MXPA02012678A - Complejos de rutenio-difosfina y su uso como catalizadores. - Google Patents
Complejos de rutenio-difosfina y su uso como catalizadores.Info
- Publication number
- MXPA02012678A MXPA02012678A MXPA02012678A MXPA02012678A MXPA02012678A MX PA02012678 A MXPA02012678 A MX PA02012678A MX PA02012678 A MXPA02012678 A MX PA02012678A MX PA02012678 A MXPA02012678 A MX PA02012678A MX PA02012678 A MXPA02012678 A MX PA02012678A
- Authority
- MX
- Mexico
- Prior art keywords
- catalysts
- diphosphine complexes
- ruthenium diphosphine
- ruthenium
- complexes
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- QMVQPDHYQQDAJA-UHFFFAOYSA-N phosphane;ruthenium Chemical class P.P.[Ru] QMVQPDHYQQDAJA-UHFFFAOYSA-N 0.000 title 1
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 238000009876 asymmetric hydrogenation reaction Methods 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 150000007942 carboxylates Chemical group 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000001072 heteroaryl group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Complejos novedosos, adecuados en particular para uso como catalizadores en la hidrogenacion asimetrica de cetonas, son de la formula (1) o un diastereoisomero de los mismos, en donde cada Ar es un grupo aromatico o heteroaromatico de hasta 20 atomos; X es haluro o carboxilato; y R1, R2, R3, R4 son independientemente hidrogeno, arilo o alquilo, ligados opcionalmente o parte de un anillo.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0007785A GB0007785D0 (en) | 2000-03-30 | 2000-03-30 | Complexes |
GB0018143A GB0018143D0 (en) | 2000-07-24 | 2000-07-24 | Complexes |
PCT/GB2001/001313 WO2001074829A1 (en) | 2000-03-30 | 2001-03-23 | Ruthenium-diphosphine complexes and their use as catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA02012678A true MXPA02012678A (es) | 2004-09-10 |
Family
ID=26243997
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MXPA02012678A MXPA02012678A (es) | 2000-03-30 | 2001-03-23 | Complejos de rutenio-difosfina y su uso como catalizadores. |
Country Status (8)
Country | Link |
---|---|
US (1) | US6486337B2 (es) |
EP (1) | EP1276745B1 (es) |
AT (1) | ATE495183T1 (es) |
AU (1) | AU2001239442A1 (es) |
CA (1) | CA2414049A1 (es) |
DE (1) | DE60143842D1 (es) |
MX (1) | MXPA02012678A (es) |
WO (1) | WO2001074829A1 (es) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6887820B1 (en) * | 1995-12-06 | 2005-05-03 | Japan Science And Technology Corporation | Method for producing optically active compounds |
JP3720235B2 (ja) * | 2000-03-14 | 2005-11-24 | 高砂香料工業株式会社 | 光学活性ルテニウムホスフィン錯体の製造方法及び該錯体を用いた光学活性アルコールの製造方法 |
WO2002057278A1 (en) * | 2001-01-19 | 2002-07-25 | Chirotech Technology Limited | Ligands and their use |
JP3566955B2 (ja) | 2001-12-28 | 2004-09-15 | 関東化学株式会社 | 新規ルテニウム錯体およびこれを触媒として用いるアルコール化合物の製造方法 |
US6743921B2 (en) * | 2002-01-24 | 2004-06-01 | Dsm Catalytica Pharmaceuticals, Inc. | Process for the preparation of nonracemic syn-1-(4-hydroxy-phenyl)-2-(4-hydroxy-4-phenyl-piperidin-1-yl)-1-propanol compounds |
EP1469006A3 (de) * | 2003-02-12 | 2005-03-16 | Bayer Chemicals AG | Verfahren zur Reduktion von Ketocarbonsäureestern |
JP2006527246A (ja) * | 2003-06-13 | 2006-11-30 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニー | 配位子 |
DE10326916A1 (de) * | 2003-06-16 | 2005-01-05 | Bayer Chemicals Ag | Verfahren zur Reduktion von Ketocarbonsäureestern |
US7094725B2 (en) | 2003-07-11 | 2006-08-22 | The Hong Kong Polytechnic University | Biphenyldiphosphine compounds |
GB0316439D0 (en) | 2003-07-15 | 2003-08-20 | Johnson Matthey Plc | Catalysts |
EP1661903B8 (en) | 2003-08-13 | 2011-10-19 | Takasago International Corporation | Novel transition metal complex and process for producing optically active alcohol with the complex |
ATE453654T1 (de) * | 2005-07-01 | 2010-01-15 | Reddy S Lab Eu Ltd Dr | Verfahren zur herstellung von diphosphin- ruthenium-diamin-komplexen |
GB0716714D0 (en) | 2007-08-29 | 2007-10-10 | Johnson Matthey Plc | Ligands |
GB201104522D0 (en) | 2011-03-17 | 2011-05-04 | Johnson Matthey Plc | Complexes |
CN103857468B (zh) * | 2011-10-06 | 2016-04-13 | 弗门尼舍有限公司 | 用ru/双齿配体络合物对醛的选择性氢化 |
WO2013119751A1 (en) * | 2012-02-09 | 2013-08-15 | Boehringer Ingelheim International Gmbh | Process for preparing carboxamidine compounds |
JP6419096B2 (ja) * | 2013-03-15 | 2018-11-07 | フイルメニツヒ ソシエテ アノニムFirmenich Sa | Ru/二座配位子錯体を用いたアルデヒドの選択水素化 |
EP3798209A1 (en) * | 2013-10-22 | 2021-03-31 | Chiesi Farmaceutici S.p.A. | Process for the preparation of a crystal form of a pde4 inhibitor |
GB201509664D0 (en) * | 2015-06-03 | 2015-07-15 | Johnson Matthey Plc And Universit Di Udine | Process |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5874629A (en) * | 1996-06-12 | 1999-02-23 | Merck & Co., Inc. | Chiral bisphosphines |
GB2351735A (en) * | 1999-07-01 | 2001-01-10 | Merck & Co Inc | Synthesis of (r)-1-(3,5-bis(trifluoromethyl)-phenyl)ethan-1-ol by asymmetric hydrogenation |
DE60106928T2 (de) * | 2000-07-24 | 2005-03-10 | Chirotech Technology Ltd. | Rutheniumkomplexe und ihre verwendung zur asymmetrischen hydrierung |
-
2001
- 2001-03-23 CA CA002414049A patent/CA2414049A1/en not_active Abandoned
- 2001-03-23 AU AU2001239442A patent/AU2001239442A1/en not_active Abandoned
- 2001-03-23 EP EP01914056A patent/EP1276745B1/en not_active Expired - Lifetime
- 2001-03-23 DE DE60143842T patent/DE60143842D1/de not_active Expired - Lifetime
- 2001-03-23 MX MXPA02012678A patent/MXPA02012678A/es unknown
- 2001-03-23 WO PCT/GB2001/001313 patent/WO2001074829A1/en active Application Filing
- 2001-03-23 AT AT01914056T patent/ATE495183T1/de not_active IP Right Cessation
- 2001-03-29 US US09/821,222 patent/US6486337B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE60143842D1 (de) | 2011-02-24 |
US20020026064A1 (en) | 2002-02-28 |
CA2414049A1 (en) | 2001-10-11 |
EP1276745A1 (en) | 2003-01-22 |
US6486337B2 (en) | 2002-11-26 |
EP1276745B1 (en) | 2011-01-12 |
ATE495183T1 (de) | 2011-01-15 |
WO2001074829A1 (en) | 2001-10-11 |
AU2001239442A1 (en) | 2001-10-15 |
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