MX9307032A - Procedimiento, en fase de gas, para producir copolimeros de propileno y de etileno, y las peliculas de poliolefinas obtenidas de los mismos. - Google Patents

Procedimiento, en fase de gas, para producir copolimeros de propileno y de etileno, y las peliculas de poliolefinas obtenidas de los mismos.

Info

Publication number
MX9307032A
MX9307032A MX9307032A MX9307032A MX9307032A MX 9307032 A MX9307032 A MX 9307032A MX 9307032 A MX9307032 A MX 9307032A MX 9307032 A MX9307032 A MX 9307032A MX 9307032 A MX9307032 A MX 9307032A
Authority
MX
Mexico
Prior art keywords
procedure
gas phase
ethylene copolymers
films obtained
polyolefin films
Prior art date
Application number
MX9307032A
Other languages
English (en)
Inventor
Lisa K Johnson
Paul E Bowen
Thaddeus W Klimek
Michael B Edwards
Charles K Buehler
Original Assignee
Quantum Chem Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/975,485 external-priority patent/US5314746A/en
Application filed by Quantum Chem Corp filed Critical Quantum Chem Corp
Publication of MX9307032A publication Critical patent/MX9307032A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

La presente invención se refiere a un procedimiento mejorado, en fase de gas, para producir las poliolefinas termoplásticas (TPO) in situ o copolímeros de propileno y etileno en múltiples que usan catalizadores de Ti/Al de alta actividad. La mejora consiste en el desarrollo de un parámetro de control derivado de ocho regiones integrales del espectro de resonancia magnético nuclear (RMN) 13C del copolímero, que define los límites del parámetro de control para el procedimiento para el procedimiento, y operar este procedimiento para mantener parámetro dentro de los límites definidos. Esto se logra ajustando la cantidad del etileno alimentado a los reactores y ajustando otras variables del proceso, según sea requerido.
MX9307032A 1992-11-12 1993-11-11 Procedimiento, en fase de gas, para producir copolimeros de propileno y de etileno, y las peliculas de poliolefinas obtenidas de los mismos. MX9307032A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US97548792A 1992-11-12 1992-11-12
US97548892A 1992-11-12 1992-11-12
US07/975,485 US5314746A (en) 1992-11-12 1992-11-12 Soft, puncture- and tear-resistant polyolefin films

Publications (1)

Publication Number Publication Date
MX9307032A true MX9307032A (es) 1994-05-31

Family

ID=27420770

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9307032A MX9307032A (es) 1992-11-12 1993-11-11 Procedimiento, en fase de gas, para producir copolimeros de propileno y de etileno, y las peliculas de poliolefinas obtenidas de los mismos.

Country Status (8)

Country Link
EP (1) EP0597461B1 (es)
JP (2) JPH06211939A (es)
KR (1) KR100291885B1 (es)
AU (1) AU670826B2 (es)
CA (1) CA2102542A1 (es)
DE (1) DE69311062T2 (es)
MX (1) MX9307032A (es)
TW (1) TW249806B (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2114969T3 (es) * 1992-06-18 1998-06-16 Montell Technology Company Bv Procedimiento y aparato para la polimerizacion en fase gaseosa de olefinas.
GB9712663D0 (en) 1997-06-16 1997-08-20 Borealis As Process
DE19726796A1 (de) 1997-06-24 1999-01-07 Basf Ag Propylenpolymerisate
EP0991719B1 (en) 1997-06-24 2003-12-17 Borealis Technology Oy Process for the preparation of heterophasic propylene copolymer
DE19758124C1 (de) * 1997-12-30 1999-11-18 Borealis Ag Polypropylenrohr mit hoher Festigkeit
EP1186618A1 (en) 2000-09-08 2002-03-13 ATOFINA Research Controlled rheology polypropylene heterophasic copolymers
DE60106219T2 (de) * 2001-06-27 2006-03-09 Borealis Technology Oy Propylen-Copolymer mit zufälliger Comonomerverteilung und Verfahren zu seiner Herstellung
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
EP1312617A1 (en) * 2001-11-14 2003-05-21 ATOFINA Research Impact strength polypropylene
EP2432809B1 (en) * 2009-05-21 2015-01-21 Basell Poliolefine Italia S.r.l. Propylene polymer compositions
EP2264099A1 (en) * 2009-05-21 2010-12-22 Basell Poliolefine Italia S.R.L. Propylene polymer compositions
CN103282425A (zh) 2010-12-21 2013-09-04 巴塞尔聚烯烃股份有限公司 具有高弹性和透明度的聚丙烯组合物
RU2707101C1 (ru) * 2013-11-26 2019-11-22 У.Р. Грейс Энд Ко.-Конн Получение ударопрочных сополимеров и продуктов на основе пропилена
WO2015091839A1 (en) 2013-12-18 2015-06-25 Borealis Ag Bopp film with improved stiffness/toughness balance
CN109575171B (zh) * 2018-10-09 2022-09-09 中国石油化工股份有限公司 一种聚丙烯流延膜树脂的制备方法
EP3808809A1 (de) 2019-10-16 2021-04-21 Evonik Operations GmbH Amorphes poly-alpha-olefin enthaltendes polyolefingemenge

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2462449A1 (fr) * 1979-07-30 1981-02-13 Naphtachimie Sa Procede de fabrication de copolymeres de propylene et de butene-1, produits en resultant et leurs applications
JPS6045645B2 (ja) * 1980-10-09 1985-10-11 三井化学株式会社 オレフイン類の気相重合方法
DE3274455D1 (en) * 1981-08-22 1987-01-15 Showa Denko Kk Propylene-ethylene random copolymer, production process thereof, and film derived therefrom
FR2577558B1 (fr) * 1985-02-19 1987-03-06 Bp Chimie Sa Polymerisation en plusieurs etapes d'alpha-olefines en phase gazeuse
CA1340037C (en) * 1985-06-17 1998-09-08 Stanley Lustig Puncture resistant, heat-shrinkable films containing very low density polyethylene copolymer
DE3702038A1 (de) * 1987-01-24 1988-08-04 Basf Ag Verfahren zum herstellen von propylen-ethylen-polymerisaten
US5110870A (en) * 1989-01-06 1992-05-05 Mitsubishi Kasei Corporation Extensible film or sheet and process for producing the same

Also Published As

Publication number Publication date
DE69311062D1 (de) 1997-07-03
TW249806B (es) 1995-06-21
AU670826B2 (en) 1996-08-01
AU5056993A (en) 1994-05-26
KR940011487A (ko) 1994-06-21
DE69311062T2 (de) 1997-09-11
KR100291885B1 (ko) 2001-10-24
JPH06211939A (ja) 1994-08-02
EP0597461A3 (en) 1995-01-11
EP0597461A2 (en) 1994-05-18
JP2002088167A (ja) 2002-03-27
CA2102542A1 (en) 1994-05-13
EP0597461B1 (en) 1997-05-28

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FG Grant or registration
PD Change of proprietorship

Owner name: NOVOLEN TECHNOLOGY HOLDINGS C.V.

MM Annulment or lapse due to non-payment of fees