MX9801801A - Complejos de metal que contienen peroxo, y tienen oxido de amina, oxido de fosfina, oxido de arsina, n-oxido de piridina o ligaduras de piridina, como catalizadores de la epoxidacion. - Google Patents

Complejos de metal que contienen peroxo, y tienen oxido de amina, oxido de fosfina, oxido de arsina, n-oxido de piridina o ligaduras de piridina, como catalizadores de la epoxidacion.

Info

Publication number
MX9801801A
MX9801801A MX9801801A MX9801801A MX9801801A MX 9801801 A MX9801801 A MX 9801801A MX 9801801 A MX9801801 A MX 9801801A MX 9801801 A MX9801801 A MX 9801801A MX 9801801 A MX9801801 A MX 9801801A
Authority
MX
Mexico
Prior art keywords
oxide
arsane
pyridin
phosphane
metal complexes
Prior art date
Application number
MX9801801A
Other languages
English (en)
Other versions
MXPA98001801A (es
Inventor
Michael Schulz
Joaquim Henrique Teles
Joerg Sundermeyer
Guenter Wahl
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of MX9801801A publication Critical patent/MX9801801A/es
Publication of MXPA98001801A publication Critical patent/MXPA98001801A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten

Abstract

Las olefinas se pueden epoxidar usando los catalizadores I: (Ver Formula) donde M es una metal del grupo de transicion 4. a 7?? de la Tabla periodica de los Elementos, L1 es una ligadura de oxido de amina, oxido de fosfina, oxido de areina, N-oxido de piridina o piridina, de las formulas II, III, VII o VII, L2 es una ligadura auxiliar acostumbrada o una ligadura ulterior L1, o un sitio de coordinacion libre, X es oxígeno de oxo o una ligadura de imido, m es 1 o 2, y n es 1, 2 o 3.
MXPA/A/1998/001801A 1995-09-11 1998-03-06 Complejos de metal que contienen peroxo, y tienenoxido de amina, oxido de fosfina, oxido de arsina, n-oxido de piridina o ligaduras de piridina, como catalizadores de la epoxidacion MXPA98001801A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19533331A DE19533331A1 (de) 1995-09-11 1995-09-11 Peroxogruppenhaltige Metallkomplexe mit Aminoxid- oder Phosphanoxid-Liganden als Epoxidierungskatalysatoren
DE19533331.4 1995-09-11

Publications (2)

Publication Number Publication Date
MX9801801A true MX9801801A (es) 1998-08-30
MXPA98001801A MXPA98001801A (es) 1998-11-12

Family

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Also Published As

Publication number Publication date
EP0876213A1 (de) 1998-11-11
ZA967618B (en) 1998-03-10
RU2176930C2 (ru) 2001-12-20
DE19533331A1 (de) 1997-03-13
CA2229344A1 (en) 1997-03-20
AU6986996A (en) 1997-04-01
US6054407A (en) 2000-04-25
JPH11512335A (ja) 1999-10-26
CN1201406A (zh) 1998-12-09
KR19990044533A (ko) 1999-06-25
CN1091655C (zh) 2002-10-02
WO1997010054A1 (de) 1997-03-20

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FG Grant or registration
MM Annulment or lapse due to non-payment of fees