MX9709130A - Process for the synthesis of vinyl sulfenic acid derivatives. - Google Patents

Process for the synthesis of vinyl sulfenic acid derivatives.

Info

Publication number
MX9709130A
MX9709130A MX9709130A MX9709130A MX9709130A MX 9709130 A MX9709130 A MX 9709130A MX 9709130 A MX9709130 A MX 9709130A MX 9709130 A MX9709130 A MX 9709130A MX 9709130 A MX9709130 A MX 9709130A
Authority
MX
Mexico
Prior art keywords
synthesis
acid derivatives
sulfenic acid
vinyl sulfenic
vinyl
Prior art date
Application number
MX9709130A
Other languages
Spanish (es)
Other versions
MXPA97009130A (en
Inventor
David Warren Hoard
Wayne Douglas Luke
Original Assignee
Lilly Co Eli
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/482,692 external-priority patent/US5512701A/en
Priority claimed from US08/483,607 external-priority patent/US5514826A/en
Application filed by Lilly Co Eli filed Critical Lilly Co Eli
Publication of MX9709130A publication Critical patent/MX9709130A/en
Publication of MXPA97009130A publication Critical patent/MXPA97009130A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/10—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C323/11—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/16—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C313/00—Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C313/00—Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C313/08—Sulfenic acids; Derivatives thereof
    • C07C313/18—Sulfenamides
    • C07C313/20—Sulfenamides having sulfur atoms of sulfenamide groups bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/08—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/52—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes
    • C07D333/54—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the hetero ring
    • C07D333/56—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The present invention is directed to novel vinyl sulfenic acid derivatives, and to a new process for the synthesis of novel vinyl sulfenic acid derivatives. These compounds are useful for the synthesis of benzo[b]thiophenes, in particular 2-aryl-benzo[b]thiophenes.
MXPA/A/1997/009130A 1995-06-07 1997-11-26 Process for the synthesis of acid derivatives vinilsulfen MXPA97009130A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US08/482,692 US5512701A (en) 1995-06-07 1995-06-07 Process for the synthesis of vinyl sulfenic acid derivatives
US08483607 1995-06-07
US08482692 1995-06-07
US08/483,607 US5514826A (en) 1995-06-07 1995-06-07 Vinyl sulfenic acid derivatives
PCT/US1996/009460 WO1996040693A1 (en) 1995-06-07 1996-06-04 Process for the synthesis of vinyl sulfenic acid derivatives

Publications (2)

Publication Number Publication Date
MX9709130A true MX9709130A (en) 1998-03-31
MXPA97009130A MXPA97009130A (en) 1998-10-15

Family

ID=

Also Published As

Publication number Publication date
HUP9900923A3 (en) 2000-02-28
EP0830362A4 (en) 1998-09-02
HUP9900923A2 (en) 1999-07-28
CN1192215A (en) 1998-09-02
EA000606B1 (en) 1999-12-29
JPH11507346A (en) 1999-06-29
TR199701511T1 (en) 1998-04-21
BR9608847A (en) 1999-06-08
AU6100396A (en) 1996-12-30
AU698076B2 (en) 1998-10-22
IL122127A (en) 2001-05-20
NO975633D0 (en) 1997-12-04
NZ310241A (en) 1999-07-29
CN1330071A (en) 2002-01-09
CN1068883C (en) 2001-07-25
IL122127A0 (en) 1998-04-05
EA199800026A1 (en) 1998-06-25
PL323907A1 (en) 1998-04-27
NO975633L (en) 1998-01-28
EP0830362A1 (en) 1998-03-25
WO1996040693A1 (en) 1996-12-19
CZ387997A3 (en) 1998-09-16
CA2224225A1 (en) 1996-12-19
KR19990022503A (en) 1999-03-25

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