MX9702145A - A method for the demercaptanization of petroleum distillates. - Google Patents
A method for the demercaptanization of petroleum distillates.Info
- Publication number
- MX9702145A MX9702145A MX9702145A MX9702145A MX9702145A MX 9702145 A MX9702145 A MX 9702145A MX 9702145 A MX9702145 A MX 9702145A MX 9702145 A MX9702145 A MX 9702145A MX 9702145 A MX9702145 A MX 9702145A
- Authority
- MX
- Mexico
- Prior art keywords
- demercaptanization
- petroleum distillates
- iron
- copper
- mass percent
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000003209 petroleum derivative Substances 0.000 title abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 239000003575 carbonaceous material Substances 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 239000010949 copper Substances 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 239000002638 heterogeneous catalyst Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000002759 woven fabric Substances 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/58—Fabrics or filaments
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Working-Up Tar And Pitch (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The demercaptanization of petroleum distillates may be carried out by means of the oxidation of the mercaptans contained therein using the oxygen in the air, at a temperature of about 80 to about 220 degree C, in the presence of about 0.01 to about 10.0 mass percent of a water-soluble salt of copper, iron, nickel, or cobalt, on a fibrous carbonaceous material in the form of a woven fabric, felt, rope, or twisted strand, used as a heterogeneous catalyst. The fibrous carbonaceous material used in the process contains oxides of calcium, magnesium, copper, manganese, iron, zinc, and aluminum in an amount of up to about 0.03 mass percent.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/313,635 US5741415A (en) | 1994-09-27 | 1994-09-27 | Method for the demercaptanization of petroleum distillates |
| RU94039238A RU2076892C1 (en) | 1994-10-18 | 1994-10-18 | Method of demercaptanization of oil distillates |
| PCT/US1995/012339 WO1996009891A1 (en) | 1994-09-27 | 1995-09-26 | A method for the demercaptanization of petroleum distillates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX9702145A true MX9702145A (en) | 1997-06-28 |
Family
ID=26653803
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX9702145A MX9702145A (en) | 1994-09-27 | 1995-09-26 | A method for the demercaptanization of petroleum distillates. |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0783369A4 (en) |
| CN (1) | CN1071136C (en) |
| AU (1) | AU3686195A (en) |
| CA (1) | CA2199373A1 (en) |
| MX (1) | MX9702145A (en) |
| NO (1) | NO971379L (en) |
| WO (1) | WO1996009891A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1067709C (en) * | 1998-10-23 | 2001-06-27 | 中国石化广州石油化工总厂 | Process of demercaptaning for gasoline by catalyst cracking |
| US8016999B2 (en) | 2004-05-31 | 2011-09-13 | Agency For Science, Technology And Research | Process for removing sulfur from fuels |
| WO2005116169A1 (en) * | 2004-05-31 | 2005-12-08 | Agency For Science, Technology And Research | Novel process for removing sulfur from fuels |
| CN1320958C (en) * | 2005-05-30 | 2007-06-13 | 北京三聚环保新材料有限公司 | Double-effect catalyst and its production process |
| US9068128B2 (en) * | 2011-10-18 | 2015-06-30 | Baker Hughes Incorporated | Method for reducing hydrogen sulfide evolution from asphalt and heavy fuel oils |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL259485A (en) * | 1959-12-28 | |||
| US4028269A (en) * | 1975-08-21 | 1977-06-07 | Uop Inc. | Process for the preparation of a solid bed catalyst system |
| US4364843A (en) * | 1979-11-28 | 1982-12-21 | Uop Inc. | Catalytic composite, method of manufacture, and process for use |
| US4672047A (en) * | 1984-03-08 | 1987-06-09 | Travis Chandler | Mercaptan oxidation catalyst |
| FR2601263B1 (en) * | 1986-07-11 | 1988-11-25 | Total France | NEW CATALYTIC COMPOSITE PRODUCT FOR THE OXIDATION OF MERCAPTANS AND ITS USE FOR THE SOFTENING OF OIL CUTTINGS. |
| JPS63283750A (en) * | 1987-05-14 | 1988-11-21 | Asahi Chem Ind Co Ltd | Catalyst using carbon fibers as carrier |
| JPH05184940A (en) * | 1992-01-14 | 1993-07-27 | Nippon Steel Corp | Catalyst for removing nitrogen oxide, and method and apparatus therefor |
-
1995
- 1995-09-26 CA CA002199373A patent/CA2199373A1/en not_active Abandoned
- 1995-09-26 EP EP95934553A patent/EP0783369A4/en not_active Withdrawn
- 1995-09-26 AU AU36861/95A patent/AU3686195A/en not_active Abandoned
- 1995-09-26 CN CN95194720A patent/CN1071136C/en not_active Expired - Fee Related
- 1995-09-26 MX MX9702145A patent/MX9702145A/en not_active IP Right Cessation
- 1995-09-26 WO PCT/US1995/012339 patent/WO1996009891A1/en not_active Application Discontinuation
-
1997
- 1997-03-24 NO NO971379A patent/NO971379L/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| WO1996009891A1 (en) | 1996-04-04 |
| AU3686195A (en) | 1996-04-19 |
| NO971379D0 (en) | 1997-03-24 |
| CA2199373A1 (en) | 1996-04-04 |
| EP0783369A4 (en) | 1998-12-09 |
| CN1155853A (en) | 1997-07-30 |
| CN1071136C (en) | 2001-09-19 |
| EP0783369A1 (en) | 1997-07-16 |
| NO971379L (en) | 1997-03-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration | ||
| MM | Annulment or lapse due to non-payment of fees |