MX390822B - Proceso para preparar compuestos fenolicos de acido etilendiamina diacetico. - Google Patents
Proceso para preparar compuestos fenolicos de acido etilendiamina diacetico.Info
- Publication number
- MX390822B MX390822B MX2017016691A MX2017016691A MX390822B MX 390822 B MX390822 B MX 390822B MX 2017016691 A MX2017016691 A MX 2017016691A MX 2017016691 A MX2017016691 A MX 2017016691A MX 390822 B MX390822 B MX 390822B
- Authority
- MX
- Mexico
- Prior art keywords
- diacetic acid
- reaction mixture
- phenolic compounds
- ethylenediamine
- ethylenediamine diacetic
- Prior art date
Links
- IFQUWYZCAGRUJN-UHFFFAOYSA-N ethylenediaminediacetic acid Chemical compound OC(=O)CNCCNCC(O)=O IFQUWYZCAGRUJN-UHFFFAOYSA-N 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title 1
- 150000002989 phenols Chemical class 0.000 title 1
- 239000011541 reaction mixture Substances 0.000 abstract 4
- GRUVVLWKPGIYEG-UHFFFAOYSA-N 2-[2-[carboxymethyl-[(2-hydroxyphenyl)methyl]amino]ethyl-[(2-hydroxyphenyl)methyl]amino]acetic acid Chemical compound C=1C=CC=C(O)C=1CN(CC(=O)O)CCN(CC(O)=O)CC1=CC=CC=C1O GRUVVLWKPGIYEG-UHFFFAOYSA-N 0.000 abstract 2
- 229910001413 alkali metal ion Inorganic materials 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 125000006290 2-hydroxybenzyl group Chemical group [H]OC1=C(C([H])=C([H])C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 229910001414 potassium ion Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/14—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing already amino and carboxyl groups or derivatives thereof
- C07C227/18—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing already amino and carboxyl groups or derivatives thereof by reactions involving amino or carboxyl groups, e.g. hydrolysis of esters or amides, by formation of halides, salts or esters
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/14—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing already amino and carboxyl groups or derivatives thereof
- C07C227/16—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing already amino and carboxyl groups or derivatives thereof by reactions not involving the amino or carboxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente invención se refiere a un proceso para preparar ácido N,N'-di(2-hidroxibencil)etilendiamina-N,N'-diacético y sus sales (HBED) que comprende una reacción entre formaldehído, ácido etilendiamina diacético o una sal del mismo (EDDA) y fenol, en donde la mezcla de reacción contiene de 0.2 a 1.1 equivalentes molares de iones de metal alcalino sobre la base de la cantidad molar de EDDA y la mezcla de reacción se procesa mediante un paso en el cual por lo menos parte de los compuestos orgánicos distintos del HBED formado se eliminan de la mezcla de reacción y opcionalmente se reciclan, durante cuyo paso por lo menos 50% y hasta e incluyendo 100% de los iones de metal alcalino en la mezcla de reacción son iones de potasio, para productos obtenibles mediante dicho proceso y su uso.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15173800 | 2015-06-25 | ||
| PCT/EP2016/064501 WO2016207266A1 (en) | 2015-06-25 | 2016-06-23 | Process to prepare phenolic ethylenediamine diacetic acid compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2017016691A MX2017016691A (es) | 2018-03-09 |
| MX390822B true MX390822B (es) | 2025-03-21 |
Family
ID=53488254
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2017016691A MX390822B (es) | 2015-06-25 | 2016-06-23 | Proceso para preparar compuestos fenolicos de acido etilendiamina diacetico. |
| MX2022003400A MX2022003400A (es) | 2015-06-25 | 2017-12-18 | Proceso para preparar compuestos fenolicos de acido etilendiamina diacetico. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2022003400A MX2022003400A (es) | 2015-06-25 | 2017-12-18 | Proceso para preparar compuestos fenolicos de acido etilendiamina diacetico. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10472320B2 (es) |
| EP (1) | EP3313813B1 (es) |
| CN (1) | CN107743480B (es) |
| CA (1) | CA2989973C (es) |
| ES (1) | ES2733466T3 (es) |
| MX (2) | MX390822B (es) |
| PL (1) | PL3313813T3 (es) |
| TR (1) | TR201909965T4 (es) |
| WO (1) | WO2016207266A1 (es) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10093612B2 (en) | 2015-06-25 | 2018-10-09 | Akzo Nobel Chemicals International B.V. | Process to prepare phenolic ethylenediamine diacetic acid compounds |
| EP3848349B1 (en) | 2020-12-01 | 2023-03-15 | Przedsiebiorstwo Produkcyjno-Consultingowe ADOB Sp. z o.o. | A process for the preparation of salts of n,n'-disubstituted ethylenediamine-n,n'-diacetic acid derivatives and their use |
| US12180328B2 (en) | 2021-05-04 | 2024-12-31 | Sachem, Inc. | Strong binding metal-chelating resins |
| TW202308755A (zh) | 2021-05-04 | 2023-03-01 | 美商沙坎公司 | 使用大環分子的強結合金屬螯合樹脂 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2967196A (en) | 1955-12-06 | 1961-01-03 | Geigy Chem Corp | Ethylenediaminediacetic acids containing phenolic groups |
| US3632637A (en) * | 1968-02-13 | 1972-01-04 | Arthur E Martell | Hydroxyaryl-containing aminocarboxylic chelating agents |
| US4338460A (en) * | 1975-11-11 | 1982-07-06 | W. R. Grace & Co. | Process for preparing chelating agents |
| EP0093536B1 (en) | 1982-04-29 | 1986-10-08 | EASTMAN KODAK COMPANY (a New Jersey corporation) | Stabilised photographic color developer compositions and processes |
| US5342604A (en) | 1988-10-31 | 1994-08-30 | The Dow Chemical Company | Complexes possessing ortho ligating functionality |
| US5776894A (en) | 1988-12-05 | 1998-07-07 | Novartis Ag | Chelated somatostatin peptides and complexes thereof, pharmaceutical compositions containing them and their use in treating tumors |
| DE69922787T2 (de) | 1998-02-04 | 2005-12-15 | University of Florida Research Foundation, Inc., Gainesville | N,n'-bis(2-hydroxybenzyl)ethylendiamin-n,n'-diessigsäure und natriumsalze davon zur eisenchelatierungstherapie |
| CA2394524A1 (en) | 1999-12-21 | 2001-06-28 | Raymond J. Bergeron | N,n'-bis(2-hydroxybenzyl)ethylenediamine-n,n'-diacetic acid in iron chelating therapy |
| US20040121273A1 (en) | 2002-12-03 | 2004-06-24 | Hajime Nakagawa | Photothermographic material |
| US20070099132A1 (en) | 2000-09-18 | 2007-05-03 | Hajime Nakagawa | Photothermographic material |
| JP4084645B2 (ja) | 2002-12-03 | 2008-04-30 | 富士フイルム株式会社 | 熱現像感光材料 |
| US7226728B2 (en) | 2004-09-24 | 2007-06-05 | Fujifilm Corporation | Photothermographic material |
| JP2007229988A (ja) | 2006-02-28 | 2007-09-13 | Fujifilm Corp | 感熱転写受像シートおよびその製造方法 |
| JP2007229985A (ja) | 2006-02-28 | 2007-09-13 | Fujifilm Corp | 感熱転写受像シート |
| JP4490382B2 (ja) | 2006-02-28 | 2010-06-23 | 富士フイルム株式会社 | 感熱転写受像シートおよびその製造方法 |
| US20080248951A1 (en) | 2007-03-30 | 2008-10-09 | Fujifilm Corporation | Coating composition for thermal transfer image-receiving sheet, and thermal transfer image-receiving sheet |
| JP4878327B2 (ja) | 2007-03-30 | 2012-02-15 | 富士フイルム株式会社 | 感熱転写受像シートおよびその製造方法 |
| EP2039679B1 (en) | 2007-09-20 | 2015-08-12 | Przedsiebiorstwo Produkcyjno-Consultingowe ADOB sp. z o.o. sp. k. | A process for the preparation of N,N'-bis(2-hydroxybenzyl)ethylenediamine-N,N'-diacetic acid and its derivatives |
| DK2289869T3 (da) | 2009-07-17 | 2012-09-17 | Przed Prod Consultingowe Adob Sp Z O O Sp K | Fremgangsmåde til fremstilling af Fe(III)-chelater af N,N´-di(2-hydroxybenzyl)-ethylendiamin-N,N´-dieddikesyre og derivater deraf |
| GB201117187D0 (en) | 2011-10-06 | 2011-11-16 | Fujifilm Imaging Colorants Ltd | A process for preparing a dispersion, dispersion, use and method |
| US10093612B2 (en) * | 2015-06-25 | 2018-10-09 | Akzo Nobel Chemicals International B.V. | Process to prepare phenolic ethylenediamine diacetic acid compounds |
-
2016
- 2016-06-23 WO PCT/EP2016/064501 patent/WO2016207266A1/en not_active Ceased
- 2016-06-23 CA CA2989973A patent/CA2989973C/en active Active
- 2016-06-23 MX MX2017016691A patent/MX390822B/es unknown
- 2016-06-23 TR TR2019/09965T patent/TR201909965T4/tr unknown
- 2016-06-23 ES ES16731168T patent/ES2733466T3/es active Active
- 2016-06-23 CN CN201680033895.6A patent/CN107743480B/zh active Active
- 2016-06-23 PL PL16731168T patent/PL3313813T3/pl unknown
- 2016-06-23 EP EP16731168.7A patent/EP3313813B1/en active Active
- 2016-06-23 US US15/736,372 patent/US10472320B2/en active Active
-
2017
- 2017-12-18 MX MX2022003400A patent/MX2022003400A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US10472320B2 (en) | 2019-11-12 |
| CN107743480B (zh) | 2020-07-17 |
| US20180186727A1 (en) | 2018-07-05 |
| MX2022003400A (es) | 2022-04-18 |
| CN107743480A (zh) | 2018-02-27 |
| EP3313813B1 (en) | 2019-04-10 |
| MX2017016691A (es) | 2018-03-09 |
| EP3313813A1 (en) | 2018-05-02 |
| TR201909965T4 (tr) | 2019-07-22 |
| WO2016207266A1 (en) | 2016-12-29 |
| CA2989973A1 (en) | 2016-12-29 |
| PL3313813T3 (pl) | 2019-10-31 |
| ES2733466T3 (es) | 2019-11-29 |
| CA2989973C (en) | 2023-07-18 |
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