MXPA05006585A - Aductos basados en dicloruro de magnesio, y componentes de catalizador obtenidos de los mismos. - Google Patents

Aductos basados en dicloruro de magnesio, y componentes de catalizador obtenidos de los mismos.

Info

Publication number
MXPA05006585A
MXPA05006585A MXPA05006585A MXPA05006585A MXPA05006585A MX PA05006585 A MXPA05006585 A MX PA05006585A MX PA05006585 A MXPA05006585 A MX PA05006585A MX PA05006585 A MXPA05006585 A MX PA05006585A MX PA05006585 A MXPA05006585 A MX PA05006585A
Authority
MX
Mexico
Prior art keywords
adducts
obtained therefrom
catalyst components
components obtained
magnesium dichloride
Prior art date
Application number
MXPA05006585A
Other languages
English (en)
Inventor
Daniele Evangelisti
Original Assignee
Basell Poliolefine Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Poliolefine Spa filed Critical Basell Poliolefine Spa
Publication of MXPA05006585A publication Critical patent/MXPA05006585A/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0209—Esters of carboxylic or carbonic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0205—Oxygen-containing compounds comprising carbonyl groups or oxygen-containing derivatives, e.g. acetals, ketals, cyclic peroxides
    • B01J31/0208—Ketones or ketals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/22—Magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Polymerization Catalysts (AREA)

Abstract

La presente invencion se refiere a aductos de Lewis solidos que comprenden MgCI2, una base de Lewis, LB, que pertenece a eteres, esteres, cetonas, silanos o aminas y un alcohol ROH, en donde R es un grupo hidrocarburo de C1-C15 sustituido opcionalmente con grupos que contienen heteroatomos, cuyos compuestos estan en relaciones molares entre si definidas por la formula MgCI2(ROH)m(LB)n, en donde m varia de 0.05 a 6, y n varia de 0.08 a 6; estos aductos permiten preparar catalizadores que tienen una buena estabilidad morfologica y altas actividades de polimerizacion.
MXPA05006585A 2002-12-18 2003-11-25 Aductos basados en dicloruro de magnesio, y componentes de catalizador obtenidos de los mismos. MXPA05006585A (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP02080616 2002-12-18
US43519502P 2002-12-20 2002-12-20
EP03101357 2003-05-14
US48269703P 2003-06-26 2003-06-26
PCT/EP2003/013818 WO2004054711A1 (en) 2002-12-18 2003-11-25 Magnesium dichloride-based adducts and catalyst components obtained therefrom

Publications (1)

Publication Number Publication Date
MXPA05006585A true MXPA05006585A (es) 2005-08-16

Family

ID=44257197

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA05006585A MXPA05006585A (es) 2002-12-18 2003-11-25 Aductos basados en dicloruro de magnesio, y componentes de catalizador obtenidos de los mismos.

Country Status (14)

Country Link
US (1) US7932206B2 (es)
EP (1) EP1572355B1 (es)
JP (1) JP5069414B2 (es)
KR (1) KR20050085800A (es)
CN (1) CN103073661B (es)
AR (1) AR042497A1 (es)
AT (1) ATE514484T1 (es)
AU (1) AU2003293783A1 (es)
BR (1) BR0316911B1 (es)
CA (1) CA2510254A1 (es)
MX (1) MXPA05006585A (es)
RU (1) RU2342998C2 (es)
TW (1) TW200415158A (es)
WO (1) WO2004054711A1 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1697433A1 (en) * 2003-12-23 2006-09-06 Basell Poliolefine Italia S.r.l. Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom
EP2036928B1 (en) * 2006-04-06 2015-12-23 China Petroleum & Chemical Corporation Magnesium halide adduct, olefins polymerization catalyst component and catalyst made therefrom
SA3686B1 (ar) 2009-10-16 2014-10-22 China Petroleum& Chemical Corp مكون حفاز لبلمرة الأولفين وحفاز يشتمل عليه
KR20120120178A (ko) * 2009-12-23 2012-11-01 바셀 폴리올레핀 이탈리아 에스.알.엘 이염화마그네슘-물 부가물 및 그로부터 수득되는 촉매 성분
KR101835309B1 (ko) * 2010-08-24 2018-03-08 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀 중합용 촉매 성분
WO2012041944A1 (en) * 2010-09-30 2012-04-05 Basell Poliolefine Italia S.R.L. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
US9862781B2 (en) 2011-08-08 2018-01-09 Basell Poliolefine Italia S.R.L. Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom
EP2610273B1 (en) * 2011-12-30 2018-02-07 Borealis AG Catalyst component
EP2692743A1 (en) * 2012-08-03 2014-02-05 Basell Poliolefine Italia S.r.l. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
US9663596B2 (en) 2013-01-31 2017-05-30 Saudi Basic Industries Corporation Catalyst composition for polymerization of olefins
BR112016020160B1 (pt) 2014-03-14 2021-12-14 Basell Poliolefine Italia S.R.L. Componentes catalisadores para polimerização de olefinas, seu processo de preparação, catalisador para (co)polimerização de olefinas, processo de (co)polimerização de olefinas e aduto de base de lewis
CN111051359A (zh) 2017-08-29 2020-04-21 格雷斯公司 烯烃聚合催化剂
US20230416424A1 (en) * 2020-10-26 2023-12-28 China Petroleum & Chemical Corporation Solid component for preparing olefin polymerization catalyst, and preparation method therefor and application thereof
CN114478857B (zh) * 2020-10-26 2023-07-21 中国石油化工股份有限公司 烯烃聚合催化剂载体及其制备方法

Family Cites Families (18)

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Publication number Priority date Publication date Assignee Title
YU35844B (en) 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
IT1054410B (it) 1975-11-21 1981-11-10 Mitsui Petrochemical Ind Catalizzatori per la polimerizzazione delle alfa olefine
IT1114822B (it) * 1977-07-04 1986-01-27 Montedison Spa Componenti di catalizzatori per la polimerizzazione delle alfa-olefine
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
IT1209255B (it) * 1980-08-13 1989-07-16 Montedison Spa Catalizzatori per la polimerizzazione di olefine.
JPH07642B2 (ja) 1984-12-19 1995-01-11 三菱油化株式会社 オレフイン重合用触媒成分
FI80055C (fi) 1986-06-09 1990-04-10 Neste Oy Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner.
IT1227258B (it) 1988-09-30 1991-03-28 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
JPH03140308A (ja) * 1989-10-27 1991-06-14 Chisso Corp ポリオレフィン用重合触媒の製法
FR2669915B1 (fr) 1990-11-29 1993-01-29 Atochem Particules de chlorure de magnesium a structure polyedre, composante catalytique supportee sur ces particules, procedes de fabrication de ces produits et des polyolefines obtenues a partir de cette composante catalytique.
JPH04331210A (ja) 1990-11-30 1992-11-19 Chisso Corp オレフィン重合用触媒
IT1245250B (it) * 1991-03-27 1994-09-13 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
FR2728181B1 (fr) 1994-12-16 1997-01-31 Appryl Snc Composante catalytique pour la polymerisation des olefines, son procede de fabrication, et procede de polymerisation des olefines en presence de ladite composante catalytique
IL117114A (en) 1995-02-21 2000-02-17 Montell North America Inc Components and catalysts for the polymerization ofolefins
EP0914351B1 (en) 1997-03-29 2004-02-18 Basell Poliolefine Italia S.p.A. Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom
GB2325004B (en) 1997-05-09 1999-09-01 Samsung General Chemicals Co A catalyst for polymerization and copolymerization of olefins
CN1086191C (zh) 1998-03-17 2002-06-12 中国石油化工集团公司 用于乙烯聚合或共聚合的催化剂及其制法

Also Published As

Publication number Publication date
BR0316911A (pt) 2005-10-18
RU2342998C2 (ru) 2009-01-10
RU2005122494A (ru) 2006-01-20
US7932206B2 (en) 2011-04-26
WO2004054711A1 (en) 2004-07-01
CA2510254A1 (en) 2004-07-01
EP1572355A1 (en) 2005-09-14
AR042497A1 (es) 2005-06-22
JP2006518772A (ja) 2006-08-17
US20060025300A1 (en) 2006-02-02
BR0316911B1 (pt) 2013-05-07
CN103073661A (zh) 2013-05-01
ATE514484T1 (de) 2011-07-15
TW200415158A (en) 2004-08-16
JP5069414B2 (ja) 2012-11-07
EP1572355B1 (en) 2011-06-29
KR20050085800A (ko) 2005-08-29
CN103073661B (zh) 2018-06-12
AU2003293783A1 (en) 2004-07-09

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