MX9709138A - Intercalados formados por la co-intercalacion de intercalantes de monomero, oligomero o polimero e intercalantes modificadores de superficie y materiales estratificados y nanocompuestos preparados con estos intercalados. - Google Patents

Intercalados formados por la co-intercalacion de intercalantes de monomero, oligomero o polimero e intercalantes modificadores de superficie y materiales estratificados y nanocompuestos preparados con estos intercalados.

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Publication number
MX9709138A
MX9709138A MX9709138A MX9709138A MX9709138A MX 9709138 A MX9709138 A MX 9709138A MX 9709138 A MX9709138 A MX 9709138A MX 9709138 A MX9709138 A MX 9709138A MX 9709138 A MX9709138 A MX 9709138A
Authority
MX
Mexico
Prior art keywords
intercalates
long chain
composite materials
materials containing
containing same
Prior art date
Application number
MX9709138A
Other languages
English (en)
Other versions
MXPA97009138A (es
Inventor
Tie Lan
Gary W Beall
Semeon Tsipursky
Fernando M Serrano
Steven J Engman
Original Assignee
Amcol International Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Amcol International Corp filed Critical Amcol International Corp
Publication of MX9709138A publication Critical patent/MX9709138A/es
Publication of MXPA97009138A publication Critical patent/MXPA97009138A/es

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/40Compounds of aluminium
    • C09C1/42Clays
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/20Silicates
    • C01B33/36Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C01B33/44Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/10Treatment with macromolecular organic compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/08Intercalated structures, i.e. with atoms or molecules intercalated in their structure
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/54Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

La presente invencion se relaciona con intercalados formados al poner en contacto un material estratificado, por ejemplo filosilicato, con un modificador de superficie monomérico intercalante que incluye un radical alquilo con por lo menos 6 átomos de carbono y un monomero y oligomero polimerizable o bien un polímero. El modificador de superficie monomérico intercalante convierte la region intercapa de los materiales intercalados de ser hidrofílica a ser hidrofobica, y por lo tanto los oligomeros o monomeros polimerizables o los polímeros pueden intercalarse fácilmente dentro de la separacion intercapa. La presencia conjunta del modificador de superficie monomérico intercalante y del monomero u oligomero polimerizable o del polímero proporcionan un ambiente para más monomeros u oligomeros polimerizables o polímeros que vana a intercalarse dentro de la separacion intercapa y los intercalados se exfolian fácilmente en las matrices poliméricas para forma nanocompuestos. Los nanocompuestos (por ejemplo epoxi-arcilla) que se preparan a partir de los intercalados demostraron propiedades mejoradas de resistencia química, térmica y mecánica en comparacion con las matrices poliméricas de pristina.
MXPA/A/1997/009138A 1996-12-06 1997-11-26 Intercalados formados por la co-intercalacion deintercalantes de monomero, oligomero o polimero eintercalantes modificadores de superficie y materiales estratificados y nanocompuestos preparados con estos intercalados MXPA97009138A (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08758740 1996-12-06
US08/758,740 US5952095A (en) 1996-12-06 1996-12-06 Intercalates and exfoliates formed with long chain (C10 +) monomeric organic intercalant compounds; and composite materials containing same
US08907950 1997-08-11
US08/907,950 US6057396A (en) 1996-12-06 1997-08-11 Intercalates formed by co-intercalation of monomer, oligomer or polymer intercalants and surface modifier intercalants and layered materials and nonocomposites prepared with the intercalates

Publications (2)

Publication Number Publication Date
MX9709138A true MX9709138A (es) 1998-09-30
MXPA97009138A MXPA97009138A (es) 1998-11-16

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Also Published As

Publication number Publication date
EP0846660A2 (en) 1998-06-10
EP0846661A3 (en) 1999-07-28
CA2218303A1 (en) 1998-06-06
EP0846661A2 (en) 1998-06-10
CA2218356A1 (en) 1998-06-06
JPH10194727A (ja) 1998-07-28
US6057396A (en) 2000-05-02
EP0846660A3 (en) 1999-07-28
US5952095A (en) 1999-09-14

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