MX395158B - Proceso de polimerizacion en masa para preparacion de polidienos. - Google Patents

Proceso de polimerizacion en masa para preparacion de polidienos.

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Publication number
MX395158B
MX395158B MX2018015419A MX2018015419A MX395158B MX 395158 B MX395158 B MX 395158B MX 2018015419 A MX2018015419 A MX 2018015419A MX 2018015419 A MX2018015419 A MX 2018015419A MX 395158 B MX395158 B MX 395158B
Authority
MX
Mexico
Prior art keywords
comonomer
com
optionally
reaction mixture
diene monomer
Prior art date
Application number
MX2018015419A
Other languages
English (en)
Other versions
MX2018015419A (es
Inventor
Marcus Vater
Michael Bartke
Ulrich Wendler
Original Assignee
Fraunhofer Ges Forschung
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fraunhofer Ges Forschung filed Critical Fraunhofer Ges Forschung
Publication of MX2018015419A publication Critical patent/MX2018015419A/es
Publication of MX395158B publication Critical patent/MX395158B/es

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/02—Polymerisation in bulk
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/045—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated conjugated hydrocarbons other than butadiene or isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/20—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of antimony, bismuth, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00—Characteristics for processes of polymerization
    • C08F2400/02—Control or adjustment of polymerization parameters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)

Abstract

La presente invención se dirige a un proceso de polimerización en masa para la preparación de un polímero (P) que comprende los pasos de: (i) proporcionar por lo menos un monómero de dieno (DM) y opcionalmente por lo menos un comonómero (COM); (ii) poner en contacto por lo menos un monómero de dieno (DM) y opcionalmente por lo menos un comonómero (COM) con un sistema catalizador (CS) que forma una mezcla de reacción (RM); (iii) polimerizar la mezcla de reacción (RM) que comprende por lo menos un monómero de dieno (DM) y opcionalmente por lo menos un comonómero (COM) en por lo menos un recipiente de reactor (RV); (iv) aislar el polímero (P) obtenido de por lo menos un recipiente del reactor (RV); en donde la mezcla de reacción (RM) comprende solvente, diluyente y/o dispersante en una cantidad de = 10% en peso, con base en el peso de la mezcla de reacción (RM); y en donde la tasa de conversión del monómero dieno (DM) y opcionalmente el comonómero (COM) es =80%.
MX2018015419A 2016-06-30 2017-06-29 Proceso de polimerizacion en masa para preparacion de polidienos. MX395158B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16177220.7A EP3263606A1 (en) 2016-06-30 2016-06-30 Bulkpolymerisation process for the preparation of polydienes
PCT/EP2017/066196 WO2018002256A1 (en) 2016-06-30 2017-06-29 Bulkpolymerisation process for the preparation of polydienes

Publications (2)

Publication Number Publication Date
MX2018015419A MX2018015419A (es) 2019-04-11
MX395158B true MX395158B (es) 2025-03-25

Family

ID=56321808

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2018015419A MX395158B (es) 2016-06-30 2017-06-29 Proceso de polimerizacion en masa para preparacion de polidienos.

Country Status (15)

Country Link
US (1) US20190202944A1 (es)
EP (2) EP3263606A1 (es)
JP (1) JP2019519648A (es)
KR (1) KR102129218B1 (es)
CN (1) CN109476770A (es)
BR (1) BR112018076854A2 (es)
CA (1) CA3029327C (es)
ES (1) ES2802798T3 (es)
HU (1) HUE051643T2 (es)
MX (1) MX395158B (es)
PL (1) PL3478726T3 (es)
RU (1) RU2714204C1 (es)
SA (1) SA518400753B1 (es)
SG (1) SG11201811301RA (es)
WO (1) WO2018002256A1 (es)

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3770710A (en) * 1971-08-23 1973-11-06 Firestone Tire & Rubber Co Bulk polymerization of diolefins
JPS55110107A (en) * 1979-02-19 1980-08-25 Maruzen Sekiyu Kagaku Kk Bulk alternating copolymerization of propylene and butadiene
JPS5730712A (en) * 1980-07-30 1982-02-19 Japan Synthetic Rubber Co Ltd Impact-resistant resin
IN173082B (es) * 1986-02-19 1994-02-05 Goodyear Tire & Rubber
JPH02308834A (ja) * 1989-05-23 1990-12-21 Bridgestone Corp 空気入りタイヤ
US5171800A (en) 1989-06-28 1992-12-15 Basf Aktiengesellschaft Anionic polymerization with bifunctional initiators
DE4030400A1 (de) 1990-09-26 1992-04-02 Basf Ag Lebende polymere, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von telechele
JPH0852334A (ja) * 1994-08-10 1996-02-27 Hitachi Ltd 高粘度液の連続撹拌装置及び連続塊状重合方法
JPH0871395A (ja) * 1994-08-31 1996-03-19 Sumitomo Heavy Ind Ltd 横型２軸を備えた高粘度液連続処理装置の使用方法
WO1997033923A1 (fr) 1996-03-14 1997-09-18 Asahi Kasei Kogyo Kabushiki Kaisha Procede de preparation de polymeres vinyliques, initiateur de polymerisation de monomeres vinyliques et composition de resine styrenique
JPH10139808A (ja) * 1996-11-08 1998-05-26 Ube Ind Ltd 共役ジエン重合体の製造方法
US7094849B2 (en) * 2003-12-15 2006-08-22 Bridgestone Corporation Bulk polymerization process for producing polydienes
ZA200711158B (en) * 2006-12-28 2009-03-25 Bridgestone Corp A method for producing functionalized cis-1,4-polydienes having high cis-1,4-linkage content and high functionality
US7741418B2 (en) * 2007-12-31 2010-06-22 Bridgestone Corporation Process for producing polydienes
US7807763B2 (en) * 2008-04-07 2010-10-05 Bridgestone Corporation Method for bulk polymerization
CN101608003B (zh) * 2009-07-27 2012-05-16 中国科学院长春应用化学研究所 本体聚合制备中低分子量液体聚异戊二烯橡胶的方法
FR2992649B1 (fr) * 2012-07-02 2015-06-19 Michelin & Cie Procede de synthese en continu d'un elastomere dienique

Also Published As

Publication number Publication date
JP2019519648A (ja) 2019-07-11
EP3263606A1 (en) 2018-01-03
CN109476770A (zh) 2019-03-15
KR102129218B1 (ko) 2020-07-01
CA3029327A1 (en) 2018-01-04
RU2714204C1 (ru) 2020-02-13
SA518400753B1 (ar) 2022-07-05
ES2802798T3 (es) 2021-01-21
HUE051643T2 (hu) 2021-03-01
EP3478726B1 (en) 2020-05-27
US20190202944A1 (en) 2019-07-04
BR112018076854A2 (pt) 2019-04-02
SG11201811301RA (en) 2019-01-30
EP3478726A1 (en) 2019-05-08
MX2018015419A (es) 2019-04-11
WO2018002256A1 (en) 2018-01-04
CA3029327C (en) 2021-01-19
PL3478726T3 (pl) 2020-11-02
KR20190017971A (ko) 2019-02-20

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