermediate products. According to the invention, preference is given to combinations of active compounds comprising the compounds of the formula (I) or a compound of the group 2 and also at least one compound of the formula (II) wherein the individual radicals are a combination of the meanings given above as preferred (preferable). According to the invention, particular preference is given to combinations of active compounds comprising the compounds of the formula (I) or a compound of the group 2 and also at least one compound of the formula (II) wherein the individual radicals are a combination of the meanings given above as particularly preferred. According to the invention, particular preference is given to combinations of active compounds comprising the compounds of the formula (I) or a compound of the group 2 and also at least one compound of the formula (II) wherein the individual radicals are a combination of the meanings given above as very particularly preferred. The saturated or unsaturated hydrocarbon radicals, such as alkyl or alkenyl, can in each case be straight or branched chain as far as possible, even in combination with heteroatoms, such as, for example, in alkoxy. The optionally substituted radicals can be mono- or polysubstituted, where in the case of the polysubstitution, the substituents can be identical or different. In addition, combinations of active compounds can also additionally comprise active co-components from the fungicidal, acaricidal or insecticidal point of view. If the active compounds in the combinations of active compounds according to the invention are present in certain weight ratios, the synergistic effect is particularly pronounced. The mixing ratios required to find the synergism are not necessarily the preferred mixing ratios that are relevant for 100% activity. However, the weight ratios of the active compounds in the combinations of active compounds can be varied within a relatively wide range. In general, the combinations according to the invention comprise active compounds of the formula (I) or a compound of group 2 and the mixing partner of the formula (II) in preferred and particularly preferred mixing ratios, stated: Mixed are based on weight ratios. The relation should be understood as meaning the active compound of the formula (I): mixing partner Mixing partner Mixing ratio Preferred mixing ratio Particularly preferred (la-4) 10: 1 to 1:10 5: 1 to 1: 5 Amitraz 5: 1 to 1: 20 1: 1 to 1:10 Buprofezin 10: 1 at 1: 10 5: 1 at 1: 5 Pymetrozine 10: 1 at 1: 10 5: 1 at 1: 5 Pyriproxyfen 10: 1 at 1: 10 5: 1 at 1: 5 Triazamate 10: 1 at 1: 10 5 : 1 to 1: 5 Flonicamid 10: 1 to 1: 10 5: 1 to 1: 5 Pirimicarb 10: 1 to 1: 10 5: 1 to 1: 5 Combinations of preferred compounds of the invention are suitable for controlling pests of animals, preferably arthropods and nematodes, in particular insects and arachnids, found in agriculture, in animal health, in forests, in gardens and in recreational facilities. , in the protection of stored products and materials and in the hygiene sector, while exhibiting good tolerability for plants, low toxicity for warm-blooded species and good environmental compatibility. These are active against normally sensitive and resistant species and against the stages of total or individual development. The pests mentioned above include: From the order of Isopoda, for example, Oniscus asellus, Armadillidium vulgare, Porcellio scaber. From the order of Diplopoda, for example, Blaniulus guttulatus. From the order of Chilopoda, for example, Geophilus carpophagus, Scutigera spp. From the order of Symphyla, for example, Scutigerella immaculata. From the order of Thysanura, for example, Lepisma saccharina. From the order of Collembola, for example, Onychiurus armatus. From the order of Orthoptera, for example, Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp. , Schistocerca gregaria. From the order of Blattaria, for example, Blatta orientals, Periplaneta americana, Leucophaea maderae, Germanic Blattella. From the order of Dermaptera, for example, Forfícula auricularia. From the order of Isoptera, for example, Reticulitermes spp. From the order of Phthiraptera, for example, Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp. On the order of Thysanoptera, for example, Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis. From the order of Heteroptera, for example, Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp. From the order of Homoptera, for example, Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp.

From the order of Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hypono euta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp. , Feltia spp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella , Hofmannophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanimous, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae. From the order of Coleoptera, for example, Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assiimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus. From the order of Hymenoptera, for example, Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp. From the order of Diptera, for example, Aedes spp. Anopheles spp. Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Typula paludosa, Hylemyia spp., Liriomyza spp. From the order of Siphonaptera, for example, Xenopsylla cheopis, Ceratophyllus spp. From the Arachnida class, for example, Scorpio maurus, Latrodectus mactans, Acarus siró, Argas spp., Omithodoros spp., Dermanyssus gallinae; Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp. , Hyalomma spp. , Ixodes spp. , Psoroptes spp. , Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp. Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.

Plant parasitic nematodes include, for example, Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp. ., Bursaphelenchus spp. The combinations of active compounds of the invention of the compounds of the formula (I) and at least one of the compounds 1 to 15 are particularly suitable for controlling the "chopping" pests. These include, in particular, the following pests: From the order of Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanimous, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae. From the order of Coleoptera, for example, Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus. The combinations of active compounds of the invention of the compounds of the formula (I) and at least one of the compounds 5 to 8 are additionally suitable in particular for controlling "sucking" pests. These include, in particular, the following pests: From the order of Homoptera, for example, Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix , Pemphigus spp., Macrosiphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp. The combinations of active compounds of the invention have, in particular, excellent activity against caterpillars, larvae of beetles, red mites, aphids and leaf-boring flies. The combinations of active compounds of the invention can be converted into customary formulations such as solutions, emulsions, wettable powders, suspensions, powders, very fine powders, pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic materials impregnated with an active compound and microencapsulations in polymeric materials. These formulations are produced in a known manner, for example by mixing the active compounds with extenders, ie liquid solvents and / or solid carriers, optionally with the use of surfactants, ie emulsifiers and / or dispersants and / or foam formers. If the extender used is water, it is also possible, for example, to use organic solvents as co-solvents. The following are essentially suitable as liquid solvents: aromatic solvents such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic solvents or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, for example fractions of mineral oil, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl- ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide or else water. Suitable solid carriers are: for example, amino salts and natural, ground minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic, milled materials such as silica, alumina and finely divided silicates; solid carriers, suitable for granules are: for example crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite and dolomite or also synthetic granules of inorganic and organic flours and granules of organic materials such as sawdust, coconut husks, cobs of corn and tobacco stalks; suitable emulsifiers and / or foam formers are, for example, nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example, alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl -sulfonates or also protein hydrolysates; Suitable dispersants are: for example lignin-sulfite waste liquors and methylcellulose. In the formulations tackifiers such as carboxymethylcellulose and natural and synthetic polymers can be used in the form of powders, granules or latexes, such as gum arabic, polyvinyl alcohol and polyvinyl acetate or else natural phospholipids such as cephalides, lecithins and phospholipids. synthetic Other additives can be mineral and vegetable oils. It is possible to use dyes such as inorganic pigments, for example iron oxide, titanium oxide and Prussian blue and organic dyes such as alizarin dyes, azo dyes and metal phthalocyanine dyes and micronutrients such as iron, manganese salts, boron, copper, cobalt, molybdenum and zinc. The formulations generally comprise between 0.1 and 95% by weight of an active compound, preferably between 0.5 and 90%. The combinations of active compounds of the invention may be present in their commercially available formulations and in the forms of use, prepared from these formulations as a mixture with other active compounds, such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides. , fungicides, growth regulating substances or herbicides. Insecticides include, for example, phosphates, carbamates, carboxylates, chlorinated hydrocarbons, phenylureas and substances produced by microorganisms, inter alia. Mixtures with other known active compounds such as herbicides or with fertilizers and growth regulators are also possible. When used as insecticides, the combinations of active compounds of the invention may also be present in their commercially available formulations and in the forms of use, prepared from these formulations, as a mixture with synergists. The synergists are compounds that increase the action of the active compounds, without it being necessary for the added synergist to be active by itself. The active compound content of the use forms prepared from the commercially available formulations can vary within wide limits. The active compound concentration of the use forms can be from 0.0000001 to 95% by weight of the active compound, preferably between 0.0001 and 1% by weight. The compounds are used in a usual manner, which is appropriate for the forms of use. When used against hygiene pests and stored product pests, combinations of active compounds are distinguished by an excellent residual action on wood and clay as well as good alkali stability on limestone substrates. The combinations of active compounds of the invention are not only active against plant pests, hygiene pests and pests of stored products, but also in the field of veterinary medicine against animal parasites (ectoparasites) such as hard ticks, soft ticks , scabies mites, harvest mites, flies (choppers and lickers), fly larvae infestation parasites, lice, head lice, bird lice and fleas. These parasites include: From the order of Anoplurida, for example, Haematopinus spp., linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp. From the order of Mallophagida and the suborders Amblycerina and Ischnocerina, for example, Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp. From the order of Diptera and the suborders Nematocerina and Brachycerina, for example, Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybo itra spp. , Atylotus spp. , Tabanus spp. , Haematopota spp. , Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia. spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp. , Melophagus spp. From the order of Siphonapterida, for example, Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp. From the order of Heteropterida, for example, Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp. From the order of Blattarida, for example, Blatta orientalis, Periplaneta americana, Blattella germanica, Supella spp. From the subclass of Acaria (Acarida) and the orders of Meta- and Mesostigmata, for example, Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp. ., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp. From the order of Actinedida (Prostigmata) and Acaridida (Astigmata), for example, Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp. ., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp. The combinations of active compounds of the invention are also suitable for controlling arthropods which attack agricultural livestock such as, for example, cattle, sheep, goats, horses, pigs, donkeys, camels, buffaloes, rabbits, chickens, turkeys, ducks. , geese, bees, other domestic animals such as, for example, dogs, cats, caged birds, aquarium fish and animals commonly called experimental animals such as, for example, hamsters, guinea pigs, rats and mice. By controlling these arthropods, the cases of deaths and reductions in productivity (for meat, milk, wool, skins, eggs, honey and the like) should be reduced, so that a cheaper and simpler animal breeding is possible. means of using the combinations of active compounds of the invention. The combinations of active compounds of the invention are used in the veterinary field in a known manner by means of enteral administration in the form of, for example, tablets, capsules, potions, purgative doses, granules, pastes, boluses, the method through of food, suppositories, by means of parenteral administration such as, for example, by means of injections (by the intramuscular, subcutaneous, intravenous, intraperitoneal route and the like), implants, by means of nasal administration, by means of administration dermal in the form of, for example, dipping or soaking, spraying, shedding, swabbing, washing, dusting and with the aid of molded articles comprising the active compounds such as collars, ear tags, tail tags, bands for limbs, collars, marker devices and the like. When used for cattle, poultry, pets and the like, combinations of active compounds can be applied as formulations (eg powders, emulsions, fluid products) comprising the active products in an amount of 1 to 80% in weigh, either directly or after a dilution of 100 to 10,000 times or can be used as a chemical dressing. In addition, it has been discovered that the combinations of active compounds of the invention show a potent insecticidal action against insects that destroy industrial materials. The following insects may be mentioned by way of example and preferably, but not by way of limitation: Beetles such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec., Tryptodendron spec., Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec., Dinoderus minutus. Dermapteros such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur. Termites such as Kalotermes flavicollis, Cryptoter is brevis, Heterotermes indicala, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus. Silverfish such as Lepisma saccharina. It is understood that industrial materials in the present context mean non-living materials such as, preferably, polymers, adhesives, glues, paper and board, leather, wool, wood products for construction and paints. The material that must be protected from the attack of insects are particularly preferably wood and wood products for construction. It should be understood that wood and construction wood products that can be protected by the composition of the invention, or mixtures that comprise it, mean, for example: Construction wood, wooden joists, railway sleepers, components for bridges, springs , vehicles made of wood, boxes, pallets, containers, telephone poles, wood cladding, windows and doors made of wood, plywood, ordinary cardboard, joinery or wood products for construction which are generally used in the construction of houses or in the building cabinetmaking. The combinations of active compounds can be used as such, in the form of concentrates or generally as usual formulations such as powders, granules, solutions, suspensions, emulsions or pastes. The aforementioned formulations can be prepared in a manner known per se, for example by mixing the active compounds with at least one solvent or diluent, emulsifier, dispersant and / or binder or fixative, water repellent, if desired desiccants and stabilizers are desired. Ultraviolet light and if you want dye and pigments and other processing aids. The insecticidal compositions or concentrates that are used to protect wood and wood products for construction comprise the active compound of the invention in a concentration of 0. 0001 to 95% by weight, in particular 0.001 to 60% by weight. The amount of composition or concentrate used depends on the species and the abundance of the insects and the environment. The optimal quantity to be used can be determined in each case by series of tests with the application. In general, however, it will be sufficient to employ 0.0001 to 20% by weight, preferably 0.001 to 10% by weight, of the active compound, based on the material that is protected. A suitable solvent and / or diluent is an organochemical solvent or a mixture of solvents and / or an oily or oil-like organochemical solvent or mixtures of low volatility solvents and / or a polar organochemical solvent or a mixture of solvents and / or water and, if appropriate, an emulsifier and / or wetting agent. The organochemical solvents which are preferably used are oily or oil-type solvents with an evaporation number greater than 35 and an instantaneous flash point greater than 30 ° C, preferably higher than 45 ° C. These oily or oil-type solvents which are insoluble in water and of low volatility and which are used are suitable mineral oils or their aromatic fractions or solvent mixtures containing mineral oils, preferably white alcohol, petroleum and / or alkylbenzene. Mineral oils with a boiling range of 170 to 220 ° C, white alcohol with a boiling range of 170 to 220 ° C, very fine lubricant with a boiling range of 250 to 350 ° C, petroleum and aromatic products with a boiling range of 160 to 280 ° C, the turpentine essence and the like are advantageously used. In a preferred embodiment, aliphatic hydrocarbons, liquids with a boiling range of 180 to 210 ° C or mixtures with high boiling point of aromatic and aliphatic hydrocarbons with a boiling point range of 180 to 220 ° C are used and / or very fine lubricant and / or monochloronaphthalene, preferably -monocloronaphthalene. Organic, oily or oil-type solvents of low volatility and with an evaporation index greater than 35 and an instantaneous flash point greater than 30 ° C, preferably higher than 45 ° C, can be replaced in part by volatility organochemical solvents high or intermediate, provided that the solvent mixture also has an evaporation index above 35 and an instant flash point above 30 ° C, preferably above 45 ° C, and that the mixture is soluble or emulsifiable in this mixture of solvents. In a preferred embodiment, some of the organochemical solvent or mixture of solvents or an organochemical, polar, aliphatic solvent or solvent mixture is replaced. The organochemical, aliphatic solvents containing hydroxyl and / or ester and / or ether groups are preferably used such as, for example, ethers, glycol esters and the like. The organochemical binding substances which are used for the purposes of the present invention are the synthetic resins and / or the agglutination drying oils which are known per se and which can be diluted in water and / or can be dissolved or dispersed or emulsified in the organochemical solvents used, in particular binder substances composed of, or comprising, an acrylate resin, a vinyl resin, for example polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenol resin, hydrocarbon resin such as indene / coumarone resin, silicone resin, vegetable oils, drying and / or drying agents and / or physically drying binder substances based on a natural and / or synthetic resin. The synthetic resin used as binder can be used in the form of an emulsion, dispersion or solution. Biturnen or bituminous substances can also be used as binders, in amounts of up to 10% by weight. In addition, colorants, pigments, water repellents, odor masking agents and inhibitors or anti-corrosive agents and the like, all of which are known per se, can be used. According to the invention, the composition or concentrate preferably comprises, as organochemical binder substances, at least one alkyd resin or modified alkyd resin and / or a drying vegetable oil. The alkyd resins which are preferably used according to the invention are those with an oil content greater than 45% by weight, preferably 50 to 68% by weight. Some or all of the binder substance mentioned above can be replaced by a fixative (mixture) or plasticizer (mixture). These additives are proposed to prevent the volatilization of the active compounds and also the crystallization or precipitation. These preferably replace 0.01 to 30% of the binder (based on 100% of the binder used). The plasticizers are from the chemical classes of the phthalic esters, such as dibutyl phthalate, dioctyl phthalate or benzyl butyl phthalate, phosphoric esters such as tributyl phosphate, adipic esters such as di (2-ethylhexyl) adipate, stearates such as butyl stearate or amyl stearate, oleates such as butyl oleate, glycerol ethers or higher molecular weight glycol ethers, glycerol esters and p-toluenesulfonic esters. The fixatives are chemically based on polyvinyl-alkyl ethers such as, for example, polyvinyl methyl ether or ketones such as benzophenone and ethylenebenzophenone. Other suitable solvents or diluents are, in particular, water, if appropriate as a mixture with one or more of the solvents or diluents, emulsifiers and organochemical dispersants mentioned above. The particularly effective protection of wood for construction is achieved through impregnation processes at industrial scale, for example vacuum, double vacuum or pressure processes. The combinations of active compounds of the invention can be used at the same time to protect objects that come into contact with salt water or brackish water, such as ship hulls, screens, nets, buildings, moorings and signaling systems, against biofouling. Biofouling by sessile Oligochaeta, such as Serpulidae and by shellfish and species of the group Ledamorpha (rose hips), such as the species Lepas and Scalpellum or by species of the Balanomorpha group (sea acorn), such as the species Balanus and Pollicipes, increase the frictional drag of the boats and, as a consequence, lead to a marked increase in Operating costs due to higher energy consumption and additionally frequent arrests in the launching dam. In addition to biofouling by algae, for example Ectocarpus sp. and Ceramium sp, the sessile biofouling of the Entomostraka groups, which come under the generic name Cirripedia (cirriped crustacean), is of particular importance. Surprisingly, it has now been discovered that the combinations of active compounds of the invention have a remarkable antibioincrustation action. The use of the active compound combinations of the invention allows the use of heavy metals such as, for example, in bis (trialkyltin) sulphides, tri-n-tributyltin laurate, tri-n-butyltin chloride, copper oxide (I), triethyltin chloride, tri-n-butyl (2-phenyl-4-chlorophenoxy) tin, tributyltin oxide, molybdenum disulfide, antimony oxide, polymeric butyl titanate, phenyl (bispyridine) bismuth chloride, fluoride of tri-n-butyltin, manganese ethylenebistiocarbamate, zinc dimethyldithiocarbamate, zinc ethylenebistiocarbamate, zinc salts and copper salts of 2-pyridinium-1-oxide, bisdimethyldithiocarbamoylzinc ethylenebicyclocarbamate, zinc oxide, copper ethylenebisdithiocarbamate (I), copper thiocyanate, copper naphthenate and tributyltin halides to be supplied with, or the concentration of these compounds to be substantially reduced. If appropriate, the easy-to-use antibioincrustation paints may additionally comprise other active compounds, preferably algicides, fungicides, herbicides, molluscicides and other antibioincrustation active compounds. Suitable components, preferably in combination with the antibioincrustation compositions according to the invention, are: algicides such as 2-erc-butylamino-4-cyclopropylamino-6-methylthio-1,3,5-triazine, dichlorophen, diuron, endotal, acetate of fentin, isoproturon, metabenzthiazuron, oxyfluorfen, quinoclamine and terbutrin; fungicides such as S, S-benzo [b] thiophenecarboxylic acid chlorohexyl amide, diclofluanide, fluorfolpet, 3-iodo-2-propynyl-butylcarbamate, tolylfluanid and azoles such as azaconazole, ciproconazole, epoxiconazole, hexaconazole, metconazole, propiconazole and tebuconazole; molluscicides such as fentin acetate, metaldehyde, methiocarb, niclosamid, thiodicarb and trimethacarb; or conventional antibioincrustation active compounds such as 4,5-dichloro-2-octyl-4-isothiazolin-3-one, diiodomethylparatritylsulphone, 2- (N, N-dimethylthiocarbamoylthio) -5-nitrothiacyl, potassium, copper, sodium salts and zinc of 2-pyridinium oxide, pyridine / triphenylborane tetrabutyldistanoxane, 2,3,5,6-tetrachloro-4- (methylsulfonyl) -pyridine, 2,4,5,6-tetrachloroisophthalonitrile, tetramethylthiuram disulfide and 2,4, 6-trichlorophenylmaleimide. The antibioincrustation compositions used comprise the combinations of active compounds of the invention in a concentration of 0.001 to 50% by weight, in particular 0.01 to 20% by weight. In addition, the antibioincrustation compositions of the invention comprise the usual components such as, for example, those described in Ungerer, Chem. Ind. 1985, 37, 730-732 and Williams, 7? Ntifling Marine Coatings, Noyes, Park Ridge, 1973. In addition to the active ingredients algaecides, fungicides, molluscicides and the insecticidal active compounds of the invention, the antibioincrustation paints comprise, in particular, binding substances. Examples of recognized binder substances are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, acrylic resins in a solvent system, in particular in an aqueous system, vinyl chloride / vinyl acetate copolymer systems in the form of aqueous dispersions or in the form of organic solvent systems, butadiene / styrene / acrylonitrile rubbers, drying oils such as linseed oil, resin esters or hardened resins, modified in combination with pitch bitumen, asphalt and epoxy, small amounts of chlorine rubber, chlorinated polypropylene and vinyl resins. If appropriate, the paints also comprise inorganic pigments, organic pigments or dyes which are preferably insoluble in salt water. The paints may further comprise materials such as rosin to allow controlled release of the active compounds. In addition, the paints may comprise plasticizers, modifiers which affect the rheological properties and other conventional constituents. The compounds of the invention or the aforementioned mixtures can also be incorporated in self-polishing anti-fouling systems. Combinations of active compounds are also suitable for controlling pests of animals, in particular insects, arachnids and mites, which are in closed spaces such as, for example, rooms, halls of factories, offices, cabins of vehicles and the like. These can be used in insecticide, domestic products to control these pests. These are active against sensitive and resistant species and against all stages of development. These pests include: From the order of Scorpionidea, for example, Buthus occitanus. From the order of Acariña, for example, Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae. From the order of Araneae, for example, Aviculariidae, Arañeidae. From the order of Opiliones, for example, Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium. From the order of Isopoda, for example, Oniscus asellus, Porcellio scaber. From the order of Diplopoda, for example, Blaniulus guttulatus, Polydesmus spp. From the order of Chilopoda, for example, Geophilus spp. From the order of Zygentoma, for example, Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus. From the order of Blattaria, for example, Blatta orientalis, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa. From the order of Saltatoria, for example, Acheta domesticus. From the order of Dermaptera, for example, Forfícula auricularia. From the order of Isoptera, for example, Kalotermes spp., Reticulitermes spp. From the order of Psocoptera, for example, Lepinatus spp., Liposcelis spp. From the order of Coleptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum. From the order of Diptera, for example, Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carniaria, Simulium spp., Stomoxys calcitrans, Typula paludosa. From the order of Lepidoptera, for example, Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.

From the order of Siphonaptera, for example, Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis. From the order of Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum. From the order of Anoplura, for example, Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis. From the order of Heteroptera, for example, Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans. These are used as sprays, pressureless spray products, for example pump and atomizer sprays, automatic fogging systems, foggers, foams, gels, evaporator products with evaporating tablets made of cellulose or polymer, liquid evaporators, gel evaporators. and membrane, evaporators driven by propellants, energy-free or passive evaporation systems, paper for moths, bags for moths and gels for moths, such as granules or powders, in baits for recreation or in baiting stations. According to the invention, it is possible to treat all the plants and parts of the plants. It should be understood here that plants mean all plants and plant populations such as desired and unwanted wild plants or crop plants (including crop plants of natural origin). The crop plants can be plants which can be obtained by means of conventional cultivation and optimization methods or by means of biotechnological and genetic engineering methods or combinations of these methods, including transgenic plants and even plant cultivars that can be protected or not by certificates of technicians. It should be understood that plant parts mean all parts and organs of plants above ground and underground, such as buds, foliage, flowers and roots, examples that may be mentioned are leaves, spikes, stems, trunks, flowers, carpophores, fruits and seeds and also roots, tubers and rhizomes. Parts of plants also include harvested plants and vegetative and generative propagating material, for example seedlings, tubers, rhizomes, barns and seeds. The treatment of the invention of the plants and parts of the plants with the active compounds is carried out directly or by action on their environment, habitat or storage area according to usual treatment methods, for example by means of immersion , spraying, evaporation, atomization, diffusion, brush application and, in the case of the propagation material, in particular in the case of the seeds, additionally by the cng of one or multiple layers. As already mentioned above, it is possible to treat all the plants and their parts according to the invention. In a preferred embodiment, wild plant and plant cultivar species, or those obtained by conventional biological culture methods, such as cross fusion or protoplast fusion and parts thereof, are treated. In a further preferred embodiment, the transgenic plants and cultivars of plants obtained by genetic engineering are treated, if appropriate in combination with conventional methods.

(Genetically Modified Organisms) and parts thereof. The terms "parts", "parts of plants" and "parts of plants" have been explained above. Particularly preferably, the plants of the plant cultivars that are commercially available in each case or are in use are treated according to the invention. Depending on the plant species or plant cultivars, their location and growth conditions (soils, climate, vegetation period, diet), the treatment of the invention can also result in superadditive ("synergistic") effects. In this way, for example, reduced application rates and / or an expansion of the activity spectrum and / or an increase in the activity of the substances and compositions that can be used according to the invention are possible, a better growth of the plants, increased tolerance to high or low temperatures, increased tolerance to follow-up or to water or soil salt content, increased flowering performance, easier harvesting, accelerated maturation, higher harvest yields, better quality and / or a higher nutritional value of the products harvested, better stability in storage and / or processability of the products harvested, which exceeds the effects that were actually expected. Transgenic plants or plant cultivars (ie those obtained by means of genetic engineering) that are preferred and should be treated according to the invention include all plants that, in genetic modification, received genetic material that provides useful characteristics in particular advantageous to those plants. Examples of these characteristics are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or water or soil salt content, increased flowering performance, easier harvesting, accelerated maturation, higher harvesting yields, better quality and / or higher nutritional value of the products harvested, better storage stability and / or processability of the harvested products. Particularly emphasized and additional examples of these characteristics are a better defense of plants against animal pests and microbial pests, such as against insects, mites, fungi, phytopathogens, bacteria and / or viruses and also an increased tolerance of plants towards certain active compounds from the herbicide point of view. Examples of transgenic plants that may be mentioned are important crop plants, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, tobacco, rapeseed oilseeds and also fruit plants (with fruits that are apples, pears, citrus fruits and grapes) and particular emphasis is given to corn, soybeans, potatoes, cotton, tobacco and oilseed rape. The features that are particularly emphasized are the increased defense of the plants against insects, arachnids, nematodes and worms by toxins formed in the plants, in particular those formed in the plants by the genetic material of Bacillus thuringiensis (for example by the Cry? A (a), Cry? A (b), Cry? A (c), CrylIA, CrylIIA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CrylF and also combinations thereof) (hereinafter referred to as "Bt plants") ). The characteristics that are also emphasized in particular are the increased defense of plants against fungi, bacteria and viruses by means of acquired, systemic resistance (SAR), systemin, phytoalexins, elicitors and also resistance and protein genes. and toxins expressed accordingly. The features that are particularly emphasized are also the increased tolerance of the plants to certain active compounds from the herbicidal point of view., for example imidazolinones, sulfonylureas, glyphosate or phosphinothricin (for example the "PAT" gene). The genes in question that provide the desired characteristics may also be present in combination with another in the transgenic plants. Examples of "Bt plants" that may be mentioned are maize varieties, cotton varieties, soybean varieties and potato varieties that are sold under the trademarks YIELD GA O * 01 (eg corn, cotton, seeds). soybean), KnockOut * 111 (for example corn), StarLink ™ 1 (for example corn), Bollgard1111 (cotton), Nucotn ™ (cotton) and Ne Leaf1 ^ (potato). Examples of herbicide tolerant plants that can be mentioned are maize varieties, cotton varieties and varieties of soybeans that are sold under the trade names Roundup Ready ™ (tolerance to glyphosate, eg corn, cotton, soybeans) , Liberty Link101 (tolerance to phosphinothricin, for example oilseed rape), IMI ™ (imidazolinone tolerance) and STS1111 (tolerance to sulfonylureas, for example corn). Plants with resistance to herbicides (plants conventionally grown for herbicide tolerance) that may be mentioned include varieties sold under the name Clearfield ™ (for example corn). Of course, these statements also apply to cultivars of plants that have these genetic characteristics or genetic characteristics yet to be developed, plants that will be developed and / or marketed in the future. The listed plants can be treated according to the invention in a particularly advantageous manner with the mixtures of active compounds of the invention. The preferred ranges that were previously established for the mixtures also apply to the treatment of those plants. Particular emphasis is given to the treatment of plants with the mixtures specifically mentioned in the present text. The good insecticidal and acaricidal action of the combinations of active compounds of the invention can be observed from the following examples. While the individual active compounds show weakness in their action, the combinations show an action that exceeds a simple sum of actions.

A synergistic effect in insecticides and acaricides is always present when the action of the combinations of active compounds exceeds the total actions of the active compounds when applied individually. The expected action for a given combination of two active compounds can be calculated as follows, using the "Colby formula" (see SR Colby "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 1967, 15, 20-22): Yes X is the elimination proportion, expressed as a percentage of the untreated control, when the active compound A is used at an application rate of mg / ha or at a concentration of m ppm, and is the elimination ratio, expressed as a percentage of the untreated control, when the active compound B is used at an application rate ng / ha or at a concentration of n ppm and E is the elimination rate, expressed as a percentage of the untreated control, when the compounds are used active A and B at application rates of m or n / ha or at a concentration of m and ppm, then XY E = X + Y - 100 If the actual insecticide removal rate exceeds the calculated value , the action of the combination is superadditive, meaning that a synergistic effect is present. In this case, the observed elimination rate must actually exceed the value calculated using the formula above for the expected elimination rate (E).

Examples of use Example A Test of Aphis gossypii Solvent: 7 parts by weight of dimethylformamide Emulsifier: 2 parts by weight of alkylaryl-polyglycol ether To produce a suitable preparation of the active compound, 1 part by weight of the active compound is mixed with the established amounts of solvent and emulsifier and the concentrate is diluted with water containing emulsifier to the desired concentration. The cotton leaves (Gossypium hirsutum) which are excessively infested by the cotton aphid (Aphis Gossypii) are treated by being submerged in the preparation of the active compound at the desired concentration. After the desired period of time, the% elimination is determined. 100% means that all aphids have been eliminated; 0% means that none of the aphids has been eliminated. The determined elimination ratios are introduced in the Colby formula (see page 41). In this test, for example, the following combination of active compounds according to the present application shows a synergistically enhanced activity compared to the independently applied active compounds: Table Al: Insects harmful to plants Test of Aphis gossypii * found '= activity found ** calculated = activity calculated using Colby's formula Table A2: Insects harmful to plants Test of Aphis gossypii * found = activity found ** calculated = activity calculated using Colby's formula Example B Myzus persicae test Solvent: 7 parts by weight of dimethylformamide Emulsifier: 2 parts by weight of alkylaryl-polyglycol ether To produce a suitable preparation of the active compound, 1 part by weight of the active compound is mixed with the established amounts of solvent and emulsifier and the concentrate is diluted with water containing emulsifier to the. desired concentration. The leaves of cabbage (Brassica olerácea) which are excessively infested by the gray aphid of the peach (Myzus persicae) are treated by being submerged in the preparation of the active compound at the desired concentration. After the desired period of time, the% elimination is determined. 100% means that all aphids have been eliminated; 0% means that none of the aphids has been eliminated. The determined elimination ratios are introduced in the Colby formula (see page 41). In this test, for example, the following combination of active compounds according to the present application shows a synergistically enhanced activity compared to the independently applied active compounds: Table Bl: Insects harmful to plants Test of Myzus persicae * found activity found ** calculated activity calculated using the formula of Colby Table B2: Insects harmful to plants Test of Myzus persicae * found = activity found ** calculated = activity calculated using Colby's formula Example C Phaedon cochleariae larvae test Solvent: 7 parts by weight of dimethylformamide Emulsifier: 2 parts by weight of alkylaryl-polyglycol ether To produce an adequate preparation of the compound active, 1 part by weight of the active compound is mixed with the established amounts of solvent and emulsifier and the concentrate is diluted with water containing emulsifier to the desired concentration. Cabbage leaves (Brassica olerácea) are treated by being submerged in the preparation of the active compound at the desired concentration and are populated with watercress larvae (Phaedon cochleariae) while the leaves are still moist. After the desired period of time, the% elimination is determined. 100% means that all chrysomela larvae have been eliminated; 0% means that none of the chrysomela larvae has been eliminated. The determined elimination ratios are introduced in the Colby formula (see page 41). In this test, for example, the following combination of active compounds according to the present application shows a synergistically enhanced activity compared to the independently applied active compounds: Table Cl: Insects harmful to plants Phaedon sochleariae larvae test * found = activity found ** calculated = activity calculated using the formula of Colby Table C2: Insects harmful to plants Phaedon larvae test cochleariae * found = activity found ** calculated - activity calculated using Colby's formula Example D Plutella xylostella test (resistant strain) Solvent: 7 parts by weight of d -? ^ ethylformamide Emulsifier: 2 parts by weight of alkylaryl-polyglycol ether to produce a suitable preparation of the active compound, 1 part by weight of the active compound is mixed with the established amounts of solvent and emulsifier and the concentrate is diluted with water containing emulsifier to the desired concentration. The leaves of cabbage (Brassica olerácea) are treated by being submerged in the preparation of the active compound at the desired concentration and are populated with caterpillars of the diamondback moth (Plutella xylostella, resistant strain) while the leaves are still wet. After the desired period of time, the% elimination is determined. 100% means that all the caterpillars have been eliminated; 0% means that none of the caterpillars has been eliminated. The determined elimination ratios are introduced in the Colby formula (see page 41). In this test, for example, the following combination of active compounds according to the present application shows a synergistically enhanced activity compared to the independently applied active compounds: Table D: Insects that are harmful to plants. Plutella xylostella test (resistant strain) * found = activity found ** calculated = activity calculated using Colby's formula E use E Test of Spodoptera frugiperda Solvent: 7 parts by weight of dimethylformamide Emulsifier: 2 parts by weight of alkylaryl-polyglycol ether To produce a suitable preparation of the active compound, 1 part by weight of the active compound is mixed with the established amounts of solvent and emulsifier and the concentrate is diluted with water containing emulsifier to the desired concentration. The leaves of cabbage (Brassica olerácea) are treated by being submerged in the preparation of the active compound at the desired concentration and are populated with caterpillars of the armyworm (Spodoptera frugiperda) while the leaves are still wet. After the desired period of time, the% elimination is determined. 100% means that all caterpillars have been eliminated; 0% means that none of the caterpillars has been eliminated. The determined elimination ratios are introduced in the Colby formula (see page 41). In this test, for example, the following combination of active compounds according to the present application shows a synergistically enhanced activity compared to the independently applied active compounds: Table E: Insects harmful to plants Test Spodoptera frugiperda * found = activity found ** calculated = activity calculated using Colby's formula It is noted that in relation to this date, the best method known to the applicant to carry out the aforementioned invention, is that which is clear from the present description of the invention.

Claims

CLAIMS Having described the invention as above, the content of the following claims is claimed as property: 1. A composition, characterized in that it comprises a combination of synergistically effective active compounds of the compounds of the formula (I) (group 1) wherein X represents halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano, W1, Y and Z independently represent hydrogen, halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano, A3 represents hydrogen, in each case optionally substituted alkyl by halogen, alkoxyalkyl, optionally substituted cycloalkyl, saturated in which optionally at least one ring atom is replaced by a heteroatom, A4 represents hydrogen or alkyl, A3 and A4 together with the carbon atom to which they are attached further represent a substituted ring or unsubstituted, saturated or unsaturated which optionally contains at least one heteroatom, D represents hydrogen or a radical optionally substituted from the group consisting of alkyl, alkenyl, alkoxyalkyl, saturated cycloalkyl in which optionally one or more ring members are replaced by heteroatoms, A3 and D together with the atoms to which they are attached represent a cycle or unsaturated which is unsubstituted or substituted in the portion A3, D and optionally contains at least one heteroatom, G1 represents hydrogen (a) or represents one of the groups
E represents a metal ion or an ammonium ion, L1 represents oxygen or sulfur, M1 represents oxygen or sulfur, R20 represents in each case alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl optionally substituted by halogen or cycloalkyl optionally substituted by halogen, alkyl or alkoxy which can be interrupted by at least one heteroatom, in each case optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl, R21 represents in each case alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl optionally substituted by halogen or represents in each case cycloalkyl optionally substituted phenyl or benzyl, R22 represents alkyl optionally substituted by halogen or optionally substituted phenyl, R23 and R24 each independently represent alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio optionally substituted by halogen or represents In each case optionally substituted phenyl, benzyl, phenoxy or phenylthio and R25 and R2d independently represent hydrogen, in each case alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl optionally substituted by halogen, represent phenyl optionally substituted, represent optionally substituted benzyl or together with the nitrogen atom to which they are attached represent an optionally substituted ring which is optionally interrupted by oxygen or sulfur, or an insecticidally active compound (group 2), preferably (2-1) to itraz (known from DE-A 20 61 132) and / or (2-2) buprofezin (known from DE-A 28 24 126) and / or (2-3) triazamate (known from EP-A 0 213 718) and / or (2-4) pymetrozine (known from EP-A 0 314 615) and / or (2-5) pyriproxyfen (known from EP-A 0 128 648) and / or (2-6) flonicamid (known from EP-A 0 580 374) and / or (2-7) pirimicarb (known from GB 1 181 657) and at least one active compound from the group of anthranilamides of the formula (II). 2. The composition according to claim 1, characterized in that it comprises at least one compound of the formula (I) in which W1 represents hydrogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, chlorine , bromine or fluorine, X represents alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, haloalkyl of 1 to 4 carbon atoms, fluorine, chlorine or bromine, Y and Z independently represent hydrogen, alkyl from 1 to 4 carbon atoms, halogen, alkoxy of 1 to 4 carbon atoms or haloalkyl of 1 to 4 carbon atoms, A3 represents hydrogen or in each case alkyl of 1 to 6 carbon atoms or cycloalkyl of 3 to 8 carbon atoms optionally substituted by halogen, A4 represents hydrogen, methyl or ethyl, A3 and A4 together with the carbon atom to which they are attached further represent saturated cycloalkyl of 3 to 6 carbon atoms in which optionally a ring member is replaced by oxygen or sulfur and which is mono- or di-substituted optionally by alkyl of 1 to 4 carbon atoms, trifluoromethyl or alkoxy of 1 to 4 carbon atoms, D represents hydrogen, in each case alkyl of 1 to 6 carbon atoms, alkenyl of 3 to 4 carbon atoms or cycloalkyl of 3 to 6 carbon atoms optionally substituted by fluorine or chlorine, A3 and D together represent alkanediyl of 3 to 4 carbon atoms optionally substituted by methyl in which optionally a methylene group or is replaced by sulfur, G1 represents hydrogen (a) or represents one of the groups
R25 E (f) or L1 'R28 (g), in particular (a), (b), (c) or (g)
E represents a metal ion or an ammonium ion, L1 represents oxygen or sulfur, M1 represents oxygen or sulfur, R20 represents in each case alkyl of 1 to 10 carbon atoms, alkenyl of 2 to 10 carbon atoms, alkoxy- ( C1-C4) -alkyl of 1 to 4 carbon atoms, alkylthio- (C 1 -C 4) -alkyl of 1 to 4 carbon atoms optionally substituted by halogen or cycloalkyl of 3 to 6 carbon atoms optionally substituted by fluorine, chlorine, alkyl of 1 to 4 carbon atoms or alkoxy of 1 to 2 carbon atoms, represents phenyl optionally substituted by fluorine, chlorine, bromine, cyano, nitro, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms , trifluoromethyl or trifluoromethoxy, represents in each case pyridyl or thienyl optionally substituted by chlorine or methyl, R21 represents in each case alkyl of 1 to 10 carbon atoms, alkenyl of 2 to 10 carbon atoms, alkoxy- (C1-C4) - alkyl of 2 to 4 carbon atoms optionally substituted by fluorine or chlorine, represents cycloalkyl of 5 to 6 carbon atoms optionally substituted by methyl or methoxy or represents in each case phenyl or benzyl optionally substituted by fluorine, chlorine, bromine, cyano, nitro, alkyl of 1 to 4 carbon atoms, C 1 -C 4 alkoxy, trifluoromethyl or trifluoromethoxy, R 22 represents alkyl of 1 to 4 carbon atoms optionally substituted by fluorine or represents phenyl optionally substituted by fluorine, chlorine, bromine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, trifluoromethyl, trifluoromethoxy, cyano or nitro, R 23 represents in each case alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, alkylthio of 1 at 4 carbon atoms optionally substituted by fluorine or chlorine or in each case represents phenyl, phenoxy or phenylthio optionally substituted by fluorine, chlorine, bromine, nitro, cyano, alkoxy of 1 to 4 carbon atoms, trifl uoromethoxy, alkylthio of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, alkyl of 1 to 4 carbon atoms or trifluoromethyl, R24 represents alkoxy of 1 to 4 carbon atoms or alkylthio of 1 to 4 carbon atoms , R25 represents alkyl of 1 to 6 carbon atoms, cycloalkyl of 3 to 6 carbon atoms, alkoxy of 1 to 6 carbon atoms, alkenyl of 3 to 6 carbon atoms, alkoxy- (C1-C4) -alkyl of 1 at 4 carbon atoms, R26 represents alkyl of 1 to 6 carbon atoms, alkenyl of 3 to 6 carbon atoms or alkoxy- (C1-C4) -alkyl of 1 to 4 carbon atoms, R25 and R26 together represent a alkylene radical of 3 to 6 carbon atoms optionally substituted by methyl or ethyl in which a carbon atom is optionally replaced by oxygen or sulfur, and at least one active compound of the formula (II). 3. The composition according to claim 1 or 2, characterized in that it comprises at least one compound of the formula (I) in which W1 represents hydrogen, methyl, ethyl, chlorine, bromine or methoxy, X represents chlorine, bromine, methyl , ethyl, propyl, isopropyl, methoxy, ethoxy or trifluoromethyl, Y and Z independently represent hydrogen, fluorine, chlorine, bromine, methyl, ethyl, propyl, isopropyl, trifluoromethyl or methoxy, A3 represents methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tere-butyl, cyclopropyl, cyclopentyl or cyclohexyl, A4 represents hydrogen, ethyl or methyl, A3 and A4 further represent together with the carbon atom to which they are attached cycloalkyl of 6 carbon atoms saturated in the which a ring member is optionally replaced by oxygen and which is optionally monosubstituted by methyl, ethyl, methoxy, ethoxy, propoxy or butoxy, D represents hydrogen, represents methyl, ethyl, propyl, isopropyl , butyl, isobutyl, allyl, cyclopropyl, cyclopentyl or cyclohexyl, A3 and D together represent alkanediyl of 3 to 4 carbon atoms optionally substituted by methyl, G1 represents hydrogen (a) or represents one of the groups
L1 represents oxygen or sulfur, M1 represents oxygen or sulfur, R20 represents alkyl of 1 to 8 carbon atoms, alkenyl of 2 to 4 carbon atoms, methoxymethyl, ethoxymethyl, ethylthiomethyl, cyclopropyl, cyclopentyl or cyclohexyl, represents phenyl which is mono optionally disubstituted by fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, methoxy, trifluoromethyl or trifluoromethoxy, represents pyridyl or thienyl, each of which is optionally mono- or disubstituted by chlorine or methyl, R21 represents alkyl 1 to 8 carbon atoms, alkenyl of 2 to 4 carbon atoms, methoxyethyl, ethoxyethyl or represents phenyl or benzyl, R25 and R26 independently of one another methyl, ethyl or together with the nitrogen atom to which they are attached represent morpholino, and at least one active compound of the formula (II). 4. The composition according to claim 1, 2 or 3, characterized in that it comprises at least one compound of the formula (I) in which W1 represents hydrogen or methyl, X represents chlorine, bromine or methyl, Y and Z independently represent hydrogen, chlorine, bromine or methyl, together with A3 and A4 further represent, together with the carbon atom to which saturated 6-carbon-cycloalkyl are attached, in which optionally a ring member is replaced by oxygen and is optionally monosubstituted by methyl , methoxy, ethoxy, propoxy or butoxy, D represents hydrogen, G1 represents hydrogen (a) or represents one of the groups
L1 represents oxygen or sulfur, M1 represents oxygen or sulfur, R20 represents alkyl of 1 to 8 carbon atoms, alkenyl of 2 to 4 carbon atoms, methoxymethyl, ethoxymethyl, ethylmethylthio, cyclopropyl, cyclopentyl, cyclohexyl, represents phenyl which is monosubstituted optionally by fluorine, chlorine, bromine, methyl, methoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro, represents pyridyl or thienyl, each of which is optionally monosubstituted by chlorine or methyl, R21 represents alkyl of 1 to 8 carbon atoms, alkenyl of 2 to 4 carbon atoms, methoxyethyl, ethoxyethyl, phenyl or benzyl, R25 and R26 independently represent methyl, ethyl or together with the nitrogen atom to which they are attached represent morpholino, and at least one active compound of the formula ( II). 5. The composition according to claims 1, 2, 3 or 4, characterized in that it comprises the compound of the formula (l-a-4) and at least one anthranilamide of the formula (II). 6. The composition according to claims 1, 2, 3, 4 or 5, characterized in that it comprises at least one anthranilamide of the formula (I) wherein A1 and A2 independently represent oxygen or sulfur, X1 represents N or CR10, R1 represents hydrogen or represents alkyl of 1 to 6 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkynyl of 2 to 6 carbon atoms carbon or cycloalkyl of 3 to 6 carbon atoms, each of which is optionally mono- or poly-substituted, wherein the substituents can be independently selected from the group consisting of R6, halogen, cyano, nitro, hydroxyl, alkoxy from 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, alkoxycarbonyl of 2 to 4 carbon atoms, alkylamino of 1 to 4 atoms of carbon, dialkylamino of 2 to 8 carbon atoms, cycloalkylamino of 3 to 6 carbon atoms, (C 1 -C 4 alkyl) -cycloalkylamino of 3 to 6 carbon atoms and R 11, R 2 represents hydrogen, alkyl of 1 to 6 atoms carbon, alkenyl from 2 to 6 carbon volumes, alkynyl of 2 to 6 carbon atoms, cycloalkyl of 3 to 6 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, cycloalkylamino of 3 to 6 carbon atoms, alkoxycarbonyl of 2 to 6 carbon atoms or alkylcarbonyl of 2 to 6 carbon atoms,
R3 represents hydrogen, R11 or represents alkyl of 1 to 6 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkynyl of 2 to 6 carbon atoms, cycloalkyl of 3 to 6 carbon atoms, each of which is mono or optionally polysubstituted, wherein the substituents can be independently selected from the group consisting of R6, halogen, cyano, nitro, hydroxyl, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, alkoxycarbonyl of 2 to 6 carbon atoms, alkylcarbonyl of 2 to 6 carbon atoms, trialkylsilyl of 3 to 6 carbon atoms carbon, R11, phenyl, phenoxy and a 5- or 6-membered heteroaromatic ring, wherein each phenyl, phenoxy and 5- or 6-membered heteroaromatic ring can be optionally substituted and where the substituents can be independently selected from each other. one to three radicals W or one or more radicals R12, or R2 and R3 can be linked together and form the ring M, R4 represents hydrogen, alkyl of 1 to 6 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkynyl from 2 to 6 carbon atoms, cycloalkyl of 3 to 6 carbon atoms, haloalkyl of 1 to 6 carbon atoms, haloalkenyl of 2 to 6 carbon atoms, haloalkynyl of 2 to 6 carbon atoms, halocycloalkyl of 3 to 6 atoms carbon, halogen, cyano, nitro, hydroxyl, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkynylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 01 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 carbon atoms, haloalkylsulfonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms , cycloalkylamino of 3 to 6 carbon atoms, trialkylsilyl of 3 to 6 carbon atoms or represents phenyl, benzyl or phenoxy, each of which is optionally mono- or poly-substituted, wherein the substituents can be independently selected from the group consisting of alkyl of 1 to 4 carbon atoms. carbon, alkenyl of 2 to 4 carbon atoms, alkynyl of 2 to 4 carbon atoms, cycloalkyl of 3 to 6 carbon atoms, haloalkyl of 1 to 4 carbon atoms, haloalkenyl of 2 to 4 carbon atoms, haloalkynyl of 2 to 4 carbon atoms, halocycloalkyl of 3 to 6 carbon atoms, halogen, cyano, nitro, alkoxy of 1 to 4 carbon atoms, haloalkoxy from 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, cycloalkylamino of 3 to 6 carbon atoms, (C3-C6 alkyl) -cycloalkylamino, alkylcarbonyl of 2 to 4 carbon atoms, alkoxycarbonyl of 2 to 6 carbon atoms, alkylaminocarbonyl of 2 to 6 carbon atoms carbon, dialkylaminocarbonyl of 3 to 8 carbon atoms and trialkylsilyl of 3 to 6 carbon atoms, R8 in each case independently represent hydrogen, halogen or in each case represent alkyl of 1 to 4 carbon atoms optionally substituted, haloalkyl of 1 to 4 carbon atoms, R12, G, J, -OJ, -OG, -S (0) pJ, -S (0) pG, -S (0) p-phenyl, where the substituents can be independently selected from each other one to three radicals W or the group consisting of R12, alkyl of 1 to 10 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkynyl of 2 to 6 carbon atoms, alkoxy of 1 to 4 carbon atoms and alkylthio of 1 to 4 carbon atoms, where each substituent can be substituted by one or more constituents independently selected from the group consisting of G, J, R6, halogen, cyano, nitro, amino, hydroxyl, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 atoms carbon, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 carbon atoms, haloalkylsulfonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, trialkylsilyl of 3 to 6 carbon atoms, phenyl and phenoxy, where each phenyl or phenoxy ring can be optionally substituted and where the substituents can be independently selected from each other to three radicals W or from one to more radicals R12, G represents in each case independently a carbocyclic or heterocyclic, non-aromatic ring of 5 or 6 members which may optionally contain one or two ring members of the group consisting of C (= 0), SO and S (= 0) 2 and which may be optionally substituted by one to 'four substituents independently selected from the group consisting of alkyl of 1 to 2 carbon atoms. carbon, halogen, cyano, nitro and alkoxy of 1 to 2 carbon atoms or independently represents alkenyl of 2 to 6 carbon atoms, alkynyl of 2 to 6 carbon atoms, cycloalkyl of 3 to 7 carbon atoms, (cyano) ) - cycloalkyl of 3 to 7 carbon atoms, (C 1 -C 4 alkyl) -cycloalkyl of 3 to 6 carbon atoms, (3-C 6 cycloalkyl) -alkyl of 1 to 4 carbon atoms, where each cycloalkyl, (alkyl) cycloalkyl and (cycloalkyl) -alkyl can optionally be substituted by one or more halogen atoms, J represents in each case independently a 5- or 6-membered heteroaromatic ring optionally substituted, where the substituents can be independently selected from each other three radicals or one or more radicals R12, R6 independently represents each other -C (= E1) R19, -LC (= E1) R19, -C (= E1) LR19, -LC (= E1) LR19, -0P (= Q) (OR19) 2, -S02LR18 or -LS02LR19, where each E1 independently represents 0, S, NR 15, N-OR15, N- N (R15) 2, NS = 0, N-CN or N-N02, R7 represents hydrogen, alkyl of 1 to 4 carbon atoms, haloalkyl of 1 to 4 carbon atoms, halogen, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 carbon atoms, haloalkylsulfonyl of 1 to 4 carbon atoms, R9 represents haloalkyl of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 carbon atoms or halogen, R10 represents hydrogen, alkyl of 1 to 4 carbon atoms, haloalkyl of 1 to 4 carbon atoms, halogen, cyano or haloalkoxy of 1 to 4 carbon atoms, R11 represents in each case independently alkylthio of 1 to 6 carbon atoms, alkylsulfenyl of 1 to 6 carbon atoms, haloalkylthio of 1 to 6 atoms of carbon, haloalkylsulfenyl of 1 to 6 carbon atoms, phenylthio or phenylsulfenyl mono- to trisubstituted optionally, where the substituents can be independently selected from the list consisting of, -S (0) nN (R16) 2, -C (= 0) R13, -L (C = 0) R14, -S (C = 0) LR14, -C (= 0) LR13, -S (0) nNR13C (= 0 =) R13, -S (0) nR13C (= 0) LR14 or -S (O) nNR13S (O) 2LR14, L represents in each case independently O,
NR18 or S, R12 represents in each case independently of each other B (OR17) 2 / amino, SH, thiocyanate, trialkylsilyloxy of 3 to 8 carbon atoms, alkyl disulfide of 1 to 4 carbon atoms, -SF5, -C ( = E1) R19, -LC (= E) R19, -C (= E1) LR19, -LC ^ E ^ LR19, -OP (= Q) (OR19) 2, S02LR19 or -LS02LR19, Q represents O or S, R 13 in each case independently represents hydrogen or represents in each case alkyl of 1 to 6 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkynyl of 2 to 6 carbon atoms or cycloalkyl of 3 to 6 carbon atoms mono or optionally polysubstituted, wherein the substituents can be independently selected from the group consisting of R6, halogen, cyano, nitro, hydroxyl, alkoxy of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulphonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, cycloalkylamino of 3 to 6 carbon atoms oo (C 1 -C 4 alkyl) -cycloalkylamino of 3 to 6 carbon atoms each independently represents alkyl of 1 to 20 carbon atoms, alkenyl of 2 to 20 carbon atoms, alkynyl of 2 to 20 carbon atoms or cycloalkyl of 3 to 6 carbon atoms mono- or polysubstituted optionally, wherein the substituents can be independently selected from the group consisting of R6, halogen, cyano, nitro, hydroxyl, alkoxy of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, cycloalkylamino of 3 to 6 carbon atoms and (C1-C4 alkyl) - cycloalkylamino of 3 to 6 carbon atoms or represents phenyl optionally substituted, wherein the substituents can be independently selected from one to three radicals or one or more radicals R12, R15 represents in each case independently Hydrogen or represents in each case haloalkyl of 1 to 6 carbon atoms or alkyl of 1 to 6 carbon atoms mono- or polysubstituted optionally, wherein the substituents can be independently selected from each other from the group consisting of cyano, nitro, hydroxyl alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 carbon atoms, haloalkylsulfonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, alkoxycarbonyl of 2 to 6 carbon atoms, alkylcarbonyl of 2 to 6 carbon atoms, trialkylsilyl of 3 to 6 carbon atoms and optionally substituted phenyl, wherein the substituents can be independently selected from one to three W radicals or one or more radicals R12 or N (R15) 2 represents a ring which forms the ring M, R16 represents alkyl of 1 to 12 carbon atoms or haloalkyl of 1 to 12 carbon atoms or N (R16) 2 represents the cycle in which the ring M, R17 in each case independently represents hydrogen or alkyl of 1 to 4 carbon atoms or B (OR17) 2 represents a ring in which the two oxygen atoms are linked via a chain having two to three carbon atoms which are optionally substituted by one or two substituents independently selected from the group consisting of methyl and alkoxycarbonyl of 2 to 6 carbon atoms, R18 each independently represents hydrogen, alkyl of 1 to 6 atoms carbon or haloalkyl of 1 to 6 carbon atoms or N (R13) (R18) represents a ring which forms the ring M, R19 represents in each case independently hydrogen or represents in each case alkyl of 1 to 6 atoms optionally mono- or polysubstituted carbon, wherein the substituents can be independently selected from the group consisting of cyano, nitro, hydroxyl, alkoxy of 1 to 4 carbon atom, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 carbon atoms, haloalkylsufonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino of 2 to 8 carbon atoms, C02H, alkoxycarbonyl of 2 to 6 carbon atoms, alkylcarbonyl of 2 to 6 carbon atoms, trialkylsilyl of 3 to 6 carbon atoms and phenyl optionally substituted, where the substituents can be independently selected from one to three radicals W, haloalkyl of 1 to 6 atoms of carbon, cycloalkyl of 3 to 6 carbon atoms or phenyl or pyridyl, each of which is mono- to trisubstituted optionally by, M represents in each case a mono-a tetrasubstituted ring optionally which, in addition to the and nitrogen attached to the pair of substituents R13 and R18,
(R15) 2 or (R16) 2 contains from two to six carbon atoms and optionally additionally an additional nitrogen, sulfur or oxygen atom, wherein the substituents can be independently selected from the group consisting of alkyl of 1 to 2 atoms of carbon, halogen, cyano, nitro and alkoxy having 1 to 2 carbon atoms, each independently represents alkyl of 1 to 4 carbon atoms, alkenyl of 2 to 4 carbon atoms, alkynyl of 2 to 4 carbon atoms, carbon, cycloalkyl of 3 to 6 carbon atoms, haloalkyl of 1 to 4 carbon atoms, haloalkenyl of 2 to 4 carbon atoms, haloalkynyl of 2 to 4 carbon atoms, halocycloalkyl 3 to 6 carbon atoms, halogen, cyano, nitro, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino not of 2 to 8 carbon atoms, cycloalkylamino of 3 to 6 carbon atoms, (C 1 -C 4 alkyl) -cycloalkylamino of 3 to 6 carbon atoms, alkylcarbonyl of 2 to 4 carbon atoms, alkoxycarbonyl of 2 to 6 carbon atoms carbon, CO2H, alkylaminocarbonyl of 2 to 6 carbon atoms, dialkylaminocarbonyl of 3 to 8 carbon atoms or trialkylsilyl of 3 to 6 carbon atoms, n independently represents in each case 0 or 1, p represents in each case independently yes 0, 1 or 2, where, if (a) R5 represents hydrogen, alkyl of 1 to 6 carbon atoms, haloalkyl of 1 to 6 carbon atoms, haloalkenyl of 2 to 6 carbon atoms, haloalkynyl of 2 to 6 atoms of carbon, haloalkoxy of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms or halogen and (b) R8 represents hydrogen, alkyl of 1 to 6 carbon atoms, haloalkyl of 1 to 6 carbon atoms, haloalkenyl of 2 to 6 carbon atoms, haloalkynyl of 2 to 6 carbons or halo, haloalkoxy of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, halogen, to the carbonylcarbonyl of 2 to 4 carbon atoms, alkoxycarbonyl of 2 to 6 carbon atoms, alkylaminocarbonyl of 2 to 6 carbon atoms or dialkylaminocarbonyl of 3 to 8 carbon atoms, (c) at least one substituent selected from the group consisting of R6, R11 and R12 is present and (d) if R12 is not present, at least one of the radicals R6 and R11 is different of alkylcarbonyl of 2 to 6 carbon atoms, alkoxycarbonyl of 2 to 6 carbon atoms, alkylaminocarbonyl of 2 to 6 carbon atoms and dialkylaminocarbonyl of 3 to 8 carbon atoms. The composition according to claims 1, 2, 3, 4, 5 or 6, characterized in that it comprises an anthranilamide of the formula (II-1) wherein R2 represents hydrogen or alkyl of 1 to 6 carbon atoms, R3 represents alkyl of 1 to 6 carbon atoms which is optionally substituted by an R6, R4 represents alkyl of 1 to 4 carbon atoms, haloalkyl of 1 to 2 carbon atoms, haloalkoxy of 1 to 2 carbon atoms or halogen, R5 represents hydrogen, alkyl of 1 to 4 carbon atoms, haloalkyl of 1 to 2 carbon atoms, haloalkoxy of 1 to 2 carbon atoms or halogen, R6 represents -C (= E2) R19, -LC (= E2) R19, -C (= E2) LR19 or -LC (= E2) LR19, where each E2 represents independently of each other 0, S, N-R15, N- OR15, 'NN (R15) 2, and each L independently represents 0 or NR18, R7 represents haloalkyl of 1 to 4 carbon atoms or halogen, R9 represents haloalkyl of 1 to 2 carbon atoms, haloalkoxy of 1 to 2 atoms of carbon, S (O) p-haloalkyl of 1 to 2 carbon atoms or halogen, R 15 represents in each case independently of each other hydrogen or represents Haloalkyl is optionally substituted by 1 to 6 carbon atoms or alkyl of 1 to 6 carbon atoms, where the substituents can be independently selected from the group consisting of cyano, alkoxy of 1 to 4 carbon atoms, haloalkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, haloalkylthio of 1 to 4 carbon atoms, haloalkylsulfinyl of 1 to 4 carbon atoms and haloalkylsulfonyl of 1 to 4 carbon atoms, R18 represents in each case hydrogen or alkyl of 1 to 4 carbon atoms, R19 represents in each case independently of each other hydrogen or alkyl of 1 to 6 carbon atoms, p independently of each other 0, 1, 2 8. The composition according to claims 1, 2, 3, 4, 5, 6 or 7, characterized in that it comprises the compounds of the formula (I) (group 1) and at least one active compound from the point of view acaricide (group 2) and at least one anthranilamide of the formula (II) in a ratio of 500: 1 to 1:50. 9. The use of a synergistically effective mixture according to claims 1, 2, 3, 4, 5, 6 or 7, to control animal pests.
10. A process for preparing insecticides, characterized in that a synergistically effective mixture according to claims 1, 2, 3, 4, 5, 6 or 7 is mixed with extenders and / or surfactants.
11. A method for controlling animal pests, characterized in that the synergistically effective mixtures according to claims 1, 2, 3, 4, 5, 6 or 7 are allowed to act on animal pests and / or their habitats.